NL8003883A - Werkwijze voor het verknopen van cellulosesulfaatesters met tetravalente metaalionen, als zodanig verkregen verknoopte produkten, samenstellingen van genoemde esters en metaalionen, alsmede waterige samenstellingen die genoemde produkten als verknopingsmiddel bevatten. - Google Patents

Werkwijze voor het verknopen van cellulosesulfaatesters met tetravalente metaalionen, als zodanig verkregen verknoopte produkten, samenstellingen van genoemde esters en metaalionen, alsmede waterige samenstellingen die genoemde produkten als verknopingsmiddel bevatten. Download PDF

Info

Publication number: NL8003883A
Authority: NL; Netherlands
Prior art keywords: cellulose sulfate; cellulose; cross; tetravalent metal; salt
Prior art date: 1979-07-05

Application number

NL8003883A

Other languages

English (en)

Dutch (nl)

Original Assignee

Schweiger Richard Georg

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-07-05

Filing date

1980-07-04

Publication date

1981-01-07

1980-07-04 Application filed by Schweiger Richard Georg filed Critical Schweiger Richard Georg

1981-01-07 Publication of NL8003883A publication Critical patent/NL8003883A/nl

Links

229920002678 cellulose Polymers 0.000 title claims description 288
239000001913 cellulose Substances 0.000 title claims description 287
238000004132 cross linking Methods 0.000 title claims description 60
239000000203 mixture Substances 0.000 title claims description 45
229910021645 metal ion Inorganic materials 0.000 title claims description 43
150000003467 sulfuric acid derivatives Chemical class 0.000 title claims description 41
238000000034 method Methods 0.000 title claims description 29
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 135
150000003839 salts Chemical class 0.000 claims description 76
-1 sulfate ester Chemical class 0.000 claims description 67
229910052751 metal Inorganic materials 0.000 claims description 48
239000002184 metal Substances 0.000 claims description 48
239000012736 aqueous medium Substances 0.000 claims description 32
238000006243 chemical reaction Methods 0.000 claims description 27
150000002500 ions Chemical class 0.000 claims description 24
IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims description 18
238000006467 substitution reaction Methods 0.000 claims description 12
239000003795 chemical substances by application Substances 0.000 claims description 10
239000010936 titanium Substances 0.000 claims description 8
230000008569 process Effects 0.000 claims description 7
229910052684 Cerium Inorganic materials 0.000 claims description 5
229910021653 sulphate ion Inorganic materials 0.000 claims description 4
229910052719 titanium Inorganic materials 0.000 claims description 4
239000002609 medium Substances 0.000 claims description 3
229910052845 zircon Inorganic materials 0.000 claims description 3
GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims description 3
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 2
GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 2
241000405961 Scomberomorus regalis Species 0.000 claims 1
229910052788 barium Inorganic materials 0.000 claims 1
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical group [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims 1
239000000243 solution Substances 0.000 description 64
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 41
239000002904 solvent Substances 0.000 description 31
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 30
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 24
239000011541 reaction mixture Substances 0.000 description 21
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 20
239000011734 sodium Substances 0.000 description 20
229910052708 sodium Inorganic materials 0.000 description 20
AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 20
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 18
239000008186 active pharmaceutical agent Substances 0.000 description 18
238000003756 stirring Methods 0.000 description 18
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 17
230000015572 biosynthetic process Effects 0.000 description 15
238000007034 nitrosation reaction Methods 0.000 description 14
239000002585 base Substances 0.000 description 13
239000000376 reactant Substances 0.000 description 13
QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 13
239000000499 gel Substances 0.000 description 12
239000000463 material Substances 0.000 description 12
238000005670 sulfation reaction Methods 0.000 description 12
239000000543 intermediate Substances 0.000 description 11
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 10
239000004157 Nitrosyl chloride Substances 0.000 description 10
GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 10
239000007864 aqueous solution Substances 0.000 description 10
