NO324842B1 - Fremgangsmate for a modifisere et rent gassturbinanlegg til et kombinert dampturbinanlegg, og regenerert katalysator. - Google Patents

Fremgangsmate for a modifisere et rent gassturbinanlegg til et kombinert dampturbinanlegg, og regenerert katalysator. Download PDF

Info

Publication number: NO324842B1
Authority: NO; Norway
Prior art keywords: catalyst; temperature; turbine plant; denitrification catalyst; denitrification
Prior art date: 2002-04-10

Application number

NO20031511A

Other languages

English (en)

Norwegian (no)

Other versions

NO20031511D0 (no

NO20031511L (no

Inventor

Kozo Iida

Hitoshi Nakamura

Norihisa Kobayashi

Osamu Naito

Yoshiaki Obayashi

Original Assignee

Mitsubishi Heavy Ind Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2002-04-10

Filing date

2003-04-03

Publication date

2007-12-17

2003-04-03 Application filed by Mitsubishi Heavy Ind Ltd filed Critical Mitsubishi Heavy Ind Ltd

2003-04-03 Publication of NO20031511D0 publication Critical patent/NO20031511D0/no

2003-10-13 Publication of NO20031511L publication Critical patent/NO20031511L/no

2007-12-17 Publication of NO324842B1 publication Critical patent/NO324842B1/no

Links

239000003054 catalyst Substances 0.000 title claims abstract description 99
238000000034 method Methods 0.000 title claims abstract description 17
230000001172 regenerating effect Effects 0.000 claims abstract description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 10
238000007654 immersion Methods 0.000 claims description 8
229910052720 vanadium Inorganic materials 0.000 claims description 8
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 8
238000001035 drying Methods 0.000 claims description 4
229910010413 TiO 2 Inorganic materials 0.000 claims description 3
239000007789 gas Substances 0.000 description 27
239000000567 combustion gas Substances 0.000 description 12
238000010276 construction Methods 0.000 description 12
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 10
238000012986 modification Methods 0.000 description 9
230000004048 modification Effects 0.000 description 9
239000000243 solution Substances 0.000 description 5
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
239000007864 aqueous solution Substances 0.000 description 4
238000011084 recovery Methods 0.000 description 4
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
239000000203 mixture Substances 0.000 description 3
235000006408 oxalic acid Nutrition 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
238000005516 engineering process Methods 0.000 description 2
239000007788 liquid Substances 0.000 description 2
JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Inorganic materials O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 2
230000008929 regeneration Effects 0.000 description 2
238000011069 regeneration method Methods 0.000 description 2
239000002918 waste heat Substances 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
239000012530 fluid Substances 0.000 description 1
239000000446 fuel Substances 0.000 description 1
XDBSEZHMWGHVIL-UHFFFAOYSA-M hydroxy(dioxo)vanadium Chemical compound O[V](=O)=O XDBSEZHMWGHVIL-UHFFFAOYSA-M 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
229910000476 molybdenum oxide Inorganic materials 0.000 description 1
LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
229910000069 nitrogen hydride Inorganic materials 0.000 description 1
QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 description 1
PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
239000000843 powder Substances 0.000 description 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
229910001930 tungsten oxide Inorganic materials 0.000 description 1
229910001935 vanadium oxide Inorganic materials 0.000 description 1
238000005406 washing Methods 0.000 description 1
239000002699 waste material Substances 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/92—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
- B01D53/8628—Processes characterised by a specific catalyst
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/96—Regeneration, reactivation or recycling of reactants
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
- B01J38/485—Impregnating or reimpregnating with, or deposition of metal compounds or catalytically active elements
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K23/00—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids
- F01K23/02—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled
- F01K23/06—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle
- F01K23/10—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle with exhaust fluid of one cycle heating the fluid in another cycle
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Environmental & Geological Engineering (AREA)
Organic Chemistry (AREA)
Materials Engineering (AREA)
General Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Health & Medical Sciences (AREA)
Combustion & Propulsion (AREA)
Analytical Chemistry (AREA)
Biomedical Technology (AREA)
Mechanical Engineering (AREA)
Sustainable Development (AREA)
General Engineering & Computer Science (AREA)
Life Sciences & Earth Sciences (AREA)
Catalysts (AREA)
Exhaust Gas Treatment By Means Of Catalyst (AREA)
Engine Equipment That Uses Special Cycles (AREA)

NO20031511A 2002-04-10 2003-04-03 Fremgangsmate for a modifisere et rent gassturbinanlegg til et kombinert dampturbinanlegg, og regenerert katalysator. NO324842B1 (no)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
JP2002107720		2002-04-10
JP2002296071A JP4167039B2 (ja)	2002-04-10	2002-10-09	ガスタービン単独プラントの改造方法、触媒の再利用方法

Publications (3)

Publication Number	Publication Date
NO20031511D0 NO20031511D0 (no)	2003-04-03
NO20031511L NO20031511L (no)	2003-10-13
NO324842B1 true NO324842B1 (no)	2007-12-17

Family

ID=26625718

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO20031511A NO324842B1 (no)	2002-04-10	2003-04-03	Fremgangsmate for a modifisere et rent gassturbinanlegg til et kombinert dampturbinanlegg, og regenerert katalysator.

