NL8700208A - Verbeterde met rubber versterkte monovinylideen-aromatische polymeerharsen en een werkwijze voor de bereiding daarvan. - Google Patents

Verbeterde met rubber versterkte monovinylideen-aromatische polymeerharsen en een werkwijze voor de bereiding daarvan. Download PDF

Info

Publication number: NL8700208A
Authority: NL; Netherlands
Prior art keywords: rubber; polymer; monovinylidene aromatic; aromatic polymer; viscosity
Prior art date: 1987-01-28

Application number

NL8700208A

Other languages

English (en)

Dutch (nl)

Original Assignee

Dow Chemical Nederland

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-01-28

Filing date

1987-01-28

Publication date

1988-08-16

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=19849486&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=NL8700208(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1987-01-28 Application filed by Dow Chemical Nederland filed Critical Dow Chemical Nederland

1987-01-28 Priority to NL8700208A priority Critical patent/NL8700208A/nl

1988-01-14 Priority to CA000556507A priority patent/CA1307865C/fr

1988-01-15 Priority to AU10321/88A priority patent/AU606645B2/en

1988-01-26 Priority to KR1019880000571A priority patent/KR960000567B1/ko

1988-01-26 Priority to JP63013737A priority patent/JPS63248809A/ja

1988-01-27 Priority to DE3889555T priority patent/DE3889555T3/de

1988-01-27 Priority to EP88200136A priority patent/EP0277687B2/fr

1988-08-16 Publication of NL8700208A publication Critical patent/NL8700208A/nl

Links

229920001971 elastomer Polymers 0.000 title claims description 184
239000005060 rubber Substances 0.000 title claims description 182
238000000034 method Methods 0.000 title claims description 53
239000002952 polymeric resin Substances 0.000 title claims description 8
238000002360 preparation method Methods 0.000 title description 18
239000002245 particle Substances 0.000 claims description 94
229920000642 polymer Polymers 0.000 claims description 93
239000000178 monomer Substances 0.000 claims description 56
150000001993 dienes Chemical class 0.000 claims description 31
125000003118 aryl group Chemical group 0.000 claims description 25
238000004090 dissolution Methods 0.000 claims description 25
229920001577 copolymer Polymers 0.000 claims description 23
239000000203 mixture Substances 0.000 claims description 23
241001441571 Hiodontidae Species 0.000 claims description 16
229920001519 homopolymer Polymers 0.000 claims description 13
150000002825 nitriles Chemical class 0.000 claims description 13
238000006243 chemical reaction Methods 0.000 claims description 9
239000007822 coupling agent Substances 0.000 claims description 8
239000004793 Polystyrene Substances 0.000 claims description 7
229920002223 polystyrene Polymers 0.000 claims description 7
229920003002 synthetic resin Polymers 0.000 claims description 7
230000008569 process Effects 0.000 claims description 6
230000000379 polymerizing effect Effects 0.000 claims description 5
238000004519 manufacturing process Methods 0.000 claims description 2
238000006116 polymerization reaction Methods 0.000 description 55
239000000047 product Substances 0.000 description 36
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 33
239000000243 solution Substances 0.000 description 25
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 20
238000002474 experimental method Methods 0.000 description 17
238000012662 bulk polymerization Methods 0.000 description 15
239000011159 matrix material Substances 0.000 description 14
YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 12
229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 12
229920005989 resin Polymers 0.000 description 12
239000011347 resin Substances 0.000 description 12
230000000052 comparative effect Effects 0.000 description 9
230000000704 physical effect Effects 0.000 description 9
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 8
239000003085 diluting agent Substances 0.000 description 8
238000009826 distribution Methods 0.000 description 8
229920005669 high impact polystyrene Polymers 0.000 description 8
239000004797 high-impact polystyrene Substances 0.000 description 8
239000000463 material Substances 0.000 description 8
238000010998 test method Methods 0.000 description 8
150000001491 aromatic compounds Chemical class 0.000 description 7
230000002902 bimodal effect Effects 0.000 description 7
239000003999 initiator Substances 0.000 description 7
239000002002 slurry Substances 0.000 description 7
238000003756 stirring Methods 0.000 description 7
238000002347 injection Methods 0.000 description 6
239000007924 injection Substances 0.000 description 6
239000007788 liquid Substances 0.000 description 6
239000007787 solid Substances 0.000 description 6
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 5
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 5
229920002554 vinyl polymer Polymers 0.000 description 5
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 4
238000007720 emulsion polymerization reaction Methods 0.000 description 4
-1 nitrile compounds Chemical class 0.000 description 4
150000003440 styrenes Chemical class 0.000 description 4
239000000126 substance Substances 0.000 description 4
238000010557 suspension polymerization reaction Methods 0.000 description 4
238000012546 transfer Methods 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
238000007796 conventional method Methods 0.000 description 3
238000005859 coupling reaction Methods 0.000 description 3
238000000465 moulding Methods 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
239000003963 antioxidant agent Substances 0.000 description 2
239000012736 aqueous medium Substances 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