239000001110 calcium chloride Substances 0.000 description 10
229910001628 calcium chloride Inorganic materials 0.000 description 10
VPCDQGACGWYTMC-UHFFFAOYSA-N nitrosyl chloride Chemical compound ClN=O VPCDQGACGWYTMC-UHFFFAOYSA-N 0.000 description 10
235000019392 nitrosyl chloride Nutrition 0.000 description 10
CMOAHYOGLLEOGO-UHFFFAOYSA-N oxozirconium;dihydrochloride Chemical compound Cl.Cl.[Zr]=O CMOAHYOGLLEOGO-UHFFFAOYSA-N 0.000 description 10
230000019635 sulfation Effects 0.000 description 10
239000000370 acceptor Substances 0.000 description 9
150000002148 esters Chemical class 0.000 description 9
150000002826 nitrites Chemical class 0.000 description 9
239000011780 sodium chloride Substances 0.000 description 9
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 8
238000005553 drilling Methods 0.000 description 8
230000009935 nitrosation Effects 0.000 description 8
230000001180 sulfating effect Effects 0.000 description 8
239000000725 suspension Substances 0.000 description 7
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
241000157282 Aesculus Species 0.000 description 6
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
229920000742 Cotton Polymers 0.000 description 6
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
230000000694 effects Effects 0.000 description 6
230000032050 esterification Effects 0.000 description 6
238000005886 esterification reaction Methods 0.000 description 6
235000010181 horse chestnut Nutrition 0.000 description 6
230000003381 solubilizing effect Effects 0.000 description 6
230000008961 swelling Effects 0.000 description 6
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 5
235000011114 ammonium hydroxide Nutrition 0.000 description 5
230000008859 change Effects 0.000 description 5
238000006386 neutralization reaction Methods 0.000 description 5
239000001272 nitrous oxide Substances 0.000 description 5
239000003586 protic polar solvent Substances 0.000 description 5
239000007787 solid Substances 0.000 description 5
ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 4
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 4
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 4
239000002253 acid Substances 0.000 description 4
229910052784 alkaline earth metal Inorganic materials 0.000 description 4
239000000908 ammonium hydroxide Substances 0.000 description 4
239000003880 polar aprotic solvent Substances 0.000 description 4
238000001556 precipitation Methods 0.000 description 4
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 4
230000008719 thickening Effects 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 3
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
239000003513 alkali Substances 0.000 description 3
230000009286 beneficial effect Effects 0.000 description 3
WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical group OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 3
229910000019 calcium carbonate Inorganic materials 0.000 description 3
150000004649 carbonic acid derivatives Chemical class 0.000 description 3
XMPZTFVPEKAKFH-UHFFFAOYSA-P ceric ammonium nitrate Chemical compound [NH4+].[NH4+].[Ce+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O XMPZTFVPEKAKFH-UHFFFAOYSA-P 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
229940113088 dimethylacetamide Drugs 0.000 description 3
238000001035 drying Methods 0.000 description 3
230000007717 exclusion Effects 0.000 description 3
125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
238000006116 polymerization reaction Methods 0.000 description 3
229910000029 sodium carbonate Inorganic materials 0.000 description 3
229910052938 sodium sulfate Inorganic materials 0.000 description 3
235000011152 sodium sulphate Nutrition 0.000 description 3
150000003512 tertiary amines Chemical class 0.000 description 3
PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 2
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
150000001342 alkaline earth metals Chemical class 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
YKYOUMDCQGMQQO-UHFFFAOYSA-L cadmium dichloride Chemical compound Cl[Cd]Cl YKYOUMDCQGMQQO-UHFFFAOYSA-L 0.000 description 2
ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 2
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
238000001816 cooling Methods 0.000 description 2
239000002537 cosmetic Substances 0.000 description 2
239000003431 cross linking reagent Substances 0.000 description 2
239000011243 crosslinked material Substances 0.000 description 2
238000005520 cutting process Methods 0.000 description 2
230000007423 decrease Effects 0.000 description 2
239000008367 deionised water Substances 0.000 description 2
229910021641 deionized water Inorganic materials 0.000 description 2
WFPZPJSADLPSON-UHFFFAOYSA-N dinitrogen tetraoxide Chemical compound [O-][N+](=O)[N+]([O-])=O WFPZPJSADLPSON-UHFFFAOYSA-N 0.000 description 2
