NL7908135A - Werkwijze voor de bereiding van een alkeenoxydatie- katalysator, katalysator verkregen volgens deze werk- wijze alsmede werkwijze voor het oxyderen van alkenen. - Google Patents

Werkwijze voor de bereiding van een alkeenoxydatie- katalysator, katalysator verkregen volgens deze werk- wijze alsmede werkwijze voor het oxyderen van alkenen. Download PDF

Info

Publication number: NL7908135A
Authority: NL; Netherlands
Prior art keywords: catalyst; oxidation; oxygen; molecular oxygen; preparation
Prior art date: 1978-11-13

Application number

NL7908135A

Other languages

English (en)

Dutch (nl)

Original Assignee

Celanese Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-11-13

Filing date

1979-11-07

Publication date

1980-05-16

1979-11-07 Application filed by Celanese Corp filed Critical Celanese Corp

1980-05-16 Publication of NL7908135A publication Critical patent/NL7908135A/nl

Links

239000003054 catalyst Substances 0.000 title claims description 124
238000000034 method Methods 0.000 title claims description 61
238000007254 oxidation reaction Methods 0.000 title claims description 59
230000003647 oxidation Effects 0.000 title claims description 56
238000002360 preparation method Methods 0.000 title claims description 38
230000008569 process Effects 0.000 title claims description 36
150000001336 alkenes Chemical class 0.000 title description 14
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title description 8
PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 57
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 53
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 47
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 41
238000006243 chemical reaction Methods 0.000 claims description 25
239000000463 material Substances 0.000 claims description 25
239000000203 mixture Substances 0.000 claims description 25
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 25
229910052698 phosphorus Inorganic materials 0.000 claims description 24
229910052759 nickel Inorganic materials 0.000 claims description 23
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 23
239000011574 phosphorus Substances 0.000 claims description 22
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 21
229910052742 iron Inorganic materials 0.000 claims description 21
229910052797 bismuth Inorganic materials 0.000 claims description 20
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 19
229910052750 molybdenum Inorganic materials 0.000 claims description 19
229910052760 oxygen Inorganic materials 0.000 claims description 19
229910052700 potassium Inorganic materials 0.000 claims description 19
239000011591 potassium Substances 0.000 claims description 19
238000001354 calcination Methods 0.000 claims description 18
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 16
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 16
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 16
229910017052 cobalt Inorganic materials 0.000 claims description 16
239000010941 cobalt Substances 0.000 claims description 16
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 16
229910001882 dioxygen Inorganic materials 0.000 claims description 16
239000001301 oxygen Substances 0.000 claims description 16
239000012808 vapor phase Substances 0.000 claims description 16
150000001299 aldehydes Chemical class 0.000 claims description 15
229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 15
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 12
239000011733 molybdenum Substances 0.000 claims description 12
150000001875 compounds Chemical class 0.000 claims description 11
238000002156 mixing Methods 0.000 claims description 9
239000002002 slurry Substances 0.000 claims description 9
STNJBCKSHOAVAJ-UHFFFAOYSA-N Methacrolein Chemical compound CC(=C)C=O STNJBCKSHOAVAJ-UHFFFAOYSA-N 0.000 claims description 7
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 6
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 6
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 5
229910052732 germanium Inorganic materials 0.000 claims description 5
GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical group [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 5
125000004430 oxygen atom Chemical group O* 0.000 claims description 5
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
229910052684 Cerium Inorganic materials 0.000 claims description 4
DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims description 4
229910052787 antimony Inorganic materials 0.000 claims description 4
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 4
239000012736 aqueous medium Substances 0.000 claims description 4
239000011230 binding agent Substances 0.000 claims description 4
ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical group [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 claims description 4
239000007789 gas Substances 0.000 claims description 4
238000010438 heat treatment Methods 0.000 claims description 4
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical group [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 4
JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 claims description 4
229910052701 rubidium Inorganic materials 0.000 claims description 4
IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims description 4
239000007900 aqueous suspension Substances 0.000 claims description 3
229910002092 carbon dioxide Inorganic materials 0.000 claims description 3
239000001569 carbon dioxide Substances 0.000 claims description 3
239000011572 manganese Substances 0.000 claims description 3
229910052715 tantalum Inorganic materials 0.000 claims description 3
GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 3
239000000758 substrate Substances 0.000 claims description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 23
239000000243 solution Substances 0.000 description 23
239000000725 suspension Substances 0.000 description 21
229910052681 coesite Inorganic materials 0.000 description 10
229910052906 cristobalite Inorganic materials 0.000 description 10
229910052682 stishovite Inorganic materials 0.000 description 10
229910052905 tridymite Inorganic materials 0.000 description 10
239000002253 acid Substances 0.000 description 9
239000002609 medium Substances 0.000 description 9
239000000047 product Substances 0.000 description 8
238000001035 drying Methods 0.000 description 7
230000000694 effects Effects 0.000 description 7
239000000377 silicon dioxide Substances 0.000 description 7
HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 6
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
239000012071 phase Substances 0.000 description 6
235000012239 silicon dioxide Nutrition 0.000 description 6
239000007858 starting material Substances 0.000 description 6
230000003197 catalytic effect Effects 0.000 description 5
229910004298 SiO 2 Inorganic materials 0.000 description 4
239000003153 chemical reaction reagent Substances 0.000 description 4
239000012154 double-distilled water Substances 0.000 description 4
MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 4
150000003112 potassium compounds Chemical class 0.000 description 4
FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 4
239000002244 precipitate Substances 0.000 description 4
230000009257 reactivity Effects 0.000 description 4
229910002012 Aerosil® Inorganic materials 0.000 description 3
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
150000007513 acids Chemical class 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
239000012018 catalyst precursor Substances 0.000 description 3
229910052739 hydrogen Inorganic materials 0.000 description 3
239000007788 liquid Substances 0.000 description 3
-1 molybdate compound Chemical class 0.000 description 3
229910017604 nitric acid Inorganic materials 0.000 description 3
239000000126 substance Substances 0.000 description 3
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
229910002651 NO3 Inorganic materials 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
230000002411 adverse Effects 0.000 description 2
229910052785 arsenic Inorganic materials 0.000 description 2
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 2
229910052792 caesium Chemical group 0.000 description 2
TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical group [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 2
BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 2
KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 description 2
229940112669 cuprous oxide Drugs 0.000 description 2
239000003085 diluting agent Substances 0.000 description 2
YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical compound O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 2
239000003701 inert diluent Substances 0.000 description 2
230000007774 longterm Effects 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
150000002823 nitrates Chemical class 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
230000001590 oxidative effect Effects 0.000 description 2
239000002245 particle Substances 0.000 description 2
239000004323 potassium nitrate Substances 0.000 description 2
235000010333 potassium nitrate Nutrition 0.000 description 2
238000001144 powder X-ray diffraction data Methods 0.000 description 2
239000002243 precursor Substances 0.000 description 2
HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
229910010271 silicon carbide Inorganic materials 0.000 description 2
239000011949 solid catalyst Substances 0.000 description 2
229910052717 sulfur Inorganic materials 0.000 description 2
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
101100515517 Arabidopsis thaliana XI-I gene Proteins 0.000 description 1
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
229910000608 Fe(NO3)3.9H2O Inorganic materials 0.000 description 1
244000178870 Lavandula angustifolia Species 0.000 description 1
235000010663 Lavandula angustifolia Nutrition 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
229910017709 Ni Co Inorganic materials 0.000 description 1
IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 description 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 1
239000011609 ammonium molybdate Substances 0.000 description 1
235000018660 ammonium molybdate Nutrition 0.000 description 1
229940010552 ammonium molybdate Drugs 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
230000003078 antioxidant effect Effects 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
229910052786 argon Inorganic materials 0.000 description 1
229910052788 barium Inorganic materials 0.000 description 1
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
239000002585 base Substances 0.000 description 1
150000001621 bismuth Chemical class 0.000 description 1
150000001622 bismuth compounds Chemical class 0.000 description 1
229910000416 bismuth oxide Inorganic materials 0.000 description 1
229910052796 boron Inorganic materials 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
229910002091 carbon monoxide Inorganic materials 0.000 description 1
229910002090 carbon oxide Inorganic materials 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
XMPZTFVPEKAKFH-UHFFFAOYSA-P ceric ammonium nitrate Chemical compound [NH4+].[NH4+].[Ce+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O XMPZTFVPEKAKFH-UHFFFAOYSA-P 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
QGUAJWGNOXCYJF-UHFFFAOYSA-N cobalt dinitrate hexahydrate Chemical compound O.O.O.O.O.O.[Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O QGUAJWGNOXCYJF-UHFFFAOYSA-N 0.000 description 1
KYYSIVCCYWZZLR-UHFFFAOYSA-N cobalt(2+);dioxido(dioxo)molybdenum Chemical compound [Co+2].[O-][Mo]([O-])(=O)=O KYYSIVCCYWZZLR-UHFFFAOYSA-N 0.000 description 1
239000012141 concentrate Substances 0.000 description 1
239000013256 coordination polymer Substances 0.000 description 1
238000005336 cracking Methods 0.000 description 1
DKUYEPUUXLQPPX-UHFFFAOYSA-N dibismuth;molybdenum;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Mo].[Mo].[Bi+3].[Bi+3] DKUYEPUUXLQPPX-UHFFFAOYSA-N 0.000 description 1
TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 1
238000009826 distribution Methods 0.000 description 1
239000012467 final product Substances 0.000 description 1
239000003546 flue gas Substances 0.000 description 1
239000005350 fused silica glass Substances 0.000 description 1
239000008246 gaseous mixture Substances 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
238000002329 infrared spectrum Methods 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
230000003993 interaction Effects 0.000 description 1
150000002506 iron compounds Chemical class 0.000 description 1
MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 description 1
239000001102 lavandula vera Substances 0.000 description 1
235000018219 lavender Nutrition 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
238000003801 milling Methods 0.000 description 1
239000005078 molybdenum compound Substances 0.000 description 1
150000002752 molybdenum compounds Chemical class 0.000 description 1
150000002816 nickel compounds Chemical class 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen(.) Chemical compound [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
239000008188 pellet Substances 0.000 description 1
150000003018 phosphorus compounds Chemical class 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
235000010289 potassium nitrite Nutrition 0.000 description 1
239000001294 propane Substances 0.000 description 1
239000000376 reactant Substances 0.000 description 1
238000011084 recovery Methods 0.000 description 1
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
239000012086 standard solution Substances 0.000 description 1
238000011282 treatment Methods 0.000 description 1
229910001935 vanadium oxide Inorganic materials 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8872—Alkali or alkaline earth metals
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8875—Germanium, tin or lead
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8876—Arsenic, antimony or bismuth
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8877—Vanadium, tantalum, niobium or polonium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
- B01J27/19—Molybdenum
- B01J27/192—Molybdenum with bismuth
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

