NL8201574A - Werkwijze voor het bereiden van een vaste katalytische titaankomponent en werkwijze voor het polymeriseren van alkenen-1 onder toepassing van een dergelijke titaankomponent. - Google Patents

Werkwijze voor het bereiden van een vaste katalytische titaankomponent en werkwijze voor het polymeriseren van alkenen-1 onder toepassing van een dergelijke titaankomponent. Download PDF

Info

Publication number: NL8201574A
Authority: NL; Netherlands
Prior art keywords: titanium; aluminum; compound; halide; magnesium
Prior art date: 1982-04-15

Application number

NL8201574A

Other languages

English (en)

Dutch (nl)

Original Assignee

Stamicarbon

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1982-04-15

Filing date

1982-04-15

Publication date

1983-11-01

1982-04-15 Application filed by Stamicarbon filed Critical Stamicarbon

1982-04-15 Priority to NL8201574A priority Critical patent/NL8201574A/nl

1983-04-13 Priority to EP83200525A priority patent/EP0093464B1/de

1983-04-13 Priority to AT83200525T priority patent/ATE22090T1/de

1983-04-13 Priority to DE8383200525T priority patent/DE3365983D1/de

1983-04-14 Priority to CA000425825A priority patent/CA1199317A/en

1983-04-15 Priority to JP58066860A priority patent/JPS58189207A/ja

1983-08-23 Priority to US06/525,825 priority patent/US4546092A/en

1983-11-01 Publication of NL8201574A publication Critical patent/NL8201574A/nl

Links

RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title claims abstract description 43
238000000034 method Methods 0.000 title claims abstract description 30
230000003197 catalytic effect Effects 0.000 title claims description 9
230000000379 polymerizing effect Effects 0.000 title claims description 6
238000004519 manufacturing process Methods 0.000 title claims description 3
-1 titanium halide compound Chemical class 0.000 claims abstract description 76
239000010936 titanium Substances 0.000 claims abstract description 73
229910052719 titanium Inorganic materials 0.000 claims abstract description 69
229910052782 aluminium Inorganic materials 0.000 claims abstract description 26
239000007788 liquid Substances 0.000 claims abstract description 13
239000002904 solvent Substances 0.000 claims abstract description 13
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 10
239000005977 Ethylene Substances 0.000 claims abstract description 10
229920000642 polymer Polymers 0.000 claims abstract description 10
239000003054 catalyst Substances 0.000 claims abstract description 9
238000000227 grinding Methods 0.000 claims abstract description 8
238000001556 precipitation Methods 0.000 claims abstract description 7
239000003960 organic solvent Substances 0.000 claims abstract description 6
150000001875 compounds Chemical class 0.000 claims description 20
125000004432 carbon atom Chemical group C* 0.000 claims description 15
239000011777 magnesium Substances 0.000 claims description 12
229910052749 magnesium Inorganic materials 0.000 claims description 12
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 9
150000002148 esters Chemical class 0.000 claims description 9
239000007787 solid Substances 0.000 claims description 9
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
125000005843 halogen group Chemical group 0.000 claims description 5
229910052751 metal Inorganic materials 0.000 claims description 5
239000002184 metal Substances 0.000 claims description 5
150000002736 metal compounds Chemical class 0.000 claims description 5
125000002524 organometallic group Chemical group 0.000 claims description 5
150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 4
125000001931 aliphatic group Chemical group 0.000 claims description 3
150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 3
125000003118 aryl group Chemical group 0.000 claims description 3
239000003795 chemical substances by application Substances 0.000 claims description 3
230000002140 halogenating effect Effects 0.000 claims description 3