230000008878 coupling Effects 0.000 description 2
238000010168 coupling process Methods 0.000 description 2
238000007872 degassing Methods 0.000 description 2
238000005227 gel permeation chromatography Methods 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
239000000155 melt Substances 0.000 description 2
239000002480 mineral oil Substances 0.000 description 2
235000010446 mineral oil Nutrition 0.000 description 2
238000002156 mixing Methods 0.000 description 2
238000004806 packaging method and process Methods 0.000 description 2
229920002857 polybutadiene Polymers 0.000 description 2
239000003505 polymerization initiator Substances 0.000 description 2
239000011541 reaction mixture Substances 0.000 description 2
229920006395 saturated elastomer Polymers 0.000 description 2
230000006641 stabilisation Effects 0.000 description 2
238000011105 stabilization Methods 0.000 description 2
238000012360 testing method Methods 0.000 description 2
239000008096 xylene Substances 0.000 description 2
PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
OEVVKKAVYQFQNV-UHFFFAOYSA-N 1-ethenyl-2,4-dimethylbenzene Chemical compound CC1=CC=C(C=C)C(C)=C1 OEVVKKAVYQFQNV-UHFFFAOYSA-N 0.000 description 1
UVHXEHGUEKARKZ-UHFFFAOYSA-N 1-ethenylanthracene Chemical compound C1=CC=C2C=C3C(C=C)=CC=CC3=CC2=C1 UVHXEHGUEKARKZ-UHFFFAOYSA-N 0.000 description 1
HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 description 1
SXZSFWHOSHAKMN-UHFFFAOYSA-N 2,3,4,4',5-Pentachlorobiphenyl Chemical compound C1=CC(Cl)=CC=C1C1=CC(Cl)=C(Cl)C(Cl)=C1Cl SXZSFWHOSHAKMN-UHFFFAOYSA-N 0.000 description 1
OMNYXCUDBQKCMU-UHFFFAOYSA-N 2,4-dichloro-1-ethenylbenzene Chemical compound ClC1=CC=C(C=C)C(Cl)=C1 OMNYXCUDBQKCMU-UHFFFAOYSA-N 0.000 description 1
150000003923 2,5-pyrrolediones Chemical class 0.000 description 1
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
SZSWKGVWJBZNIH-UHFFFAOYSA-N 2-chloro-1-ethenyl-4-methylbenzene Chemical compound CC1=CC=C(C=C)C(Cl)=C1 SZSWKGVWJBZNIH-UHFFFAOYSA-N 0.000 description 1
SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
TVONJMOVBKMLOM-UHFFFAOYSA-N 2-methylidenebutanenitrile Chemical compound CCC(=C)C#N TVONJMOVBKMLOM-UHFFFAOYSA-N 0.000 description 1
DXIJHCSGLOHNES-UHFFFAOYSA-N 3,3-dimethylbut-1-enylbenzene Chemical compound CC(C)(C)C=CC1=CC=CC=C1 DXIJHCSGLOHNES-UHFFFAOYSA-N 0.000 description 1
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
238000004566 IR spectroscopy Methods 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
238000007792 addition Methods 0.000 description 1
238000013019 agitation Methods 0.000 description 1
125000002723 alicyclic group Chemical group 0.000 description 1
150000007824 aliphatic compounds Chemical class 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
230000003078 antioxidant effect Effects 0.000 description 1
BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
SQHOHKQMTHROSF-UHFFFAOYSA-N but-1-en-2-ylbenzene Chemical compound CCC(=C)C1=CC=CC=C1 SQHOHKQMTHROSF-UHFFFAOYSA-N 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
230000001413 cellular effect Effects 0.000 description 1
238000005119 centrifugation Methods 0.000 description 1
239000012986 chain transfer agent Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
229920006026 co-polymeric resin Polymers 0.000 description 1
238000011437 continuous method Methods 0.000 description 1
239000002826 coolant Substances 0.000 description 1
238000012937 correction Methods 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
229920003244 diene elastomer Polymers 0.000 description 1
WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical group CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000001493 electron microscopy Methods 0.000 description 1
239000003995 emulsifying agent Substances 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000012467 final product Substances 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
239000004816 latex Substances 0.000 description 1
229920000126 latex Polymers 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
229920002521 macromolecule Polymers 0.000 description 1
238000005259 measurement Methods 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
239000006082 mold release agent Substances 0.000 description 1
238000013365 molecular weight analysis method Methods 0.000 description 1
230000000877 morphologic effect Effects 0.000 description 1
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
239000011368 organic material Substances 0.000 description 1
230000020477 pH reduction Effects 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
238000002135 phase contrast microscopy Methods 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
238000012545 processing Methods 0.000 description 1
HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
238000012797 qualification Methods 0.000 description 1
230000003746 surface roughness Effects 0.000 description 1
239000000725 suspension Substances 0.000 description 1
229920003051 synthetic elastomer Polymers 0.000 description 1
239000005061 synthetic rubber Substances 0.000 description 1
230000007704 transition Effects 0.000 description 1
238000004627 transmission electron microscopy Methods 0.000 description 1
229920001567 vinyl ester resin Polymers 0.000 description 1
230000000007 visual effect Effects 0.000 description 1
239000003039 volatile agent Substances 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
238000004260 weight control Methods 0.000 description 1
XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
- C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Graft Or Block Polymers (AREA)
Compositions Of Macromolecular Compounds (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

