NL9001027A - Werkwijze voor de bereiding van calciumbindende polycarboxyverbindingen op basis van polysacchariden, alsmede fosfaat-vervangers voor wasmiddelen op basis van deze polycarboxyverbindingen. - Google Patents

Werkwijze voor de bereiding van calciumbindende polycarboxyverbindingen op basis van polysacchariden, alsmede fosfaat-vervangers voor wasmiddelen op basis van deze polycarboxyverbindingen. Download PDF

Info

Publication number: NL9001027A
Authority: NL; Netherlands
Prior art keywords: oxidation; calcium; inulin; polycarboxyinulin; bromide
Prior art date: 1990-04-27

Application number

NL9001027A

Other languages

English (en)

Dutch (nl)

Original Assignee

Tno

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-04-27

Filing date

1990-04-27

Publication date

1991-11-18

1990-04-27 Application filed by Tno filed Critical Tno

1990-04-27 Priority to NL9001027A priority Critical patent/NL9001027A/nl

1990-11-08 Priority to ES90202964T priority patent/ES2074528T3/es

1990-11-08 Priority to DK90202964.4T priority patent/DK0427349T3/da

1990-11-08 Priority to DE69020861T priority patent/DE69020861T2/de

1990-11-08 Priority to EP90202964A priority patent/EP0427349B1/fr

1990-11-08 Priority to AT90202964T priority patent/ATE124960T1/de

1990-11-09 Priority to JP30284790A priority patent/JP3172171B2/ja

1990-11-09 Priority to CA002029542A priority patent/CA2029542C/fr

1991-04-26 Priority to ES91907826T priority patent/ES2126570T3/es

1991-04-26 Priority to US07/949,498 priority patent/US5326864A/en

1991-04-26 Priority to DK91907826T priority patent/DK0526494T3/da

1991-04-26 Priority to KR1019920702652A priority patent/KR100204437B1/ko

1991-04-26 Priority to DE69130608T priority patent/DE69130608T2/de

1991-04-26 Priority to JP3507729A priority patent/JP3004052B2/ja

1991-04-26 Priority to AU76960/91A priority patent/AU649038B2/en

1991-04-26 Priority to AT91907826T priority patent/ATE174346T1/de

1991-04-26 Priority to CA002081483A priority patent/CA2081483C/fr

1991-04-26 Priority to EP91907826A priority patent/EP0526494B1/fr

1991-04-26 Priority to PCT/NL1991/000068 priority patent/WO1991017189A1/fr

1991-11-18 Publication of NL9001027A publication Critical patent/NL9001027A/nl

1992-10-26 Priority to FI924843A priority patent/FI105479B/fi

1992-10-26 Priority to NO924134A priority patent/NO306215B1/no

1995-08-23 Priority to GR950402308T priority patent/GR3017196T3/el

1999-02-26 Priority to GR990400612T priority patent/GR3029515T3/el

Links

239000003599 detergent Substances 0.000 title claims abstract description 11
150000001875 compounds Chemical class 0.000 title claims abstract description 9
229910019142 PO4 Inorganic materials 0.000 title abstract description 9
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 title abstract description 6
239000010452 phosphate Substances 0.000 title abstract description 6
238000004519 manufacturing process Methods 0.000 title abstract description 3
238000009739 binding Methods 0.000 title description 2
229920001202 Inulin Polymers 0.000 claims abstract description 31
JYJIGFIDKWBXDU-MNNPPOADSA-N inulin Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)OC[C@]1(OC[C@]2(OC[C@]3(OC[C@]4(OC[C@]5(OC[C@]6(OC[C@]7(OC[C@]8(OC[C@]9(OC[C@]%10(OC[C@]%11(OC[C@]%12(OC[C@]%13(OC[C@]%14(OC[C@]%15(OC[C@]%16(OC[C@]%17(OC[C@]%18(OC[C@]%19(OC[C@]%20(OC[C@]%21(OC[C@]%22(OC[C@]%23(OC[C@]%24(OC[C@]%25(OC[C@]%26(OC[C@]%27(OC[C@]%28(OC[C@]%29(OC[C@]%30(OC[C@]%31(OC[C@]%32(OC[C@]%33(OC[C@]%34(OC[C@]%35(OC[C@]%36(O[C@@H]%37[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O%37)O)[C@H]([C@H](O)[C@@H](CO)O%36)O)[C@H]([C@H](O)[C@@H](CO)O%35)O)[C@H]([C@H](O)[C@@H](CO)O%34)O)[C@H]([C@H](O)[C@@H](CO)O%33)O)[C@H]([C@H](O)[C@@H](CO)O%32)O)[C@H]([C@H](O)[C@@H](CO)O%31)O)[C@H]([C@H](O)[C@@H](CO)O%30)O)[C@H]([C@H](O)[C@@H](CO)O%29)O)[C@H]([C@H](O)[C@@H](CO)O%28)O)[C@H]([C@H](O)[C@@H](CO)O%27)O)[C@H]([C@H](O)[C@@H](CO)O%26)O)[C@H]([C@H](O)[C@@H](CO)O%25)O)[C@H]([C@H](O)[C@@H](CO)O%24)O)[C@H]([C@H](O)[C@@H](CO)O%23)O)[C@H]([C@H](O)[C@@H](CO)O%22)O)[C@H]([C@H](O)[C@@H](CO)O%21)O)[C@H]([C@H](O)[C@@H](CO)O%20)O)[C@H]([C@H](O)[C@@H](CO)O%19)O)[C@H]([C@H](O)[C@@H](CO)O%18)O)[C@H]([C@H](O)[C@@H](CO)O%17)O)[C@H]([C@H](O)[C@@H](CO)O%16)O)[C@H]([C@H](O)[C@@H](CO)O%15)O)[C@H]([C@H](O)[C@@H](CO)O%14)O)[C@H]([C@H](O)[C@@H](CO)O%13)O)[C@H]([C@H](O)[C@@H](CO)O%12)O)[C@H]([C@H](O)[C@@H](CO)O%11)O)[C@H]([C@H](O)[C@@H](CO)O%10)O)[C@H]([C@H](O)[C@@H](CO)O9)O)[C@H]([C@H](O)[C@@H](CO)O8)O)[C@H]([C@H](O)[C@@H](CO)O7)O)[C@H]([C@H](O)[C@@H](CO)O6)O)[C@H]([C@H](O)[C@@H](CO)O5)O)[C@H]([C@H](O)[C@@H](CO)O4)O)[C@H]([C@H](O)[C@@H](CO)O3)O)[C@H]([C@H](O)[C@@H](CO)O2)O)[C@@H](O)[C@H](O)[C@@H](CO)O1 JYJIGFIDKWBXDU-MNNPPOADSA-N 0.000 claims abstract description 31