150000002681 magnesium compounds Chemical class 0.000 claims description 3
229910052760 oxygen Inorganic materials 0.000 claims description 3
239000001301 oxygen Substances 0.000 claims description 3
239000004215 Carbon black (E152) Substances 0.000 claims description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
229930195733 hydrocarbon Natural products 0.000 claims description 2
150000007524 organic acids Chemical class 0.000 claims description 2
230000000737 periodic effect Effects 0.000 claims description 2
239000003599 detergent Substances 0.000 claims 1
125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
229910001507 metal halide Inorganic materials 0.000 claims 1
150000005309 metal halides Chemical class 0.000 claims 1
229910052736 halogen Inorganic materials 0.000 abstract description 10
150000002367 halogens Chemical class 0.000 abstract description 10
238000005406 washing Methods 0.000 abstract description 6
239000004743 Polypropylene Substances 0.000 abstract description 5
230000000694 effects Effects 0.000 abstract description 4
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 3
239000002685 polymerization catalyst Substances 0.000 abstract description 3
229920001155 polypropylene Polymers 0.000 abstract description 3
239000000843 powder Substances 0.000 abstract 1
239000000047 product Substances 0.000 description 14
238000006116 polymerization reaction Methods 0.000 description 12
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 10
MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 10
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 9
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 6
NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 6
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
125000000217 alkyl group Chemical group 0.000 description 5
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 5
150000002430 hydrocarbons Chemical group 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 4
239000000460 chlorine Substances 0.000 description 4
239000002270 dispersing agent Substances 0.000 description 4
239000000203 mixture Substances 0.000 description 4
239000002244 precipitate Substances 0.000 description 4
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 4
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 3
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
229910003074 TiCl4 Inorganic materials 0.000 description 3
239000002253 acid Substances 0.000 description 3
125000005234 alkyl aluminium group Chemical group 0.000 description 3
229920001400 block copolymer Polymers 0.000 description 3
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 3
239000001273 butane Substances 0.000 description 3
229910052801 chlorine Inorganic materials 0.000 description 3
239000007789 gas Substances 0.000 description 3
239000001257 hydrogen Substances 0.000 description 3
229910052739 hydrogen Inorganic materials 0.000 description 3
239000000178 monomer Substances 0.000 description 3
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 3
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
239000000243 solution Substances 0.000 description 3
239000000725 suspension Substances 0.000 description 3
CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 3
239000008096 xylene Substances 0.000 description 3
150000003738 xylenes Chemical class 0.000 description 3
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
WNZQDUSMALZDQF-UHFFFAOYSA-N 2-benzofuran-1(3H)-one Chemical compound C1=CC=C2C(=O)OCC2=C1 WNZQDUSMALZDQF-UHFFFAOYSA-N 0.000 description 2
YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
FHUODBDRWMIBQP-UHFFFAOYSA-N Ethyl p-anisate Chemical compound CCOC(=O)C1=CC=C(OC)C=C1 FHUODBDRWMIBQP-UHFFFAOYSA-N 0.000 description 2
UUGLJVMIFJNVFH-UHFFFAOYSA-N Hexyl benzoate Chemical compound CCCCCCOC(=O)C1=CC=CC=C1 UUGLJVMIFJNVFH-UHFFFAOYSA-N 0.000 description 2
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