NL8700208A 1987-01-28 1987-01-28 Verbeterde met rubber versterkte monovinylideen-aromatische polymeerharsen en een werkwijze voor de bereiding daarvan. NL8700208A (nl)

Priority Applications (7)

Application Number	Priority Date	Filing Date	Title
NL8700208A NL8700208A (nl)	1987-01-28	1987-01-28	Verbeterde met rubber versterkte monovinylideen-aromatische polymeerharsen en een werkwijze voor de bereiding daarvan.
CA000556507A CA1307865C (fr)	1987-01-28	1988-01-14	Resines de polymeres aromatiques de type monovinylidene renforces par du caoutchouc, et methode pour leur preparation
AU10321/88A AU606645B2 (en)	1987-01-28	1988-01-15	Rubber-reinforced monovinylidene aromatic polymer resins and a method for their preparation
KR1019880000571A KR960000567B1 (ko)	1987-01-28	1988-01-26	고무-강화된 모노비닐리덴 방향족 중합체 수지 및 이의 제조방법
JP63013737A JPS63248809A (ja)	1987-01-28	1988-01-26	ゴム強化モノビニリデン芳香族ポリマー樹脂およびその製造法
DE3889555T DE3889555T3 (de)	1987-01-28	1988-01-27	Kautschukmodifizierte Vinylaromat-Polymerharze und Verfahren zu ihrer Herstellung.
EP88200136A EP0277687B2 (fr)	1987-01-28	1988-01-27	Résines de polymère vinyl-aromatique renforcées par du caoutchouc et leur méthode de préparation

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
NL8700208A NL8700208A (nl)	1987-01-28	1987-01-28	Verbeterde met rubber versterkte monovinylideen-aromatische polymeerharsen en een werkwijze voor de bereiding daarvan.
NL8700208		1987-01-28

Publications (1)

Publication Number	Publication Date
NL8700208A true NL8700208A (nl)	1988-08-16

Family

ID=19849486

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NL8700208A NL8700208A (nl)	1987-01-28	1987-01-28	Verbeterde met rubber versterkte monovinylideen-aromatische polymeerharsen en een werkwijze voor de bereiding daarvan.