238000009826 distribution Methods 0.000 description 2
239000002360 explosive Substances 0.000 description 2
238000001914 filtration Methods 0.000 description 2
150000004679 hydroxides Chemical class 0.000 description 2
239000004615 ingredient Substances 0.000 description 2
AWJUIBRHMBBTKR-UHFFFAOYSA-N isoquinoline Chemical compound C1=NC=CC2=CC=CC=C21 AWJUIBRHMBBTKR-UHFFFAOYSA-N 0.000 description 2
229910001629 magnesium chloride Inorganic materials 0.000 description 2
VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 2
239000000347 magnesium hydroxide Substances 0.000 description 2
229910001862 magnesium hydroxide Inorganic materials 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
239000011159 matrix material Substances 0.000 description 2
230000007246 mechanism Effects 0.000 description 2
238000002156 mixing Methods 0.000 description 2
230000003472 neutralizing effect Effects 0.000 description 2
DCKVFVYPWDKYDN-UHFFFAOYSA-L oxygen(2-);titanium(4+);sulfate Chemical compound [O-2].[Ti+4].[O-]S([O-])(=O)=O DCKVFVYPWDKYDN-UHFFFAOYSA-L 0.000 description 2
239000000123 paper Substances 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
239000001103 potassium chloride Substances 0.000 description 2
235000011164 potassium chloride Nutrition 0.000 description 2
239000000843 powder Substances 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
239000012266 salt solution Substances 0.000 description 2
SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
239000001632 sodium acetate Substances 0.000 description 2
235000017281 sodium acetate Nutrition 0.000 description 2
238000003860 storage Methods 0.000 description 2
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
229910000348 titanium sulfate Inorganic materials 0.000 description 2
238000009827 uniform distribution Methods 0.000 description 2
238000005406 washing Methods 0.000 description 2
VNDYJBBGRKZCSX-UHFFFAOYSA-L zinc bromide Chemical compound Br[Zn]Br VNDYJBBGRKZCSX-UHFFFAOYSA-L 0.000 description 2
TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 1
WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
229910021555 Chromium Chloride Inorganic materials 0.000 description 1
FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
239000004593 Epoxy Substances 0.000 description 1
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
241000252067 Megalops atlanticus Species 0.000 description 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
239000000020 Nitrocellulose Substances 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
229920001131 Pulp (paper) Polymers 0.000 description 1
229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
229910006213 ZrOCl2 Inorganic materials 0.000 description 1
FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
VEUACKUBDLVUAC-UHFFFAOYSA-N [Na].[Ca] Chemical compound [Na].[Ca] VEUACKUBDLVUAC-UHFFFAOYSA-N 0.000 description 1
239000002250 absorbent Substances 0.000 description 1
230000002745 absorbent Effects 0.000 description 1
239000003377 acid catalyst Substances 0.000 description 1
230000003213 activating effect Effects 0.000 description 1
230000004913 activation Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
230000001476 alcoholic effect Effects 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
229910001854 alkali hydroxide Inorganic materials 0.000 description 1
229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 description 1
239000012670 alkaline solution Substances 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
ZNTDPNGPCIUBQZ-UHFFFAOYSA-I aluminum zirconium(4+) pentachloride Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Zr+4].[Al+3] ZNTDPNGPCIUBQZ-UHFFFAOYSA-I 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
229910052921 ammonium sulfate Inorganic materials 0.000 description 1
235000011130 ammonium sulphate Nutrition 0.000 description 1
239000000010 aprotic solvent Substances 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
239000000872 buffer Substances 0.000 description 1
239000006172 buffering agent Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910001622 calcium bromide Inorganic materials 0.000 description 1
WGEFECGEFUFIQW-UHFFFAOYSA-L calcium dibromide Chemical compound [Ca+2].[Br-].[Br-] WGEFECGEFUFIQW-UHFFFAOYSA-L 0.000 description 1
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
239000000920 calcium hydroxide Substances 0.000 description 1
229910001861 calcium hydroxide Inorganic materials 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
238000005119 centrifugation Methods 0.000 description 1
239000013522 chelant Substances 0.000 description 1
230000009920 chelation Effects 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
