NO130734B - - Google Patents

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Info

Publication number: NO130734B
Authority: NO; Norway
Prior art keywords: titanium; polymerization; titanium trichloride; catalyst; product
Prior art date: 1966-08-06

Application number

NO16880667A

Other languages

English (en)

Norwegian (no)

Other versions

NO130734C (de

Inventor

W Schoen

H Nisser

Original Assignee

Voith Gmbh J M

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1966-08-06

Filing date

1967-06-28

Publication date

1974-10-21

1967-06-28 Application filed by Voith Gmbh J M filed Critical Voith Gmbh J M

1974-10-21 Publication of NO130734B publication Critical patent/NO130734B/no

1975-01-29 Publication of NO130734C publication Critical patent/NO130734C/no

Links

YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 claims description 47
-1 alkyl aluminum compound Chemical class 0.000 claims description 41
239000007788 liquid Substances 0.000 claims description 32
239000003054 catalyst Substances 0.000 claims description 31
238000006116 polymerization reaction Methods 0.000 claims description 30
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 21
238000000034 method Methods 0.000 claims description 16
239000007795 chemical reaction product Substances 0.000 claims description 15
238000010438 heat treatment Methods 0.000 claims description 13
239000000047 product Substances 0.000 claims description 12
238000009835 boiling Methods 0.000 claims description 11
229910052751 metal Inorganic materials 0.000 claims description 11
239000002184 metal Substances 0.000 claims description 11
239000010936 titanium Substances 0.000 claims description 11
238000004821 distillation Methods 0.000 claims description 9
229930195733 hydrocarbon Natural products 0.000 claims description 9
229910052719 titanium Inorganic materials 0.000 claims description 9
239000004215 Carbon black (E152) Substances 0.000 claims description 8
150000002430 hydrocarbons Chemical class 0.000 claims description 8
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 7
230000000737 periodic effect Effects 0.000 claims description 7
239000003638 chemical reducing agent Substances 0.000 claims description 6
150000002902 organometallic compounds Chemical class 0.000 claims description 6
150000004678 hydrides Chemical class 0.000 claims description 5
230000008569 process Effects 0.000 claims description 5
238000006722 reduction reaction Methods 0.000 claims description 5
125000004432 carbon atom Chemical group C* 0.000 claims description 4
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 32
239000006227 byproduct Substances 0.000 description 18
239000004743 Polypropylene Substances 0.000 description 17
229920001155 polypropylene Polymers 0.000 description 17
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 17
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 17
229920000642 polymer Polymers 0.000 description 14
239000000725 suspension Substances 0.000 description 13
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 9
239000011541 reaction mixture Substances 0.000 description 8
238000003756 stirring Methods 0.000 description 8
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 7
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 6
238000006243 chemical reaction Methods 0.000 description 6
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
239000004711 α-olefin Substances 0.000 description 6
239000003350 kerosene Substances 0.000 description 5
238000004519 manufacturing process Methods 0.000 description 5
239000000203 mixture Substances 0.000 description 5
239000007787 solid Substances 0.000 description 5
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
125000005234 alkyl aluminium group Chemical group 0.000 description 4
239000002612 dispersion medium Substances 0.000 description 4
238000001914 filtration Methods 0.000 description 4
239000002244 precipitate Substances 0.000 description 4
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
239000005977 Ethylene Substances 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
125000000217 alkyl group Chemical group 0.000 description 3
229910052782 aluminium Inorganic materials 0.000 description 3
239000012298 atmosphere Substances 0.000 description 3
SIPUZPBQZHNSDW-UHFFFAOYSA-N bis(2-methylpropyl)aluminum Chemical compound CC(C)C[Al]CC(C)C SIPUZPBQZHNSDW-UHFFFAOYSA-N 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 3
238000002474 experimental method Methods 0.000 description 3
238000005406 washing Methods 0.000 description 3
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
QQTGJVBUIOTPGZ-UHFFFAOYSA-N CCC[Zn]CCC Chemical compound CCC[Zn]CCC QQTGJVBUIOTPGZ-UHFFFAOYSA-N 0.000 description 2
238000007792 addition Methods 0.000 description 2
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
230000008901 benefit Effects 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
UJYLYGDHTIVYRI-UHFFFAOYSA-N cadmium(2+);ethane Chemical compound [Cd+2].[CH2-]C.[CH2-]C UJYLYGDHTIVYRI-UHFFFAOYSA-N 0.000 description 2
MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