Country Status (7)

Country	Link
EP (1)	EP0277687B2 (fr)
JP (1)	JPS63248809A (fr)
KR (1)	KR960000567B1 (fr)
AU (1)	AU606645B2 (fr)
CA (1)	CA1307865C (fr)
DE (1)	DE3889555T3 (fr)
NL (1)	NL8700208A (fr)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
IT1230085B (it) *	1989-05-24	1991-10-05	Montedipe Spa	Processo per la produzione in massa e in continuo di (co) polimeri vinil aromatici antiurto.
GB8920574D0 (en) *	1989-09-12	1989-10-25	Dow Benelux	Monovinylidene aromatic polymers with improved properties and a process for their preparation
US5264492A (en) *	1989-09-12	1993-11-23	The Dow Chemical Company	Monovinylidene aromatic polymers with improved properties
DE19632556A1 (de)	1996-08-13	1998-02-19	Bayer Ag	Verfahren zur Herstellung von hochkautschukhaltigen ABS-Formmassen
WO1999009081A1 (fr) *	1997-08-13	1999-02-25	The Dow Chemical Company	Polymeres aromatiques de monovinylidene a brillant eleve et a grande resistance
AU733887B2 (en) *	1997-08-13	2001-05-31	Styron Europe Gmbh	High gloss high impact monovinylidene aromatic polymers
ID29814A (id) *	1999-02-09	2001-10-11	Dow Chemical Co	Polimer-polimer aromatik monovinilidena benturan tinggi
HU225132B1 (en)	1999-05-17	2006-06-28	Dow Global Technologies Inc	Bimodal rubbers and rubber modified high impact monovinylidene aromatic polymers produced therefrom
US6380304B1 (en) *	1999-09-30	2002-04-30	The Dow Chemical Company	Mass polymerized rubber-modified monovinylidene aromatic copolymer compositions
KR20020063256A (ko)	1999-12-23	2002-08-01	다우 글로벌 테크놀로지스 인크.	특성이 개선된 모노비닐리덴 방향족 중합체 및 이의제조방법
WO2001068766A2 (fr) *	2000-03-13	2001-09-20	The Dow Chemical Company	Composition de polymere aromatique de monovinylidene ignifuge a haute resistance aux chocs
US7312277B2 (en)	2004-04-21	2007-12-25	Dow Global Technologies Inc.	Mass polymerized rubber-modified monovinylidene aromatic copolymer composition
BRPI0510870A (pt) *	2004-05-14	2007-12-26	Dow Global Technologies Inc	composição resistente ao impacto
KR100671135B1 (ko)	2004-09-08	2007-01-17	주식회사 엘지화학	고충격 고광택 고무변성 스티렌계 공중합 수지의 제조방법
EP2075270A1 (fr)	2007-12-28	2009-07-01	Cheil Industries Inc.	Copolymère de cyanure de vinyle, vinyle aromatique modifié au caoutchouc non brillant, et procédé de préparation continue
IT1393666B1 (it) *	2008-12-16	2012-05-08	Polimeri Europa Spa	(co)polimero vinilaromatico rinforzato con gomma avente un ottimo bilancio di proprieta' fisico-meccaniche ed una elevata lucentezza
EP3431511A1 (fr)	2017-07-19	2019-01-23	ARLANXEO Deutschland GmbH	Caoutchouc diénique ramifié en étoile
EP3950816B1 (fr)	2020-03-31	2025-01-08	Lg Chem, Ltd.	Latex de copolymère à base de nitrile modifié par un acide carboxylique, composition de latex pour moulage par immersion le comprenant et article moulé formé à partir de celle-ci
US11834537B2 (en)	2020-03-31	2023-12-05	Lg Chem, Ltd.	Carboxylic acid modified-nitrile based copolymer latex and latex composition for dip-forming comprising the copolymer latex and article formed by the composition
CN113795528B (zh)	2020-03-31	2024-07-05	株式会社Lg化学	羧酸改性的腈类共聚物胶乳、包含它的用于浸渍成型的胶乳组合物和由该组合物形成的制品
MY197860A (en)	2020-03-31	2023-07-21	Lg Chemical Ltd	Carboxylic acid-modified nitrile-based copolymer latex
KR102563070B1 (ko)	2020-03-31	2023-08-03	주식회사 엘지화학	카르본산 변성 니트릴계 공중합체 라텍스
JP7408212B2 (ja)	2020-03-31	2024-01-05	エルジー・ケム・リミテッド	カルボン酸変性ニトリル系共重合体ラテックス
CN119638908A (zh) *	2024-12-26	2025-03-18	惠州仁信新材料股份有限公司	一种高性能高光泽高抗冲击聚苯乙烯的制备方法和应用

