NL8800748A - Samenstelling die met ultraviolet licht uithardbare onverzadigde monomeren en/of oligomeren, een fotoinitiator en colloidaal silica met een organosilaanverbinding bevat en de toepassing van deze samenstelling in bekledingsmiddelen. - Google Patents

Samenstelling die met ultraviolet licht uithardbare onverzadigde monomeren en/of oligomeren, een fotoinitiator en colloidaal silica met een organosilaanverbinding bevat en de toepassing van deze samenstelling in bekledingsmiddelen. Download PDF

Info

Publication number: NL8800748A
Authority: NL; Netherlands
Prior art keywords: composition; oligomers; colloidal silica; organosilane compound; unsaturated monomers
Prior art date: 1988-03-25

Application number

NL8800748A

Other languages

English (en)

Dutch (nl)

Original Assignee

Stamicarbon

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1988-03-25

Filing date

1988-03-25

Publication date

1989-10-16

1988-03-25 Application filed by Stamicarbon filed Critical Stamicarbon

1988-03-25 Priority to NL8800748A priority Critical patent/NL8800748A/nl

1989-03-21 Priority to DE8989200714T priority patent/DE68904583T2/de

1989-03-21 Priority to EP89200714A priority patent/EP0336474B1/de

1989-03-21 Priority to AT89200714T priority patent/ATE85059T1/de

1989-03-24 Priority to US07/328,562 priority patent/US5086087A/en

1989-03-27 Priority to JP1072053A priority patent/JPH01315403A/ja

1989-10-16 Publication of NL8800748A publication Critical patent/NL8800748A/nl

Links

VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 41
239000000203 mixture Substances 0.000 title claims abstract description 29
-1 ORGANOSILANE COMPOUND Chemical class 0.000 title claims abstract description 15
239000000178 monomer Substances 0.000 title claims abstract description 11
239000008119 colloidal silica Substances 0.000 title abstract description 17
239000003999 initiator Substances 0.000 title description 3
239000003377 acid catalyst Substances 0.000 claims abstract description 5
239000000377 silicon dioxide Substances 0.000 claims description 12
229910000077 silane Inorganic materials 0.000 claims description 10
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 9
239000000758 substrate Substances 0.000 claims description 9
239000003054 catalyst Substances 0.000 claims description 8
229920003023 plastic Polymers 0.000 claims description 7
239000004033 plastic Substances 0.000 claims description 6
239000002253 acid Substances 0.000 claims description 5
LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 claims description 3
229920006352 transparent thermoplastic Polymers 0.000 claims description 2
239000011248 coating agent Substances 0.000 claims 4
239000000084 colloidal system Substances 0.000 claims 2
238000004519 manufacturing process Methods 0.000 claims 1
238000000034 method Methods 0.000 claims 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
238000000576 coating method Methods 0.000 description 4
229910052681 coesite Inorganic materials 0.000 description 4
229910052906 cristobalite Inorganic materials 0.000 description 4
238000001723 curing Methods 0.000 description 4
239000006185 dispersion Substances 0.000 description 4
235000012239 silicon dioxide Nutrition 0.000 description 4
229910052682 stishovite Inorganic materials 0.000 description 4
229910052905 tridymite Inorganic materials 0.000 description 4
ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
229910004298 SiO 2 Inorganic materials 0.000 description 3
230000002378 acidificating effect Effects 0.000 description 3
229920000515 polycarbonate Polymers 0.000 description 3
239000004417 polycarbonate Substances 0.000 description 3
JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical class CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
238000003848 UV Light-Curing Methods 0.000 description 2
XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
239000008199 coating composition Substances 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
239000011521 glass Substances 0.000 description 2
150000002576 ketones Chemical class 0.000 description 2
239000002245 particle Substances 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
GRDGBWVSVMLKBV-UHFFFAOYSA-N (2-amino-5-nitrophenyl)-(2-chlorophenyl)methanone Chemical compound NC1=CC=C([N+]([O-])=O)C=C1C(=O)C1=CC=CC=C1Cl GRDGBWVSVMLKBV-UHFFFAOYSA-N 0.000 description 1