ZYSISUVVLXHRAH-UHFFFAOYSA-K [Mg].[Al+3].[Cl-].[Cl-].[Cl-] Chemical compound [Mg].[Al+3].[Cl-].[Cl-].[Cl-] ZYSISUVVLXHRAH-UHFFFAOYSA-K 0.000 description 2
239000000654 additive Substances 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 2
SESFRYSPDFLNCH-UHFFFAOYSA-N benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 description 2
SIPUZPBQZHNSDW-UHFFFAOYSA-N bis(2-methylpropyl)aluminum Chemical compound CC(C)C[Al]CC(C)C SIPUZPBQZHNSDW-UHFFFAOYSA-N 0.000 description 2
229910052794 bromium Inorganic materials 0.000 description 2
MOWCKQDNXMYJOF-UHFFFAOYSA-M butyl-chloro-methylalumane Chemical compound CCCC[Al](C)Cl MOWCKQDNXMYJOF-UHFFFAOYSA-M 0.000 description 2
239000012876 carrier material Substances 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
150000004796 dialkyl magnesium compounds Chemical class 0.000 description 2
VJRUISVXILMZSL-UHFFFAOYSA-M dibutylalumanylium;chloride Chemical compound CCCC[Al](Cl)CCCC VJRUISVXILMZSL-UHFFFAOYSA-M 0.000 description 2
HJXBDPDUCXORKZ-UHFFFAOYSA-N diethylalumane Chemical compound CC[AlH]CC HJXBDPDUCXORKZ-UHFFFAOYSA-N 0.000 description 2
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 2
USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
238000009826 distribution Methods 0.000 description 2
229940052296 esters of benzoic acid for local anesthesia Drugs 0.000 description 2
150000002170 ethers Chemical class 0.000 description 2
FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
238000001914 filtration Methods 0.000 description 2
150000004820 halides Chemical class 0.000 description 2
239000012433 hydrogen halide Substances 0.000 description 2
229910000039 hydrogen halide Inorganic materials 0.000 description 2
229910052740 iodine Inorganic materials 0.000 description 2
239000011630 iodine Substances 0.000 description 2
239000001282 iso-butane Substances 0.000 description 2
239000007791 liquid phase Substances 0.000 description 2
239000000395 magnesium oxide Substances 0.000 description 2
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
KJJBSBKRXUVBMX-UHFFFAOYSA-N magnesium;butane Chemical compound [Mg+2].CCC[CH2-].CCC[CH2-] KJJBSBKRXUVBMX-UHFFFAOYSA-N 0.000 description 2
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 2
TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
238000003801 milling Methods 0.000 description 2
LPNBBFKOUUSUDB-UHFFFAOYSA-N p-toluenecarboxylic acid Natural products CC1=CC=C(C(O)=O)C=C1 LPNBBFKOUUSUDB-UHFFFAOYSA-N 0.000 description 2
239000002245 particle Substances 0.000 description 2
OSORMYZMWHVFOZ-UHFFFAOYSA-N phenethyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCCC1=CC=CC=C1 OSORMYZMWHVFOZ-UHFFFAOYSA-N 0.000 description 2
230000037048 polymerization activity Effects 0.000 description 2
229910001220 stainless steel Inorganic materials 0.000 description 2
239000010935 stainless steel Substances 0.000 description 2
ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 2
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 2
LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 2
CNWZYDSEVLFSMS-UHFFFAOYSA-N tripropylalumane Chemical compound CCC[Al](CCC)CCC CNWZYDSEVLFSMS-UHFFFAOYSA-N 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
WOYWLLHHWAMFCB-UHFFFAOYSA-N 2-ethylhexyl acetate Chemical compound CCCCC(CC)COC(C)=O WOYWLLHHWAMFCB-UHFFFAOYSA-N 0.000 description 1
RFONJRMUUALMBA-UHFFFAOYSA-N 2-methanidylpropane Chemical compound CC(C)[CH2-] RFONJRMUUALMBA-UHFFFAOYSA-N 0.000 description 1
GOLORTLGFDVFDW-UHFFFAOYSA-N 3-(1h-benzimidazol-2-yl)-7-(diethylamino)chromen-2-one Chemical compound C1=CC=C2NC(C3=CC4=CC=C(C=C4OC3=O)N(CC)CC)=NC2=C1 GOLORTLGFDVFDW-UHFFFAOYSA-N 0.000 description 1
ZEYHEAKUIGZSGI-UHFFFAOYSA-N 4-methoxybenzoic acid Chemical compound COC1=CC=C(C(O)=O)C=C1 ZEYHEAKUIGZSGI-UHFFFAOYSA-N 0.000 description 1
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
235000016068 Berberis vulgaris Nutrition 0.000 description 1
241000335053 Beta vulgaris Species 0.000 description 1
