NL7908134A - Werkwijze voor de bereiding van een oxydatiekataly- sator, oxydatiekatalysator verkregen volgens deze werkwijze alsmede werkwijze voor het oxyderen van alkenisch onverzadigde koolwaterstoffen. - Google Patents

Werkwijze voor de bereiding van een oxydatiekataly- sator, oxydatiekatalysator verkregen volgens deze werkwijze alsmede werkwijze voor het oxyderen van alkenisch onverzadigde koolwaterstoffen. Download PDF

Info

Publication number: NL7908134A
Authority: NL; Netherlands
Prior art keywords: catalyst; oxygen; oxidation catalyst; oxidation; molecular oxygen
Prior art date: 1978-11-13

Application number

NL7908134A

Other languages

English (en)

Dutch (nl)

Original Assignee

Celanese Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-11-13

Filing date

1979-11-07

Publication date

1980-05-16

1979-11-07 Application filed by Celanese Corp filed Critical Celanese Corp

1980-05-16 Publication of NL7908134A publication Critical patent/NL7908134A/nl

Links

239000003054 catalyst Substances 0.000 title claims description 86
238000000034 method Methods 0.000 title claims description 55
238000007254 oxidation reaction Methods 0.000 title claims description 47
230000003647 oxidation Effects 0.000 title claims description 45
230000008569 process Effects 0.000 title claims description 36
238000002360 preparation method Methods 0.000 title claims description 26
229930195735 unsaturated hydrocarbon Natural products 0.000 title claims description 15
PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 40
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 36
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 28
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 24
229910052759 nickel Inorganic materials 0.000 claims description 22
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 22
239000000203 mixture Substances 0.000 claims description 21
238000006243 chemical reaction Methods 0.000 claims description 20
229910052760 oxygen Inorganic materials 0.000 claims description 20
229910052750 molybdenum Inorganic materials 0.000 claims description 19
239000011701 zinc Substances 0.000 claims description 19
229910052797 bismuth Inorganic materials 0.000 claims description 18
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
229910052725 zinc Inorganic materials 0.000 claims description 18
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 17
229910017052 cobalt Inorganic materials 0.000 claims description 17
239000010941 cobalt Substances 0.000 claims description 17
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 17
229910052742 iron Inorganic materials 0.000 claims description 17
239000001301 oxygen Substances 0.000 claims description 17
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 16
229910001882 dioxygen Inorganic materials 0.000 claims description 16
239000012808 vapor phase Substances 0.000 claims description 16
239000000463 material Substances 0.000 claims description 15
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 14
150000001299 aldehydes Chemical class 0.000 claims description 14
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 13
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 12
229910052787 antimony Inorganic materials 0.000 claims description 12
239000011733 molybdenum Substances 0.000 claims description 12
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 11
229910052700 potassium Inorganic materials 0.000 claims description 11
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 10
239000011591 potassium Substances 0.000 claims description 10
238000001354 calcination Methods 0.000 claims description 9
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 8
150000001875 compounds Chemical class 0.000 claims description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 5
238000010438 heat treatment Methods 0.000 claims description 5
-1 nismuth Chemical compound 0.000 claims description 5
229910052701 rubidium Inorganic materials 0.000 claims description 5
IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims description 5
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 claims description 4
DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims description 4
239000012736 aqueous medium Substances 0.000 claims description 4
239000007900 aqueous suspension Substances 0.000 claims description 4
239000011230 binding agent Substances 0.000 claims description 4
229910002092 carbon dioxide Inorganic materials 0.000 claims description 4
239000001569 carbon dioxide Substances 0.000 claims description 4
238000002156 mixing Methods 0.000 claims description 4
JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 claims description 3
STNJBCKSHOAVAJ-UHFFFAOYSA-N Methacrolein Chemical compound CC(=C)C=O STNJBCKSHOAVAJ-UHFFFAOYSA-N 0.000 claims description 2
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
230000001590 oxidative effect Effects 0.000 claims description 2
239000000758 substrate Substances 0.000 claims description 2
125000004430 oxygen atom Chemical group O* 0.000 claims 3
239000000725 suspension Substances 0.000 description 17
239000002253 acid Substances 0.000 description 10
150000001336 alkenes Chemical class 0.000 description 9
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
239000002609 medium Substances 0.000 description 8
239000000243 solution Substances 0.000 description 8
239000000047 product Substances 0.000 description 7
150000001463 antimony compounds Chemical class 0.000 description 6
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 5
150000007513 acids Chemical class 0.000 description 4
230000003197 catalytic effect Effects 0.000 description 4
239000012071 phase Substances 0.000 description 4
239000002002 slurry Substances 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
239000012018 catalyst precursor Substances 0.000 description 3
239000003153 chemical reaction reagent Substances 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000007789 gas Substances 0.000 description 3
150000003112 potassium compounds Chemical class 0.000 description 3
239000000377 silicon dioxide Substances 0.000 description 3
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
