NL9201916A - Werkwijze voor het bereiden van hydrazine-nitroform. - Google Patents

Werkwijze voor het bereiden van hydrazine-nitroform. Download PDF

Info

Publication number: NL9201916A
Authority: NL; Netherlands
Prior art keywords: nitroform; hydrazine; solvent; water; volume
Prior art date: 1992-11-03

Application number

NL9201916A

Other languages

English (en)

Dutch (nl)

Original Assignee

Aerospace Propulsion Prod

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-11-03

Filing date

1992-11-03

Publication date

1994-06-01

1992-11-03 Application filed by Aerospace Propulsion Prod filed Critical Aerospace Propulsion Prod

1992-11-03 Priority to NL9201916A priority Critical patent/NL9201916A/nl

1993-11-03 Priority to CA002148352A priority patent/CA2148352C/fr

1993-11-03 Priority to EP94901065A priority patent/EP0670823B1/fr

1993-11-03 Priority to PCT/NL1993/000230 priority patent/WO1994010104A1/fr

1993-11-03 Priority to DE69320061T priority patent/DE69320061T2/de

1993-11-03 Priority to US08/424,412 priority patent/US5557015A/en

1994-06-01 Publication of NL9201916A publication Critical patent/NL9201916A/nl

1995-05-02 Priority to NO951678A priority patent/NO304883B1/no

Links

RPZOYWMMVQTBOH-UHFFFAOYSA-N NN.[O-][N+](=O)C([N+]([O-])=O)[N+]([O-])=O Chemical compound NN.[O-][N+](=O)C([N+]([O-])=O)[N+]([O-])=O RPZOYWMMVQTBOH-UHFFFAOYSA-N 0.000 title claims description 32
238000004519 manufacturing process Methods 0.000 title description 4
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 68
LZGVDNRJCGPNDS-UHFFFAOYSA-N trinitromethane Chemical compound [O-][N+](=O)C([N+]([O-])=O)[N+]([O-])=O LZGVDNRJCGPNDS-UHFFFAOYSA-N 0.000 claims description 35
238000000034 method Methods 0.000 claims description 28
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
239000002904 solvent Substances 0.000 claims description 18
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 12
SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 claims description 9
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 9
150000003839 salts Chemical class 0.000 claims description 9
239000000203 mixture Substances 0.000 claims description 8
238000001953 recrystallisation Methods 0.000 claims description 6
239000011780 sodium chloride Substances 0.000 claims description 6
239000007864 aqueous solution Substances 0.000 claims description 5
239000003960 organic solvent Substances 0.000 claims description 4
239000007788 liquid Substances 0.000 claims description 2
238000005185 salting out Methods 0.000 claims description 2
229920006395 saturated elastomer Polymers 0.000 claims description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 9
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
150000001875 compounds Chemical class 0.000 description 8
239000000047 product Substances 0.000 description 8
239000000446 fuel Substances 0.000 description 7
239000000243 solution Substances 0.000 description 7
239000003381 stabilizer Substances 0.000 description 7
238000006243 chemical reaction Methods 0.000 description 6
239000012467 final product Substances 0.000 description 5
238000002360 preparation method Methods 0.000 description 5
239000000460 chlorine Substances 0.000 description 4
229910052801 chlorine Inorganic materials 0.000 description 4
238000002844 melting Methods 0.000 description 4
230000008018 melting Effects 0.000 description 4
238000003756 stirring Methods 0.000 description 4
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
229910052782 aluminium Inorganic materials 0.000 description 3
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
239000012043 crude product Substances 0.000 description 3
239000012535 impurity Substances 0.000 description 3
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
-1 chlorine ions Chemical class 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
238000001035 drying Methods 0.000 description 2
239000011521 glass Substances 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
239000002244 precipitate Substances 0.000 description 2
230000035945 sensitivity Effects 0.000 description 2
239000007787 solid Substances 0.000 description 2
239000004449 solid propellant Substances 0.000 description 2
239000011550 stock solution Substances 0.000 description 2
IDCPFAYURAQKDZ-UHFFFAOYSA-N 1-nitroguanidine Chemical compound NC(=N)N[N+]([O-])=O IDCPFAYURAQKDZ-UHFFFAOYSA-N 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
229910052790 beryllium Inorganic materials 0.000 description 1
ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
239000013058 crude material Substances 0.000 description 1
238000010908 decantation Methods 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
239000002360 explosive Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000007789 gas Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
BXDUJMLIUYJHNH-UHFFFAOYSA-L mercury(2+);oxalate Chemical compound [Hg+2].[O-]C(=O)C([O-])=O BXDUJMLIUYJHNH-UHFFFAOYSA-L 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
239000007800 oxidant agent Substances 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
238000009938 salting Methods 0.000 description 1
238000000926 separation method Methods 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
239000006228 supernatant Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/082—Compounds containing nitrogen and non-metals and optionally metals
- C01B21/16—Hydrazine; Salts thereof
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B47/00—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase
- C06B47/02—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase the components comprising a binary propellant
- C06B47/08—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase the components comprising a binary propellant a component containing hydrazine or a hydrazine derivative

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

NL9201916A 1992-11-03 1992-11-03 Werkwijze voor het bereiden van hydrazine-nitroform. NL9201916A (nl)

Priority Applications (7)