229940029339 inulin Drugs 0.000 claims abstract description 31
238000000034 method Methods 0.000 claims abstract description 28
JGJLWPGRMCADHB-UHFFFAOYSA-N hypobromite Chemical compound Br[O-] JGJLWPGRMCADHB-UHFFFAOYSA-N 0.000 claims abstract description 24
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims abstract description 21
102000005701 Calcium-Binding Proteins Human genes 0.000 claims abstract description 16
108010045403 Calcium-Binding Proteins Proteins 0.000 claims abstract description 16
239000011230 binding agent Substances 0.000 claims abstract description 8
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 6
238000002360 preparation method Methods 0.000 claims abstract description 6
230000003197 catalytic effect Effects 0.000 claims abstract description 5
150000002772 monosaccharides Chemical group 0.000 claims abstract 2
WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims description 54
238000007254 oxidation reaction Methods 0.000 claims description 41
230000003647 oxidation Effects 0.000 claims description 38
150000004676 glycans Chemical class 0.000 claims description 21
229920001282 polysaccharide Polymers 0.000 claims description 21
239000005017 polysaccharide Substances 0.000 claims description 21
239000011575 calcium Substances 0.000 claims description 15
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 13
229910052791 calcium Inorganic materials 0.000 claims description 13
230000035484 reaction time Effects 0.000 claims description 7
230000000536 complexating effect Effects 0.000 claims description 6
239000012429 reaction media Substances 0.000 claims description 3
238000006056 electrooxidation reaction Methods 0.000 abstract description 3
238000011065 in-situ storage Methods 0.000 abstract description 2
239000000126 substance Substances 0.000 abstract description 2
239000000047 product Substances 0.000 description 26
238000006243 chemical reaction Methods 0.000 description 17
JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 16
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 14
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
239000007800 oxidant agent Substances 0.000 description 11
235000002639 sodium chloride Nutrition 0.000 description 9
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
229920002472 Starch Polymers 0.000 description 8
239000011541 reaction mixture Substances 0.000 description 8
235000021317 phosphate Nutrition 0.000 description 7
150000003839 salts Chemical class 0.000 description 7
235000019698 starch Nutrition 0.000 description 7
239000008107 starch Substances 0.000 description 7
239000010457 zeolite Substances 0.000 description 7
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 6
150000001720 carbohydrates Chemical class 0.000 description 6
230000001590 oxidative effect Effects 0.000 description 6
KHIWWQKSHDUIBK-UHFFFAOYSA-N periodic acid Chemical compound OI(=O)(=O)=O KHIWWQKSHDUIBK-UHFFFAOYSA-N 0.000 description 6
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
239000000460 chlorine Substances 0.000 description 5
229910052801 chlorine Inorganic materials 0.000 description 5
229910001919 chlorite Inorganic materials 0.000 description 5
229910052619 chlorite group Inorganic materials 0.000 description 5
QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 5
BJHIKXHVCXFQLS-UYFOZJQFSA-N fructose group Chemical group OCC(=O)[C@@H](O)[C@H](O)[C@H](O)CO BJHIKXHVCXFQLS-UYFOZJQFSA-N 0.000 description 5
241000723343 Cichorium Species 0.000 description 4
235000007542 Cichorium intybus Nutrition 0.000 description 4