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Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

NL7908135A 1978-11-13 1979-11-07 Werkwijze voor de bereiding van een alkeenoxydatie- katalysator, katalysator verkregen volgens deze werk- wijze alsmede werkwijze voor het oxyderen van alkenen. NL7908135A (nl)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US05/960,201 US4224187A (en)	1978-11-13	1978-11-13	Olefin oxidation catalyst and process for its preparation
US96020178		1978-11-13

Publications (1)

Publication Number	Publication Date
NL7908135A true NL7908135A (nl)	1980-05-16

Family

ID=25502934

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NL7908135A NL7908135A (nl)	1978-11-13	1979-11-07	Werkwijze voor de bereiding van een alkeenoxydatie- katalysator, katalysator verkregen volgens deze werk- wijze alsmede werkwijze voor het oxyderen van alkenen.

Country Status (9)

Country	Link
US (1)	US4224187A (fr)
JP (1)	JPS5567339A (fr)
BE (1)	BE879966A (fr)
CA (1)	CA1122957A (fr)
DE (1)	DE2943707A1 (fr)
FR (1)	FR2441423A1 (fr)
GB (1)	GB2037603A (fr)
IT (1)	IT1127219B (fr)
NL (1)	NL7908135A (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
NL8200521A (nl) *	1982-02-11	1983-09-01	Standard Oil Co Ohio	Werkwijze ter bereiding van oxydatie en/of ammoxydatie katalysatoren.