MYWOJODOMFBVCB-UHFFFAOYSA-N 1,2,6-trimethylphenanthrene Chemical compound CC1=CC=C2C3=CC(C)=CC=C3C=CC2=C1C MYWOJODOMFBVCB-UHFFFAOYSA-N 0.000 description 1
LDMOEFOXLIZJOW-UHFFFAOYSA-N 1-dodecanesulfonic acid Chemical compound CCCCCCCCCCCCS(O)(=O)=O LDMOEFOXLIZJOW-UHFFFAOYSA-N 0.000 description 1
KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 1
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
SUAYFRHPQLERMW-UHFFFAOYSA-N 2-methyl-1,2-diphenylpropan-1-one Chemical compound C=1C=CC=CC=1C(C)(C)C(=O)C1=CC=CC=C1 SUAYFRHPQLERMW-UHFFFAOYSA-N 0.000 description 1
239000004593 Epoxy Substances 0.000 description 1
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical class COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 1
WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
239000004793 Polystyrene Substances 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
244000028419 Styrax benzoin Species 0.000 description 1
235000000126 Styrax benzoin Nutrition 0.000 description 1
235000008411 Sumatra benzointree Nutrition 0.000 description 1
BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
238000005299 abrasion Methods 0.000 description 1
239000000654 additive Substances 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
125000000746 allylic group Chemical group 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
229960002130 benzoin Drugs 0.000 description 1
RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
239000012965 benzophenone Substances 0.000 description 1
LKFAPHHHWRMPGC-UHFFFAOYSA-N butan-1-ol prop-2-enoic acid Chemical compound CCCCO.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C LKFAPHHHWRMPGC-UHFFFAOYSA-N 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000007859 condensation product Substances 0.000 description 1
230000029087 digestion Effects 0.000 description 1
239000002270 dispersing agent Substances 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
239000001530 fumaric acid Substances 0.000 description 1
235000019382 gum benzoic Nutrition 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
239000007788 liquid Substances 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
238000013008 moisture curing Methods 0.000 description 1
PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
125000004957 naphthylene group Chemical group 0.000 description 1
238000006384 oligomerization reaction Methods 0.000 description 1
LYXOWKPVTCPORE-UHFFFAOYSA-N phenyl-(4-phenylphenyl)methanone Chemical compound C=1C=C(C=2C=CC=CC=2)C=CC=1C(=O)C1=CC=CC=C1 LYXOWKPVTCPORE-UHFFFAOYSA-N 0.000 description 1
125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
238000006068 polycondensation reaction Methods 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
239000004800 polyvinyl chloride Substances 0.000 description 1
229920000915 polyvinyl chloride Polymers 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
239000000047 product Substances 0.000 description 1
238000010526 radical polymerization reaction Methods 0.000 description 1
238000007761 roller coating Methods 0.000 description 1
239000006120 scratch resistant coating Substances 0.000 description 1
150000004756 silanes Chemical class 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000005507 spraying Methods 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
UQMOLLPKNHFRAC-UHFFFAOYSA-N tetrabutyl silicate Chemical compound CCCCO[Si](OCCCC)(OCCCC)OCCCC UQMOLLPKNHFRAC-UHFFFAOYSA-N 0.000 description 1
ZQZCOBSUOFHDEE-UHFFFAOYSA-N tetrapropyl silicate Chemical compound CCCO[Si](OCCC)(OCCC)OCCC ZQZCOBSUOFHDEE-UHFFFAOYSA-N 0.000 description 1
229920006305 unsaturated polyester Polymers 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
JNELGWHKGNBSMD-UHFFFAOYSA-N xanthone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3OC2=C1 JNELGWHKGNBSMD-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/42—Introducing metal atoms or metal-containing groups
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Paints Or Removers (AREA)
Polymerisation Methods In General (AREA)
Graft Or Block Polymers (AREA)

NL8800748A 1988-03-25 1988-03-25 Samenstelling die met ultraviolet licht uithardbare onverzadigde monomeren en/of oligomeren, een fotoinitiator en colloidaal silica met een organosilaanverbinding bevat en de toepassing van deze samenstelling in bekledingsmiddelen. NL8800748A (nl)

Priority Applications (6)

