NO752958L - - Google Patents

Info

Publication number: NO752958L
Authority: NO; Norway
Prior art keywords: initiator; organic; reactor; initiators; temperature
Prior art date: 1974-08-29

Application number

NO752958A

Other languages

English (en)

Norwegian (no)

Inventor

Jr J P Marano

Original Assignee

Union Carbide Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1974-08-29

Filing date

1975-08-28

Publication date

1976-03-02

1975-08-28 Application filed by Union Carbide Corp filed Critical Union Carbide Corp

1976-03-02 Publication of NO752958L publication Critical patent/NO752958L/no

Links

239000003999 initiator Substances 0.000 claims description 74
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 17
239000005977 Ethylene Substances 0.000 claims description 17
238000000034 method Methods 0.000 claims description 17
230000000977 initiatory effect Effects 0.000 claims description 12
150000001875 compounds Chemical class 0.000 claims description 10
150000003254 radicals Chemical class 0.000 claims description 10
239000012986 chain transfer agent Substances 0.000 claims description 6
230000003287 optical effect Effects 0.000 claims description 6
229910052799 carbon Inorganic materials 0.000 claims description 4
229920000573 polyethylene Polymers 0.000 claims description 3
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 2
229910001882 dioxygen Inorganic materials 0.000 claims description 2
229920001519 homopolymer Polymers 0.000 claims description 2
239000000178 monomer Substances 0.000 description 34
238000006243 chemical reaction Methods 0.000 description 23
229920000642 polymer Polymers 0.000 description 20
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 18
239000001301 oxygen Substances 0.000 description 18
229910052760 oxygen Inorganic materials 0.000 description 18
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 14
239000003795 chemical substances by application Substances 0.000 description 13
-1 perester compounds Chemical class 0.000 description 13
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
238000006116 polymerization reaction Methods 0.000 description 9
239000011347 resin Substances 0.000 description 5
229920005989 resin Polymers 0.000 description 5
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
239000003054 catalyst Substances 0.000 description 4
150000002978 peroxides Chemical class 0.000 description 4
229920006395 saturated elastomer Polymers 0.000 description 4
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
239000003085 diluting agent Substances 0.000 description 3
238000002474 experimental method Methods 0.000 description 3
239000003960 organic solvent Substances 0.000 description 3
239000002904 solvent Substances 0.000 description 3
KVNYFPKFSJIPBJ-UHFFFAOYSA-N 1,2-diethylbenzene Chemical compound CCC1=CC=CC=C1CC KVNYFPKFSJIPBJ-UHFFFAOYSA-N 0.000 description 2
OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
239000000654 additive Substances 0.000 description 2
125000000751 azo group Chemical group [*]N=N[*] 0.000 description 2
238000009835 boiling Methods 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
238000001816 cooling Methods 0.000 description 2
LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 2
239000012969 di-tertiary-butyl peroxide Substances 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
238000009413 insulation Methods 0.000 description 2
NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
150000002894 organic compounds Chemical class 0.000 description 2
239000003208 petroleum Substances 0.000 description 2
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 2
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
230000009466 transformation Effects 0.000 description 2
MHCVCKDNQYMGEX-UHFFFAOYSA-N 1,1'-biphenyl;phenoxybenzene Chemical compound C1=CC=CC=C1C1=CC=CC=C1.C=1C=CC=CC=1OC1=CC=CC=C1 MHCVCKDNQYMGEX-UHFFFAOYSA-N 0.000 description 1
PAOHAQSLJSMLAT-UHFFFAOYSA-N 1-butylperoxybutane Chemical group CCCCOOCCCC PAOHAQSLJSMLAT-UHFFFAOYSA-N 0.000 description 1
MNZAKDODWSQONA-UHFFFAOYSA-N 1-dibutylphosphorylbutane Chemical compound CCCCP(=O)(CCCC)CCCC MNZAKDODWSQONA-UHFFFAOYSA-N 0.000 description 1
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
150000001491 aromatic compounds Chemical class 0.000 description 1
239000001273 butane Substances 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
238000005336 cracking Methods 0.000 description 1
239000012933 diacyl peroxide Substances 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
239000011953 free-radical catalyst Substances 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
150000002432 hydroperoxides Chemical class 0.000 description 1
NFMHSPWHNQRFNR-UHFFFAOYSA-N hyponitrous acid Chemical class ON=NO NFMHSPWHNQRFNR-UHFFFAOYSA-N 0.000 description 1
238000005286 illumination Methods 0.000 description 1
230000002401 inhibitory effect Effects 0.000 description 1
239000001282 iso-butane Substances 0.000 description 1
239000007788 liquid Substances 0.000 description 1
239000000155 melt Substances 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
239000002480 mineral oil Substances 0.000 description 1
235000010446 mineral oil Nutrition 0.000 description 1
239000000203 mixture Substances 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
150000001451 organic peroxides Chemical class 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
150000004965 peroxy acids Chemical class 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229920006254 polymer film Polymers 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
239000001294 propane Substances 0.000 description 1
KOPQZJAYZFAPBC-UHFFFAOYSA-N propanoyl propaneperoxoate Chemical compound CCC(=O)OOC(=O)CC KOPQZJAYZFAPBC-UHFFFAOYSA-N 0.000 description 1
229910000077 silane Inorganic materials 0.000 description 1
239000007858 starting material Substances 0.000 description 1
OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 1
XTXFUQOLBKQKJU-UHFFFAOYSA-N tert-butylperoxy(trimethyl)silane Chemical compound CC(C)(C)OO[Si](C)(C)C XTXFUQOLBKQKJU-UHFFFAOYSA-N 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Polymerization Catalysts (AREA)
Polymerisation Methods In General (AREA)

