NL8004886A - Werkwijze ter bereiding van selectieve mengsels van piperazine en ethyleendiamine. - Google Patents

Werkwijze ter bereiding van selectieve mengsels van piperazine en ethyleendiamine. Download PDF

Info

Publication number: NL8004886A
Authority: NL; Netherlands
Prior art keywords: piperazine; hydrogen; monoethanolamine; ethylenediamine; catalyst
Prior art date: 1979-09-24

Application number

NL8004886A

Other languages

English (en)

Dutch (nl)

Original Assignee

Texaco Development Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-09-24

Filing date

1980-08-28

Publication date

1981-03-26

1980-08-28 Application filed by Texaco Development Corp filed Critical Texaco Development Corp

1981-03-26 Publication of NL8004886A publication Critical patent/NL8004886A/nl

Links

GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 title claims description 38
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 title claims description 16
239000000203 mixture Substances 0.000 title claims description 11
238000004519 manufacturing process Methods 0.000 title description 5
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 28
229910052739 hydrogen Inorganic materials 0.000 claims description 23
239000001257 hydrogen Substances 0.000 claims description 23
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 21
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 20
238000006243 chemical reaction Methods 0.000 claims description 20
239000003054 catalyst Substances 0.000 claims description 19
238000000034 method Methods 0.000 claims description 14
229910021529 ammonia Inorganic materials 0.000 claims description 10
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
235000016709 nutrition Nutrition 0.000 claims description 4
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
229910052802 copper Inorganic materials 0.000 claims description 3
239000010949 copper Substances 0.000 claims description 3
229910052751 metal Inorganic materials 0.000 claims description 3
239000002184 metal Substances 0.000 claims description 3
150000002739 metals Chemical class 0.000 claims description 3
229910052759 nickel Inorganic materials 0.000 claims description 3
229910052804 chromium Inorganic materials 0.000 claims description 2
239000011651 chromium Substances 0.000 claims description 2
GXDVEXJTVGRLNW-UHFFFAOYSA-N [Cr].[Cu] Chemical compound [Cr].[Cu] GXDVEXJTVGRLNW-UHFFFAOYSA-N 0.000 claims 1
229910044991 metal oxide Inorganic materials 0.000 claims 1
XRBURMNBUVEAKD-UHFFFAOYSA-N chromium copper nickel Chemical compound [Cr].[Ni].[Cu] XRBURMNBUVEAKD-UHFFFAOYSA-N 0.000 description 3
239000007788 liquid Substances 0.000 description 3
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
230000007423 decrease Effects 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
238000005984 hydrogenation reaction Methods 0.000 description 2
PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
BSDZCOOBOBLWAW-UHFFFAOYSA-N [O-2].[Cr+3].[Cu+2].[Ni+2] Chemical compound [O-2].[Cr+3].[Cu+2].[Ni+2] BSDZCOOBOBLWAW-UHFFFAOYSA-N 0.000 description 1
238000010923 batch production Methods 0.000 description 1
239000003610 charcoal Substances 0.000 description 1
150000004985 diamines Chemical class 0.000 description 1
238000004821 distillation Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000003754 machining Methods 0.000 description 1
230000035764 nutrition Effects 0.000 description 1
239000008188 pellet Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
- C07D295/023—Preparation; Separation; Stabilisation; Use of additives

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)

NL8004886A 1979-09-24 1980-08-28 Werkwijze ter bereiding van selectieve mengsels van piperazine en ethyleendiamine. NL8004886A (nl)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US7811779		1979-09-24
US06/078,117 US4234730A (en)	1979-09-24	1979-09-24	Process of preparing selective mixtures of piperazine and ethylenediamine

Publications (1)

Publication Number	Publication Date
NL8004886A true NL8004886A (nl)	1981-03-26

Family

ID=22142001

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NL8004886A NL8004886A (nl)	1979-09-24	1980-08-28	Werkwijze ter bereiding van selectieve mengsels van piperazine en ethyleendiamine.

Country Status (10)

Country	Link
US (1)	US4234730A (fr)
JP (1)	JPS5646847A (fr)
BR (1)	BR8004840A (fr)
CA (1)	CA1138462A (fr)
DE (1)	DE3034000A1 (fr)
FR (1)	FR2465730B1 (fr)
GB (1)	GB2058755B (fr)
MX (1)	MX6504E (fr)
NL (1)	NL8004886A (fr)
SE (1)	SE447110B (fr)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5410086A (en) *	1989-06-27	1995-04-25	Burgess; Lloyd M.	Selective preparation of diethylenetriamine
DE10335991A1 (de) *	2003-08-01	2005-02-24	Basf Ag	Verfahren zur Herstellung von Ethylenaminen
US7635790B2 (en) *	2006-02-14	2009-12-22	Basf Se	Method for producing ethylene amines and ethanol amines by the hydrogenating amination of monoethylene glycol and ammonia in the presence of a catalyst
RU2480449C2 (ru) *	2007-08-29	2013-04-27	Басф Се	Способ получения аминов из глицерина
CN102002020B (zh) *	2010-11-24	2012-05-30	西安近代化学研究所	一种精制哌嗪的方法
CN102153526B (zh) *	2010-12-20	2012-06-27	金坛市爱特生物科技有限公司	一种n-叔丁氧羰基哌嗪的合成方法
CN103159630B (zh) *	2011-12-14	2015-05-20	中国科学院大连化学物理研究所	一种以乙醇胺和氨为原料制备乙二胺的方法
CN102895978B (zh) *	2012-10-19	2014-11-12	南京信息工程大学	一种用于合成多氨基化合物的催化剂及其制备方法与应用
CN105080595B (zh) *	2015-07-27	2017-10-20	河北科技大学	一种乙二胺合成哌嗪反应专用催化剂的制备方法
CN110776430B (zh) *	2018-07-31	2022-10-14	中国石油化工股份有限公司	一种三(2-氨基乙基)胺的制备方法
CN119930438B (zh) *	2025-01-22	2025-11-21	河北工业大学	一种制备乙二胺的方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3126383A (en) *		1964-03-24		Method for recovering alkylamine-free
FR1186341A (fr) *	1956-09-25	1959-08-20	Jefferson Chem Co Inc	Procédé pour la préparation de la pipérazine
US3037023A (en) *	1957-06-03	1962-05-29	Jefferson Chem Co Inc	Process for preparation of piperazine
FR1176880A (fr) *	1957-06-27	1959-04-16	Dow Chemical Co	Procédé de conversion de l'éthanolamine
US3112318A (en) *	1957-10-09	1963-11-26	Union Carbide Corp	Method for producing piperazine
NL134685C (fr) *	1960-06-08

