NO20070161L - Syntese av mikroporos silikagel og dens anvendelse for fremstilling av katalysatorer for C2-oksygenater fra syngas - Google Patents

Syntese av mikroporos silikagel og dens anvendelse for fremstilling av katalysatorer for C2-oksygenater fra syngas

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Publication number
NO20070161L
NO20070161L NO20070161A NO20070161A NO20070161L NO 20070161 L NO20070161 L NO 20070161L NO 20070161 A NO20070161 A NO 20070161A NO 20070161 A NO20070161 A NO 20070161A NO 20070161 L NO20070161 L NO 20070161L
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NO
Norway
Prior art keywords
synthesis
metal salts
catalysts
microporous
silica gel
Prior art date
Application number
NO20070161A
Other languages
English (en)
Inventor
Hongyuan Luo
Yunjie Ding
Hongmei Yin
Original Assignee
Dalian Chemical Physics Inst
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Filing date
Publication date
Application filed by Dalian Chemical Physics Inst filed Critical Dalian Chemical Physics Inst
Publication of NO20070161L publication Critical patent/NO20070161L/no

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/124—Preparation of adsorbing porous silica not in gel form and not finely divided, i.e. silicon skeletons, by acidic treatment of siliceous materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/464—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8986—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • C07C29/157—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof
    • C07C29/158—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof containing rhodium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B01J37/033—Using Hydrolysis

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Silicon Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Det er beskrevet en syntese av mikroporøs silikagel og dens anvendelse for fremstilling av katalysatorer for C-oksygenatsyntese fra syngas. De små partiklene av silikagel som er fremstilt ved solgelprosessen oppvarmes i en basisk oppløsning, etterfulgt av tørking og/eller kalsineringer, og danner derved mikroporøs silika som katalysatorbærer. Den basiske oppløsningen kan være en eller en blandet oppløsning av hydroksyder, karbonater, bikarbonater, formater og acetater av alkalimetall og ammonium. Den oppnådde mikroporøse silika kan impregneres med oppløsningene av rhodiumsalt og andre overgangselementsalter (som promoterforstadier), etterfulgt av tørking og/eller kalsineringer, for derved å danne en mikroporøs, silikabåret rhodiumbasert katalysator. Rhodiumsaltet kan være RhCleller Rh(N0). Promoterforstadiene kan være vannoppløsbare overgangsmetallsalter, sjeldne jordartsmetallsalter, alkalimetallsalter og jordalkalimetallsalter. De oppnådde katalysatorene viser høy aktivitet og selektivitet ved syntesen av C-oksygenater ved hydrogeneringen av CO under milde prosessbetingelser.
NO20070161A 2004-06-23 2007-01-09 Syntese av mikroporos silikagel og dens anvendelse for fremstilling av katalysatorer for C2-oksygenater fra syngas NO20070161L (no)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/GB2004/002701 WO2006000734A1 (en) 2004-06-23 2004-06-23 The synthesis of the micro-porous silica gel and its application to the preparation of catalysts for c2 oxygenates synthesis from syngas

Publications (1)

Publication Number Publication Date
NO20070161L true NO20070161L (no) 2007-01-09

Family

ID=34957799

Family Applications (1)

Application Number Title Priority Date Filing Date
NO20070161A NO20070161L (no) 2004-06-23 2007-01-09 Syntese av mikroporos silikagel og dens anvendelse for fremstilling av katalysatorer for C2-oksygenater fra syngas

Country Status (10)

Country Link
US (1) US20070249874A1 (no)
EP (1) EP1771245A1 (no)
JP (1) JP2008503440A (no)
AU (1) AU2004320979A1 (no)
BR (1) BRPI0418926A (no)
CA (1) CA2586418A1 (no)
EA (1) EA200602293A1 (no)
NO (1) NO20070161L (no)
RS (1) RS20060683A (no)
WO (1) WO2006000734A1 (no)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MXPA05004966A (es) 2002-11-12 2005-08-02 Mallinckrodt Inc Derivados cristalinos de canabinoide y procesos de purificacion de canabinoide.
JP2010116328A (ja) * 2008-11-11 2010-05-27 Nippon Oil Corp 不飽和炭化水素および含酸素化合物の製造方法、触媒およびその製造方法
TWI473652B (zh) 2008-12-26 2015-02-21 Nippon Oil Corp Hydrogenated isomerization catalyst, method for producing the same, dewaxing method for hydrocarbon oil and method for producing lubricating base oil
KR101404214B1 (ko) 2011-12-28 2014-06-10 한국에너지기술연구원 동시 용융함침에 의한 혼성 합금 촉매 담지체 제조 방법 및 그 혼성 합금 촉매 담지체
JP5999569B2 (ja) 2012-02-28 2016-09-28 積水化学工業株式会社 Ｃ２酸素化物合成用の触媒、ｃ２酸素化物の製造装置及びｃ２酸素化物の製造方法
JP6037305B2 (ja) * 2012-12-27 2016-12-07 積水化学工業株式会社 Ｃ２酸素化物合成用の触媒、ｃ２酸素化物の製造装置及びｃ２酸素化物の製造方法
WO2014114822A1 (es) 2013-01-24 2014-07-31 Abengoa Bioenergía Nuevas Tecnologías, S.A Catalizador de rodio promovido para la conversión selectiva de gas de síntesis en etanol
JP2015178101A (ja) * 2014-02-28 2015-10-08 積水化学工業株式会社 酸素化物合成用の触媒、酸素化物合成用の触媒の製造方法、酸素化物の製造装置及び酸素化物の製造方法
JP2020509925A (ja) * 2017-03-10 2020-04-02 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 合成ガスをアルコール類に転化するための触媒
CN113842905B (zh) * 2020-06-28 2023-08-29 中国石油化工股份有限公司 一种载体和催化剂及其制备方法和应用
CN116983971A (zh) * 2023-08-02 2023-11-03 青岛邦凯高新技术材料有限公司 一种石油化工中用催化剂载体二氧化硅的制备方法

Family Cites Families (6)

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JPS6049617B2 (ja) * 1983-08-03 1985-11-02 工業技術院長 エタノ−ルなどの含酸素化合物を製造する方法
US5256386A (en) * 1987-06-29 1993-10-26 Eka Nobel Ab Method for preparation of silica particles
DE3803895C1 (no) * 1988-02-09 1989-04-13 Degussa Ag, 6000 Frankfurt, De
DE3803899C1 (no) * 1988-02-09 1989-04-13 Degussa Ag, 6000 Frankfurt, De
CN1074306C (zh) * 1996-09-25 2001-11-07 中国科学院大连化学物理研究所 一种用于一氧化碳加氢合成乙醇乙酸乙醛的铑基催化剂
DE19929281A1 (de) * 1999-06-25 2000-12-28 Basf Ag Verfahren und Katalysator zur Herstellung von C¶2¶-Oxygenaten aus Synthesegas

Also Published As

Publication number Publication date
JP2008503440A (ja) 2008-02-07
BRPI0418926A (pt) 2007-11-27
WO2006000734A1 (en) 2006-01-05
EA200602293A1 (ru) 2007-06-29
RS20060683A (sr) 2008-06-05
AU2004320979A1 (en) 2006-01-05
CA2586418A1 (en) 2006-01-05
EP1771245A1 (en) 2007-04-11
US20070249874A1 (en) 2007-10-25

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