NO318680B1 - Metode for a fremstille krystallinsk, mikroporost metalloaluminofosfat fra et fast legeme og anvendelse derav - Google Patents
Metode for a fremstille krystallinsk, mikroporost metalloaluminofosfat fra et fast legeme og anvendelse derav Download PDFInfo
- Publication number
- NO318680B1 NO318680B1 NO20015437A NO20015437A NO318680B1 NO 318680 B1 NO318680 B1 NO 318680B1 NO 20015437 A NO20015437 A NO 20015437A NO 20015437 A NO20015437 A NO 20015437A NO 318680 B1 NO318680 B1 NO 318680B1
- Authority
- NO
- Norway
- Prior art keywords
- sapo
- particles
- metal
- elapo
- synthesis
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 40
- 239000007787 solid Substances 0.000 title claims description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 58
- 238000003786 synthesis reaction Methods 0.000 claims description 42
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 36
- 239000000203 mixture Substances 0.000 claims description 35
- 230000015572 biosynthetic process Effects 0.000 claims description 34
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 30
- 239000007788 liquid Substances 0.000 claims description 29
- 238000004519 manufacturing process Methods 0.000 claims description 29
- 229940073455 tetraethylammonium hydroxide Drugs 0.000 claims description 28
- LRGJRHZIDJQFCL-UHFFFAOYSA-M tetraethylazanium;hydroxide Chemical compound [OH-].CC[N+](CC)(CC)CC LRGJRHZIDJQFCL-UHFFFAOYSA-M 0.000 claims description 28
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 claims description 27
- 239000002245 particle Substances 0.000 claims description 27
- 229910017119 AlPO Inorganic materials 0.000 claims description 23
- 239000011541 reaction mixture Substances 0.000 claims description 21
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 claims description 18
- 239000000377 silicon dioxide Substances 0.000 claims description 18
- 239000003054 catalyst Substances 0.000 claims description 17
- 239000003795 chemical substances by application Substances 0.000 claims description 16
- 238000002425 crystallisation Methods 0.000 claims description 15
- 230000008025 crystallization Effects 0.000 claims description 15
- 239000002808 molecular sieve Substances 0.000 claims description 15
- 239000011148 porous material Substances 0.000 claims description 15
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 15
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 claims description 14
- 239000000376 reactant Substances 0.000 claims description 14
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 claims description 14
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 239000002184 metal Substances 0.000 claims description 12
- 229910052710 silicon Inorganic materials 0.000 claims description 11
- 239000010703 silicon Substances 0.000 claims description 11
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 9
- 229940043279 diisopropylamine Drugs 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 8
- 150000001336 alkenes Chemical class 0.000 claims description 8
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims description 8
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 claims description 8
- 239000013078 crystal Substances 0.000 claims description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 238000001027 hydrothermal synthesis Methods 0.000 claims description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 239000011651 chromium Substances 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 239000010941 cobalt Substances 0.000 claims description 4
- 229910017052 cobalt Inorganic materials 0.000 claims description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 241000269350 Anura Species 0.000 claims description 2
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 claims description 2
- XOBKSJJDNFUZPF-UHFFFAOYSA-N Methoxyethane Chemical compound CCOC XOBKSJJDNFUZPF-UHFFFAOYSA-N 0.000 claims description 2
- 239000003463 adsorbent Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims 1
- 238000002441 X-ray diffraction Methods 0.000 description 38
- 239000000463 material Substances 0.000 description 28
- 238000002156 mixing Methods 0.000 description 17