Families Citing this family (39)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4332971A (en) *	1979-08-09	1982-06-01	Celanese Corporation	Process for the oxidation of olefinically unsaturated hydrocarbons to aldehydes using attrition resistant catalysts
US4306090A (en) *	1979-10-12	1981-12-15	Rohm And Haas Company	Catalyst compositions and their use for the preparation of methacrolein
FR2481146A1 (fr) *	1980-04-25	1981-10-30	Rhone Poulenc Ind	Procede pour la preparation de catalyseurs a base d'oxydes de molybdene et/ou de tungstene et d'oxydes d'autres metaux
FR2495015B1 (fr) *	1980-11-28	1985-07-05	Rhone Poulenc Chim Base	Procede pour la preparation de catalyseurs a base d'oxydes de molybdene et/ou de tungstene et d'oxydes d'autres metaux
US4537998A (en) *	1981-04-27	1985-08-27	Atlantic Richfield Company	Process for the oxidation of isobutylene oxide to methacrolein
US4558154A (en) *	1981-04-27	1985-12-10	Atlantic Richfield Company	Oxidation of isobutylene oxide to methacrylic acid and methacrolein
JPS58119346A (ja)	1982-01-06	1983-07-15	Nippon Shokubai Kagaku Kogyo Co Ltd	プロピレン酸化用触媒
US4788173A (en) *	1985-12-20	1988-11-29	The Standard Oil Company	Catalytic mixtures for ammoxidation of paraffins
US4783545A (en) *	1985-12-20	1988-11-08	The Standard Oil Company	Method for ammoxidation of paraffins and catalyst system therefor
US4837233A (en) *	1986-07-21	1989-06-06	The Standard Oil Company	Catalyst system for ammoxidation of paraffins
JP2701065B2 (ja) *	1989-03-23	1998-01-21	日東化学工業株式会社	モリブデン―ビスマス含有複合酸化物触媒の製法
DE59602040D1 (de) *	1995-03-10	1999-07-08	Basf Ag	Verfahren der kontinuierlich betriebenen heterogen katalysierten Gasphasenoxidation von Propylen zu Acrolein, Acrylsäure oder deren Gemisch
DE19600955A1 (de)	1996-01-12	1997-07-17	Basf Ag	Verfahren zur Herstellung von Acrylsäure und deren Ester
JP3793317B2 (ja) *	1996-05-14	2006-07-05	日本化薬株式会社	触媒及び不飽和アルデヒドおよび不飽和酸の製造方法
DE19624674A1 (de)	1996-06-20	1998-01-02	Basf Ag	Verfahren zur Entsorgung von bei der Acrylsäure- oder Methacrylsäure-Herstellung anfallenden Nebenkomponenten
DE19717165A1 (de)	1997-04-23	1998-10-29	Basf Ag	Vorrichtung und Verfahren zur Temperaturmessung in Rohrreaktoren
DE19740252A1 (de)	1997-09-12	1999-03-18	Basf Ag	Verfahren zur Herstellung von Acrylsäure und Methacrylsäure
DE19833049A1 (de)	1998-07-22	2000-01-27	Basf Ag	Verfahren zur Herstellung von Acrylsäure
DE19902562A1 (de)	1999-01-22	2000-07-27	Basf Ag	Verfahren zur Herstellung von Acrolein durch heterogen katalysierte Gasphasen-Partialoxidation von Propen
DE19926082A1 (de)	1999-06-08	2000-12-14	Basf Ag	Verfahren zur Reinigung und Herstellung von Acrylsäure oder Methacrylsäure
DE10031518A1 (de) *	2000-06-28	2002-01-10	Basf Ag	Verfahren zur Herstellung von Hydroformylierungsprodukten des Propylens und von Acrylsäure und/oder Acrolein
JP4092090B2 (ja) *	2001-06-26	2008-05-28	株式会社日本触媒	固体粒子充填反応器およびその反応器を用いた接触気相酸化方法
DE10220494A1 (de)	2002-05-07	2003-11-20	Basf Ag	Verfahren zur Herstellung einer wässrigen Alkaliacrylat-Lösung
KR100513664B1 (ko) *	2002-05-16	2005-09-07	주식회사 엘지화학	프로필렌의 부분 산화 반응용 촉매의 제조 방법
DE102004005863A1 (de) *	2004-02-05	2005-09-08	Stockhausen Gmbh	Reaktor mit einem einen Einsatz aufweisenden Wärmetauscherbereich
KR100561073B1 (ko)	2004-02-25	2006-03-17	주식회사 엘지화학	기상 부분 산화 반응용 촉매 및 그의 제조방법
US7732367B2 (en)	2005-07-25	2010-06-08	Saudi Basic Industries Corporation	Catalyst for methacrolein oxidation and method for making and using same
US7851397B2 (en)	2005-07-25	2010-12-14	Saudi Basic Industries Corporation	Catalyst for methacrolein oxidation and method for making and using same
US7649112B2 (en)	2005-07-25	2010-01-19	Saudi Basic Industries Corporation	Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon
US7649111B2 (en)	2005-07-25	2010-01-19	Saudi Basic Industries Corporation	Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same
DE102008020688B3 (de) *	2008-04-24	2009-11-05	Evonik Stockhausen Gmbh	Verfahren zur Herstellung und Aufreinigung wässriger Phasen
CN102049261B (zh) *	2010-11-18	2013-03-27	中国海洋石油总公司	一种用于丙烯氧化制备丙烯醛的催化剂的制备方法
US8921257B2 (en)	2011-12-02	2014-12-30	Saudi Basic Industries Corporation	Dual function partial oxidation catalyst for propane to acrylic acid conversion
US8722940B2 (en)	2012-03-01	2014-05-13	Saudi Basic Industries Corporation	High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
CN120129670A (zh)	2022-10-28	2025-06-10	巴斯夫欧洲公司	用于由可再生来源的乙醇制造感兴趣的丙烯衍生的化学品、特别是丙烯酸酯的方法
EP4638400A1 (fr)	2022-12-20	2025-10-29	Basf Se	Fabrication d'un produit chimique d'intérêt dérivé de l'éthylène, en particulier de l'acide acrylique, en combinaison avec la génération de vapeur chauffée
WO2025078362A1 (fr)	2023-10-09	2025-04-17	Basf Se	Procédé de fabrication de copolymères acryliques de styrène ayant une teneur en carbone d'origine renouvelable
WO2025224042A1 (fr)	2024-04-23	2025-10-30	Basf Se	Procédé de fabrication de n-butanol ou de 2-éthylhexanol renouvelable
WO2026002694A1 (fr)	2024-06-26	2026-01-02	Basf Se	Fabrication d'un ou de plusieurs produits chimiques à base de propylène à partir d'éthylène obtenu par déshydratation d'éthanol

