NL1009841C2 - Werkwijze voor de hydrogenering van koolstof-koolstof dubbele bindingen van een onverzadigd polymeer. - Google Patents

Werkwijze voor de hydrogenering van koolstof-koolstof dubbele bindingen van een onverzadigd polymeer. Download PDF

Info

Publication number: NL1009841C2
Authority: NL; Netherlands
Prior art keywords: hydrogenation; hydrazine; process according; carbon; catalyst
Prior art date: 1998-08-11

Application number

NL1009841A

Other languages

English (en)

Dutch (nl)

Inventor

Jacobus Adriaan Anto Vermeulen

Johannus Wilhelmus Belt

Mike Koestermann

Original Assignee

Dsm Nv

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1998-08-11

Filing date

1998-08-11

Publication date

2000-02-15

1998-08-11 Priority to NL1009841A priority Critical patent/NL1009841C2/nl

1998-08-11 Application filed by Dsm Nv filed Critical Dsm Nv

1999-08-09 Priority to AT99939623T priority patent/ATE253084T1/de

1999-08-09 Priority to EP99939624A priority patent/EP1114066B1/de

1999-08-09 Priority to AU53881/99A priority patent/AU5388199A/en

1999-08-09 Priority to DE69912465T priority patent/DE69912465T2/de

1999-08-09 Priority to DE69906328T priority patent/DE69906328T2/de

1999-08-09 Priority to JP2000565012A priority patent/JP4496646B2/ja

1999-08-09 Priority to AT99939624T priority patent/ATE235515T1/de

1999-08-09 Priority to ES99939623T priority patent/ES2211140T3/es

1999-08-09 Priority to PCT/NL1999/000508 priority patent/WO2000009568A1/en

1999-08-09 Priority to JP2000565019A priority patent/JP4752112B2/ja

1999-08-09 Priority to AU53880/99A priority patent/AU5388099A/en

1999-08-09 Priority to PCT/NL1999/000507 priority patent/WO2000009576A1/en

1999-08-09 Priority to EP99939623A priority patent/EP1114068B1/de

2000-02-15 Application granted granted Critical

2000-02-15 Publication of NL1009841C2 publication Critical patent/NL1009841C2/nl

2001-02-09 Priority to US09/779,699 priority patent/US6521694B2/en

2001-02-09 Priority to US09/779,700 priority patent/US6552132B2/en

2003-03-05 Priority to US10/378,690 priority patent/US20030144428A1/en

Links

229920000642 polymer Polymers 0.000 title claims abstract description 42
238000000034 method Methods 0.000 title claims abstract description 28
239000011203 carbon fibre reinforced carbon Substances 0.000 title claims abstract description 13
238000005984 hydrogenation reaction Methods 0.000 title claims description 49
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims abstract description 46
150000001875 compounds Chemical class 0.000 claims abstract description 22
239000003054 catalyst Substances 0.000 claims abstract description 18
239000003638 chemical reducing agent Substances 0.000 claims abstract description 6
230000000737 periodic effect Effects 0.000 claims abstract description 6
229920000126 latex Polymers 0.000 claims description 23
239000004816 latex Substances 0.000 claims description 22
230000001590 oxidative effect Effects 0.000 claims description 13
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 5
125000004432 carbon atom Chemical group C* 0.000 claims description 4
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 2
125000000217 alkyl group Chemical group 0.000 claims description 2
125000003118 aryl group Chemical group 0.000 claims description 2
229910052796 boron Inorganic materials 0.000 claims description 2
125000000753 cycloalkyl group Chemical group 0.000 claims description 2
125000005843 halogen group Chemical group 0.000 claims description 2
125000005842 heteroatom Chemical group 0.000 claims description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
239000003446 ligand Substances 0.000 claims description 2
239000011541 reaction mixture Substances 0.000 claims description 2
238000011835 investigation Methods 0.000 claims 2
229910052799 carbon Inorganic materials 0.000 claims 1
150000004677 hydrates Chemical class 0.000 claims 1
125000001183 hydrocarbyl group Chemical group 0.000 claims 1
239000000463 material Substances 0.000 claims 1
239000007800 oxidant agent Substances 0.000 claims 1
239000013589 supplement Substances 0.000 claims 1
150000002429 hydrazines Chemical class 0.000 abstract description 2
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 20
IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine hydrate Chemical class O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 description 13
239000011521 glass Substances 0.000 description 8
-1 acrylonitrile and Chemical class 0.000 description 7
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 6
239000004327 boric acid Substances 0.000 description 6
238000002474 experimental method Methods 0.000 description 5
239000000243 solution Substances 0.000 description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
238000006243 chemical reaction Methods 0.000 description 4
230000000052 comparative effect Effects 0.000 description 4
239000000178 monomer Substances 0.000 description 4
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
229920002554 vinyl polymer Polymers 0.000 description 4
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
239000002518 antifoaming agent Substances 0.000 description 3
RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
239000003999 initiator Substances 0.000 description 3
229910021645 metal ion Inorganic materials 0.000 description 3
150000004682 monohydrates Chemical class 0.000 description 3
229920002545 silicone oil Polymers 0.000 description 3
239000002904 solvent Substances 0.000 description 3
