NL1006441C2 - Werkwijze voor het ontzwavelen en verbeteren van de kwaliteit van koolwaterstoffen. - Google Patents

Werkwijze voor het ontzwavelen en verbeteren van de kwaliteit van koolwaterstoffen. Download PDF

Info

Publication number: NL1006441C2
Authority: NL; Netherlands
Prior art keywords: hydrocarbon; acid; lime; catalyst; compounds
Prior art date: 1996-07-03

Application number

NL1006441A

Other languages

English (en)

Dutch (nl)

Other versions

NL1006441A1 (nl

Inventor

John Joseph Darcy

Original Assignee

Interglobal Desulfurization Sy

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-07-03

Filing date

1997-07-01

Publication date

2000-02-08

1997-07-01 Application filed by Interglobal Desulfurization Sy filed Critical Interglobal Desulfurization Sy

1998-01-07 Publication of NL1006441A1 publication Critical patent/NL1006441A1/xx

2000-02-08 Application granted granted Critical

2000-02-08 Publication of NL1006441C2 publication Critical patent/NL1006441C2/nl

Links

238000000034 method Methods 0.000 title claims description 85
150000002430 hydrocarbons Chemical class 0.000 title claims description 74
229930195733 hydrocarbon Natural products 0.000 title claims description 66
230000003009 desulfurizing effect Effects 0.000 title description 2
239000004215 Carbon black (E152) Substances 0.000 claims description 56
239000003054 catalyst Substances 0.000 claims description 41
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 39
235000008733 Citrus aurantifolia Nutrition 0.000 claims description 35
235000011941 Tilia x europaea Nutrition 0.000 claims description 35
239000004571 lime Substances 0.000 claims description 35
150000003464 sulfur compounds Chemical class 0.000 claims description 27
239000003345 natural gas Substances 0.000 claims description 18
238000010438 heat treatment Methods 0.000 claims description 15
ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 13
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
238000009835 boiling Methods 0.000 claims description 11
HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical class CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 claims description 10
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 10
235000019738 Limestone Nutrition 0.000 claims description 9
239000003377 acid catalyst Substances 0.000 claims description 9
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 9
239000000292 calcium oxide Substances 0.000 claims description 9
239000006028 limestone Substances 0.000 claims description 9
238000012546 transfer Methods 0.000 claims description 9
238000002156 mixing Methods 0.000 claims description 7
YLUIKWVQCKSMCF-UHFFFAOYSA-N calcium;magnesium;oxygen(2-) Chemical compound [O-2].[O-2].[Mg+2].[Ca+2] YLUIKWVQCKSMCF-UHFFFAOYSA-N 0.000 claims description 6
239000000203 mixture Substances 0.000 claims description 6
229910000019 calcium carbonate Inorganic materials 0.000 claims description 5
235000010216 calcium carbonate Nutrition 0.000 claims description 5
150000001991 dicarboxylic acids Chemical class 0.000 claims description 5
239000000395 magnesium oxide Substances 0.000 claims description 5
KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 5
235000011037 adipic acid Nutrition 0.000 claims description 4
229960000250 adipic acid Drugs 0.000 claims description 4
TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 claims description 4
TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 claims description 4
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 2
JFCQEDHGNNZCLN-UHFFFAOYSA-N glutaric acid Chemical compound OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims 4
BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 claims 2
WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 claims 2
CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims 2