QSWDMMVNRMROPK-UHFFFAOYSA-K chromium(3+) trichloride Chemical compound [Cl-].[Cl-].[Cl-].[Cr+3] QSWDMMVNRMROPK-UHFFFAOYSA-K 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
239000012459 cleaning agent Substances 0.000 description 1
239000011362 coarse particle Substances 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
230000000536 complexating effect Effects 0.000 description 1
239000002826 coolant Substances 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
239000008121 dextrose Substances 0.000 description 1
RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 description 1
238000007599 discharging Methods 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
239000003814 drug Substances 0.000 description 1
239000000975 dye Substances 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
239000011790 ferrous sulphate Substances 0.000 description 1
235000003891 ferrous sulphate Nutrition 0.000 description 1
239000002657 fibrous material Substances 0.000 description 1
239000012530 fluid Substances 0.000 description 1
238000011010 flushing procedure Methods 0.000 description 1
238000001879 gelation Methods 0.000 description 1
229960001031 glucose Drugs 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
239000005457 ice water Substances 0.000 description 1
239000012535 impurity Substances 0.000 description 1
239000012442 inert solvent Substances 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
230000003993 interaction Effects 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
239000002655 kraft paper Substances 0.000 description 1
229940046892 lead acetate Drugs 0.000 description 1
TWNIBLMWSKIRAT-VFUOTHLCSA-N levoglucosan Chemical group O[C@@H]1[C@@H](O)[C@H](O)[C@H]2CO[C@@H]1O2 TWNIBLMWSKIRAT-VFUOTHLCSA-N 0.000 description 1
239000007788 liquid Substances 0.000 description 1
230000001050 lubricating effect Effects 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
238000005259 measurement Methods 0.000 description 1
BRMYZIKAHFEUFJ-UHFFFAOYSA-L mercury diacetate Chemical compound CC(=O)O[Hg]OC(C)=O BRMYZIKAHFEUFJ-UHFFFAOYSA-L 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
238000003801 milling Methods 0.000 description 1
235000010755 mineral Nutrition 0.000 description 1
239000011707 mineral Substances 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
AFDQGRURHDVABZ-UHFFFAOYSA-N n,n-dimethylformamide;sulfur trioxide Chemical compound O=S(=O)=O.CN(C)C=O AFDQGRURHDVABZ-UHFFFAOYSA-N 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
229920001220 nitrocellulos Polymers 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
150000002895 organic esters Chemical class 0.000 description 1
239000003973 paint Substances 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229920005862 polyol Polymers 0.000 description 1
150000003077 polyols Chemical class 0.000 description 1
239000011591 potassium Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
229910001414 potassium ion Inorganic materials 0.000 description 1
238000011084 recovery Methods 0.000 description 1
230000008929 regeneration Effects 0.000 description 1
238000011069 regeneration method Methods 0.000 description 1
239000011833 salt mixture Substances 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
230000028327 secretion Effects 0.000 description 1
238000000926 separation method Methods 0.000 description 1
238000007086 side reaction Methods 0.000 description 1
229910001961 silver nitrate Inorganic materials 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
239000000600 sorbitol Substances 0.000 description 1
239000007921 spray Substances 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
239000001119 stannous chloride Substances 0.000 description 1
235000011150 stannous chloride Nutrition 0.000 description 1
239000007858 starting material Substances 0.000 description 1
229910001631 strontium chloride Inorganic materials 0.000 description 1
AHBGXTDRMVNFER-UHFFFAOYSA-L strontium dichloride Chemical compound [Cl-].[Cl-].[Sr+2] AHBGXTDRMVNFER-UHFFFAOYSA-L 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000004753 textile Substances 0.000 description 1
239000002562 thickening agent Substances 0.000 description 1
125000005270 trialkylamine group Chemical group 0.000 description 1
238000005303 weighing Methods 0.000 description 1
238000009736 wetting Methods 0.000 description 1
229940102001 zinc bromide Drugs 0.000 description 1
NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
229910000368 zinc sulfate Inorganic materials 0.000 description 1
229960001763 zinc sulfate Drugs 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B15/00—Preparation of other cellulose derivatives or modified cellulose, e.g. complexes
- C08B15/005—Crosslinking of cellulose derivatives
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B5/00—Preparation of cellulose esters of inorganic acids, e.g. phosphates
- C08B5/14—Cellulose sulfate