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4183877A (en) *	1975-05-12	1980-01-15	Asahi Kasei Kogyo Kabushiki Kaisha	High-impact polystyrene composition and production thereof
US4096205A (en) *	1975-08-29	1978-06-20	Standard Oil Company (Indiana)	Method to produce improved rubber-modified styrene polymer
EP0029622B1 (fr) *	1979-11-16	1984-07-25	Shell Internationale Researchmaatschappij B.V.	Polymère étoilé hydrogéné modifié, sa préparation et une huile lubrifiante contenant ce polymère
DE3047293A1 (de) *	1980-12-16	1982-07-29	Basf Ag, 6700 Ludwigshafen	Verfahren zur herstellung von abs-polymerisaten, verwendung derselben, sowie formteile aus diesen
JPS584934A (ja) *	1981-06-30	1983-01-12	Fujitsu Ltd	半導体装置の組立て方法
JPS58109516A (ja) *	1981-12-24	1983-06-29	Asahi Chem Ind Co Ltd	合成樹脂組成物
JPS59217712A (ja) *	1983-05-26	1984-12-07	Nippon Erasutomaa Kk	耐衝撃性スチレン系樹脂
JPS60104112A (ja) *	1983-11-11	1985-06-08	Asahi Chem Ind Co Ltd	耐衝撃性ポリスチレン系樹脂およびその製造方法
JPS60181112A (ja) *	1984-02-28	1985-09-14	Sumitomo Chem Co Ltd	ポリスチレンの製造方法
IT1173589B (it) *	1984-05-08	1987-06-24	Montedison Spa	Polimeri vinil-aromatici antiurto modificati
JPH0692469B2 (ja) *	1984-12-21	1994-11-16	旭化成工業株式会社	耐衝撃性ポリスチレン系樹脂およびその製造法
JP2584211B2 (ja) *	1986-06-30	1997-02-26	日本エラストマ−株式会社	耐衝撃性スチレン系樹脂組成物
JP2588701B2 (ja) *	1986-09-17	1997-03-12	日本エラストマ−株式会社	ゴム変性されたスチレン系樹脂組成物

1987
- 1987-01-28 NL NL8700208A patent/NL8700208A/nl not_active Application Discontinuation
1988
- 1988-01-14 CA CA000556507A patent/CA1307865C/fr not_active Expired - Lifetime
- 1988-01-15 AU AU10321/88A patent/AU606645B2/en not_active Expired
- 1988-01-26 KR KR1019880000571A patent/KR960000567B1/ko not_active Expired - Fee Related
- 1988-01-26 JP JP63013737A patent/JPS63248809A/ja active Pending
- 1988-01-27 DE DE3889555T patent/DE3889555T3/de not_active Expired - Lifetime
- 1988-01-27 EP EP88200136A patent/EP0277687B2/fr not_active Expired - Lifetime