229960005137 succinic acid Drugs 0.000 claims 2
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229920000305 Nylon 6,10 Polymers 0.000 claims 1
229960002255 azelaic acid Drugs 0.000 claims 1
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239000011593 sulfur Substances 0.000 description 29
229910052717 sulfur Inorganic materials 0.000 description 29
238000006243 chemical reaction Methods 0.000 description 28
239000003921 oil Substances 0.000 description 26
239000000047 product Substances 0.000 description 23
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239000010779 crude oil Substances 0.000 description 12
229910000037 hydrogen sulfide Inorganic materials 0.000 description 12
239000004615 ingredient Substances 0.000 description 12
238000011282 treatment Methods 0.000 description 12
239000003208 petroleum Substances 0.000 description 11
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XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 7
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239000002253 acid Substances 0.000 description 7
150000001875 compounds Chemical class 0.000 description 7
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239000012808 vapor phase Substances 0.000 description 7
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KVNYFPKFSJIPBJ-UHFFFAOYSA-N 1,2-diethylbenzene Chemical compound CCC1=CC=CC=C1CC KVNYFPKFSJIPBJ-UHFFFAOYSA-N 0.000 description 6
LETYIFNDQBJGPJ-UHFFFAOYSA-N 1-ethyl-1-methylcyclopentane Chemical compound CCC1(C)CCCC1 LETYIFNDQBJGPJ-UHFFFAOYSA-N 0.000 description 6
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CYISMTMRBPPERU-UHFFFAOYSA-N 1-ethyl-4-methylcyclohexane Chemical compound CCC1CCC(C)CC1 CYISMTMRBPPERU-UHFFFAOYSA-N 0.000 description 3
ADQJFBQXLAAVQA-UHFFFAOYSA-N 1-methyl-2-propylcyclopentane Chemical compound CCCC1CCCC1C ADQJFBQXLAAVQA-UHFFFAOYSA-N 0.000 description 3
WZCQBAUYZLJHRE-UHFFFAOYSA-N 2,3-dihydro-1H-indene Chemical compound C1=CC=C2CCCC2=C1.C1=CC=C2CCCC2=C1 WZCQBAUYZLJHRE-UHFFFAOYSA-N 0.000 description 3
AEXMKKGTQYQZCS-UHFFFAOYSA-N 3,3-dimethylpentane Chemical compound CCC(C)(C)CC AEXMKKGTQYQZCS-UHFFFAOYSA-N 0.000 description 3
IALRSQMWHFKJJA-UHFFFAOYSA-N 4-Methylnonane Natural products CCCCCC(C)CCC IALRSQMWHFKJJA-UHFFFAOYSA-N 0.000 description 3
XMROPFQWHHUFFS-UHFFFAOYSA-N 4-ethylheptane Chemical compound CCCC(CC)CCC XMROPFQWHHUFFS-UHFFFAOYSA-N 0.000 description 3
ZVNPWFOVUDMGRP-UHFFFAOYSA-N 4-methylaminophenol sulfate Chemical compound OS(O)(=O)=O.CNC1=CC=C(O)C=C1.CNC1=CC=C(O)C=C1 ZVNPWFOVUDMGRP-UHFFFAOYSA-N 0.000 description 3
TYSIILFJZXHVPU-UHFFFAOYSA-N 5-methylnonane Chemical compound CCCCC(C)CCCC TYSIILFJZXHVPU-UHFFFAOYSA-N 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
IALRSQMWHFKJJA-JTQLQIEISA-N Nonane, 4-methyl- Chemical compound CCCCC[C@@H](C)CCC IALRSQMWHFKJJA-JTQLQIEISA-N 0.000 description 3
229910000831 Steel Inorganic materials 0.000 description 3
125000003118 aryl group Chemical group 0.000 description 3
239000010426 asphalt Substances 0.000 description 3
ZAGHKONXGGSVDV-UHFFFAOYSA-N butylcyclopentane Chemical compound CCCCC1CCCC1 ZAGHKONXGGSVDV-UHFFFAOYSA-N 0.000 description 3
KVZJLSYJROEPSQ-OCAPTIKFSA-N cis-1,2-dimethylcyclohexane Chemical compound C[C@H]1CCCC[C@H]1C KVZJLSYJROEPSQ-OCAPTIKFSA-N 0.000 description 3
DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 3
235000005911 diet Nutrition 0.000 description 3
239000000446 fuel Substances 0.000 description 3
239000003502 gasoline Substances 0.000 description 3
DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 3
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239000001282 iso-butane Substances 0.000 description 3
KXUHSQYYJYAXGZ-UHFFFAOYSA-N isobutylbenzene Chemical compound CC(C)CC1=CC=CC=C1 KXUHSQYYJYAXGZ-UHFFFAOYSA-N 0.000 description 3
BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 3
239000012188 paraffin wax Substances 0.000 description 3
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 3
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
ZJMWRROPUADPEA-UHFFFAOYSA-N sec-butylbenzene Chemical compound CCC(C)C1=CC=CC=C1 ZJMWRROPUADPEA-UHFFFAOYSA-N 0.000 description 3
239000007921 spray Substances 0.000 description 3
239000010959 steel Substances 0.000 description 3
KVZJLSYJROEPSQ-HTQZYQBOSA-N trans-1,2-dimethylcyclohexane Chemical compound C[C@@H]1CCCC[C@H]1C KVZJLSYJROEPSQ-HTQZYQBOSA-N 0.000 description 3
QRMPKOFEUHIBNM-ZKCHVHJHSA-N trans-1,4-dimethylcyclohexane Chemical compound C[C@H]1CC[C@H](C)CC1 QRMPKOFEUHIBNM-ZKCHVHJHSA-N 0.000 description 3
MEBONNVPKOBPEA-UHFFFAOYSA-N trimethyl cyclohexane Natural products CC1CCCCC1(C)C MEBONNVPKOBPEA-UHFFFAOYSA-N 0.000 description 3
WGECXQBGLLYSFP-UHFFFAOYSA-N (+-)-2,3-dimethyl-pentane Natural products CCC(C)C(C)C WGECXQBGLLYSFP-UHFFFAOYSA-N 0.000 description 2
WINCSBAYCULVDU-UHFFFAOYSA-N 1,1,2-trimethylcyclopentane Chemical compound CC1CCCC1(C)C WINCSBAYCULVDU-UHFFFAOYSA-N 0.000 description 2
QWHNJUXXYKPLQM-UHFFFAOYSA-N 1,1-dimethylcyclopentane Chemical compound CC1(C)CCCC1 QWHNJUXXYKPLQM-UHFFFAOYSA-N 0.000 description 2
AUHZEENZYGFFBQ-UHFFFAOYSA-N 1,3,5-trimethylbenzene Chemical compound CC1=CC(C)=CC(C)=C1 AUHZEENZYGFFBQ-UHFFFAOYSA-N 0.000 description 2
YPJRYQGOKHKNKZ-UHFFFAOYSA-N 1-ethyl-1-methylcyclohexane Chemical compound CCC1(C)CCCCC1 YPJRYQGOKHKNKZ-UHFFFAOYSA-N 0.000 description 2
QUBBAXISAHIDNM-UHFFFAOYSA-N 1-ethyl-2,3-dimethylbenzene Chemical compound CCC1=CC=CC(C)=C1C QUBBAXISAHIDNM-UHFFFAOYSA-N 0.000 description 2
RLPGDEORIPLBNF-UHFFFAOYSA-N 2,3,4-trimethylpentane Chemical compound CC(C)C(C)C(C)C RLPGDEORIPLBNF-UHFFFAOYSA-N 0.000 description 2
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
CHIKRULMSSADAF-UHFFFAOYSA-N 2-ethyl-1,3-dimethylbenzene Chemical compound CCC1=C(C)C=CC=C1C CHIKRULMSSADAF-UHFFFAOYSA-N 0.000 description 2
KUMXLFIBWFCMOJ-UHFFFAOYSA-N 3,3-dimethylhexane Chemical compound CCCC(C)(C)CC KUMXLFIBWFCMOJ-UHFFFAOYSA-N 0.000 description 2
PSVQKOKKLWHNRP-UHFFFAOYSA-N 3-ethylheptane Chemical compound CCCCC(CC)CC PSVQKOKKLWHNRP-UHFFFAOYSA-N 0.000 description 2
LNNSODHYZXCEJP-UHFFFAOYSA-N 4-methyl-2,3-dihydro-1h-indene Chemical compound CC1=CC=CC2=C1CCC2 LNNSODHYZXCEJP-UHFFFAOYSA-N 0.000 description 2
RFXBCGVZEJEYGG-UHFFFAOYSA-N 5-methyl-2,3-dihydro-1h-indene Chemical compound CC1=CC=C2CCCC2=C1 RFXBCGVZEJEYGG-UHFFFAOYSA-N 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical group SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 2
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
239000001361 adipic acid Substances 0.000 description 2
150000001334 alicyclic compounds Chemical class 0.000 description 2
239000008346 aqueous phase Substances 0.000 description 2
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
229910052791 calcium Inorganic materials 0.000 description 2
OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
JGIATAMCQXIDNZ-UHFFFAOYSA-N calcium sulfide Chemical compound [Ca]=S JGIATAMCQXIDNZ-UHFFFAOYSA-N 0.000 description 2
238000005260 corrosion Methods 0.000 description 2
230000007797 corrosion Effects 0.000 description 2
150000001924 cycloalkanes Chemical class 0.000 description 2
JBDSSBMEKXHSJF-UHFFFAOYSA-N cyclopentanecarboxylic acid Chemical compound OC(=O)C1CCCC1 JBDSSBMEKXHSJF-UHFFFAOYSA-N 0.000 description 2
238000006356 dehydrogenation reaction Methods 0.000 description 2
230000037213 diet Effects 0.000 description 2
ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
150000002019 disulfides Chemical class 0.000 description 2
210000002683 foot Anatomy 0.000 description 2
239000000295 fuel oil Substances 0.000 description 2
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