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Biochemistry (AREA)
Materials Engineering (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Polysaccharides And Polysaccharide Derivatives (AREA)
Compositions Of Macromolecular Compounds (AREA)

NL8003883A 1979-07-05 1980-07-04 Werkwijze voor het verknopen van cellulosesulfaatesters met tetravalente metaalionen, als zodanig verkregen verknoopte produkten, samenstellingen van genoemde esters en metaalionen, alsmede waterige samenstellingen die genoemde produkten als verknopingsmiddel bevatten. NL8003883A (nl)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US5468379		1979-07-05
US06/054,683 US4242506A (en)	1979-07-05	1979-07-05	Cross-linking of cellulose sulfate esters with tetravalent metal ions

Publications (1)

Publication Number	Publication Date
NL8003883A true NL8003883A (nl)	1981-01-07

Family

ID=21992810

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NL8003883A NL8003883A (nl)	1979-07-05	1980-07-04	Werkwijze voor het verknopen van cellulosesulfaatesters met tetravalente metaalionen, als zodanig verkregen verknoopte produkten, samenstellingen van genoemde esters en metaalionen, alsmede waterige samenstellingen die genoemde produkten als verknopingsmiddel bevatten.

Country Status (15)

Country	Link
US (1)	US4242506A (it)
JP (1)	JPS5611901A (it)
AU (1)	AU5925180A (it)
BE (1)	BE884165A (it)
BR (1)	BR8004009A (it)
CA (1)	CA1127151A (it)
DE (1)	DE3025094A1 (it)
FI (1)	FI802012A7 (it)
FR (1)	FR2460963A1 (it)
GB (1)	GB2055105A (it)
IT (1)	IT1133031B (it)
NL (1)	NL8003883A (it)
NO (1)	NO802016L (it)
PH (1)	PH14735A (it)
SE (1)	SE8004956L (it)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4480091A (en) *	1983-10-31	1984-10-30	Eastman Kodak Company	Process for preparing cellulose sulfate esters
DE3546771C2 (it) *	1984-04-27	1993-08-12	Pioneer Electronic Corp., Tokio/Tokyo, Jp
US4664713A (en) *	1984-05-04	1987-05-12	Halliburton Company	Composition for and method of altering the permeability of a subterranean formation
US4707523A (en) *	1985-10-11	1987-11-17	California Institute Of Technology	Magnetic particles
US4889562A (en) *	1987-06-16	1989-12-26	Ciba-Geigy Corporation	Organic pigments coated with crosslinked ethyl cellulose
US5378828A (en) *	1993-09-02	1995-01-03	Dextran Products Limited	Process for preparing soluble alkali metal salts of cellulose sulfate using chlorosulfuric acid and pyridine
US5522967A (en) *	1994-05-27	1996-06-04	Kimberly-Clark Corporation	Sulfonated cellulose and method of preparation
US5703225A (en) *	1995-12-13	1997-12-30	Kimberly-Clark Worldwide, Inc.	Sulfonated cellulose having improved absorbent properties
US5907037A (en) *	1996-04-26	1999-05-25	Central Technology, Inc.	Cellulosic ion-exchange medium, and method of making and using the same
EP0813105A1 (en) *	1996-06-13	1997-12-17	Agfa-Gevaert N.V.	Recording materials and method for manufacturing said materials coated from hydrophilic layers having no gelatin or low amounts of gelatin