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3959384A (en) *	1969-05-02	1976-05-25	Nippon Kayaku Kabushiki Kaisha	Oxidation catalyst and process for oxidation of olefins to unsaturated aldehydes
BE749305A (fr) *	1969-05-02	1970-10-01	Nippon Kayaku Kk	Catalyseur d'oxydation et son utilisation (
BE757476A (fr) *	1969-10-17	1971-03-16	Nippon Kayaku Kk	Procede d'oxydeshydrogenation
JPS4843096B1 (fr) *	1970-01-31	1973-12-17
CA1049553A (fr) *	1973-04-30	1979-02-27	The Standard Oil Company	Synthese d'acide acrylique ou methacrylique a partir de propylene ou d'isobutylene
US4001317A (en) *	1974-07-22	1977-01-04	Standard Oil Company	Process for the oxidation of olefins using catalysts containing various promoter elements
US4040978A (en) *	1975-11-28	1977-08-09	Monsanto Company	Production of (amm)oxidation catalyst

1978
- 1978-11-13 US US05/960,201 patent/US4224187A/en not_active Expired - Lifetime
1979
- 1979-10-30 DE DE19792943707 patent/DE2943707A1/de not_active Withdrawn
- 1979-11-07 CA CA339,336A patent/CA1122957A/fr not_active Expired
- 1979-11-07 NL NL7908135A patent/NL7908135A/nl not_active Application Discontinuation
- 1979-11-08 JP JP14392879A patent/JPS5567339A/ja active Pending
- 1979-11-12 GB GB7939080A patent/GB2037603A/en not_active Withdrawn
- 1979-11-12 IT IT27227/79A patent/IT1127219B/it active
- 1979-11-12 BE BE0/198065A patent/BE879966A/fr unknown
- 1979-11-12 FR FR7927808A patent/FR2441423A1/fr active Pending

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
NL8200521A (nl) *	1982-02-11	1983-09-01	Standard Oil Co Ohio	Werkwijze ter bereiding van oxydatie en/of ammoxydatie katalysatoren.