NO752958A 1974-08-29 1975-08-28 NO752958L (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US05/501,701 US4000357A (en)	1974-08-29	1974-08-29	Polymerization of ethylene with oxygen and organic initiators

Publications (1)

Publication Number	Publication Date
NO752958L true NO752958L (de)	1976-03-02

Family

ID=23994679

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO752958A NO752958L (de)	1974-08-29	1975-08-28

Country Status (12)

Country	Link
US (1)	US4000357A (de)
JP (1)	JPS5150387A (de)
AU (1)	AU501340B2 (de)
BR (1)	BR7505513A (de)
CA (1)	CA1064197A (de)
ES (1)	ES440547A1 (de)
FI (1)	FI61497C (de)
GB (1)	GB1516146A (de)
IN (1)	IN143620B (de)
IT (1)	IT1042145B (de)
NO (1)	NO752958L (de)
SE (1)	SE423817B (de)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4452956A (en) *	1979-11-09	1984-06-05	Union Carbide Corporation	Discrete spiral flow imparting device
DE3912975A1 (de) *	1989-04-20	1990-11-08	Basf Ag	Polyethylen sowie copolymerisate aus ueberwiegenden anteilen von ethylen
US6359083B1 (en) *	2000-05-02	2002-03-19	Eastman Chemical Company	Olefin polymerization process
DE10064752A1 (de) *	2000-12-22	2002-07-04	Basell Polyolefine Gmbh	Geruchlose Polyethylenhomo- und copolymere mit guten mechanischen Eigenschaften
WO2003019252A1 (fr) *	2001-08-31	2003-03-06	Fuji Photo Film Co., Ltd.	Procede permettant la production de composants optiques en plastique
WO2019238555A1 (en) *	2018-06-12	2019-12-19	Nouryon Chemicals International B.V.	Process for the production of composite articles

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3142666A (en) *	1959-03-05	1964-07-28	Monsanto Co	Ethylene polymerization utilizing two organic peroxygen compounds as catalysts
US3092614A (en) *	1962-02-15	1963-06-04	Union Carbide Corp	Ethylene polymerization process
US3293233A (en) *	1963-04-09	1966-12-20	Rexall Drug Chemical	Process for polymerizing ethylene at high pressures in the presence of a mixture of peroxides having different half lives
US3691145A (en) *	1970-08-06	1972-09-12	Basf Ag	Production of polyethylene by the high pressure process using a mixture of tertiary butyl hydroperoxide and oxygen as the initiator