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
235000014633 carbohydrates Nutrition 0.000 description 4
239000003795 chemical substances by application Substances 0.000 description 4
239000011777 magnesium Substances 0.000 description 4
229910052749 magnesium Inorganic materials 0.000 description 4
MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 4
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 3
240000008892 Helianthus tuberosus Species 0.000 description 3
235000003230 Helianthus tuberosus Nutrition 0.000 description 3
229920000881 Modified starch Polymers 0.000 description 3
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 3
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 3
229910052794 bromium Inorganic materials 0.000 description 3
239000008103 glucose Substances 0.000 description 3
239000000203 mixture Substances 0.000 description 3
150000003013 phosphoric acid derivatives Chemical class 0.000 description 3
238000006116 polymerization reaction Methods 0.000 description 3
SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 3
VYSWEVWBWJBBHH-UHFFFAOYSA-N 2-[5-[[3,4-dihydroxy-2,5-bis(hydroxymethyl)oxolan-2-yl]oxymethyl]-2-[[2-[[3,4-dihydroxy-2,5-bis(hydroxymethyl)oxolan-2-yl]oxymethyl]-3,4-dihydroxy-5-(hydroxymethyl)oxolan-2-yl]oxymethyl]-3,4-dihydroxyoxolan-2-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound OCC1OC(OC2(COC3(COC4(CO)OC(CO)C(O)C4O)OC(CO)C(O)C3O)OC(COC5(CO)OC(CO)C(O)C5O)C(O)C2O)C(O)C(O)C1O VYSWEVWBWJBBHH-UHFFFAOYSA-N 0.000 description 2
229920000856 Amylose Polymers 0.000 description 2
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
244000019459 Cynara cardunculus Species 0.000 description 2
235000019106 Cynara scolymus Nutrition 0.000 description 2
229920001503 Glucan Polymers 0.000 description 2
229920000377 Sinistrin Polymers 0.000 description 2
239000005708 Sodium hypochlorite Substances 0.000 description 2
229910021536 Zeolite Inorganic materials 0.000 description 2
230000002411 adverse Effects 0.000 description 2
230000008901 benefit Effects 0.000 description 2
229920002678 cellulose Polymers 0.000 description 2
239000001913 cellulose Substances 0.000 description 2
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
238000001704 evaporation Methods 0.000 description 2
230000008020 evaporation Effects 0.000 description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
239000007788 liquid Substances 0.000 description 2
235000013808 oxidized starch Nutrition 0.000 description 2
239000001254 oxidized starch Substances 0.000 description 2
229920005646 polycarboxylate Polymers 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
239000011780 sodium chloride Substances 0.000 description 2
FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
FJNCXZZQNBKEJT-UHFFFAOYSA-N 8beta-hydroxymarrubiin Natural products O1C(=O)C2(C)CCCC3(C)C2C1CC(C)(O)C3(O)CCC=1C=COC=1 FJNCXZZQNBKEJT-UHFFFAOYSA-N 0.000 description 1
229920000945 Amylopectin Polymers 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
AEMOLEFTQBMNLQ-BZINKQHNSA-N D-Guluronic Acid Chemical compound OC1O[C@H](C(O)=O)[C@H](O)[C@@H](O)[C@H]1O AEMOLEFTQBMNLQ-BZINKQHNSA-N 0.000 description 1
244000115658 Dahlia pinnata Species 0.000 description 1
235000012040 Dahlia pinnata Nutrition 0.000 description 1
244000259832 Dahlia sp Species 0.000 description 1
229920001353 Dextrin Polymers 0.000 description 1
239000004375 Dextrin Substances 0.000 description 1
ZNZYKNKBJPZETN-WELNAUFTSA-N Dialdehyde 11678 Chemical compound N1C2=CC=CC=C2C2=C1[C@H](C[C@H](/C(=C/O)C(=O)OC)[C@@H](C=C)C=O)NCC2 ZNZYKNKBJPZETN-WELNAUFTSA-N 0.000 description 1
QEVGZEDELICMKH-UHFFFAOYSA-N Diglycolic acid Chemical compound OC(=O)COCC(O)=O QEVGZEDELICMKH-UHFFFAOYSA-N 0.000 description 1
QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
240000003361 Drimia maritima Species 0.000 description 1
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
229920002670 Fructan Polymers 0.000 description 1
229930091371 Fructose Natural products 0.000 description 1
239000005715 Fructose Substances 0.000 description 1
RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