MVECFARLYQAUNR-UHFFFAOYSA-N CCCC[Mg]CC Chemical compound CCCC[Mg]CC MVECFARLYQAUNR-UHFFFAOYSA-N 0.000 description 1
KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
YYLLIJHXUHJATK-UHFFFAOYSA-N Cyclohexyl acetate Chemical compound CC(=O)OC1CCCCC1 YYLLIJHXUHJATK-UHFFFAOYSA-N 0.000 description 1
VUXKVKAHWOVIDN-UHFFFAOYSA-N Cyclohexyl formate Chemical compound O=COC1CCCCC1 VUXKVKAHWOVIDN-UHFFFAOYSA-N 0.000 description 1
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
ICMAFTSLXCXHRK-UHFFFAOYSA-N Ethyl pentanoate Chemical compound CCCCC(=O)OCC ICMAFTSLXCXHRK-UHFFFAOYSA-N 0.000 description 1
KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical class O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
JGFBQFKZKSSODQ-UHFFFAOYSA-N Isothiocyanatocyclopropane Chemical compound S=C=NC1CC1 JGFBQFKZKSSODQ-UHFFFAOYSA-N 0.000 description 1
239000002879 Lewis base Substances 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical class OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
CLGLRNZWNSOYFG-UHFFFAOYSA-M [I-].C(CCCCCCCCC)[Mg+] Chemical compound [I-].C(CCCCCCCCC)[Mg+] CLGLRNZWNSOYFG-UHFFFAOYSA-M 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
150000004703 alkoxides Chemical class 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
125000005907 alkyl ester group Chemical group 0.000 description 1
150000001350 alkyl halides Chemical class 0.000 description 1
150000004791 alkyl magnesium halides Chemical class 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
229940072049 amyl acetate Drugs 0.000 description 1
PGMYKACGEOXYJE-UHFFFAOYSA-N anhydrous amyl acetate Natural products CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 description 1
239000002585 base Substances 0.000 description 1
229960002903 benzyl benzoate Drugs 0.000 description 1
238000009954 braiding Methods 0.000 description 1
RDHPKYGYEGBMSE-UHFFFAOYSA-N bromoethane Chemical compound CCBr RDHPKYGYEGBMSE-UHFFFAOYSA-N 0.000 description 1
KMGBZBJJOKUPIA-UHFFFAOYSA-N butyl iodide Chemical compound CCCCI KMGBZBJJOKUPIA-UHFFFAOYSA-N 0.000 description 1
SHOVVTSKTTYFGP-UHFFFAOYSA-L butylaluminum(2+);dichloride Chemical compound CCCC[Al](Cl)Cl SHOVVTSKTTYFGP-UHFFFAOYSA-L 0.000 description 1
PWLNAUNEAKQYLH-UHFFFAOYSA-N butyric acid octyl ester Natural products CCCCCCCCOC(=O)CCC PWLNAUNEAKQYLH-UHFFFAOYSA-N 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
238000005119 centrifugation Methods 0.000 description 1
NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 description 1
230000000536 complexating effect Effects 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
235000014113 dietary fatty acids Nutrition 0.000 description 1
UWAMTZZJXXCIOH-UHFFFAOYSA-M diethyl(phenoxy)alumane Chemical compound CC[Al+]CC.[O-]C1=CC=CC=C1 UWAMTZZJXXCIOH-UHFFFAOYSA-M 0.000 description 1
LDCRTTXIJACKKU-ARJAWSKDSA-N dimethyl maleate Chemical compound COC(=O)\C=C/C(=O)OC LDCRTTXIJACKKU-ARJAWSKDSA-N 0.000 description 1
GCPCLEKQVMKXJM-UHFFFAOYSA-N ethoxy(diethyl)alumane Chemical compound CCO[Al](CC)CC GCPCLEKQVMKXJM-UHFFFAOYSA-N 0.000 description 1
OUGJKAQEYOUGKG-UHFFFAOYSA-N ethyl 2-methylidenebutanoate Chemical compound CCOC(=O)C(=C)CC OUGJKAQEYOUGKG-UHFFFAOYSA-N 0.000 description 1
JJOYCHKVKWDMEA-UHFFFAOYSA-N ethyl cyclohexanecarboxylate Chemical compound CCOC(=O)C1CCCCC1 JJOYCHKVKWDMEA-UHFFFAOYSA-N 0.000 description 1
125000004494 ethyl ester group Chemical group 0.000 description 1
UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 1
229920001038 ethylene copolymer Polymers 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
229930195729 fatty acid Natural products 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
229910052732 germanium Inorganic materials 0.000 description 1
GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
150000008282 halocarbons Chemical class 0.000 description 1
MNWFXJYAOYHMED-UHFFFAOYSA-M heptanoate Chemical compound CCCCCCC([O-])=O MNWFXJYAOYHMED-UHFFFAOYSA-M 0.000 description 1