238000003756 stirring Methods 0.000 description 3
NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 description 2
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
FUSNOPLQVRUIIM-UHFFFAOYSA-N 4-amino-2-(4,4-dimethyl-2-oxoimidazolidin-1-yl)-n-[3-(trifluoromethyl)phenyl]pyrimidine-5-carboxamide Chemical compound O=C1NC(C)(C)CN1C(N=C1N)=NC=C1C(=O)NC1=CC=CC(C(F)(F)F)=C1 FUSNOPLQVRUIIM-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 description 2
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
238000001069 Raman spectroscopy Methods 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
HEDRZPFGACZZDS-MICDWDOJSA-N Trichloro(2H)methane Chemical compound [2H]C(Cl)(Cl)Cl HEDRZPFGACZZDS-MICDWDOJSA-N 0.000 description 2
BIVUUOPIAYRCAP-UHFFFAOYSA-N aminoazanium;chloride Chemical compound Cl.NN BIVUUOPIAYRCAP-UHFFFAOYSA-N 0.000 description 2
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
238000004132 cross linking Methods 0.000 description 2
150000001993 dienes Chemical class 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
238000000605 extraction Methods 0.000 description 2
239000012493 hydrazine sulfate Substances 0.000 description 2
229910000377 hydrazine sulfate Inorganic materials 0.000 description 2
150000002432 hydroperoxides Chemical class 0.000 description 2
WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
125000002560 nitrile group Chemical group 0.000 description 2
150000002978 peroxides Chemical class 0.000 description 2
150000004977 peroxyborates Chemical class 0.000 description 2
239000000344 soap Substances 0.000 description 2
229920003048 styrene butadiene rubber Polymers 0.000 description 2
229920001567 vinyl ester resin Polymers 0.000 description 2
PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
HIACAHMKXQESOV-UHFFFAOYSA-N 1,2-bis(prop-1-en-2-yl)benzene Chemical compound CC(=C)C1=CC=CC=C1C(C)=C HIACAHMKXQESOV-UHFFFAOYSA-N 0.000 description 1
RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
MGADZUXDNSDTHW-UHFFFAOYSA-N 2H-pyran Chemical compound C1OC=CC=C1 MGADZUXDNSDTHW-UHFFFAOYSA-N 0.000 description 1
ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical compound N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 description 1
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
238000005079 FT-Raman Methods 0.000 description 1
244000043261 Hevea brasiliensis Species 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Natural products C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 description 1
239000005062 Polybutadiene Substances 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 description 1
CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 description 1
238000001237 Raman spectrum Methods 0.000 description 1
239000002174 Styrene-butadiene Substances 0.000 description 1
YFHNDHXQDJQEEE-UHFFFAOYSA-N acetic acid;hydrazine Chemical compound NN.CC(O)=O YFHNDHXQDJQEEE-UHFFFAOYSA-N 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
125000005619 boric acid group Chemical group 0.000 description 1
229910052795 boron group element Inorganic materials 0.000 description 1
150000001642 boronic acid derivatives Chemical class 0.000 description 1
238000012662 bulk polymerization Methods 0.000 description 1
VLLYOYVKQDKAHN-UHFFFAOYSA-N buta-1,3-diene;2-methylbuta-1,3-diene Chemical compound C=CC=C.CC(=C)C=C VLLYOYVKQDKAHN-UHFFFAOYSA-N 0.000 description 1
CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
229920006037 cross link polymer Polymers 0.000 description 1
LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
238000007720 emulsion polymerization reaction Methods 0.000 description 1
238000010528 free radical solution polymerization reaction Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229910001385 heavy metal Inorganic materials 0.000 description 1
150000002430 hydrocarbons Chemical group 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
229920003049 isoprene rubber Polymers 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
239000000155 melt Substances 0.000 description 1
150000002736 metal compounds Chemical group 0.000 description 1
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
239000000203 mixture Substances 0.000 description 1
229920003052 natural elastomer Polymers 0.000 description 1
229920001194 natural rubber Polymers 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
229910000073 phosphorus hydride Inorganic materials 0.000 description 1
PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
229920002857 polybutadiene Polymers 0.000 description 1
229920001195 polyisoprene Polymers 0.000 description 1
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
238000010992 reflux Methods 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
238000004611 spectroscopical analysis Methods 0.000 description 1
238000001228 spectrum Methods 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
229920001897 terpolymer Polymers 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/04—Reduction, e.g. hydrogenation
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/02—Hydrogenation
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L15/00—Compositions of rubber derivatives
- C08L15/005—Hydrogenated nitrile rubber

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Carbon And Carbon Compounds (AREA)

NL1009841A 1998-08-11 1998-08-11 Werkwijze voor de hydrogenering van koolstof-koolstof dubbele bindingen van een onverzadigd polymeer. NL1009841C2 (nl)

Priority Applications (17)