241000208818 Helianthus Species 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
229920002774 Maltodextrin Polymers 0.000 description 1
239000005913 Maltodextrin Substances 0.000 description 1
229910019093 NaOCl Inorganic materials 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
240000001949 Taraxacum officinale Species 0.000 description 1
235000005187 Taraxacum officinale ssp. officinale Nutrition 0.000 description 1
239000002253 acid Substances 0.000 description 1
229940072056 alginate Drugs 0.000 description 1
235000010443 alginic acid Nutrition 0.000 description 1
229920000615 alginic acid Polymers 0.000 description 1
GUBGYTABKSRVRQ-ASMJPISFSA-N alpha-maltose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-ASMJPISFSA-N 0.000 description 1
235000016520 artichoke thistle Nutrition 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
-1 bromine compound Chemical class 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
239000003518 caustics Substances 0.000 description 1
239000008139 complexing agent Substances 0.000 description 1
238000006482 condensation reaction Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
235000019425 dextrin Nutrition 0.000 description 1
238000000502 dialysis Methods 0.000 description 1
238000007323 disproportionation reaction Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000003792 electrolyte Substances 0.000 description 1
229940071106 ethylenediaminetetraacetate Drugs 0.000 description 1
238000012851 eutrophication Methods 0.000 description 1
238000000605 extraction Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
238000004108 freeze drying Methods 0.000 description 1
125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
239000010439 graphite Substances 0.000 description 1
229910002804 graphite Inorganic materials 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical group 0.000 description 1
150000002402 hexoses Chemical group 0.000 description 1
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 1
QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
230000014759 maintenance of location Effects 0.000 description 1
229940035034 maltodextrin Drugs 0.000 description 1
238000005259 measurement Methods 0.000 description 1
235000019426 modified starch Nutrition 0.000 description 1
231100000989 no adverse effect Toxicity 0.000 description 1
231100000252 nontoxic Toxicity 0.000 description 1
230000003000 nontoxic effect Effects 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
239000011591 potassium Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
238000000746 purification Methods 0.000 description 1
230000008929 regeneration Effects 0.000 description 1
238000011069 regeneration method Methods 0.000 description 1
238000007142 ring opening reaction Methods 0.000 description 1
LSMIOFMZNVEEBR-ICLSSMQGSA-N scilliroside Chemical compound C=1([C@@H]2[C@@]3(C)CC[C@H]4[C@@]([C@]3(CC2)O)(O)C[C@H](C2=C[C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O3)O)CC[C@@]24C)OC(=O)C)C=CC(=O)OC=1 LSMIOFMZNVEEBR-ICLSSMQGSA-N 0.000 description 1
238000000926 separation method Methods 0.000 description 1
238000004904 shortening Methods 0.000 description 1
CRWJEUDFKNYSBX-UHFFFAOYSA-N sodium;hypobromite Chemical compound [Na+].Br[O-] CRWJEUDFKNYSBX-UHFFFAOYSA-N 0.000 description 1
238000001228 spectrum Methods 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
239000007858 starting material Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000002352 surface water Substances 0.000 description 1
150000003658 tungsten compounds Chemical class 0.000 description 1
238000000108 ultra-filtration Methods 0.000 description 1
229940100445 wheat starch Drugs 0.000 description 1
238000010626 work up procedure Methods 0.000 description 1
238000004383 yellowing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B33/00—Preparation of derivatives of amylose
- C08B33/08—Oxidised amylose
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B31/00—Preparation of derivatives of starch
- C08B31/18—Oxidised starch
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/223—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin oxidised