Application Number	Priority Date	Filing Date	Title
NL8800748A NL8800748A (nl)	1988-03-25	1988-03-25	Samenstelling die met ultraviolet licht uithardbare onverzadigde monomeren en/of oligomeren, een fotoinitiator en colloidaal silica met een organosilaanverbinding bevat en de toepassing van deze samenstelling in bekledingsmiddelen.
DE8989200714T DE68904583T2 (de)	1988-03-25	1989-03-21	Ein uv-haertbares ungesaettigtes monomer und/oder oligomer, ein fotoinitiator und kolloidales silica mit einer eine organosilan-verbindung enthaltenden zusammensetzung und die verwendung dieser zusammensetzung als ueberzugsmittel.
EP89200714A EP0336474B1 (de)	1988-03-25	1989-03-21	Ein UV-härtbares ungesättigtes Monomer und/oder Oligomer, ein Fotoinitiator und kolloidales Silica mit einer eine Organosilan-Verbindung enthaltenden Zusammensetzung und die Verwendung dieser Zusammensetzung als Überzugsmittel
AT89200714T ATE85059T1 (de)	1988-03-25	1989-03-21	Ein uv-haertbares ungesaettigtes monomer und/oder oligomer, ein fotoinitiator und kolloidales silica mit einer eine organosilan-verbindung enthaltenden zusammensetzung und die verwendung dieser zusammensetzung als ueberzugsmittel.
US07/328,562 US5086087A (en)	1988-03-25	1989-03-24	Composition containing uv curable unsaturated monomers and/or oligomers, a photoinitiator and colloidal silica with an oragnosilane compound, and the application of this composition in coatings
JP1072053A JPH01315403A (ja)	1988-03-25	1989-03-27	Ｕｖ硬化性不飼和モノマー及び／又はオリゴマー、光重合開始剤及びオルガノシラン化合物を有するコロイド状シリカを含有する組成物該組成物からなる被覆剤、被覆支持体及び該被覆支持体の製法

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
NL8800748		1988-03-25
NL8800748A NL8800748A (nl)	1988-03-25	1988-03-25	Samenstelling die met ultraviolet licht uithardbare onverzadigde monomeren en/of oligomeren, een fotoinitiator en colloidaal silica met een organosilaanverbinding bevat en de toepassing van deze samenstelling in bekledingsmiddelen.

Publications (1)

Publication Number	Publication Date
NL8800748A true NL8800748A (nl)	1989-10-16

Family

ID=19851999

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NL8800748A NL8800748A (nl)	1988-03-25	1988-03-25	Samenstelling die met ultraviolet licht uithardbare onverzadigde monomeren en/of oligomeren, een fotoinitiator en colloidaal silica met een organosilaanverbinding bevat en de toepassing van deze samenstelling in bekledingsmiddelen.

Country Status (6)