239000010687 lubricating oil Substances 0.000 description 2
239000011777 magnesium Substances 0.000 description 2
ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 2
238000012423 maintenance Methods 0.000 description 2
229910001092 metal group alloy Inorganic materials 0.000 description 2
CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 2
125000005608 naphthenic acid group Chemical group 0.000 description 2
239000012071 phase Substances 0.000 description 2
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
229910000028 potassium bicarbonate Inorganic materials 0.000 description 2
230000001172 regenerating effect Effects 0.000 description 2
239000002002 slurry Substances 0.000 description 2
235000017557 sodium bicarbonate Nutrition 0.000 description 2
229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
229910000029 sodium carbonate Inorganic materials 0.000 description 2
235000017550 sodium carbonate Nutrition 0.000 description 2
KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 2
BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical compound CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 description 2
239000001993 wax Substances 0.000 description 2
YGARNADKFWBJEX-UHFFFAOYSA-N 1,2,3,4-tetramethylbenzene;1,2,3,5-tetramethylbenzene Chemical compound CC1=CC(C)=C(C)C(C)=C1.CC1=CC=C(C)C(C)=C1C YGARNADKFWBJEX-UHFFFAOYSA-N 0.000 description 1
REHQLKUNRPCYEW-UHFFFAOYSA-N 1-methylcyclohexane-1-carboxylic acid Chemical compound OC(=O)C1(C)CCCCC1 REHQLKUNRPCYEW-UHFFFAOYSA-N 0.000 description 1
239000005711 Benzoic acid Substances 0.000 description 1
229910000975 Carbon steel Inorganic materials 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
235000003392 Curcuma domestica Nutrition 0.000 description 1
244000008991 Curcuma longa Species 0.000 description 1
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
230000006978 adaptation Effects 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
239000007900 aqueous suspension Substances 0.000 description 1
238000005899 aromatization reaction Methods 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
238000010923 batch production Methods 0.000 description 1
235000010233 benzoic acid Nutrition 0.000 description 1
239000001273 butane Substances 0.000 description 1
NKWPZUCBCARRDP-UHFFFAOYSA-L calcium bicarbonate Chemical compound [Ca+2].OC([O-])=O.OC([O-])=O NKWPZUCBCARRDP-UHFFFAOYSA-L 0.000 description 1
229910000020 calcium bicarbonate Inorganic materials 0.000 description 1
229940043430 calcium compound Drugs 0.000 description 1
150000001674 calcium compounds Chemical class 0.000 description 1
GBAOBIBJACZTNA-UHFFFAOYSA-L calcium sulfite Chemical compound [Ca+2].[O-]S([O-])=O GBAOBIBJACZTNA-UHFFFAOYSA-L 0.000 description 1
235000010261 calcium sulphite Nutrition 0.000 description 1
229910002091 carbon monoxide Inorganic materials 0.000 description 1
239000010962 carbon steel Substances 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
238000010276 construction Methods 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
238000010924 continuous production Methods 0.000 description 1
235000003373 curcuma longa Nutrition 0.000 description 1
GJBRTCPWCKRSTQ-UHFFFAOYSA-N decanedioic acid Chemical compound OC(=O)CCCCCCCCC(O)=O.OC(=O)CCCCCCCCC(O)=O GJBRTCPWCKRSTQ-UHFFFAOYSA-N 0.000 description 1
239000002283 diesel fuel Substances 0.000 description 1
230000000378 dietary effect Effects 0.000 description 1
LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 1
229940043276 diisopropanolamine Drugs 0.000 description 1
238000004821 distillation Methods 0.000 description 1
239000010459 dolomite Substances 0.000 description 1
229910000514 dolomite Inorganic materials 0.000 description 1
238000003912 environmental pollution Methods 0.000 description 1
235000013305 food Nutrition 0.000 description 1