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Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Organic Chemistry (AREA)
Polymers & Plastics (AREA)
Medicinal Chemistry (AREA)
Materials Engineering (AREA)
Biochemistry (AREA)
Molecular Biology (AREA)
Emergency Medicine (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Polysaccharides And Polysaccharide Derivatives (AREA)
Detergent Compositions (AREA)
Paper (AREA)
Compositions Of Macromolecular Compounds (AREA)

NL9001027A 1989-11-10 1990-04-27 Werkwijze voor de bereiding van calciumbindende polycarboxyverbindingen op basis van polysacchariden, alsmede fosfaat-vervangers voor wasmiddelen op basis van deze polycarboxyverbindingen. NL9001027A (nl)

Priority Applications (23)

Application Number	Priority Date	Filing Date	Title
NL9001027A NL9001027A (nl)	1990-04-27	1990-04-27	Werkwijze voor de bereiding van calciumbindende polycarboxyverbindingen op basis van polysacchariden, alsmede fosfaat-vervangers voor wasmiddelen op basis van deze polycarboxyverbindingen.
ES90202964T ES2074528T3 (es)	1989-11-10	1990-11-08	Metodo para la preparacion de polidicarboxisacaridos.
DK90202964.4T DK0427349T3 (da)	1989-11-10	1990-11-08	Fremgangsmåde til fremstilling af polydicarboxysaccharider, og erstatninger for phosphater i detergenter baseret på polydicarboxsaccharider
DE69020861T DE69020861T2 (de)	1989-11-10	1990-11-08	Verfahren zur Herstellung von Polydicarboxysacchariden.
EP90202964A EP0427349B1 (fr)	1989-11-10	1990-11-08	Procédé pour la préparation de polydicarboxysaccharides
AT90202964T ATE124960T1 (de)	1989-11-10	1990-11-08	Verfahren zur herstellung von polydicarboxysacchariden.
JP30284790A JP3172171B2 (ja)	1989-11-10	1990-11-09	ジカルボキシ多糖類の製造方法、及びジカルボキシ多糖類を基剤とした洗剤中の燐酸塩の代用品
CA002029542A CA2029542C (fr)	1989-11-10	1990-11-09	Methode de preparation des polydicarboxysaccharides, substituts de phosphates pour les detergents, bases sur les polydicarboxysaccharides
KR1019920702652A KR100204437B1 (ko)	1990-04-27	1991-04-26	칼슘결합성의 다당류계 폴리카르복시 화합물의 제조 방법 및 이 화합물을 세제 중의 인산염 대체물로서 사용하는 방법
AT91907826T ATE174346T1 (de)	1990-04-27	1991-04-26	Verfahren zur herstellung von calciumbindendem polydicarboxyinulin und desssen verwendung als phosphatersatz in detergentien
DK91907826T DK0526494T3 (da)	1990-04-27	1991-04-26	Fremgangsmåde til frembringelse af en calciumbindende polydicarboxy-inulin og dennes anvendelse som phosphaterstatning i de
ES91907826T ES2126570T3 (es)	1990-04-27	1991-04-26	Metodo para la preparacion de polidicarboxinulina como complejante del calcio y su empleo como agente sustitutivo de los fosfatos en detergentes.
DE69130608T DE69130608T2 (de)	1990-04-27	1991-04-26	Verfahren zur herstellung von calciumbindendem polydicarboxyinulin und desssen verwendung als phosphatersatz in detergentien
JP3507729A JP3004052B2 (ja)	1990-04-27	1991-04-26	多糖類を基にしたカルシウム―結合性ポリカルボキシ化合物の製造方法、およびポリカルボキシ化合物を基にした洗剤中での燐酸塩の代用
AU76960/91A AU649038B2 (en)	1990-04-27	1991-04-26	Method for preparation of calcium-binding polycarboxy compounds based on polysaccharides, and replacements for phosphates in detergents, based on these polycarboxy compounds
US07/949,498 US5326864A (en)	1990-04-27	1991-04-26	Method for the preparation of calcium-binding polycarboxy compounds based on polysaccharides, and replacements for phosphates in detergents, based on these polycarboxy compounds
CA002081483A CA2081483C (fr)	1990-04-27	1991-04-26	Methode de preparation de composes polycarboxyles, a base de polysaccharides, formant des complexes avec le calcium; utilisation de ces composes dans les detergents, a la place des phosphates
EP91907826A EP0526494B1 (fr)	1990-04-27	1991-04-26	Procede de preparation de polydicarboxyinuline comme complexant du calcium et son emploi comme agent de remplacement des phosphates dans les detergents
PCT/NL1991/000068 WO1991017189A1 (fr)	1990-04-27	1991-04-26	Procede de preparation de composes polycarboxy se liant au calcium forme a base de polysaccharides et agents de remplacement des phosphates dans des detergents, formes a base de ces composes polycarboxy
FI924843A FI105479B (fi)	1990-04-27	1992-10-26	Menetelmä kalsiumia sitovan polydikarboksi-inuliinin valmistamiseksi ja detergenttien fosfaattien korvaaminen näihin polykarboksiyhdisteisiin perustuen
NO924134A NO306215B1 (no)	1990-04-27	1992-10-26	Fremgangsmåte for fremstilling av kalsiumkompleksdannende polykarboksyforbindelse på basis av et polysakkarid, et polykarboksyinulin, et kalsiumbindende middel og et vaskemiddel
GR950402308T GR3017196T3 (en)	1989-11-10	1995-08-23	Method for the preparation of polydicarboxysaccharides.
GR990400612T GR3029515T3 (en)	1990-04-27	1999-02-26	Method for preparation of a calcium-binding polydicarboxy-inulin and its use as replacement for phosphates in detergents