JVUDQRVNABJCFL-UHFFFAOYSA-L hexylaluminum(2+);dibromide Chemical compound [Br-].[Br-].CCCCCC[Al+2] JVUDQRVNABJCFL-UHFFFAOYSA-L 0.000 description 1
150000004678 hydrides Chemical class 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
239000011872 intimate mixture Substances 0.000 description 1
125000002510 isobutoxy group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])O* 0.000 description 1
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
239000012948 isocyanate Substances 0.000 description 1
150000002513 isocyanates Chemical class 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
150000007527 lewis bases Chemical class 0.000 description 1
239000006193 liquid solution Substances 0.000 description 1
QUXHCILOWRXCEO-UHFFFAOYSA-M magnesium;butane;chloride Chemical compound [Mg+2].[Cl-].CCC[CH2-] QUXHCILOWRXCEO-UHFFFAOYSA-M 0.000 description 1
YCCXQARVHOPWFJ-UHFFFAOYSA-M magnesium;ethane;chloride Chemical compound [Mg+2].[Cl-].[CH2-]C YCCXQARVHOPWFJ-UHFFFAOYSA-M 0.000 description 1
KMYFNYFIPIGQQZ-UHFFFAOYSA-N magnesium;octane Chemical compound [Mg+2].CCCCCCC[CH2-].CCCCCCC[CH2-] KMYFNYFIPIGQQZ-UHFFFAOYSA-N 0.000 description 1
LVKCSZQWLOVUGB-UHFFFAOYSA-M magnesium;propane;bromide Chemical compound [Mg+2].[Br-].C[CH-]C LVKCSZQWLOVUGB-UHFFFAOYSA-M 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
WVWZECQNFWFVFW-UHFFFAOYSA-N methyl 2-methylbenzoate Chemical compound COC(=O)C1=CC=CC=C1C WVWZECQNFWFVFW-UHFFFAOYSA-N 0.000 description 1
QSSJZLPUHJDYKF-UHFFFAOYSA-N methyl 4-methylbenzoate Chemical compound COC(=O)C1=CC=C(C)C=C1 QSSJZLPUHJDYKF-UHFFFAOYSA-N 0.000 description 1
229940095102 methyl benzoate Drugs 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
DDIZAANNODHTRB-UHFFFAOYSA-N methyl p-anisate Chemical compound COC(=O)C1=CC=C(OC)C=C1 DDIZAANNODHTRB-UHFFFAOYSA-N 0.000 description 1
UUIQMZJEGPQKFD-UHFFFAOYSA-N n-butyric acid methyl ester Natural products CCCC(=O)OC UUIQMZJEGPQKFD-UHFFFAOYSA-N 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
150000002828 nitro derivatives Chemical class 0.000 description 1
125000004433 nitrogen atom Chemical group N* 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
ZWLPBLYKEWSWPD-UHFFFAOYSA-N o-toluenecarboxylic acid Natural products CC1=CC=CC=C1C(O)=O ZWLPBLYKEWSWPD-UHFFFAOYSA-N 0.000 description 1
VECVSKFWRQYTAL-UHFFFAOYSA-N octyl benzoate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1 VECVSKFWRQYTAL-UHFFFAOYSA-N 0.000 description 1
150000002895 organic esters Chemical class 0.000 description 1
239000011368 organic material Substances 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
TWSRVQVEYJNFKQ-UHFFFAOYSA-N pentyl propanoate Chemical compound CCCCCOC(=O)CC TWSRVQVEYJNFKQ-UHFFFAOYSA-N 0.000 description 1
239000012071 phase Substances 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
FCJSHPDYVMKCHI-UHFFFAOYSA-N phenyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OC1=CC=CC=C1 FCJSHPDYVMKCHI-UHFFFAOYSA-N 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000003003 phosphines Chemical class 0.000 description 1
AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
229920005604 random copolymer Polymers 0.000 description 1
238000010992 reflux Methods 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
239000002002 slurry Substances 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000006104 solid solution Substances 0.000 description 1
125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
238000012721 stereospecific polymerization Methods 0.000 description 1
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
229910052718 tin Inorganic materials 0.000 description 1
239000011135 tin Substances 0.000 description 1
UBZYKBZMAMTNKW-UHFFFAOYSA-J titanium tetrabromide Chemical compound Br[Ti](Br)(Br)Br UBZYKBZMAMTNKW-UHFFFAOYSA-J 0.000 description 1
PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
150000003752 zinc compounds Chemical class 0.000 description 1
PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