CA2396915A1 (en) *	2000-01-14	2001-07-19	Otsuka Pharmaceutical Factory, Inc.	Sodium ion absorption inhibitors, and preventive and therapeutic agents and foods containing the same
US6875862B2 (en) *	2001-01-29	2005-04-05	Daicel Chemical Industries, Ltd.	Self-cross-linked alkyl cellulose and processes for producing the same
US6500947B1 (en) *	2001-08-24	2002-12-31	Weyerhaeuser Company	Superabsorbent polymer
US20030035950A1 (en) *	2002-07-19	2003-02-20	Neogi Amar N.	Superabsorbent cellulosic fiber
US20030034136A1 (en) *	2002-07-19	2003-02-20	Neogi Amar N.	Superabsorbent cellulosic fiber
US20030106163A1 (en) *	2002-07-19	2003-06-12	Neogi Amar N.	Superabsorbent cellulosic fiber
US20030034137A1 (en) *	2002-07-19	2003-02-20	Neogi Amar N.	Superabsorbent cellulosic fiber
US20030024663A1 (en) *	2002-07-19	2003-02-06	Neogi Amar N.	Superabsorbent cellulosic fiber
US20060142484A1 (en) *	2004-12-29	2006-06-29	Glasser Wolfgang G	Sulfoalkylated cellulose polymer network
US20060142560A1 (en) *	2004-12-29	2006-06-29	Glasser Wolfgang G	Sulfoalkylated cellulose
DE102007035322B4 (de) *	2007-07-25	2011-11-17	Friedrich-Schiller-Universität Jena	Verfahren zur Herstellung wasserlöslicher, niedrig substituierter Cellulosesulfate

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3068063A (en) *		1962-12-11		Cellulose acetate spinning solutions
US3125458A (en) *	1960-05-20	1964-03-17		transparent
US3520960A (en) *	1967-03-22	1970-07-21	Allan S Douglas	Method of making microphorous cellulose nitrate films
US3793043A (en) *	1969-07-30	1974-02-19	Eastman Kodak Co	Cellulose ester dope solution containing inorganic chromium salts
US4141746A (en) *	1970-05-25	1979-02-27	Schweiger Richard Georg	Cellulose sulfate esters
US4138535A (en) *	1970-05-25	1979-02-06	Schweiger Richard Georg	Nitrite esters of polyhydroxy polymers
JPS4926944B1 (it) *	1970-12-30	1974-07-13
US3804174A (en) *	1973-07-20	1974-04-16	Halliburton Co	Well cementing method using thixotropic

1979
- 1979-07-05 US US06/054,683 patent/US4242506A/en not_active Expired - Lifetime
1980
- 1980-06-12 AU AU59251/80A patent/AU5925180A/en not_active Abandoned
- 1980-06-23 CA CA354,636A patent/CA1127151A/en not_active Expired
- 1980-06-23 FI FI802012A patent/FI802012A7/fi not_active Application Discontinuation
- 1980-06-26 GB GB802010A patent/GB2055105A/en not_active Withdrawn
- 1980-06-26 BR BR8004009A patent/BR8004009A/pt unknown
- 1980-07-01 PH PH24220A patent/PH14735A/en unknown
- 1980-07-01 FR FR8014614A patent/FR2460963A1/fr not_active Withdrawn
- 1980-07-02 DE DE19803025094 patent/DE3025094A1/de not_active Withdrawn
- 1980-07-03 IT IT49151/80A patent/IT1133031B/it active
- 1980-07-04 SE SE8004956A patent/SE8004956L/xx unknown
- 1980-07-04 NO NO802016A patent/NO802016L/no unknown
- 1980-07-04 JP JP9079780A patent/JPS5611901A/ja active Pending
- 1980-07-04 BE BE2/58640A patent/BE884165A/fr unknown
- 1980-07-04 NL NL8003883A patent/NL8003883A/nl not_active Application Discontinuation

