SE447110B - Sett vid framstellning av blandningar av piperazin och etylendiamin - Google Patents
Sett vid framstellning av blandningar av piperazin och etylendiaminInfo
- Publication number
- SE447110B SE447110B SE8006644A SE8006644A SE447110B SE 447110 B SE447110 B SE 447110B SE 8006644 A SE8006644 A SE 8006644A SE 8006644 A SE8006644 A SE 8006644A SE 447110 B SE447110 B SE 447110B
- Authority
- SE
- Sweden
- Prior art keywords
- piperazine
- monoethanolamine
- hydrogen
- ratio
- nickel
- Prior art date
Links
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 title claims description 24
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 title claims description 12
- 239000000203 mixture Substances 0.000 title claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 15
- 239000001257 hydrogen Substances 0.000 claims description 15
- 229910052739 hydrogen Inorganic materials 0.000 claims description 15
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 14
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 14
- 239000003054 catalyst Substances 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 12
- 229910021529 ammonia Inorganic materials 0.000 claims description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- XRBURMNBUVEAKD-UHFFFAOYSA-N chromium copper nickel Chemical compound [Cr].[Ni].[Cu] XRBURMNBUVEAKD-UHFFFAOYSA-N 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 150000002739 metals Chemical class 0.000 claims description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 239000011651 chromium Substances 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims 1
- 229910000423 chromium oxide Inorganic materials 0.000 claims 1
- 229910000431 copper oxide Inorganic materials 0.000 claims 1
- 229910000480 nickel oxide Inorganic materials 0.000 claims 1
- 239000007788 liquid Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- BSDZCOOBOBLWAW-UHFFFAOYSA-N [O-2].[Cr+3].[Cu+2].[Ni+2] Chemical compound [O-2].[Cr+3].[Cu+2].[Ni+2] BSDZCOOBOBLWAW-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
- C07D295/023—Preparation; Separation; Stabilisation; Use of additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/078,117 US4234730A (en) | 1979-09-24 | 1979-09-24 | Process of preparing selective mixtures of piperazine and ethylenediamine |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| SE8006644L SE8006644L (sv) | 1981-03-25 |
| SE447110B true SE447110B (sv) | 1986-10-27 |
Family
ID=22142001
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE8006644A SE447110B (sv) | 1979-09-24 | 1980-09-23 | Sett vid framstellning av blandningar av piperazin och etylendiamin |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4234730A (fr) |
| JP (1) | JPS5646847A (fr) |
| BR (1) | BR8004840A (fr) |
| CA (1) | CA1138462A (fr) |
| DE (1) | DE3034000A1 (fr) |
| FR (1) | FR2465730B1 (fr) |
| GB (1) | GB2058755B (fr) |
| MX (1) | MX6504E (fr) |
| NL (1) | NL8004886A (fr) |
| SE (1) | SE447110B (fr) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5410086A (en) * | 1989-06-27 | 1995-04-25 | Burgess; Lloyd M. | Selective preparation of diethylenetriamine |
| DE10335991A1 (de) * | 2003-08-01 | 2005-02-24 | Basf Ag | Verfahren zur Herstellung von Ethylenaminen |
| US7635790B2 (en) * | 2006-02-14 | 2009-12-22 | Basf Se | Method for producing ethylene amines and ethanol amines by the hydrogenating amination of monoethylene glycol and ammonia in the presence of a catalyst |
| RU2480449C2 (ru) * | 2007-08-29 | 2013-04-27 | Басф Се | Способ получения аминов из глицерина |
| CN102002020B (zh) * | 2010-11-24 | 2012-05-30 | 西安近代化学研究所 | 一种精制哌嗪的方法 |
| CN102153526B (zh) * | 2010-12-20 | 2012-06-27 | 金坛市爱特生物科技有限公司 | 一种n-叔丁氧羰基哌嗪的合成方法 |
| CN103159630B (zh) * | 2011-12-14 | 2015-05-20 | 中国科学院大连化学物理研究所 | 一种以乙醇胺和氨为原料制备乙二胺的方法 |
| CN102895978B (zh) * | 2012-10-19 | 2014-11-12 | 南京信息工程大学 | 一种用于合成多氨基化合物的催化剂及其制备方法与应用 |
| CN105080595B (zh) * | 2015-07-27 | 2017-10-20 | 河北科技大学 | 一种乙二胺合成哌嗪反应专用催化剂的制备方法 |
| CN110776430B (zh) * | 2018-07-31 | 2022-10-14 | 中国石油化工股份有限公司 | 一种三(2-氨基乙基)胺的制备方法 |
| CN119930438B (zh) * | 2025-01-22 | 2025-11-21 | 河北工业大学 | 一种制备乙二胺的方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3126383A (en) * | 1964-03-24 | Method for recovering alkylamine-free | ||
| FR1186341A (fr) * | 1956-09-25 | 1959-08-20 | Jefferson Chem Co Inc | Procédé pour la préparation de la pipérazine |
| US3037023A (en) * | 1957-06-03 | 1962-05-29 | Jefferson Chem Co Inc | Process for preparation of piperazine |
| FR1176880A (fr) * | 1957-06-27 | 1959-04-16 | Dow Chemical Co | Procédé de conversion de l'éthanolamine |
| US3112318A (en) * | 1957-10-09 | 1963-11-26 | Union Carbide Corp | Method for producing piperazine |
| NL134685C (fr) * | 1960-06-08 |
-
1979
- 1979-09-24 US US06/078,117 patent/US4234730A/en not_active Expired - Lifetime
-
1980
- 1980-05-13 JP JP6236080A patent/JPS5646847A/ja active Granted
- 1980-07-11 CA CA000356049A patent/CA1138462A/fr not_active Expired
- 1980-08-01 BR BR8004840A patent/BR8004840A/pt unknown
- 1980-08-05 GB GB8025438A patent/GB2058755B/en not_active Expired
- 1980-08-25 MX MX808992U patent/MX6504E/es unknown
- 1980-08-28 NL NL8004886A patent/NL8004886A/nl not_active Application Discontinuation
- 1980-09-10 DE DE19803034000 patent/DE3034000A1/de not_active Withdrawn
- 1980-09-22 FR FR8020316A patent/FR2465730B1/fr not_active Expired
- 1980-09-23 SE SE8006644A patent/SE447110B/sv not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| SE8006644L (sv) | 1981-03-25 |
| FR2465730A1 (fr) | 1981-03-27 |
| FR2465730B1 (fr) | 1988-05-20 |
| JPS5646847A (en) | 1981-04-28 |
| NL8004886A (nl) | 1981-03-26 |
| US4234730A (en) | 1980-11-18 |
| JPH025738B2 (fr) | 1990-02-05 |
| DE3034000A1 (de) | 1981-04-09 |
| MX6504E (es) | 1985-06-24 |
| GB2058755B (en) | 1984-06-06 |
| GB2058755A (en) | 1981-04-15 |
| CA1138462A (fr) | 1982-12-28 |
| BR8004840A (pt) | 1981-04-28 |
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