229910052785 arsenic Inorganic materials 0.000 description 2
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 2
229910052792 caesium Chemical group 0.000 description 2
TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical group [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 2
HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Chemical compound [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
229910052681 coesite Inorganic materials 0.000 description 2
BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 2
229910052906 cristobalite Inorganic materials 0.000 description 2
KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 description 2
229940112669 cuprous oxide Drugs 0.000 description 2
239000003085 diluting agent Substances 0.000 description 2
QXYJCZRRLLQGCR-UHFFFAOYSA-N dioxomolybdenum Chemical compound O=[Mo]=O QXYJCZRRLLQGCR-UHFFFAOYSA-N 0.000 description 2
239000008246 gaseous mixture Substances 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
230000004048 modification Effects 0.000 description 2
238000012986 modification Methods 0.000 description 2
MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 2
150000002823 nitrates Chemical class 0.000 description 2
229910017604 nitric acid Inorganic materials 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
239000002245 particle Substances 0.000 description 2
229910052698 phosphorus Inorganic materials 0.000 description 2
239000011574 phosphorus Substances 0.000 description 2
FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
238000001144 powder X-ray diffraction data Methods 0.000 description 2
239000002243 precursor Substances 0.000 description 2
239000000376 reactant Substances 0.000 description 2
230000009257 reactivity Effects 0.000 description 2
235000012239 silicon dioxide Nutrition 0.000 description 2
239000011949 solid catalyst Substances 0.000 description 2
229910052682 stishovite Inorganic materials 0.000 description 2
239000000126 substance Substances 0.000 description 2
229910052905 tridymite Inorganic materials 0.000 description 2
229910002012 Aerosil® Inorganic materials 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
229910002904 Bi-Co Inorganic materials 0.000 description 1
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
229910018864 CoMoO4 Inorganic materials 0.000 description 1
101000637977 Homo sapiens Neuronal calcium sensor 1 Proteins 0.000 description 1
101001083117 Microbacterium liquefaciens Hydantoin permease Proteins 0.000 description 1
102100032077 Neuronal calcium sensor 1 Human genes 0.000 description 1
229910017709 Ni Co Inorganic materials 0.000 description 1
KUGRPPRAQNPSQD-UHFFFAOYSA-N OOOOO Chemical compound OOOOO KUGRPPRAQNPSQD-UHFFFAOYSA-N 0.000 description 1
XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 1
239000011609 ammonium molybdate Substances 0.000 description 1
229940010552 ammonium molybdate Drugs 0.000 description 1
235000018660 ammonium molybdate Nutrition 0.000 description 1
229940058905 antimony compound for treatment of leishmaniasis and trypanosomiasis Drugs 0.000 description 1
229910000410 antimony oxide Inorganic materials 0.000 description 1
ZDINGUUTWDGGFF-UHFFFAOYSA-N antimony(5+) Chemical compound [Sb+5] ZDINGUUTWDGGFF-UHFFFAOYSA-N 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
229910052786 argon Inorganic materials 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
239000002585 base Substances 0.000 description 1
150000001621 bismuth Chemical class 0.000 description 1
150000001622 bismuth compounds Chemical class 0.000 description 1
229910000416 bismuth oxide Inorganic materials 0.000 description 1
229910052796 boron Inorganic materials 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
229910002091 carbon monoxide Inorganic materials 0.000 description 1
229910002090 carbon oxide Inorganic materials 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
KYYSIVCCYWZZLR-UHFFFAOYSA-N cobalt(2+);dioxido(dioxo)molybdenum Chemical compound [Co+2].[O-][Mo]([O-])(=O)=O KYYSIVCCYWZZLR-UHFFFAOYSA-N 0.000 description 1
238000005336 cracking Methods 0.000 description 1
239000013078 crystal Substances 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
DKUYEPUUXLQPPX-UHFFFAOYSA-N dibismuth;molybdenum;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Mo].[Mo].[Bi+3].[Bi+3] DKUYEPUUXLQPPX-UHFFFAOYSA-N 0.000 description 1
TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 1
238000009826 distribution Methods 0.000 description 1
239000012467 final product Substances 0.000 description 1
239000003546 flue gas Substances 0.000 description 1
230000035876 healing Effects 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
239000003701 inert diluent Substances 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
230000003993 interaction Effects 0.000 description 1
150000002506 iron compounds Chemical class 0.000 description 1
MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
239000005078 molybdenum compound Substances 0.000 description 1
150000002752 molybdenum compounds Chemical class 0.000 description 1
229910000595 mu-metal Inorganic materials 0.000 description 1
150000002816 nickel compounds Chemical class 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen(.) Chemical compound [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
239000007800 oxidant agent Substances 0.000 description 1
VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
239000008188 pellet Substances 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
239000004323 potassium nitrate Substances 0.000 description 1
235000010333 potassium nitrate Nutrition 0.000 description 1
235000010289 potassium nitrite Nutrition 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
239000001294 propane Substances 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
229910010271 silicon carbide Inorganic materials 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
239000007858 starting material Substances 0.000 description 1
229910001935 vanadium oxide Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8876—Arsenic, antimony or bismuth
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