Also Published As

Publication number	Publication date
PH14735A (en)	1981-11-19
IT8049151A0 (it)	1980-07-03
IT1133031B (it)	1986-07-09
BE884165A (fr)	1980-11-03
CA1127151A (en)	1982-07-06
FI802012A7 (fi)	1981-01-01
AU5925180A (en)	1981-01-15
JPS5611901A (en)	1981-02-05
FR2460963A1 (fr)	1981-01-30
DE3025094A1 (de)	1981-02-19
GB2055105A (en)	1981-02-25
US4242506A (en)	1980-12-30
NO802016L (no)	1981-01-06
SE8004956L (sv)	1981-01-06
BR8004009A (pt)	1981-01-21

Legal Events

Date	Code	Title	Description
1983-03-01	BV	The patent application has lapsed

Publication	Publication Date	Title
NL8003883A (nl)	1981-01-07	Werkwijze voor het verknopen van cellulosesulfaatesters met tetravalente metaalionen, als zodanig verkregen verknoopte produkten, samenstellingen van genoemde esters en metaalionen, alsmede waterige samenstellingen die genoemde produkten als verknopingsmiddel bevatten.
EP2552968B1 (en)	2017-03-01	New high viscosity carboxymethyl cellulose and method of preparation
US3702843A (en)	1972-11-14	Nitrite,nitrate and sulfate esters of polyhydroxy polymers
US4096326A (en)	1978-06-20	Dihydroxypropyl cellulose
US3892731A (en)	1975-07-01	Solvents for and purification of chitin
US4141746A (en)	1979-02-27	Cellulose sulfate esters
JPS58500485A (ja)	1983-03-31	ヘパリンの調節解重合による生物学的活性の高純度ムコ多糖類の製法
US4138535A (en)	1979-02-06	Nitrite esters of polyhydroxy polymers
US4035569A (en)	1977-07-12	Preparation of cellulose nitrite
JP2003523459A (ja)	2003-08-05	キトサン縮合生成物、その製造及び使用
CN1961005B (zh)	2010-05-26	低分子量乙基纤维素的生产
NO821071L (no)	1982-10-01	Geldannende sammensetning paa basis av en celluloseeter, fremgangsmaate til fremstilling av en gel, fremgangsmaate til reversibel oppheving av gelen og dens anvendelse ved sekundaerbefordring av jordolje
US3098869A (en)	1963-07-23	Preparation of dialdehyde polysaccharide addition products
US4177345A (en)	1979-12-04	Process for preparing a sulfate ester of a polyhydroxy polymer
JP2026512702A (ja)	2026-04-20	新規カルボキシメチルセルロース及びその調製方法
JP2008507602A (ja)	2008-03-13	アミノ酸含有セルロース誘導体の製造方法及び化粧品配合物、水処理及び製紙でのそれらの使用
CN101343329A (zh)	2009-01-14	多种羟烷基纤维素醚硝酸酯及其制备方法
US4419316A (en)	1983-12-06	Process of making films, fibers or other shaped articles consisting of, or containing, polyhydroxy polymers
US1242030A (en)	1917-10-02	Process of preparing solutions of cellulose.
CA1328256C (en)	1994-04-05	Treatment of granular starch slurries with concentrated aqueous alkaline solutions
USRE30459E (en)	1980-12-23	Nitrite esters of polyhydroxy polymers
FR2490657A1 (fr)	1982-03-26	Procede d'obtention d'une suspension aqueuse de polymere hydrophile et obtention d'une saumure servant a l'entretien des puits
US2199386A (en)	1940-05-07	Granular article containing cellulose ethers and shellac
JPH0127084B2 (it)	1989-05-26
JPS59206468A (ja)	1984-11-22	光活性化剤濃厚水溶液のゲル化を防止するための方法