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
NL9001027		1990-04-27
NL9001027A NL9001027A (nl)	1990-04-27	1990-04-27	Werkwijze voor de bereiding van calciumbindende polycarboxyverbindingen op basis van polysacchariden, alsmede fosfaat-vervangers voor wasmiddelen op basis van deze polycarboxyverbindingen.

Publications (1)

Publication Number	Publication Date
NL9001027A true NL9001027A (nl)	1991-11-18

Family

ID=19857030

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NL9001027A NL9001027A (nl)	1989-11-10	1990-04-27	Werkwijze voor de bereiding van calciumbindende polycarboxyverbindingen op basis van polysacchariden, alsmede fosfaat-vervangers voor wasmiddelen op basis van deze polycarboxyverbindingen.

Country Status (15)

Country	Link
US (1)	US5326864A (fr)
EP (1)	EP0526494B1 (fr)
JP (1)	JP3004052B2 (fr)
KR (1)	KR100204437B1 (fr)
AT (1)	ATE174346T1 (fr)
AU (1)	AU649038B2 (fr)
CA (1)	CA2081483C (fr)
DE (1)	DE69130608T2 (fr)
DK (1)	DK0526494T3 (fr)
ES (1)	ES2126570T3 (fr)
FI (1)	FI105479B (fr)
GR (1)	GR3029515T3 (fr)
NL (1)	NL9001027A (fr)
NO (1)	NO306215B1 (fr)
WO (1)	WO1991017189A1 (fr)