238000010908 decantation Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
239000007789 gas Substances 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
239000011261 inert gas Substances 0.000 description 2
230000004048 modification Effects 0.000 description 2
238000012986 modification Methods 0.000 description 2
239000012299 nitrogen atmosphere Substances 0.000 description 2
230000001590 oxidative effect Effects 0.000 description 2
239000002245 particle Substances 0.000 description 2
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
239000000843 powder Substances 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
229910052723 transition metal Inorganic materials 0.000 description 2
150000003624 transition metals Chemical class 0.000 description 2
238000011282 treatment Methods 0.000 description 2
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 2
CNWZYDSEVLFSMS-UHFFFAOYSA-N tripropylalumane Chemical compound CCC[Al](CCC)CCC CNWZYDSEVLFSMS-UHFFFAOYSA-N 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 description 1
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
238000006418 Brown reaction Methods 0.000 description 1
CAQWNKXTMBFBGI-UHFFFAOYSA-N C.[Na] Chemical compound C.[Na] CAQWNKXTMBFBGI-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
239000004793 Polystyrene Substances 0.000 description 1
229910003074 TiCl4 Inorganic materials 0.000 description 1
230000009471 action Effects 0.000 description 1
230000001464 adherent effect Effects 0.000 description 1
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
229910052786 argon Inorganic materials 0.000 description 1
239000012300 argon atmosphere Substances 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
VJWQKBDLTVGKQE-UHFFFAOYSA-N benzene;cadmium(2+) Chemical compound [Cd+2].C1=CC=[C-]C=C1.C1=CC=[C-]C=C1 VJWQKBDLTVGKQE-UHFFFAOYSA-N 0.000 description 1
HQMRIBYCTLBDAK-UHFFFAOYSA-M bis(2-methylpropyl)alumanylium;chloride Chemical compound CC(C)C[Al](Cl)CC(C)C HQMRIBYCTLBDAK-UHFFFAOYSA-M 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
ISFMCQATCMRFPY-UHFFFAOYSA-M chloro(diphenyl)alumane Chemical compound [Cl-].C=1C=CC=CC=1[Al+]C1=CC=CC=C1 ISFMCQATCMRFPY-UHFFFAOYSA-M 0.000 description 1
238000010924 continuous production Methods 0.000 description 1
WAUAJTBCLLNWQZ-UHFFFAOYSA-L dibromo(2-methylpropyl)alumane Chemical compound [Br-].[Br-].CC(C)C[Al+2] WAUAJTBCLLNWQZ-UHFFFAOYSA-L 0.000 description 1
AILPTUURQRJHHF-UHFFFAOYSA-N diethyl(2-methylpropyl)alumane Chemical compound CC[Al](CC)CC(C)C AILPTUURQRJHHF-UHFFFAOYSA-N 0.000 description 1
HJXBDPDUCXORKZ-UHFFFAOYSA-N diethylalumane Chemical compound CC[AlH]CC HJXBDPDUCXORKZ-UHFFFAOYSA-N 0.000 description 1
KZLUHGRPVSRSHI-UHFFFAOYSA-N dimethylmagnesium Chemical compound C[Mg]C KZLUHGRPVSRSHI-UHFFFAOYSA-N 0.000 description 1
ZMXPNWBFRPIZFV-UHFFFAOYSA-M dipropylalumanylium;chloride Chemical compound [Cl-].CCC[Al+]CCC ZMXPNWBFRPIZFV-UHFFFAOYSA-M 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
SHGOGDWTZKFNSC-UHFFFAOYSA-N ethyl(dimethyl)alumane Chemical compound CC[Al](C)C SHGOGDWTZKFNSC-UHFFFAOYSA-N 0.000 description 1
MGDOJPNDRJNJBK-UHFFFAOYSA-N ethylaluminum Chemical compound [Al].C[CH2] MGDOJPNDRJNJBK-UHFFFAOYSA-N 0.000 description 1
230000007717 exclusion Effects 0.000 description 1
238000000605 extraction Methods 0.000 description 1
150000008282 halocarbons Chemical class 0.000 description 1
230000006872 improvement Effects 0.000 description 1
239000012280 lithium aluminium hydride Substances 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
YSTQWZZQKCCBAY-UHFFFAOYSA-L methylaluminum(2+);dichloride Chemical compound C[Al](Cl)Cl YSTQWZZQKCCBAY-UHFFFAOYSA-L 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
229920001083 polybutene Polymers 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
230000009467 reduction Effects 0.000 description 1
229930195734 saturated hydrocarbon Natural products 0.000 description 1
239000007790 solid phase Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
230000000707 stereoselective effect Effects 0.000 description 1
PUGUQINMNYINPK-UHFFFAOYSA-N tert-butyl 4-(2-chloroacetyl)piperazine-1-carboxylate Chemical compound CC(C)(C)OC(=O)N1CCN(C(=O)CCl)CC1 PUGUQINMNYINPK-UHFFFAOYSA-N 0.000 description 1
ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
JQPMDTQDAXRDGS-UHFFFAOYSA-N triphenylalumane Chemical compound C1=CC=CC=C1[Al](C=1C=CC=CC=1)C1=CC=CC=C1 JQPMDTQDAXRDGS-UHFFFAOYSA-N 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1

Classifications

- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F1/00—Wet end of machines for making continuous webs of paper
- D21F1/02—Head boxes of Fourdrinier machines
- D21F1/028—Details of the nozzle section
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F1/00—Wet end of machines for making continuous webs of paper
- D21F1/02—Head boxes of Fourdrinier machines
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F9/00—Complete machines for making continuous webs of paper
- D21F9/02—Complete machines for making continuous webs of paper of the Fourdrinier type