Also Published As

Publication number	Publication date
BE879966A (fr)	1980-05-12
IT7927227A0 (it)	1979-11-12
FR2441423A1 (fr)	1980-06-13
US4224187A (en)	1980-09-23
IT1127219B (it)	1986-05-21
GB2037603A (en)	1980-07-16
CA1122957A (fr)	1982-05-04
JPS5567339A (en)	1980-05-21
DE2943707A1 (de)	1980-05-22

Legal Events

Date	Code	Title	Description
1982-07-01	BV	The patent application has lapsed

Publication	Publication Date	Title
US4224187A (en)	1980-09-23	Olefin oxidation catalyst and process for its preparation
US4267386A (en)	1981-05-12	Olefin oxidation catalyst
EP0437056B2 (fr)	1998-04-15	Catalyseur et procédé pour la production d'acrylonitrile et de méthycrylonitrile
US5212137A (en)	1993-05-18	Catalyst for the manufacture of acrylonitrile and methacrylonitrile
RU2341327C2 (ru)	2008-12-20	Способ приготовления катализатора для окисления и аммоксидации олефинов
US6458742B1 (en)	2002-10-01	Catalyst for the manufacture of acrylonitrile
EP0043100A1 (fr)	1982-01-06	Catalyseur d'oxydation et son procédé de préparation
KR20150089064A (ko)	2015-08-04	혼합 금속 산화물 암모니아산화 촉매용 전하소 첨가제
US5175334A (en)	1992-12-29	Process for the manufacture of acrylonitrile and methacrylonitrile
KR102431212B1 (ko)	2022-08-09	개선된 혼합 금속 산화물 가암모니아 산화 촉매
US4083804A (en)	1978-04-11	Catalyst for use in and process for preparing acrylonitrile
AU718127B2 (en)	2000-04-06	Process for the selective production of acetic acid
US4248803A (en)	1981-02-03	Olefin oxidation catalyst
KR101410586B1 (ko)	2014-06-23	시안화수소 생산을 위한 촉매적 암모니아첨가 산화반응 공정
US4224193A (en)	1980-09-23	Olefin oxidation catalyst and process for its preparation
US4552978A (en)	1985-11-12	Oxidation of unsaturated aldehydes
US4247727A (en)	1981-01-27	Dehydrocoupling of toluene
ZA200504280B (en)	2006-08-30	Mixed oxide catalyst of Rb, Ce, Ni, Fe, Bi and Mo for the manufacture of acrylonitrile
EP1155741B1 (fr)	2003-05-14	Procédé de préparation de catalyseurs hautement actifs et sélectifs pour la préparation de nitriles non-saturés
JPS6033539B2 (ja)	1985-08-03	酸化用触媒およびその調製法
US3525701A (en)	1970-08-25	Oxidation catalyst of an oxide composition of antimony,tin and copper
US4978764A (en)	1990-12-18	Method for ammoxidation of paraffins
US4560673A (en)	1985-12-24	Catalyst for the oxidation of unsaturated aldehydes
US4246190A (en)	1981-01-20	Ammoxidation with tellurium catalysts
JP2025516787A (ja)	2025-05-30	アクリロニトリルを製造するための触媒

NL7908135A - Werkwijze voor de bereiding van een alkeenoxydatie- katalysator, katalysator verkregen volgens deze werk- wijze alsmede werkwijze voor het oxyderen van alkenen. - Google Patents

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Applications Claiming Priority (2)

Publications (1)

Family

ID=25502934

Family Applications (1)

Country Status (9)

Cited By (1)

Families Citing this family (39)

Family Cites Families (7)

Cited By (1)

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