- 239000000843 powder Substances 0.000 description 14
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 8
- 229910052698 phosphorus Inorganic materials 0.000 description 8
- 239000000523 sample Substances 0.000 description 8
- 229910001220 stainless steel Inorganic materials 0.000 description 8
- 239000010935 stainless steel Substances 0.000 description 8
- 239000010457 zeolite Substances 0.000 description 8
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical group O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 7
- 239000000499 gel Substances 0.000 description 7
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 6
- 238000010335 hydrothermal treatment Methods 0.000 description 6
- 239000011159 matrix material Substances 0.000 description 6
- 239000011574 phosphorus Substances 0.000 description 6
- 229910021536 Zeolite Inorganic materials 0.000 description 5
- 230000003197 catalytic effect Effects 0.000 description 5
- 239000003153 chemical reaction reagent Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 229910019142 PO4 Inorganic materials 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 239000004809 Teflon Substances 0.000 description 4
- 229920006362 Teflon® Polymers 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 229910001408 cation oxide Inorganic materials 0.000 description 3
- 239000006259 organic additive Substances 0.000 description 3
- -1 silica hydroxides Chemical class 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 239000002178 crystalline material Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 239000013074 reference sample Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- MYXKPFMQWULLOH-UHFFFAOYSA-M tetramethylazanium;hydroxide;pentahydrate Chemical compound O.O.O.O.O.[OH-].C[N+](C)(C)C MYXKPFMQWULLOH-UHFFFAOYSA-M 0.000 description 2
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- 241000282326 Felis catus Species 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- RGYJAUFQHNHJMU-UHFFFAOYSA-K aluminum;azanium;hydroxide;phosphate Chemical compound [NH4+].[OH-].[Al+3].[O-]P([O-])([O-])=O RGYJAUFQHNHJMU-UHFFFAOYSA-K 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 239000000017 hydrogel Substances 0.000 description 1
- 239000011872 intimate mixture Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000006069 physical mixture Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000013341 scale-up Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000004876 x-ray fluorescence Methods 0.000 description 1
- 239000012690 zeolite precursor Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
- B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
- B01J29/85—Silicoaluminophosphates [SAPO compounds]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
- B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
- C01B37/065—Aluminophosphates containing other elements, e.g. metals, boron the other elements being metals only
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
- C01B37/08—Silicoaluminophosphates [SAPO compounds], e.g. CoSAPO
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
- C10G3/44—Catalytic treatment characterised by the catalyst used
- C10G3/45—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
- C10G3/44—Catalytic treatment characterised by the catalyst used
- C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
- C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0027—Powdering
- B01J37/0045—Drying a slurry, e.g. spray drying
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/82—Phosphates
- C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
- C07C2529/85—Silicoaluminophosphates (SAPO compounds)
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/20—C2-C4 olefins
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Catalysts (AREA)
Priority Applications (15)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NO20015437A NO318680B1 (no) | 2001-11-07 | 2001-11-07 | Metode for a fremstille krystallinsk, mikroporost metalloaluminofosfat fra et fast legeme og anvendelse derav |
| PCT/NO2002/000407 WO2003040037A1 (en) | 2001-11-07 | 2002-11-06 | Method of synthesising crystalline microporous metalloaluminophosphate from a solid body |