NL8201574A 1982-04-15 1982-04-15 Werkwijze voor het bereiden van een vaste katalytische titaankomponent en werkwijze voor het polymeriseren van alkenen-1 onder toepassing van een dergelijke titaankomponent. NL8201574A (nl)

Priority Applications (7)

Application Number	Priority Date	Filing Date	Title
NL8201574A NL8201574A (nl)	1982-04-15	1982-04-15	Werkwijze voor het bereiden van een vaste katalytische titaankomponent en werkwijze voor het polymeriseren van alkenen-1 onder toepassing van een dergelijke titaankomponent.
EP83200525A EP0093464B1 (de)	1982-04-15	1983-04-13	Verfahren zur Herstellung einer festen katalytischen Titankomponente und Polymerisationsverfahren von 1-Alkylenen das diese verwendet
AT83200525T ATE22090T1 (de)	1982-04-15	1983-04-13	Verfahren zur herstellung einer festen katalytischen titankomponente und polymerisationsverfahren von 1-alkylenen das diese verwendet.
DE8383200525T DE3365983D1 (en)	1982-04-15	1983-04-13	Process of preparing a solid catalytic titanium component and process for the polymerization of 1-alkenes using such a titanium component
CA000425825A CA1199317A (en)	1982-04-15	1983-04-14	Process of preparing a solid catalytic titanium component and process for the polymerization of 1- alkenes using such a titanium component
JP58066860A JPS58189207A (ja)	1982-04-15	1983-04-15	固体触媒チタン成分の製造方法、及びこのチタン成分を使用する１−アルケンの重合方法
US06/525,825 US4546092A (en)	1982-04-15	1983-08-23	Process of preparing a solid catalytic titanium component and process for the polymerization of 1-alkenes using such a titanium component

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
NL8201574A NL8201574A (nl)	1982-04-15	1982-04-15	Werkwijze voor het bereiden van een vaste katalytische titaankomponent en werkwijze voor het polymeriseren van alkenen-1 onder toepassing van een dergelijke titaankomponent.
NL8201574		1982-04-15

Publications (1)

Publication Number	Publication Date
NL8201574A true NL8201574A (nl)	1983-11-01

Family

ID=19839583

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NL8201574A NL8201574A (nl)	1982-04-15	1982-04-15	Werkwijze voor het bereiden van een vaste katalytische titaankomponent en werkwijze voor het polymeriseren van alkenen-1 onder toepassing van een dergelijke titaankomponent.

Country Status (7)

Country	Link
US (1)	US4546092A (de)
EP (1)	EP0093464B1 (de)
JP (1)	JPS58189207A (de)
AT (1)	ATE22090T1 (de)
CA (1)	CA1199317A (de)
DE (1)	DE3365983D1 (de)
NL (1)	NL8201574A (de)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0136742A3 (de) *	1983-08-23	1986-08-27	Stamicarbon B.V.	Verfahren zur Herstellung einer festen, Titan enthaltenden, katalytischen Komponente und Polymerisationsverfahren von 1-Alken die diese verwendet
NL8500521A (nl) *	1985-02-23	1986-09-16	Stamicarbon	Werkwijze voor het bereiden van een vaste katalytische titaankomponent en werkwijze voor het polymeriseren van alkenen-1 onder toepassing van een dergelijke titaankomponent.
NL8501716A (nl) *	1985-06-14	1987-01-02	Stamicarbon	Werkwijze voor het bereiden van nagenoeg bolvormige katalysatordeeltjes en een werkwijze voor het polymeriseren van alkenen-1 en voor het copolymeriseren van alkenen-1 onderling en/of met etheen onder toepassing van dergelijke bolvormige katalysatordeeltjes.
US4626519A (en) *	1985-09-06	1986-12-02	Phillips Petroleum Company	Supported polyolefin catalyst components and methods of making and using same

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE2831829A1 (de) *	1978-07-20	1980-01-31	Basf Ag	Verfahren zum herstellen einer komponente fuer polymerisationskatalysatoren
ZA801724B (en) *	1979-04-01	1981-03-25	Stamicarbon	Catalytic titanium compound,process for the manufacture thereof,and process for the polymerization of lakenes-1 with application of such a titanium component
NL7909333A (nl) *	1979-12-28	1981-07-16	Stamicarbon	Werkwijze voor het bereiden van een vaste katalytische titaankomponent en werkwijze voor het polymeriseren van alkenen-1 onder toepassing van een dergelijke titaankomponent.