NL7908134A 1978-11-13 1979-11-07 Werkwijze voor de bereiding van een oxydatiekataly- sator, oxydatiekatalysator verkregen volgens deze werkwijze alsmede werkwijze voor het oxyderen van alkenisch onverzadigde koolwaterstoffen. NL7908134A (nl)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US96020278		1978-11-13
US05/960,202 US4224193A (en)	1978-11-13	1978-11-13	Olefin oxidation catalyst and process for its preparation

Publications (1)

Publication Number	Publication Date
NL7908134A true NL7908134A (nl)	1980-05-16

Family

ID=25502935

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NL7908134A NL7908134A (nl)	1978-11-13	1979-11-07	Werkwijze voor de bereiding van een oxydatiekataly- sator, oxydatiekatalysator verkregen volgens deze werkwijze alsmede werkwijze voor het oxyderen van alkenisch onverzadigde koolwaterstoffen.

Country Status (8)

Country	Link
US (1)	US4224193A (fr)
JP (1)	JPS5567340A (fr)
BE (1)	BE879967A (fr)
CA (1)	CA1122960A (fr)
DE (1)	DE2943704A1 (fr)
FR (1)	FR2441424A1 (fr)
GB (1)	GB2036583A (fr)
NL (1)	NL7908134A (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH0813332B2 (ja) *	1989-09-25	1996-02-14	三菱レイヨン株式会社	メタクロレイン及びメタクリル酸の製造用触媒の調製法
JP3793317B2 (ja) *	1996-05-14	2006-07-05	日本化薬株式会社	触媒及び不飽和アルデヒドおよび不飽和酸の製造方法
US6337424B1 (en)	2000-04-28	2002-01-08	Saudi Basic Industries Corporation	Catalysts oxidation of lower olefins to unsaturated aldehydes, methods of making and using the same
US7851397B2 (en)	2005-07-25	2010-12-14	Saudi Basic Industries Corporation	Catalyst for methacrolein oxidation and method for making and using same
US7649111B2 (en)	2005-07-25	2010-01-19	Saudi Basic Industries Corporation	Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same
US7732367B2 (en)	2005-07-25	2010-06-08	Saudi Basic Industries Corporation	Catalyst for methacrolein oxidation and method for making and using same
US7649112B2 (en)	2005-07-25	2010-01-19	Saudi Basic Industries Corporation	Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon
US8921257B2 (en)	2011-12-02	2014-12-30	Saudi Basic Industries Corporation	Dual function partial oxidation catalyst for propane to acrylic acid conversion
US8722940B2 (en)	2012-03-01	2014-05-13	Saudi Basic Industries Corporation	High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins

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* Cited by examiner, † Cited by third party
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BE749305A (fr) *	1969-05-02	1970-10-01	Nippon Kayaku Kk	Catalyseur d'oxydation et son utilisation (
JPS5112603B1 (fr) *	1971-05-26	1976-04-21
GB1490683A (en) *	1975-03-12	1977-11-02	Mitsubishi Rayon Co	Process and a catalyst for producing unsaturated aldehydes unsaturated carboxylic acids or conjugated diene

1978
- 1978-11-13 US US05/960,202 patent/US4224193A/en not_active Expired - Lifetime
1979
- 1979-10-30 DE DE19792943704 patent/DE2943704A1/de not_active Withdrawn
- 1979-11-07 CA CA339,361A patent/CA1122960A/fr not_active Expired
- 1979-11-07 NL NL7908134A patent/NL7908134A/nl not_active Application Discontinuation
- 1979-11-12 GB GB7939079A patent/GB2036583A/en not_active Withdrawn
- 1979-11-12 FR FR7927809A patent/FR2441424A1/fr not_active Withdrawn
- 1979-11-12 BE BE0/198066A patent/BE879967A/fr unknown
- 1979-11-13 JP JP14612579A patent/JPS5567340A/ja active Pending

Also Published As

Publication number	Publication date
GB2036583A (en)	1980-07-02
JPS5567340A (en)	1980-05-21
DE2943704A1 (de)	1980-05-22
FR2441424A1 (fr)	1980-06-13
CA1122960A (fr)	1982-05-04
US4224193A (en)	1980-09-23
BE879967A (fr)	1980-05-12

Legal Events

Date	Code	Title	Description
1982-07-01	BV	The patent application has lapsed

Publication	Publication Date	Title
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