| ES02778112T ES2284936T3 (es) | 2001-11-07 | 2002-11-06 | Metodo para sintetizar metaloaluminofosfato microporoso cristalino a partir de un cuerpo solido. |
| CA2465947A CA2465947C (en) | 2001-11-07 | 2002-11-06 | Method of synthesising crystalline microporous metalloaluminophosphate from a solid body |
| AT02778112T ATE358653T1 (de) | 2001-11-07 | 2002-11-06 | Verfahren zur synthese von kristallinem mikroporösem metalloaluminiumphosphat aus einem festen körper |
| PT02778112T PT1461288E (pt) | 2001-11-07 | 2002-11-06 | Processo para síntese de metaloaluminofosfato microporoso cristalino a partir de um corpo sólido. |
| US10/494,862 US7341706B2 (en) | 2001-11-07 | 2002-11-06 | Method of synthesising crystalline microporous metalloaluminophosphate for a solid body |
| MXPA04004420A MXPA04004420A (es) | 2001-11-07 | 2002-11-06 | Metodo para sintetizar metaloaluminofosfato microporoso cristalino de un cuerpo solido. |
| BR0214000-4A BR0214000A (pt) | 2001-11-07 | 2002-11-06 | Método de sìntese de metaloaluminofosfato (elapo) microporoso cristalino a partir de um corpo sólido, e, uso de partìculas |
| DK02778112T DK1461288T3 (da) | 2001-11-07 | 2002-11-06 | Metode til syntese af krystallinsk mikroprröds metalloaluminophosphat fra et fast legeme |
| EP02778112A EP1461288B1 (de) | 2001-11-07 | 2002-11-06 | Verfahren zur synthese von kristallinem mikroporösem metalloaluminiumphosphat aus einem festen körper |
| RU2004117071/15A RU2311343C2 (ru) | 2001-11-07 | 2002-11-06 | Способ синтеза кристаллического микропористого металлоалюмофосфата из твердого вещества |
| CNB02826598XA CN1308236C (zh) | 2001-11-07 | 2002-11-06 | 由固体基质合成结晶微孔金属铝磷酸盐的方法 |
| DE60219357T DE60219357T2 (de) | 2001-11-07 | 2002-11-06 | Verfahren zur synthese von kristallinem mikroporösem metalloaluminiumphosphat aus einem festen körper |
| AU2002339763A AU2002339763B2 (en) | 2001-11-07 | 2002-11-06 | Method of synthesising crystalline microporous metalloaluminophosphate from a solid body |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NO20015437A NO318680B1 (no) | 2001-11-07 | 2001-11-07 | Metode for a fremstille krystallinsk, mikroporost metalloaluminofosfat fra et fast legeme og anvendelse derav |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO20015437D0 NO20015437D0 (no) | 2001-11-07 |
| NO20015437L NO20015437L (no) | 2003-05-08 |
| NO318680B1 true NO318680B1 (no) | 2005-04-25 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO20015437A NO318680B1 (no) | 2001-11-07 | 2001-11-07 | Metode for a fremstille krystallinsk, mikroporost metalloaluminofosfat fra et fast legeme og anvendelse derav |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US7341706B2 (de) |
| EP (1) | EP1461288B1 (de) |
| CN (1) | CN1308236C (de) |
| AT (1) | ATE358653T1 (de) |
| AU (1) | AU2002339763B2 (de) |
| BR (1) | BR0214000A (de) |
| CA (1) | CA2465947C (de) |
| DE (1) | DE60219357T2 (de) |
| DK (1) | DK1461288T3 (de) |
| ES (1) | ES2284936T3 (de) |
| MX (1) | MXPA04004420A (de) |
| NO (1) | NO318680B1 (de) |
| PT (1) | PT1461288E (de) |
| RU (1) | RU2311343C2 (de) |
| WO (1) | WO2003040037A1 (de) |
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| NO319881B1 (no) * | 2002-05-31 | 2005-09-26 | Polymers Holding As | Fremgangsmate for in-situ syntese av krystallint mikroporost metalloaluminofosfat i faste legemer samt anvendelse av de faste legemer |
| EP1733004B1 (de) | 2004-04-05 | 2012-09-12 | ExxonMobil Chemical Patents Inc. | Kristallines verwachsungsmaterial, synthese davon und verwendung davon bei der umwandlung von oxygenaten in olefine |
| CN1304291C (zh) * | 2004-06-09 | 2007-03-14 | 中国科学院上海硅酸盐研究所 | 一种无机微孔磷酸镍钴类分子筛材料及其合成方法 |
| US7067095B1 (en) * | 2004-12-09 | 2006-06-27 | Exxonmobil Chemical Patents Inc. | Synthesis of silicoaluminophosphate molecular sieves |
| US20070059236A1 (en) * | 2005-09-09 | 2007-03-15 | Broach Robert W | Molecular sieves with high selectivity towards light olefins in methanol to olefin conversion |
| US8409326B2 (en) * | 2006-05-15 | 2013-04-02 | The Regents Of The University Of Colorado | High flux and selectivity SAPO-34 membranes for CO2/CH4separations |