Country	Link
US (1)	US5086087A (de)
EP (1)	EP0336474B1 (de)
JP (1)	JPH01315403A (de)
AT (1)	ATE85059T1 (de)
DE (1)	DE68904583T2 (de)
NL (1)	NL8800748A (de)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5242719A (en) *	1992-04-06	1993-09-07	General Electric Company	Abrasion resistant UV-curable hardcoat compositions
AU4123993A (en) *	1992-06-25	1994-01-06	General Electric Company	Radiation curable hardcoat compositions
JPH0741695A (ja) *	1993-07-30	1995-02-10	Mitsubishi Chem Corp	耐摩耗性被覆組成物
US5626964A (en) *	1995-10-24	1997-05-06	Dow Corning Corporation	Radiation-curable silicone resins formulated from amine alcohols, tetra-alkoxysilanes and multifunctional acrylates
US5853809A (en) *	1996-09-30	1998-12-29	Basf Corporation	Scratch resistant clearcoats containing suface reactive microparticles and method therefore
US5776565A (en) *	1996-12-04	1998-07-07	International Paper Company	Hybrid sol-gel barrier coatings
US6355751B1 (en)	1996-12-31	2002-03-12	Lucent Technologies Inc.	Curable coatings with improved adhesion to glass
US6210790B1 (en) *	1998-07-15	2001-04-03	Rensselaer Polytechnic Institute	Glass-like composites comprising a surface-modified colloidal silica and method of making thereof
US6458468B1 (en)	1999-01-28	2002-10-01	Eastman Chemical Company	Photocurable coatings for polyester articles
DE19924172A1 (de)	1999-05-25	2000-11-30	Basf Coatings Ag	Beschichtungsstoff mit einer Mischung aus Kieselsäuren und Harnstoff und/oder Harnstoffderivaten
BR0012882A (pt)	1999-07-30	2002-04-09	Ppg Ind Ohio Inc	Revestimentos curados tendo resistência ao risco melhorada, substratos revestidos e métodos a eles relacionados
US6623791B2 (en)	1999-07-30	2003-09-23	Ppg Industries Ohio, Inc.	Coating compositions having improved adhesion, coated substrates and methods related thereto
PT1204709E (pt) *	1999-07-30	2007-05-31	Ppg Ind Ohio Inc	Composições de revestimento que têm resistência ao arranhão melhorada, substratos revestidos e métodos relacionados com eles
US6610777B1 (en)	1999-07-30	2003-08-26	Ppg Industries Ohio, Inc.	Flexible coating compositions having improved scratch resistance, coated substrates and methods related thereto
WO2001009259A1 (en)	1999-07-30	2001-02-08	Ppg Industries Ohio, Inc.	Coating compositions having improved scratch resistance, coated substrates and methods related thereto
US6653043B1 (en) *	1999-11-01	2003-11-25	Kansai Research Institute, Inc.	Active particle, photosensitive resin composition, and process for forming pattern
US6635341B1 (en) *	2000-07-31	2003-10-21	Ppg Industries Ohio, Inc.	Coating compositions comprising silyl blocked components, coating, coated substrates and methods related thereto
US6800353B1 (en) *	2000-09-08	2004-10-05	Ecolab Inc.	Scratch-resistant strippable finish
KR20020020599A (ko) *	2000-09-09	2002-03-15	황성호	자외선경화형 실리콘코팅제 조성물
KR100387535B1 (ko) *	2000-09-19	2003-06-18	주식회사 루밴틱스	콜로이달 실리카 충전재를 포함하는 광학 접착제 수지조성물 및 이의 제조방법
EP1195416A3 (de) *	2000-10-05	2005-12-28	Degussa AG	Polymerisierbare siliciumorganische Nanokapseln
US6685985B2 (en)	2001-02-09	2004-02-03	Basf Corporation	Method of improving the appearance of coated articles having both vertical and horizontal surfaces, and coating compositions for use therein
EP1256593B1 (de) *	2001-05-11	2010-07-28	Borealis Technology Oy	Verfahren zur Vernetzung von Polymerartikeln
DE10126647A1 (de) *	2001-06-01	2002-12-12	Basf Coatings Ag	Rheologiehilfsmittel, Verfahren zu seiner Herstellung und seine Verwendung
ATE335770T1 (de) *	2001-12-18	2006-09-15	Dow Corning Toray Silicone	Photohärtbare organische polymerzusammensetzung
AU2003302062A1 (en) *	2002-11-18	2004-06-15	Asahi Glass Company, Limited	Optical disc having hard-coat layer to which sebum stain proofness is imparted
WO2005103172A2 (en) *	2004-04-15	2005-11-03	Avery Dennison Corporation	Dew resistant coatings
US7723404B2 (en) *	2006-04-06	2010-05-25	Ppg Industries Ohio, Inc.	Abrasion resistant coating compositions and coated articles

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS53111336A (en) *	1977-03-11	1978-09-28	Toray Ind Inc	Coating composition
ZA807425B (en) *	1979-12-26	1982-02-24	Gen Electric	Radiation curable organopolysiloxanes
US4372835A (en) *	1980-08-01	1983-02-08	General Electric Co.	Silane-functionalized ultraviolet screen precursors
US4478876A (en) *	1980-12-18	1984-10-23	General Electric Company	Process of coating a substrate with an abrasion resistant ultraviolet curable composition
IT1157915B (it) *	1982-01-13	1987-02-18	Anic Spa	Composizione a base di policarbonato con migliorate caratteristiche meccaniche e mezzi adatti alla sua preparazione
US4417023A (en) *	1982-01-21	1983-11-22	Diamond Shamrock Corporation	Polysiloxane stabilizers for flatting agents in radiation hardenable compositions

1988
- 1988-03-25 NL NL8800748A patent/NL8800748A/nl not_active Application Discontinuation
1989
- 1989-03-21 AT AT89200714T patent/ATE85059T1/de not_active IP Right Cessation
- 1989-03-21 DE DE8989200714T patent/DE68904583T2/de not_active Expired - Fee Related
- 1989-03-21 EP EP89200714A patent/EP0336474B1/de not_active Expired - Lifetime
- 1989-03-24 US US07/328,562 patent/US5086087A/en not_active Expired - Fee Related
- 1989-03-27 JP JP1072053A patent/JPH01315403A/ja active Pending