1982
- 1982-04-15 NL NL8201574A patent/NL8201574A/nl not_active Application Discontinuation
1983
- 1983-04-13 DE DE8383200525T patent/DE3365983D1/de not_active Expired
- 1983-04-13 EP EP83200525A patent/EP0093464B1/de not_active Expired
- 1983-04-13 AT AT83200525T patent/ATE22090T1/de not_active IP Right Cessation
- 1983-04-14 CA CA000425825A patent/CA1199317A/en not_active Expired
- 1983-04-15 JP JP58066860A patent/JPS58189207A/ja active Pending
- 1983-08-23 US US06/525,825 patent/US4546092A/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
CA1199317A (en)	1986-01-14
EP0093464B1 (de)	1986-09-10
DE3365983D1 (en)	1986-10-16
JPS58189207A (ja)	1983-11-04
US4546092A (en)	1985-10-08
EP0093464A1 (de)	1983-11-09
ATE22090T1 (de)	1986-09-15

Legal Events

Date	Code	Title
1983-11-01	A1B	A search report has been drawn up
1985-01-01	A85	Still pending on 85-01-01
1985-12-02	BV	The patent application has lapsed

Publication	Publication Date	Title
US6511935B2 (en)	2003-01-28	Methods of making magnesium/transition metal alkoxide complexes and polymerization catalysts made therefrom
US4442225A (en)	1984-04-10	Catalytic component for polymerization of α-olefin and method for homo- or co-polymerization of α-olefin
CA1311741C (en)	1992-12-22	Preparation of olefin polymerization catalyst component
JPH04110308A (ja)	1992-04-10	α−オレフィンの重合方法
US20070197381A1 (en)	2007-08-23	Preparation of a magnesium halide support for olefin polymerization and a catalyst composition using the same
US4258167A (en)	1981-03-24	Process for producing powdery isotactic polyolefin
JP2004522849A (ja)	2004-07-29	エチレンの（共）重合方法
US4456695A (en)	1984-06-26	Component of catalyst for olefin polymerization
JPH04145105A (ja)	1992-05-19	エチレン重合体または共重合体の製造方法
CN1177872C (zh)	2004-12-01	用于制备双峰或宽分布聚乙烯的催化剂体系及其应用
GB2083483A (en)	1982-03-24	Polymerisation of butene-1
NL8201574A (nl)	1983-11-01	Werkwijze voor het bereiden van een vaste katalytische titaankomponent en werkwijze voor het polymeriseren van alkenen-1 onder toepassing van een dergelijke titaankomponent.
US7193022B2 (en)	2007-03-20	Method of polymerization and copolymerization of ethylene
US6800581B2 (en)	2004-10-05	Catalyst composition for polymerization of olefins and process using the composition
JPH059443B2 (de)	1993-02-05
JP3340729B2 (ja)	2002-11-05	α−オレフィンの重合方法
CA1248694A (en)	1989-01-10	Process for producing poly-1-butene
CA2058139A1 (en)	1992-06-28	Process for preparing polyolefins
NL8500521A (nl)	1986-09-16	Werkwijze voor het bereiden van een vaste katalytische titaankomponent en werkwijze voor het polymeriseren van alkenen-1 onder toepassing van een dergelijke titaankomponent.
JPH0446286B2 (de)	1992-07-29
JPH0119406B2 (de)	1989-04-11
CA1219997A (en)	1987-03-31	Method of polymerizing an olefin
CA1222503A (en)	1987-06-02	Process of preparing a solid catalytic titanium component and process for the polymerization of 1- alkenes using such a titanium component
CA1158000A (en)	1983-11-29	Process for producing copolymer of ethylene
EP0067417A2 (de)	1982-12-22	Katalysatorkomponente für die Polymerisation von alpha-Olefinen und Verfahren zur Homo- oder Co-Polymerisation von alpha-Olefinen