238000009472 formulation Methods 0.000 description 1
239000003254 gasoline additive Substances 0.000 description 1
239000010440 gypsum Substances 0.000 description 1
229910052602 gypsum Inorganic materials 0.000 description 1
239000001307 helium Substances 0.000 description 1
229910052734 helium Inorganic materials 0.000 description 1
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
YCOZIPAWZNQLMR-UHFFFAOYSA-N heptane - octane Natural products CCCCCCCCCCCCCCC YCOZIPAWZNQLMR-UHFFFAOYSA-N 0.000 description 1
XEUHNWODXVYLFD-UHFFFAOYSA-N heptanedioic acid Chemical compound OC(=O)CCCCCC(O)=O.OC(=O)CCCCCC(O)=O XEUHNWODXVYLFD-UHFFFAOYSA-N 0.000 description 1
YVSCCMNRWFOKDU-UHFFFAOYSA-N hexanedioic acid Chemical compound OC(=O)CCCCC(O)=O.OC(=O)CCCCC(O)=O YVSCCMNRWFOKDU-UHFFFAOYSA-N 0.000 description 1
239000012535 impurity Substances 0.000 description 1
239000003350 kerosene Substances 0.000 description 1
238000003754 machining Methods 0.000 description 1
QWDJLDTYWNBUKE-UHFFFAOYSA-L magnesium bicarbonate Chemical compound [Mg+2].OC([O-])=O.OC([O-])=O QWDJLDTYWNBUKE-UHFFFAOYSA-L 0.000 description 1
229910000022 magnesium bicarbonate Inorganic materials 0.000 description 1
239000002370 magnesium bicarbonate Substances 0.000 description 1
235000014824 magnesium bicarbonate Nutrition 0.000 description 1
239000001095 magnesium carbonate Substances 0.000 description 1
229910000021 magnesium carbonate Inorganic materials 0.000 description 1
150000002681 magnesium compounds Chemical class 0.000 description 1
VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
239000000347 magnesium hydroxide Substances 0.000 description 1
229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
150000002790 naphthalenes Chemical class 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
WPBWJEYRHXACLR-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O.OC(=O)CCCCCCCC(O)=O WPBWJEYRHXACLR-UHFFFAOYSA-N 0.000 description 1
231100000252 nontoxic Toxicity 0.000 description 1
230000003000 nontoxic effect Effects 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
YKEKYBOBVREARV-UHFFFAOYSA-N pentanedioic acid Chemical compound OC(=O)CCCC(O)=O.OC(=O)CCCC(O)=O YKEKYBOBVREARV-UHFFFAOYSA-N 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
235000015497 potassium bicarbonate Nutrition 0.000 description 1
239000011736 potassium bicarbonate Substances 0.000 description 1
229910000027 potassium carbonate Inorganic materials 0.000 description 1
235000015320 potassium carbonate Nutrition 0.000 description 1
150000003112 potassium compounds Chemical class 0.000 description 1
TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 1
229910001950 potassium oxide Inorganic materials 0.000 description 1
238000004445 quantitative analysis Methods 0.000 description 1
238000011084 recovery Methods 0.000 description 1
238000002407 reforming Methods 0.000 description 1
238000007363 ring formation reaction Methods 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
229910001948 sodium oxide Inorganic materials 0.000 description 1
239000002689 soil Substances 0.000 description 1
238000005507 spraying Methods 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000007858 starting material Substances 0.000 description 1
230000005654 stationary process Effects 0.000 description 1
150000004763 sulfides Chemical class 0.000 description 1
HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
229930192474 thiophene Natural products 0.000 description 1
150000003577 thiophenes Chemical class 0.000 description 1
210000003371 toe Anatomy 0.000 description 1
235000013976 turmeric Nutrition 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G19/00—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment
- C10G19/02—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment with aqueous alkaline solutions