Country Status (8)

Country	Link
US (1)	US7316988B2 (de)
EP (1)	EP1353042B1 (de)
JP (1)	JP4167039B2 (de)
CA (1)	CA2424417C (de)
DE (1)	DE60306707T2 (de)
DK (1)	DK1353042T3 (de)
ES (1)	ES2268191T3 (de)
NO (1)	NO324842B1 (de)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2011140519A2 (en)	2010-05-07	2011-11-10	Medicus Biosciences, Llc	In vivo gelling pharmaceutical pre-formulation
US11083821B2 (en)	2011-08-10	2021-08-10	C.P. Medical Corporation	Biocompatible hydrogel polymer formulations for the controlled delivery of biomolecules
US10111985B2 (en)	2011-08-10	2018-10-30	Medicus Biosciences, Llc	Biocompatible hydrogel polymer formulations for the controlled delivery of biomolecules
JP6206987B2 (ja)	2012-05-11	2017-10-04	メディカスバイオサイエンシーズ，エルエルシー	網膜剥離の処置のための生体適合性ヒドロゲル製剤
CN102698737B (zh) *	2012-05-25	2014-11-05	中国科学院过程工程研究所	一种scr烟气脱硝催化剂及其原料钛钨粉的制备方法
EP2861326A1 (de) *	2012-08-02	2015-04-22	Siemens Aktiengesellschaft	Verfahren zur minderung der konzentration an stickstoffdioxid
EP2968680B1 (de)	2013-03-14	2023-05-03	C.P. Medical Corporation	Feste biokompatible präformulierung auf polyglycolbasis
CN105435555A (zh) *	2015-11-13	2016-03-30	朱忠良	一种汽车除异味方法
CN105214406A (zh) *	2015-11-13	2016-01-06	朱忠良	一种汽车除异味方法
CN105214395A (zh) *	2015-11-14	2016-01-06	无锡清杨机械制造有限公司	一种防治雾霾的过滤网
JP6848598B2 (ja) *	2017-03-29	2021-03-24	中国電力株式会社	脱硝触媒の再利用方法
CN108067219A (zh) *	2017-12-27	2018-05-25	洛阳神佳窑业有限公司	一种scr催化剂及其制备方法
CN112999866B (zh) *	2021-03-31	2025-05-13	通化百信药业有限公司	对催化剂分区块加热防止碳酸盐中毒的方法及系统
CN115888691B (zh) *	2022-12-02	2025-01-10	国家电投集团远达环保催化剂有限公司	一种燃气轮机scr脱硝催化剂及其制备方法和应用

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
NL136758C (de) *	1963-10-21	1900-01-01
JPS5945422B2 (ja) *	1978-12-05	1984-11-06	日東化学工業株式会社	アンチモン含有酸化物触媒の再生方法
JPS56168835A (en) *	1980-05-31	1981-12-25	Mitsubishi Petrochem Co Ltd	Denitrating catalyst and denitrating method
DE3585174D1 (de) *	1984-04-05	1992-02-27	Mitsubishi Heavy Ind Ltd	Verfahren zum regenerieren eines denitrierkatalysators fuer die katalytische reduktion mit ammoniak.
US4875436A (en) *	1988-02-09	1989-10-24	W. R. Grace & Co.-Conn.	Waste heat recovery system
JP2732614B2 (ja) *	1988-10-18	1998-03-30	バブコツク日立株式会社	排ガス浄化用触媒および排ガス浄化方法
DE69009125T2 (de) *	1989-09-14	1994-09-29	Mitsubishi Heavy Ind Ltd	Vorrichtung zur Entstickung von Abgasen bei verschiedenen Temperaturen.
EP0560296B1 (de) *	1992-03-09	1998-01-14	Hitachi Metals, Ltd.	Hochgradig heisskorrosionsbeständige und hochfeste Superlegierung, hochgradig heisskorrosionsbeständiges und hochfestes Gussstück mit Einkristallgefüge, Gasturbine und kombiniertes Kreislaufenergieerzeugungssystem
JPH067639A (ja) *	1992-04-28	1994-01-18	Mitsubishi Heavy Ind Ltd	燃焼排ガスの脱硝方法
JP3224605B2 (ja)	1992-09-01	2001-11-05	三菱重工業株式会社	排ガスの脱硝方法
DE4321555C1 (de) *	1993-06-29	1994-09-15	Bayer Ag	Verfahren zur Herstellung von Mischoxidpulvern für Entstickungskatalysatoren
JPH0768172A (ja) *	1993-07-20	1995-03-14	Sakai Chem Ind Co Ltd	窒素酸化物接触還元用触媒及び方法
JP2554836B2 (ja) *	1993-12-24	1996-11-20	株式会社東芝	脱硝制御装置
JPH08260912A (ja)	1995-03-20	1996-10-08	Toshiba Corp	コンバインドサイクル発電プラント
DE19521308A1 (de) *	1995-06-12	1996-12-19	Siemens Ag	Gasturbine zur Verbrennung eines Brenngases
JP3377715B2 (ja) *	1997-02-27	2003-02-17	三菱重工業株式会社	脱硝触媒の再生方法
JP3573959B2 (ja) *	1998-05-12	2004-10-06	ダイヤニトリックス株式会社	モリブデン含有酸化物流動層触媒の再生法
US6673740B2 (en) *	2000-09-27	2004-01-06	Sk Corporation	Method for preparing a catalyst for reduction of nitrogen oxides
CN1223404C (zh) *	2001-02-13	2005-10-19	Sk株式会社	选择性催化还原氮氧化物的催化剂及其制备方法