Also Published As

Publication number	Publication date
KR880009048A (ko)	1988-09-13
EP0277687B1 (fr)	1994-05-18
AU1032188A (en)	1988-08-04
AU606645B2 (en)	1991-02-14
EP0277687B2 (fr)	1998-12-23
DE3889555D1 (de)	1994-06-23
DE3889555T3 (de)	1999-07-29
EP0277687A3 (en)	1990-12-12
DE3889555T2 (de)	1994-09-01
JPS63248809A (ja)	1988-10-17
EP0277687A2 (fr)	1988-08-10
CA1307865C (fr)	1992-09-22
KR960000567B1 (ko)	1996-01-09

Legal Events

Date	Code	Title	Description
1988-08-16	A1B	A search report has been drawn up
1989-09-01	BV	The patent application has lapsed

Publication	Publication Date	Title
NL8700208A (nl)	1988-08-16	Verbeterde met rubber versterkte monovinylideen-aromatische polymeerharsen en een werkwijze voor de bereiding daarvan.
KR100579348B1 (ko)	2006-05-12	고광택 고충격 모노비닐리덴 방향족 중합체
CA1225772A (fr)	1987-08-18	Compositions abs, et leur preparation
JPH0635500B2 (ja)	1994-05-11	光沢および物理的強度特性に独特のバランスをもつモノビニリデン芳香族化合物のゴム補強ポリマ−ならびにその製造法
US4640959A (en)	1987-02-03	ABS type resin having disperse particles of a rubber exhibiting a high solution viscosity and a method for its preparation
JPH0141177B2 (fr)	1989-09-04
KR950006261B1 (ko)	1995-06-13	유동성 및 광택성이 개선된 고무-보강된 스티렌성 중합체 수지
US20200377714A1 (en)	2020-12-03	Improved process for producing abs graft copolymers
EP0418042B1 (fr)	1994-02-16	Polymères monovinylaromatiques à propriétés modifiées et procédé pour les préparer
KR20020063256A (ko)	2002-08-01	특성이 개선된 모노비닐리덴 방향족 중합체 및 이의제조방법
CA1222339A (fr)	1987-05-26	Resines de type abs a particules dispersees, constituees d'un caoutchouc a viscosite elevee en solution; methode de preparation
US4559386A (en)	1985-12-17	ABS compositions and process for preparing same
MXPA02011747A (es)	2003-05-14	Polimeros aromaticos de monovinilideno con dureza y rigidez mejoradas y un proceso para su preparacion.
JPH0623283B2 (ja)	1994-03-30	３つの異なるタイプのゴム粒子を含有するゴム変性モノビニリデン芳香族ポリマ−組成物
EP1159322A1 (fr)	2001-12-05	Polymeres aromatiques monovinylidene a impact eleve
US4151128A (en)	1979-04-24	Graft copolymers by suspension process following emulsion
US4082820A (en)	1978-04-04	High softening maleic anhydride copolymers
US4442264A (en)	1984-04-10	Graft rubbers for modifying thermoplastic moulding compositions
JPS60190445A (ja)	1985-09-27	鉱物繊維を含有するゴム強化重合体樹脂
WO1999009081A1 (fr)	1999-02-25	Polymeres aromatiques de monovinylidene a brillant eleve et a grande resistance
EP0892820B1 (fr)	2000-09-20	Procede bimodal simplifie
NL8403453A (nl)	1986-06-02	Met rubber versterkte styrenische polymeerharsen die een vergrote rek vertonen.
JPH09286827A (ja)	1997-11-04	ゴム状重合体ラテックスの製造方法、それを用いたグラフト共重合体の製造方法およびグラフト共重合体を用いたａｂｓ系樹脂組成物
JP2002037964A (ja)	2002-02-06	芳香族ビニル系樹脂組成物およびその製造方法
KR19990052370A (ko)	1999-07-05	충격강도가 우수한 열가소성 수지의 제조방법