Landscapes

Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

NL1006441A 1996-07-03 1997-07-01 Werkwijze voor het ontzwavelen en verbeteren van de kwaliteit van koolwaterstoffen. NL1006441C2 (nl)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US08/675,583 US5858212A (en)	1996-07-03	1996-07-03	Desulfurization and hydrocarbon quality enhancement process
US67558396		1996-07-03

Publications (2)

Publication Number	Publication Date
NL1006441A1 NL1006441A1 (nl)	1998-01-07
NL1006441C2 true NL1006441C2 (nl)	2000-02-08

Family

ID=24711126

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NL1006441A NL1006441C2 (nl)	1996-07-03	1997-07-01	Werkwijze voor het ontzwavelen en verbeteren van de kwaliteit van koolwaterstoffen.

Country Status (13)

Country	Link
US (1)	US5858212A (fr)
AR (1)	AR014616A1 (fr)
AU (1)	AU3595697A (fr)
CO (1)	CO4870722A1 (fr)
HR (1)	HRP970360A2 (fr)
ID (1)	ID18744A (fr)
JO (1)	JO1973B1 (fr)
MA (1)	MA24347A1 (fr)
NL (1)	NL1006441C2 (fr)
PA (1)	PA8433501A1 (fr)
PE (1)	PE18199A1 (fr)
WO (1)	WO1998000478A1 (fr)
ZA (1)	ZA975855B (fr)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
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US5985137A (en) *	1998-02-26	1999-11-16	Unipure Corporation	Process to upgrade crude oils by destruction of naphthenic acids, removal of sulfur and removal of salts
AU4406799A (en)	1998-05-30	1999-12-20	Kansas State University Research Foundation	Porous pellet adsorbents fabricated from nanocrystals
US6656877B2 (en) *	2000-05-30	2003-12-02	Conocophillips Company	Desulfurization and sorbents for same
US6702945B2 (en) *	2000-12-28	2004-03-09	Exxonmobil Research And Engineering Company	Ionic membranes for organic sulfur separation from liquid hydrocarbon solutions
US7628966B1 (en) *	2003-02-25	2009-12-08	American Energies Corporation, Inc.	Method for scrubbing natural gas
JP2008504409A (ja) *	2004-07-07	2008-02-14	カリフォルニアインスティテュートオブテクノロジー	金属酸化物を使用して油を改良するプロセス
US7892418B2 (en) *	2005-04-11	2011-02-22	Oil Tech SARL	Process for producing low sulfur and high cetane number petroleum fuel
US8343336B2 (en) *	2007-10-30	2013-01-01	Saudi Arabian Oil Company	Desulfurization of whole crude oil by solvent extraction and hydrotreating
US8501999B2 (en) *	2009-11-07	2013-08-06	Saudi Arabian Oil Company	Hydrocarbon recovery from sulfones formed by oxidative desulfurization process
US8735820B2 (en) *	2010-04-09	2014-05-27	Tesoro Refining And Marketing Company	Direct match spectrographic determination of fuel properties
KR102167636B1 (ko)	2011-07-31	2020-10-19	사우디 아라비안 오일 컴퍼니	통합 설폰 분해로 산화적 탈황하는 방법
US9709545B2 (en)	2015-07-23	2017-07-18	Tesoro Refining & Marketing Company LLC	Methods and apparatuses for spectral qualification of fuel properties
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Also Published As

Publication number	Publication date
AR014616A1 (es)	2001-03-28
ID18744A (id)	1998-05-07
MA24347A1 (fr)	1998-07-01
ZA975855B (en)	1998-01-05
CO4870722A1 (es)	1999-12-27
AU3595697A (en)	1998-01-21
US5858212A (en)	1999-01-12
WO1998000478A1 (fr)	1998-01-08
PE18199A1 (es)	1999-03-08
JO1973B1 (en)	1997-12-15
HRP970360A2 (en)	1998-04-30
NL1006441A1 (nl)	1998-01-07
PA8433501A1 (es)	2000-05-24

Legal Events

Date	Code	Title	Description
1998-03-02	AD1A	A request for search or an international type search has been filed
1999-12-01	RD2N	Patents in respect of which a decision has been taken or a report has been made (novelty report)	Effective date: 19990923
2000-04-03	PD2B	A search report has been drawn up
2002-04-02	VD1	Lapsed due to non-payment of the annual fee	Effective date: 20020201

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