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DE4343993A1 (de) *	1993-12-22	1995-06-29	Stockhausen Chem Fab Gmbh	Pfropf-Copolymerisate von ungesättigten Monomeren und Polyhydroxyverbindungen, Verfahren zu ihrer Herstellung und ihre Verwendung
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WO1997002293A1 (fr) *	1995-06-30	1997-01-23	Lion Corporation	Acide polycarboxylique derive de polysaccharide compose d'unites de glucose anhydre, sels de cet acide, et son procede de preparation
NL1003776C2 (nl) *	1996-08-09	1998-02-20	Cooperatie Cosun U A	Milieuvriendelijke complexanten voor zware metalen
NL1007320C2 (nl) *	1997-10-20	1999-04-21	Cooperatie Cosun U A	Milieuvriendelijke complexanten voor zware metalen.
NL1009368C2 (nl) *	1998-06-10	1999-12-13	Sybron Chemie Nederland B V	Werkwijze voor het behandelen van textiel.
EP1408103A1 (fr) *	2002-10-10	2004-04-14	N.V. Solutia Europe S.A.	Composition détergente avec détachage amélioré
JP5122821B2 (ja)	2003-11-28	2013-01-16	イーストマンケミカルカンパニー	セルロースインターポリマー及び酸化方法
US8858860B2 (en)	2004-11-02	2014-10-14	Halliburton Energy Services, Inc.	Biodegradable retarder for cementing applications
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US7727945B2 (en) *	2005-07-15	2010-06-01	Akzo Nobel N.V.	Modified polysaccharides
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WO2011017223A1 (fr)	2009-07-31	2011-02-10	Akzo Nobel N.V.	Compositions de copolymère hybride pour des applications de soin personnel
US7276621B2 (en) *	2005-08-12	2007-10-02	Eastman Chemical Company	Production of di-(2-ethylhexyl) terephthalate
US7799942B2 (en) *	2005-08-12	2010-09-21	Eastman Chemical Company	Production of terephthalic acid di-esters
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US7741509B2 (en) *	2007-01-30	2010-06-22	Eastman Chemical Company	Conversion of terephthalic acid to Di-n-butyl terephthalate
AU2010224861B2 (en)	2009-03-17	2015-09-03	Italmatch Chemicals Spa	Composition for inhibiting calcium salt scale formation
EP2388308A1 (fr)	2010-05-19	2011-11-23	Dequest AG	Composition de nettoyage avec des propriétés detachantes améliorees
US8883711B2 (en)	2010-05-19	2014-11-11	Italmatch Chemicals Spa	Cleaning composition with improved stain removal
US9091158B2 (en)	2010-09-27	2015-07-28	Conocophillips Company	Processing oil from steam assisted production
US8853144B2 (en)	2011-08-05	2014-10-07	Ecolab Usa Inc.	Cleaning composition containing a polysaccharide graft polymer composition and methods of improving drainage
US8679366B2 (en)	2011-08-05	2014-03-25	Ecolab Usa Inc.	Cleaning composition containing a polysaccharide graft polymer composition and methods of controlling hard water scale
US8841246B2 (en)	2011-08-05	2014-09-23	Ecolab Usa Inc.	Cleaning composition containing a polysaccharide hybrid polymer composition and methods of improving drainage
US8636918B2 (en)	2011-08-05	2014-01-28	Ecolab Usa Inc.	Cleaning composition containing a polysaccharide hybrid polymer composition and methods of controlling hard water scale
JP2014532791A (ja)	2011-11-04	2014-12-08	アクゾノーベルケミカルズインターナショナルベスローテンフエンノートシャップＡｋｚｏＮｏｂｅｌＣｈｅｍｉｃａｌｓＩｎｔｅｒｎａｔｉｏｎａｌＢ．Ｖ．	ハイブリッド樹状コポリマー、その組成物及びそれを製造する方法
US9051406B2 (en)	2011-11-04	2015-06-09	Akzo Nobel Chemicals International B.V.	Graft dendrite copolymers, and methods for producing the same
EP2790654A2 (fr)	2011-12-12	2014-10-22	Italmatch Chemicals S.P.A.	Composition cosmétique pour les soins de la peau ou des cheveux
EP2657329B1 (fr)	2012-04-26	2017-10-18	Viking Temizlik Ve Kozmetik Ürünleri Pazarlama Sanayi Ticaret Anomim Sirketi	Agent séquestrant utilisé dans des détergents avec une grande capacité de fixation du calcium
US8945314B2 (en)	2012-07-30	2015-02-03	Ecolab Usa Inc.	Biodegradable stability binding agent for a solid detergent
US9365805B2 (en)	2014-05-15	2016-06-14	Ecolab Usa Inc.	Bio-based pot and pan pre-soak
EP3561031B1 (fr)	2018-04-27	2025-06-04	The Procter & Gamble Company	Nettoyants alcalins pour surfaces dures comprenant des alkylpyrrolidones
EP4234668A3 (fr)	2018-04-27	2023-10-04	The Procter & Gamble Company	Nettoyants de surfaces dures comprenant du fructane carboxylé
EP3561032A1 (fr)	2018-04-27	2019-10-30	The Procter & Gamble Company	Nettoyants antimicrobiens pour surfaces dures comprenant des alkylpyrrolidones
CN112020550A (zh) *	2018-05-23	2020-12-01	陶氏环球技术有限责任公司	无水自动餐具配制物
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1990
- 1990-04-27 NL NL9001027A patent/NL9001027A/nl not_active Application Discontinuation
1991
- 1991-04-26 AT AT91907826T patent/ATE174346T1/de not_active IP Right Cessation
- 1991-04-26 CA CA002081483A patent/CA2081483C/fr not_active Expired - Fee Related
- 1991-04-26 JP JP3507729A patent/JP3004052B2/ja not_active Expired - Fee Related
- 1991-04-26 AU AU76960/91A patent/AU649038B2/en not_active Ceased
- 1991-04-26 WO PCT/NL1991/000068 patent/WO1991017189A1/fr not_active Ceased
- 1991-04-26 ES ES91907826T patent/ES2126570T3/es not_active Expired - Lifetime
- 1991-04-26 US US07/949,498 patent/US5326864A/en not_active Expired - Fee Related
- 1991-04-26 DK DK91907826T patent/DK0526494T3/da active
- 1991-04-26 KR KR1019920702652A patent/KR100204437B1/ko not_active Expired - Fee Related
- 1991-04-26 EP EP91907826A patent/EP0526494B1/fr not_active Expired - Lifetime
- 1991-04-26 DE DE69130608T patent/DE69130608T2/de not_active Expired - Fee Related
1992
- 1992-10-26 NO NO924134A patent/NO306215B1/no not_active IP Right Cessation
- 1992-10-26 FI FI924843A patent/FI105479B/fi not_active IP Right Cessation
1999
- 1999-02-26 GR GR990400612T patent/GR3029515T3/el unknown