| TW200904752A (en) * | 2007-03-09 | 2009-02-01 | Univ Colorado Regents | Synthesis of zeolites and zeolite membranes using multiple structure directing agents |
| EP2246111A3 (de) * | 2007-03-26 | 2011-09-07 | PQ Corporation | Neues mikroporöses kristallines Material mit einem Molekularsieb oder Zeolith mit 8-Ring-Porenöffnungsstruktur sowie Verfahren zu dessen Herstellung und Verwendung |
| US8815764B2 (en) * | 2007-08-31 | 2014-08-26 | Uop Llc | Water treated catalyst to produce light olefins |
| WO2009140565A1 (en) * | 2008-05-15 | 2009-11-19 | Shell Oil Company | Method of making a high-performance supported gas separation molecular sieve membrane using a shortened crystallization time |
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| US8309772B2 (en) | 2008-07-31 | 2012-11-13 | Celanese International Corporation | Tunable catalyst gas phase hydrogenation of carboxylic acids |
| US8309773B2 (en) | 2010-02-02 | 2012-11-13 | Calanese International Corporation | Process for recovering ethanol |
| US8546622B2 (en) | 2008-07-31 | 2013-10-01 | Celanese International Corporation | Process for making ethanol from acetic acid using acidic catalysts |
| EP2161242A1 (de) | 2008-08-29 | 2010-03-10 | Total Petrochemicals Research Feluy | Verfahren zur Herstellung eines kristallinen Metallaluminophosphat(MeAPO)-Molekularsiebs aus amorphen Materialien |
| EP2161243A1 (de) | 2008-08-29 | 2010-03-10 | Total Petrochemicals Research Feluy | Verfahren zur Herstellung von Metallaluminophosphat(MeAPO)-Molekularsieben |
| US7820853B2 (en) | 2008-12-31 | 2010-10-26 | Celanese International Corporation | Integrated process for the production of vinyl acetate from acetic acid via ethyl acetate |
| GB0900198D0 (en) * | 2009-01-07 | 2009-02-11 | Univ Southampton | Ammoximation process |
| ES2601799T3 (es) | 2009-06-12 | 2017-02-16 | Albemarle Europe Sprl. | Catalizadores de tamiz molecular SAPO y su preparación y usos |
| US8680321B2 (en) | 2009-10-26 | 2014-03-25 | Celanese International Corporation | Processes for making ethanol from acetic acid using bimetallic catalysts |
| US8211821B2 (en) | 2010-02-01 | 2012-07-03 | Celanese International Corporation | Processes for making tin-containing catalysts |
| US8932372B2 (en) | 2010-02-02 | 2015-01-13 | Celanese International Corporation | Integrated process for producing alcohols from a mixed acid feed |
| US8858659B2 (en) | 2010-02-02 | 2014-10-14 | Celanese International Corporation | Processes for producing denatured ethanol |
| US8460405B2 (en) | 2010-02-02 | 2013-06-11 | Celanese International Corporation | Ethanol compositions |
| US8222466B2 (en) | 2010-02-02 | 2012-07-17 | Celanese International Corporation | Process for producing a water stream from ethanol production |
| US8541633B2 (en) | 2010-02-02 | 2013-09-24 | Celanese International Corporation | Processes for producing anhydrous ethanol compositions |
| US8568518B2 (en) | 2010-03-04 | 2013-10-29 | Shell Oil Company | Method of making SAPO-34 membranes for use in gas separations |
| US8679227B2 (en) | 2010-04-29 | 2014-03-25 | The Regents Of The University Of Colorado | High flux SAPO-34 membranes for CO2/CH4 separation and template removal method |
| US8569551B2 (en) | 2010-05-07 | 2013-10-29 | Celanese International Corporation | Alcohol production process integrating acetic acid feed stream comprising water from carbonylation process |
| CN102350297B (zh) * | 2011-09-14 | 2013-06-12 | 安徽师范大学 | 一种吸附剂、制备方法及其应用 |
| US8907142B2 (en) | 2011-12-29 | 2014-12-09 | Celanese International Corporation | Process for promoting catalyst activity for ethyl acetate conversion |
| US9637392B2 (en) | 2012-05-24 | 2017-05-02 | Tosoh Corporation | Silicoaluminophosphate, method for producing the same, and solid acid catalyst comprising the same |
| DK2902362T3 (en) | 2012-09-26 | 2017-08-07 | Dalian Inst Chemical Physics Cas | SAPO-34 MOLECULE AND SYNTHESIS PROCEDURES |
| US8772553B2 (en) | 2012-10-26 | 2014-07-08 | Celanese International Corporation | Hydrogenation reaction conditions for producing ethanol |
| US8957262B2 (en) | 2012-11-20 | 2015-02-17 | Celanese International Corporation | Olefin hydration for hydrogenation processes |