Application Number	Priority Date	Filing Date	Title
NL1009841A NL1009841C2 (nl)	1998-08-11	1998-08-11	Werkwijze voor de hydrogenering van koolstof-koolstof dubbele bindingen van een onverzadigd polymeer.
JP2000565019A JP4752112B2 (ja)	1998-08-11	1999-08-09	不飽和ポリマーの炭素−炭素二重結合を水素化する方法
AU53881/99A AU5388199A (en)	1998-08-11	1999-08-09	Process for the hydrogenation of a polymer composed of diene monomer units and nitrile group containing monomer units and hydrogenated polymer
DE69912465T DE69912465T2 (de)	1998-08-11	1999-08-09	Verfahren zur hydrierung von kohlenstoff-kohlenstoff doppelbindungen in ungesättigten polymeren
DE69906328T DE69906328T2 (de)	1998-08-11	1999-08-09	Verfahren zur hydrierung eines polymeren aufgebaut aus dienmonomeren und nitrilgruppen enthaltenden monomeren und hydriertes polymer
JP2000565012A JP4496646B2 (ja)	1998-08-11	1999-08-09	ジエンモノマー単位及びニトリル基含有モノマー単位からなるポリマーを水素化する方法、及び水素化されたポリマー
AT99939624T ATE235515T1 (de)	1998-08-11	1999-08-09	Verfahren zur hydrierung eines polymeren aufgebaut aus dienmonomeren und nitrilgruppen enthaltenden monomeren und hydriertes polymer
ES99939623T ES2211140T3 (es)	1998-08-11	1999-08-09	Procedimiento para la hidrogenacion de dobles enlaces carbono-carbono de un polimero insaturado.
AT99939623T ATE253084T1 (de)	1998-08-11	1999-08-09	Verfahren zur hydrierung von kohlenstoff- kohlenstoff doppelbindungen in ungesättigten polymeren
EP99939624A EP1114066B1 (de)	1998-08-11	1999-08-09	Verfahren zur hydrierung eines polymeren aufgebaut aus dienmonomeren und nitrilgruppen enthaltenden monomeren und hydriertes polymer
AU53880/99A AU5388099A (en)	1998-08-11	1999-08-09	Process for hydrogenation of carbon-carbon double bonds of an unsaturated polymer
PCT/NL1999/000507 WO2000009576A1 (en)	1998-08-11	1999-08-09	Process for hydrogenation of carbon-carbon double bonds of an unsaturated polymer
EP99939623A EP1114068B1 (de)	1998-08-11	1999-08-09	Verfahren zur hydrierung von kohlenstoff-kohlenstoff doppelbindungen in ungesättigten polymeren
PCT/NL1999/000508 WO2000009568A1 (en)	1998-08-11	1999-08-09	Process for the hydrogenation of a polymer composed of diene monomer units and nitrile group containing monomer units and hydrogenated polymer
US09/779,699 US6521694B2 (en)	1998-08-11	2001-02-09	Process for hydrogenation of carbon-carbon double bonds of an unsaturated polymer
US09/779,700 US6552132B2 (en)	1998-08-11	2001-02-09	Process for the hydrogenation of a polymer composed of diene monomer units and nitrile group containing monomer units and hydrogenated polymer
US10/378,690 US20030144428A1 (en)	1998-08-11	2003-03-05	Process for the hydrogenation of a polymer composed of diene monomer units and nitrile group containing monomer units and hydrogenated polymer

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
NL1009841		1998-08-11
NL1009841A NL1009841C2 (nl)	1998-08-11	1998-08-11	Werkwijze voor de hydrogenering van koolstof-koolstof dubbele bindingen van een onverzadigd polymeer.

Publications (1)

Publication Number	Publication Date
NL1009841C2 true NL1009841C2 (nl)	2000-02-15

Family

ID=19767634

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NL1009841A NL1009841C2 (nl)	1998-08-11	1998-08-11	Werkwijze voor de hydrogenering van koolstof-koolstof dubbele bindingen van een onverzadigd polymeer.

Country Status (8)

Country	Link
EP (1)	EP1114068B1 (de)
JP (1)	JP4752112B2 (de)
AT (1)	ATE253084T1 (de)
AU (1)	AU5388099A (de)
DE (1)	DE69912465T2 (de)
ES (1)	ES2211140T3 (de)
NL (1)	NL1009841C2 (de)
WO (1)	WO2000009576A1 (de)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6762276B2 (en)	2002-02-27	2004-07-13	Eastman Chemical Company	Hydrogenation of polyester oligomers containing terephthalic acid residues
ATE387463T1 (de) *	2002-04-11	2008-03-15	Arkema France	Verfahren zur hydrierung von polymeren in dispergiertem medium
US7655725B2 (en)	2002-07-19	2010-02-02	Zeon Corporation	Process for the preparation of a hydrogenated polymer
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Publication number	Publication date
AU5388099A (en)	2000-03-06
ATE253084T1 (de)	2003-11-15
EP1114068A1 (de)	2001-07-11
DE69912465D1 (de)	2003-12-04
EP1114068B1 (de)	2003-10-29
JP2002522603A (ja)	2002-07-23
JP4752112B2 (ja)	2011-08-17
WO2000009576A1 (en)	2000-02-24
ES2211140T3 (es)	2004-07-01
DE69912465T2 (de)	2004-08-19

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