Also Published As

Publication number	Publication date
EP0336474B1 (de)	1993-01-27
US5086087A (en)	1992-02-04
JPH01315403A (ja)	1989-12-20
DE68904583D1 (de)	1993-03-11
ATE85059T1 (de)	1993-02-15
DE68904583T2 (de)	1993-09-09
EP0336474A1 (de)	1989-10-11

Legal Events

Date	Code	Title	Description
1989-10-16	A1B	A search report has been drawn up
1990-11-01	BV	The patent application has lapsed

Publication	Publication Date	Title
NL8800748A (nl)	1989-10-16	Samenstelling die met ultraviolet licht uithardbare onverzadigde monomeren en/of oligomeren, een fotoinitiator en colloidaal silica met een organosilaanverbinding bevat en de toepassing van deze samenstelling in bekledingsmiddelen.
US5318850A (en)	1994-06-07	UV curable abrasion-resistant coatings with improved weatherability
US4455205A (en)	1984-06-19	UV Curable polysiloxane from colloidal silica, methacryloyl silane, diacrylate, resorcinol monobenzoate and photoinitiator
US5840428A (en)	1998-11-24	Organically-modified, radiation-curable siloxane resin and method of making the same
KR101021045B1 (ko)	2011-03-15	고에너지 방사선에 의해 경화 가능한 아크릴옥시 작용성실리콘 조성물
US4188451A (en)	1980-02-12	Polycarbonate article coated with an adherent, durable, silica filled organopolysiloxane coating and process for producing same
JP5491577B2 (ja)	2014-05-14	耐候性の改良された放射線硬化性コーティング
JP3616118B2 (ja)	2005-02-02	放射線硬化性硬質被覆組成物
CN102216401B (zh)	2015-12-16	具有高透明度的耐刮涂覆的聚碳酸酯，其制备方法及其用途
JPH08209027A (ja)	1996-08-13	放射線硬化可能なケイ素含有ポリアクリレートハードコート組成物の製造方法とそれによって製造された組成物
CA2141516A1 (en)	1995-12-14	Radiation-curable oligomer-based coating composition
JP2017508014A (ja)	2017-03-23	変性金属錯体のナノ分散体を有する安定なプライマー配合物及びコーティング
CA2093156A1 (en)	1993-10-07	Abrasion resistant uv-curable hardcoat compositions
WO2013146477A1 (ja)	2013-10-03	シリカ含有コーティング用樹脂組成物及び積層体
KR100386351B1 (ko)	2003-08-21	방사선경화성 규소-함유 폴리아크릴레이트 경질 도막조성물 및 그의 제조방법
JP2001302734A (ja)	2001-10-31	シリコアクリル組成物、及び製造方法及び用途
CN115232550A (zh)	2022-10-25	一种低反射涂布组合物及其制备方法
CN105143360B (zh)	2018-03-02	可辐射聚合的耐磨水性涂料
JP4759780B2 (ja)	2011-08-31	低屈折率組成物、低屈折率膜、光学多層膜および反射防止膜
NL7903333A (nl)	1980-10-28	Voortbrengselen van polycarbonaat, die bekleed zijn met een hechtende duurzame, siliciumoxide als vulstof be- vattende organopolysiloxanlaag, alsmede werkwijze ter vervaardiging hiervan.
WO2020081253A1 (en)	2020-04-23	Anti-fouling coatings
CN103387759A (zh)	2013-11-13	一种有机/无机杂化增硬剂、制备方法及应用
KR20130091593A (ko)	2013-08-19	투명성이 양호한 실리카 미립자와 아크릴 폴리머의 하이브리드 수지 및 이를 이용한 자외선 경화용 조성물
NL7903334A (nl)	1980-10-28	Voortbrengselen van polycarbonaat die bekleed zijn met een hechtende, duurzame, siliciumoxide als vulstof be- vattende organopolysiloxanlaag, alsmede werkwijze ter vervaardiging hiervan.
CN116261491B (zh)	2024-07-02	树脂玻璃用涂覆剂和树脂玻璃