| US20140171713A1 (en) * | 2012-12-14 | 2014-06-19 | Uop Llc | Nano sapo-35 and method of making |
| KR20170044145A (ko) | 2014-08-22 | 2017-04-24 | 더블유.알. 그레이스 앤드 캄파니-콘. | 모노아이소프로판올아민을 사용하여 실리코알루미노포스페이트-34 분자체를 합성하는 방법 |
| GB2540832B (en) * | 2015-02-20 | 2019-04-17 | Johnson Matthey Plc | Bi-metal molecular sieve catalysts |
| CN108602052B (zh) | 2016-05-25 | 2021-11-26 | 环球油品公司 | 高电荷密度金属磷酸盐分子筛 |
| WO2017214531A1 (en) | 2016-06-10 | 2017-12-14 | Chevron U.S.A. Inc. | Hydrophobic adsorbents and mercury removal processes therewith |
| CN108249458B (zh) * | 2018-03-19 | 2021-03-09 | 深圳科冠华太新材料技术有限公司 | 一种金属改性sapo-34分子筛的合成方法 |
| US12194446B2 (en) | 2020-09-14 | 2025-01-14 | China Petroleum & Chemical Corporation | SCM-34 molecular sieve, preparation method therefor and use thereof |
| CN119349596A (zh) * | 2024-12-30 | 2025-01-24 | 洛阳建龙微纳新材料股份有限公司 | 一种多级孔sapo-18分子筛及其合成方法和应用 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4973785A (en) * | 1984-04-13 | 1990-11-27 | Uop | Molecular sieve compositions |
| US4861743A (en) * | 1987-11-25 | 1989-08-29 | Uop | Process for the production of molecular sieves |
| NO174341B1 (no) * | 1991-12-23 | 1994-04-21 | Polymers Holding As | Fremg for fremst av krystallinske mikroporose SiAl-fosfater med kontrollert Si-innh, krystallinske mikroporose SiAl-fosfater med forbedret stabilitet mot deaktivering og en anv av disse ved fremstilling av olefiner fra metanol |
| US5879655A (en) * | 1992-11-02 | 1999-03-09 | Chevron Research And Technology Company | Method of making microporous non-zeolitic molecular sieves |
| US5514362A (en) | 1994-05-03 | 1996-05-07 | Chevron U.S.A. Inc. | Preparation of non-zeolitic molecular sieves |
| NO304108B1 (no) * | 1996-10-09 | 1998-10-26 | Polymers Holding As | En mikroporos silikoaluminofosfat-sammensetning, katalytisk materiale som omfatter denne sammensetningen og fremgangsmate for fremstilling derav, og bruken av disse for a fremstille olefiner fra metanol |
| US6004527A (en) * | 1997-09-29 | 1999-12-21 | Abb Lummus Global Inc. | Method for making molecular sieves and novel molecular sieve compositions |
-
2001
- 2001-11-07 NO NO20015437A patent/NO318680B1/no not_active IP Right Cessation
-
2002
- 2002-11-06 WO PCT/NO2002/000407 patent/WO2003040037A1/en not_active Ceased
- 2002-11-06 CN CNB02826598XA patent/CN1308236C/zh not_active Expired - Fee Related
- 2002-11-06 AT AT02778112T patent/ATE358653T1/de not_active IP Right Cessation
- 2002-11-06 DE DE60219357T patent/DE60219357T2/de not_active Expired - Lifetime
- 2002-11-06 EP EP02778112A patent/EP1461288B1/de not_active Revoked
- 2002-11-06 CA CA2465947A patent/CA2465947C/en not_active Expired - Fee Related
- 2002-11-06 US US10/494,862 patent/US7341706B2/en not_active Expired - Fee Related
- 2002-11-06 RU RU2004117071/15A patent/RU2311343C2/ru not_active IP Right Cessation
- 2002-11-06 BR BR0214000-4A patent/BR0214000A/pt not_active Application Discontinuation
- 2002-11-06 DK DK02778112T patent/DK1461288T3/da active
- 2002-11-06 PT PT02778112T patent/PT1461288E/pt unknown
- 2002-11-06 MX MXPA04004420A patent/MXPA04004420A/es active IP Right Grant
- 2002-11-06 ES ES02778112T patent/ES2284936T3/es not_active Expired - Lifetime
- 2002-11-06 AU AU2002339763A patent/AU2002339763B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| BR0214000A (pt) | 2004-11-03 |
| CA2465947C (en) | 2011-04-19 |
| MXPA04004420A (es) | 2004-08-11 |
| DE60219357D1 (de) | 2007-05-16 |
| AU2002339763B2 (en) | 2008-06-12 |
| EP1461288A1 (de) | 2004-09-29 |
| PT1461288E (pt) | 2007-07-03 |
| CN1610648A (zh) | 2005-04-27 |
| CA2465947A1 (en) | 2003-05-15 |
| RU2311343C2 (ru) | 2007-11-27 |
| ATE358653T1 (de) | 2007-04-15 |
| ES2284936T3 (es) | 2007-11-16 |
| US20050003956A1 (en) | 2005-01-06 |
| RU2004117071A (ru) | 2005-05-20 |
| DE60219357T2 (de) | 2007-12-13 |
| EP1461288B1 (de) | 2007-04-04 |
| CN1308236C (zh) | 2007-04-04 |
| US7341706B2 (en) | 2008-03-11 |
| NO20015437D0 (no) | 2001-11-07 |
| WO2003040037A1 (en) | 2003-05-15 |
| NO20015437L (no) | 2003-05-08 |
| DK1461288T3 (da) | 2007-08-13 |
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