1979
- 1979-09-24 US US06/078,117 patent/US4234730A/en not_active Expired - Lifetime
1980
- 1980-05-13 JP JP6236080A patent/JPS5646847A/ja active Granted
- 1980-07-11 CA CA000356049A patent/CA1138462A/fr not_active Expired
- 1980-08-01 BR BR8004840A patent/BR8004840A/pt unknown
- 1980-08-05 GB GB8025438A patent/GB2058755B/en not_active Expired
- 1980-08-25 MX MX808992U patent/MX6504E/es unknown
- 1980-08-28 NL NL8004886A patent/NL8004886A/nl not_active Application Discontinuation
- 1980-09-10 DE DE19803034000 patent/DE3034000A1/de not_active Withdrawn
- 1980-09-22 FR FR8020316A patent/FR2465730B1/fr not_active Expired
- 1980-09-23 SE SE8006644A patent/SE447110B/sv not_active IP Right Cessation

Also Published As

Publication number	Publication date
SE447110B (sv)	1986-10-27
SE8006644L (sv)	1981-03-25
FR2465730A1 (fr)	1981-03-27
FR2465730B1 (fr)	1988-05-20
JPS5646847A (en)	1981-04-28
US4234730A (en)	1980-11-18
JPH025738B2 (fr)	1990-02-05
DE3034000A1 (de)	1981-04-09
MX6504E (es)	1985-06-24
GB2058755B (en)	1984-06-06
GB2058755A (en)	1981-04-15
CA1138462A (fr)	1982-12-28
BR8004840A (pt)	1981-04-28

Legal Events

Date	Code	Title
1983-10-03	BA	A request for search or an international-type search has been filed
1983-10-03	BB	A search report has been drawn up
1985-01-01	A85	Still pending on 85-01-01
1987-10-01	BC	A request for examination has been filed
1993-04-01	BV	The patent application has lapsed

Publication	Publication Date	Title
US6548697B1 (en)	2003-04-15	Oxidation process for the production of alkenes and carboxylic acids
NL8004886A (nl)	1981-03-26	Werkwijze ter bereiding van selectieve mengsels van piperazine en ethyleendiamine.
KR100550202B1 (ko)	2006-02-08	1,6-헥산디올 및 6-히드록시카프로산 또는 그의에스테르의 제조 방법
EP0055512A1 (fr)	1982-07-07	Procédé de synthèse du 1-4-butanediol et du tétrahydrofuranne
KR19990063640A (ko)	1999-07-26	비닐 아세테이트 및/또는 아세트산의 통합 제조 방법
RU2275351C2 (ru)	2006-04-27	Способ окисления с получением алкенов и карбоновых кислот
NO328031B1 (no)	2009-11-10	Integrert fremgangsmate for fremstilling av vinylacetat
RU2001108529A (ru)	2003-04-20	Способ получения уксусной кислоты
EP0031693A1 (fr)	1981-07-08	Catalyseurs d'antimoniate d'étain avec promoteurs et leur utilisation
EP0037149A1 (fr)	1981-10-07	Procédé pour la préparation d'aldéhydes
WO2003055838A1 (fr)	2003-07-10	Procede integre de production de carboxylates d'alcenyle
US4225729A (en)	1980-09-30	Process for hydrogenation of diacetoxybutene
EP0069514A2 (fr)	1983-01-12	Catalyseurs pour la carboxylation d'alcools
KR0130195B1 (ko)	1998-04-07	에틸아민의 합성 방법
EP0584408A2 (fr)	1994-03-02	Procédé pour la préparation de gamma-butyrolactone
DE69424899T2 (de)	2001-02-08	Verfahren zur Herstellung von Essigsäure
EP0183160B1 (fr)	1990-03-14	Procédé pour la préparation d'indole
EP0171206B1 (fr)	1988-12-07	Préparation d'hydrocarbures et d'hydrocarbures oxydés
US4978803A (en)	1990-12-18	Vapor phase oxidation process for making glyoxal
KR100689647B1 (ko)	2007-03-09	비닐 아세테이트의 통합된 제조방법
GB1560694A (en)	1980-02-06	Process for producing butanediol or butenediol
NL8003396A (nl)	1980-12-16	Werkwijze voor het isomeriseren van diacetoxybutenen.
JPS6121215B2 (fr)	1986-05-26
KR800000056B1 (ko)	1980-01-29	몰폴린 화합물과 2-(2-아미노에톡시)에탄올 화합물을 동시에 제조하는 방법
JP2744087B2 (ja)	1998-04-28	第３級ブチルアルコールから過酸化物不純物を除去するための触媒