Also Published As

Publication number	Publication date
FI105479B (fi)	2000-08-31
JP3004052B2 (ja)	2000-01-31
US5326864A (en)	1994-07-05
WO1991017189A1 (fr)	1991-11-14
ATE174346T1 (de)	1998-12-15
CA2081483A1 (fr)	1991-10-28
EP0526494A1 (fr)	1993-02-10
FI924843L (fi)	1992-10-26
NO924134L (no)	1992-10-27
FI924843A0 (fi)	1992-10-26
GR3029515T3 (en)	1999-05-28
AU649038B2 (en)	1994-05-12
NO306215B1 (no)	1999-10-04
KR100204437B1 (ko)	1999-06-15
ES2126570T3 (es)	1999-04-01
JPH05506685A (ja)	1993-09-30
NO924134D0 (no)	1992-10-26
CA2081483C (fr)	1999-04-13
EP0526494B1 (fr)	1998-12-09
DE69130608D1 (de)	1999-01-21
DE69130608T2 (de)	1999-05-27
AU7696091A (en)	1991-11-27
DK0526494T3 (da)	1999-08-16

Legal Events

Date	Code	Title	Description
1991-11-18	A1B	A search report has been drawn up
1992-12-01	BV	The patent application has lapsed

Publication	Publication Date	Title
NL9001027A (nl)	1991-11-18	Werkwijze voor de bereiding van calciumbindende polycarboxyverbindingen op basis van polysacchariden, alsmede fosfaat-vervangers voor wasmiddelen op basis van deze polycarboxyverbindingen.
JP3172171B2 (ja)	2001-06-04	ジカルボキシ多糖類の製造方法、及びジカルボキシ多糖類を基剤とした洗剤中の燐酸塩の代用品
US3873614A (en)	1975-03-25	Process for preparing oxidized carbohydrates and products
JP3043416B2 (ja)	2000-05-22	炭水化物類の酸化方法
JP4380799B2 (ja)	2009-12-09	超吸収性材料並びに該材料の製造法
Besemer et al.	1994	Dicarboxy‐Starch by Sodium Hypochlorite/Bromide Oxidation and Its Calcium Binding Properties
WO1996038484A1 (fr)	1996-12-05	Ethers d'hydrate de carbone polymeres oxydes utilises comme agent sequestrant et leurs procedes de preparation
JPH09506387A (ja)	1997-06-24	カルボキシメチルイヌリン
EP0472042A1 (fr)	1992-02-26	Agents séquestrants du calcium à base de carbohydrates oxydés et leur utilisation comme renforçateurs pour détergents
US5383964A (en)	1995-01-24	Process for the oxidation of cationic starches and amphoteric starches, containing carboxyl and cationic groups, thus obtained
NL1004738C2 (nl)	1998-06-11	Fructaan-polycarbonzuur.
EP1341717B1 (fr)	2004-05-26	Procede de recuperation de periodate epuise
JP5544107B2 (ja)	2014-07-09	高分子ビルダー
CA2247109A1 (fr)	1997-09-04	Processus d'oxydation d'amidon
EP0892041A1 (fr)	1999-01-20	Utilisation des polysaccharides oxydés dans les compositions détergentes
CN104302672A (zh)	2015-01-21	羧甲基果聚糖的碱金属盐的浓缩水溶液的制备方法
EP1278703A1 (fr)	2003-01-29	Sequestration
Besemer et al.	1994	The relation between calcium sequestering capacity and oxidation degree of dicarboxy‐starch and dicarboxy‐inulin
NL8902786A (nl)	1991-06-03	Werkwijze voor de bereiding van polydicarboxysacchariden, en fosfaatvervangers voor wasmiddelen op basis van deze polydicarboxysacchariden.
JPH06279504A (ja)	1994-10-04	金属イオン封鎖性オリゴマー化合物の製造方法及びそのオリゴマー化合物を含む洗浄剤組成物
WO1997032903A1 (fr)	1997-09-12	Procede d'oxydation de polysaccharides au moyen d'ozone et en presence d'un catalyseur contenant un halogenure
NL8802907A (nl)	1990-06-18	Werkwijze voor het vervaardigen van dicarboxypolysacchariden.
JP2014001272A (ja)	2014-01-09	ポリウロン酸塩の製造方法