Application Number	Priority Date	Filing Date	Title
NL9201916A NL9201916A (nl)	1992-11-03	1992-11-03	Werkwijze voor het bereiden van hydrazine-nitroform.
CA002148352A CA2148352C (fr)	1992-11-03	1993-11-03	Methode de preparation de l'hydrazine nitroforme
EP94901065A EP0670823B1 (fr)	1992-11-03	1993-11-03	Procede de preparation d'hydrazine-nitroforme
PCT/NL1993/000230 WO1994010104A1 (fr)	1992-11-03	1993-11-03	Procede de preparation d'hydrazine-nitroforme
DE69320061T DE69320061T2 (de)	1992-11-03	1993-11-03	Verfahren zur herstellung von hydrazin-nitroform
US08/424,412 US5557015A (en)	1992-11-03	1993-11-03	Method of preparing hydrazine nitroform
NO951678A NO304883B1 (no)	1992-11-03	1995-05-02	FremgangsmÕte ved fremstilling av hydrazin-nitroform

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
NL9201916A NL9201916A (nl)	1992-11-03	1992-11-03	Werkwijze voor het bereiden van hydrazine-nitroform.
NL9201916		1992-11-03

Publications (1)

Publication Number	Publication Date
NL9201916A true NL9201916A (nl)	1994-06-01

Family

ID=19861469

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NL9201916A NL9201916A (nl)	1992-11-03	1992-11-03	Werkwijze voor het bereiden van hydrazine-nitroform.

Country Status (7)

Country	Link
US (1)	US5557015A (fr)
EP (1)	EP0670823B1 (fr)
CA (1)	CA2148352C (fr)
DE (1)	DE69320061T2 (fr)
NL (1)	NL9201916A (fr)
NO (1)	NO304883B1 (fr)
WO (1)	WO1994010104A1 (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0950648A1 (fr) *	1998-04-15	1999-10-20	Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno	Système propulsif à base de monoergol liquide
NL1009155C2 (nl) *	1998-05-13	1999-11-16	Tno	Hydrazinium nitroformaat.
EP0959058A1 (fr) *	1998-05-20	1999-11-24	Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno	Propergols solides à haut rendement à base d'hydrazine-nitroforme
US6841016B1 (en) *	2000-03-02	2005-01-11	Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno	Process for the production of crystalline energetic materials
KR101777605B1 (ko)	2016-01-04	2017-09-13	국방과학연구소	니트로폼히드라진의 재결정방법

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2963507A (en) *	1956-03-13	1960-12-06	Grace W R & Co	Nitroparaffin-hydrazine salts
US3213609A (en) *	1959-07-13	1965-10-26	Dow Chemical Co	High energy propellant and process employing hydrazines and nitro compounds
GB896450A (en) *	1960-04-14	1962-05-16	Grace W R & Co	New hydrazinium salts, their production and mixtures comprising a hydrazine
US3378594A (en) *	1960-08-03	1968-04-16	Exxon Research Engineering Co	Hydrazine nitroform and method of preparation
US3384674A (en) *	1961-02-27	1968-05-21	Exxon Research Engineering Co	Stabilization of nitroform salts
US3378595A (en) *	1961-02-27	1968-04-16	Exxon Research Engineering Co	Stabilization of nitroform salts
US3384675A (en) *	1961-02-27	1968-05-21	Exxon Research Engineering Co	Stabilization of nitroform salts
US3140317A (en) *	1961-03-03	1964-07-07	Dow Chemical Co	Nitroform-hydrazine coordination compounds
US3418183A (en) *	1963-12-04	1968-12-24	Thiokol Chemical Corp	Propellant comprising hydrazine nitroform stabilized with dicarboxylic acid anhydride
US3297747A (en) *	1963-12-26	1967-01-10	Atlas Chem Ind	Salts of nitroform with hydrazines
US4418183A (en) *	1981-11-12	1983-11-29	Pitney Bowes Inc.	Method for the production of high concentrations of emulsion polymers

1992
- 1992-11-03 NL NL9201916A patent/NL9201916A/nl not_active Application Discontinuation
1993
- 1993-11-03 CA CA002148352A patent/CA2148352C/fr not_active Expired - Fee Related
- 1993-11-03 EP EP94901065A patent/EP0670823B1/fr not_active Expired - Lifetime
- 1993-11-03 US US08/424,412 patent/US5557015A/en not_active Expired - Lifetime
- 1993-11-03 DE DE69320061T patent/DE69320061T2/de not_active Expired - Fee Related
- 1993-11-03 WO PCT/NL1993/000230 patent/WO1994010104A1/fr not_active Ceased
1995
- 1995-05-02 NO NO951678A patent/NO304883B1/no unknown

Also Published As

Publication number	Publication date
CA2148352A1 (fr)	1994-05-11
EP0670823B1 (fr)	1998-07-29
EP0670823A1 (fr)	1995-09-13
CA2148352C (fr)	2004-11-02
DE69320061D1 (de)	1998-09-03
NO304883B1 (no)	1999-03-01
NO951678D0 (no)	1995-05-02
WO1994010104A1 (fr)	1994-05-11
US5557015A (en)	1996-09-17
NO951678L (no)	1995-06-27
DE69320061T2 (de)	1999-04-08

Legal Events

Date	Code	Title	Description
1994-06-01	A1B	A search report has been drawn up
1996-06-03	BV	The patent application has lapsed

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