1974
- 1974-08-29 US US05/501,701 patent/US4000357A/en not_active Expired - Lifetime
1975
- 1975-07-31 CA CA232,646A patent/CA1064197A/en not_active Expired
- 1975-08-27 AU AU84295/75A patent/AU501340B2/en not_active Expired
- 1975-08-28 ES ES440547A patent/ES440547A1/es not_active Expired
- 1975-08-28 FI FI752418A patent/FI61497C/fi not_active IP Right Cessation
- 1975-08-28 GB GB35494/75A patent/GB1516146A/en not_active Expired
- 1975-08-28 IN IN1663/CAL/75A patent/IN143620B/en unknown
- 1975-08-28 IT IT26700/75A patent/IT1042145B/it active
- 1975-08-28 JP JP50103545A patent/JPS5150387A/ja active Pending
- 1975-08-28 BR BR7505513A patent/BR7505513A/pt unknown
- 1975-08-28 SE SE7509588A patent/SE423817B/xx not_active IP Right Cessation
- 1975-08-28 NO NO752958A patent/NO752958L/no unknown

Also Published As

Publication number	Publication date
IN143620B (de)	1978-01-07
CA1064197A (en)	1979-10-09
FI61497B (fi)	1982-04-30
SE423817B (sv)	1982-06-07
FI61497C (fi)	1982-08-10
US4000357A (en)	1976-12-28
AU501340B2 (en)	1979-06-14
ES440547A1 (es)	1977-03-01
SE7509588L (sv)	1976-05-03
AU8429575A (en)	1977-03-03
IT1042145B (it)	1980-01-30
BR7505513A (pt)	1977-03-15
GB1516146A (en)	1978-06-28
FI752418A7 (de)	1976-03-01
JPS5150387A (en)	1976-05-01

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US4788265A (en)	1988-11-29	Preparation of copolmers of ethylene with acrylic acid esters in a tubular reactor at above 500 bar
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US4794004A (en)	1988-12-27	Preparation of copolymers of ethylene with vinyl esters in a tubular reactor at above 500 bar
JP2003527474A (ja)	2003-09-16	ポリエチレンの製造方法
EP1678216B1 (de)	2012-11-28	Kontinuierliche herstellung von ethylenhomopolymeren oder copolymeren
US4076919A (en)	1978-02-28	Manufacture of ethylene polymers in a two-zone tubular reactor at pressure above 500 bars
US3654253A (en)	1972-04-04	Continuous production of ethylene homopolymers
US5376739A (en)	1994-12-27	Preparation of copolymers of ethylene with acrylic esters
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US6300430B1 (en)	2001-10-09	Method for copolymerizing ethylene with vinyl carboxylates
US6894126B2 (en)	2005-05-17	Method for producing ethylene homopolymers and copolymers by means of radical high pressure polymerization
US3842060A (en)	1974-10-15	Ethylene polymerization process
US3657212A (en)	1972-04-18	Continuous production of ethylene homopolymers
US6245864B1 (en)	2001-06-12	Copolymer of (a) ethylene and (b) and alkenoic acid or a derivative thereof a mixture of said monomers
US5306791A (en)	1994-04-26	Ethylene homopolymers and ethylene copolymers and a process for their preparation
CN112250780B (zh)	2021-09-07	一种用于高压烯烃聚合的方法
CA1091393A (en)	1980-12-09	Manufacture of ethylene copolymers
US3657211A (en)	1972-04-18	Continuous production of ethylene homopolymers
BR112017028002B1 (pt)	2021-12-07	Polímeros de etileno de alta densidade, composição de polímero, película e embalagem para produtos alimentares frescos que os compreendem
US3551397A (en)	1970-12-29	Process for polymerization of ethylene
JPS5831088B2 (ja)	1983-07-04	酸素および有機開始剤類によるエチレン重合
DE2558266A1 (de)	1977-07-07	Verfahren zur herstellung von aethylenpolymeren