2002
- 2002-10-09 JP JP2002296071A patent/JP4167039B2/ja not_active Expired - Fee Related
2003
- 2003-03-19 DK DK03006094T patent/DK1353042T3/da active
- 2003-03-19 DE DE60306707T patent/DE60306707T2/de not_active Expired - Lifetime
- 2003-03-19 ES ES03006094T patent/ES2268191T3/es not_active Expired - Lifetime
- 2003-03-19 EP EP03006094A patent/EP1353042B1/de not_active Expired - Lifetime
- 2003-04-03 US US10/405,618 patent/US7316988B2/en not_active Expired - Lifetime
- 2003-04-03 CA CA002424417A patent/CA2424417C/en not_active Expired - Fee Related
- 2003-04-03 NO NO20031511A patent/NO324842B1/no not_active IP Right Cessation

Also Published As

Publication number	Publication date
JP4167039B2 (ja)	2008-10-15
US20030195113A1 (en)	2003-10-16
CA2424417A1 (en)	2003-10-10
CA2424417C (en)	2007-06-19
DE60306707T2 (de)	2007-07-12
EP1353042A2 (de)	2003-10-15
US7316988B2 (en)	2008-01-08
NO20031511D0 (no)	2003-04-03
JP2004000889A (ja)	2004-01-08
EP1353042B1 (de)	2006-07-12
DE60306707D1 (de)	2006-08-24
NO20031511L (no)	2003-10-13
EP1353042A3 (de)	2004-06-16
DK1353042T3 (da)	2006-10-30
ES2268191T3 (es)	2007-03-16

Legal Events

Date	Code	Title	Description
2013-12-02	MM1K	Lapsed by not paying the annual fees

Publication	Publication Date	Title
NO324842B1 (no)	2007-12-17	Fremgangsmate for a modifisere et rent gassturbinanlegg til et kombinert dampturbinanlegg, og regenerert katalysator.
US8916119B2 (en)	2014-12-23	System using selective catalytic reduction for improving low-temperature De-NOx efficiency and reducing yellow plume
Radojevic	1998	Reduction of nitrogen oxides in flue gases
JP7221262B2 (ja)	2023-02-13	発電装置用の排気システム
KR960013449A (ko)	1996-05-22	질소산화물 접촉환원용 촉매 및 방법
US9359918B2 (en)	2016-06-07	Apparatus for reducing emissions and method of assembly
KR101449244B1 (ko)	2014-10-13	Lng 가스 터빈 복합화력 발전소의 배기가스 중 질소산화물을 처리하는 방법
CN105983340A (zh)	2016-10-05	一种低温scr脱硝催化剂的再生方法
CN101206027A (zh)	2008-06-25	低浓度瓦斯气切换催化反应稳定运行的方法
CN104857998B (zh)	2017-03-22	一种用于As中毒脱硝催化剂的高效再生方法
CN112221348B (zh)	2025-02-14	一种处理VOCs协同脱硝的一体化RTO装置及工艺
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CN105772114A (zh)	2016-07-20	一种scr脱硝催化剂再生液
KR101433611B1 (ko)	2014-08-27	가시매연 제거를 위한 선택적 촉매환원 탈질설비
CN102527406A (zh)	2012-07-04	一种用于烟气脱硝的低温scr催化剂及其制备方法
JP4681460B2 (ja)	2011-05-11	ガス化複合発電設備
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JP5723414B2 (ja)	2015-05-27	クロム含有廃液の焼却処理装置および焼却処理方法
KR20230094529A (ko)	2023-06-28	이산화탄소 포집공정과 탈질공정이 연계된 배가스 처리방법
CN201823478U (zh)	2011-05-11	新型烟气脱硝一体化处理装置
CN108826333B (zh)	2023-06-23	一种邻炉交叉汽水实现宽负荷脱硝的系统及其运行方法
Monteforte et al.	2015	Environment and Energy: Flue Gas Treatment and Production of Electrical Power in the Glass Industry
EP1690586A4 (de)	2008-08-06	Verfahren und vorrichtung zur behandlung von ammoniakhaltigem gas
CN113483343B (zh)	2024-03-22	危废烟气处理方法及危废烟气处理系统
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