Landscapes

Paper (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

NO16880667A 1966-08-06 1967-06-28 NO130734C (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DEV0031666		1966-08-06

Publications (2)

Publication Number	Publication Date
NO130734B true NO130734B (de)	1974-10-21
NO130734C NO130734C (de)	1975-01-29

Family

ID=7586605

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO16880667A NO130734C (de)	1966-08-06	1967-06-28

Country Status (7)

Country	Link
AT (1)	AT283895B (de)
CH (1)	CH451687A (de)
DE (1)	DE1511247B1 (de)
FI (1)	FI45362C (de)
GB (1)	GB1196947A (de)
NO (1)	NO130734C (de)
SE (1)	SE333865B (de)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN110016830B (zh) *	2019-04-16	2023-06-20	华南理工大学	一种斜网成型器用的非接触式密封装置及方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE62528C (de) *			CH. WANDEL in Reutlingen, Württemberg	Stopfbüchse für den Hals von rohrenden Sortircylindern, Entwässerungscylihdern u. dergl
US1742294A (en) *	1926-12-18	1930-01-07	Albert D Wood	Pulp or fiber thickener
US2737088A (en) *	1952-04-22	1956-03-06	Millspaugh Ltd	Paper-making machines

1966
- 1966-08-06 DE DE19661511247 patent/DE1511247B1/de not_active Withdrawn
1967
- 1967-06-28 NO NO16880667A patent/NO130734C/no unknown
- 1967-06-29 SE SE966867A patent/SE333865B/xx unknown
- 1967-07-24 GB GB3393867A patent/GB1196947A/en not_active Expired
- 1967-08-03 AT AT720367A patent/AT283895B/de not_active IP Right Cessation
- 1967-08-04 FI FI212067A patent/FI45362C/fi active
- 1967-08-04 CH CH1103867A patent/CH451687A/de unknown

Also Published As

Publication number	Publication date
FI45362B (de)	1972-01-31
GB1196947A (en)	1970-07-01
NO130734C (de)	1975-01-29
CH451687A (de)	1968-05-15
FI45362C (fi)	1972-05-10
AT283895B (de)	1970-08-25
DE1511247B1 (de)	1970-01-15
SE333865B (de)	1971-03-29

Publication	Publication Date	Title
NO153609B (no)	1986-01-13	Polymerisasjonskatalysator.
SU424360A3 (ru)	1974-04-15	Способ получения полиолефинов
NO833427L (no)	1984-04-02	Fremgangsmaate ved fremstilling av katalysatorer for polymerisasjon av olefiner
JPH0224282B2 (de)	1990-05-29
NO134092B (de)	1976-05-10
HU202562B (en)	1991-04-29	Process for producing solid catalyst composition and for using it for stereospecific polymerization of propylene
NO794002L (no)	1980-06-12	Katalysator og fremgangsmaate til polymerisering av alfa-alkener ved anvendelse av katalysatoren
US4199476A (en)	1980-04-22	Olefin polymerization catalyst
NO178434B (no)	1995-12-18	Fremgangsmåte for fremstilling av en fast katalysatorbestanddel, en katalysator og anvendelse av denne ved (ko)polymerisasjon av etylen
JPS5919565B2 (ja)	1984-05-07	α−オレフインの重合用触媒成分の製造法
US4250286A (en)	1981-02-10	Ultra high efficiency catalyst for polymerizing olefins
NO168651B (no)	1991-12-09	Fremgangsmaate ved polymerisasjon av olefiner.
NO160786B (no)	1989-02-20	Katalysator til polymerisering av alkener og anvendelse av katalysatoren til polymerisering av propen.
US4097659A (en)	1978-06-27	Process of polymerizing α-olefins in the liquid phase
JPS59138206A (ja)	1984-08-08	オレフィン重合用触媒成分の製造方法
GB2085016A (en)	1982-04-21	Catalytic composition and its use for producing highly stereoregular a-olefin polymers
US3100764A (en)	1963-08-13	Control of pentane-soluble polymers in the polymerization of propylene
US4276191A (en)	1981-06-30	Catalyst and process for polymerization of alpha-olefins
US3135702A (en)	1964-06-02	Polymerization catalyst
JPS6124403B2 (de)	1986-06-11
NO144389B (no)	1981-05-11	Fremgangsmaate ved homopolymerisering av etylen eller propylen eller sampolymerisering av etylen med en alfa-olefin og/eller diolefin, samt katalysatorblanding for utfoerelse av fremgangsmaaten
NO157063B (no)	1987-10-05	Fremgangsmte for fremstilling av etylen-propylen-blokk-sampolymerer.
US4008177A (en)	1977-02-15	Process for the manufacture of a catalyst
JPS6354722B2 (de)	1988-10-31
US3068216A (en)	1962-12-11	Preparation of high molecular weight isotactic polymers from alpha-olefinic hydrocarbons