NO771449L - Kopolymeriserbar, hydrofil, filmdannende stivelsesblanding - Google Patents

Kopolymeriserbar, hydrofil, filmdannende stivelsesblanding

Info

Publication number: NO771449L
Authority: NO; Norway
Prior art keywords: starch; ethylenically unsaturated; mixture; weight; water
Prior art date: 1976-04-27

Application number

NO771449A

Other languages

English (en)

Norwegian (no)

Inventor

Austin Harry Young

Frank Verbanac

Original Assignee

Staley Mfg Co A E

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-04-27

Filing date

1977-04-26

Publication date

1977-10-28

1977-04-26 Application filed by Staley Mfg Co A E filed Critical Staley Mfg Co A E

1977-10-28 Publication of NO771449L publication Critical patent/NO771449L/no

Links

229920002472 Starch Polymers 0.000 title claims description 607
235000019698 starch Nutrition 0.000 title claims description 605
239000008107 starch Substances 0.000 title claims description 549
239000000203 mixture Substances 0.000 title claims description 161
239000000178 monomer Substances 0.000 claims description 122
238000000576 coating method Methods 0.000 claims description 95
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 95
239000011248 coating agent Substances 0.000 claims description 61
-1 hydroxyalkyl acrylate Chemical compound 0.000 claims description 61
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 44
229920001577 copolymer Polymers 0.000 claims description 33
238000000034 method Methods 0.000 claims description 32
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 26
238000006116 polymerization reaction Methods 0.000 claims description 23
239000003431 cross linking reagent Substances 0.000 claims description 22
239000000654 additive Substances 0.000 claims description 21
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 21
229920000856 Amylose Polymers 0.000 claims description 20
238000007334 copolymerization reaction Methods 0.000 claims description 20
239000003599 detergent Substances 0.000 claims description 20
239000000758 substrate Substances 0.000 claims description 19
229920000642 polymer Polymers 0.000 claims description 17
230000000977 initiatory effect Effects 0.000 claims description 16
238000004519 manufacturing process Methods 0.000 claims description 16
125000000962 organic group Chemical group 0.000 claims description 16
150000001875 compounds Chemical class 0.000 claims description 14
150000003254 radicals Chemical class 0.000 claims description 11
230000008569 process Effects 0.000 claims description 10
125000000217 alkyl group Chemical group 0.000 claims description 9
239000011521 glass Substances 0.000 claims description 9
238000006467 substitution reaction Methods 0.000 claims description 9
125000004432 carbon atom Chemical group C* 0.000 claims description 8
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 8
239000004698 Polyethylene Substances 0.000 claims description 7
229910052799 carbon Inorganic materials 0.000 claims description 7
229920000573 polyethylene Polymers 0.000 claims description 7
230000000996 additive effect Effects 0.000 claims description 6
229920001519 homopolymer Polymers 0.000 claims description 6
229910052757 nitrogen Inorganic materials 0.000 claims description 6
230000009477 glass transition Effects 0.000 claims description 5
239000003505 polymerization initiator Substances 0.000 claims description 5
238000009833 condensation Methods 0.000 claims description 4
230000005494 condensation Effects 0.000 claims description 4
230000000694 effects Effects 0.000 claims description 4
239000008240 homogeneous mixture Substances 0.000 claims description 4
229910052760 oxygen Inorganic materials 0.000 claims description 4
239000001301 oxygen Substances 0.000 claims description 4
229910052717 sulfur Inorganic materials 0.000 claims description 4
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 3
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
125000004433 nitrogen atom Chemical group N* 0.000 claims description 3
239000007870 radical polymerization initiator Substances 0.000 claims description 3
238000010526 radical polymerization reaction Methods 0.000 claims description 3
239000011593 sulfur Substances 0.000 claims description 3
238000011161 development Methods 0.000 claims description 2
TWNIBLMWSKIRAT-VFUOTHLCSA-N levoglucosan Chemical group O[C@@H]1[C@@H](O)[C@H](O)[C@H]2CO[C@@H]1O2 TWNIBLMWSKIRAT-VFUOTHLCSA-N 0.000 claims description 2
125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 claims 3
125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 claims 2
230000007704 transition Effects 0.000 claims 2
150000001732 carboxylic acid derivatives Chemical class 0.000 claims 1
238000006555 catalytic reaction Methods 0.000 claims 1
235000015243 ice cream Nutrition 0.000 claims 1
150000002500 ions Chemical class 0.000 claims 1
OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 17
239000000047 product Substances 0.000 description 17
238000012360 testing method Methods 0.000 description 16
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 15
239000007787 solid Substances 0.000 description 15
230000002209 hydrophobic effect Effects 0.000 description 14
150000002170 ethers Chemical class 0.000 description 13
238000006243 chemical reaction Methods 0.000 description 12
150000002148 esters Chemical class 0.000 description 12
239000002253 acid Substances 0.000 description 11
CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical class OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 9
239000003054 catalyst Substances 0.000 description 9
239000000123 paper Substances 0.000 description 9
230000002829 reductive effect Effects 0.000 description 9
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
239000003795 chemical substances by application Substances 0.000 description 8
239000000376 reactant Substances 0.000 description 8
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
239000008199 coating composition Substances 0.000 description 7
230000002441 reversible effect Effects 0.000 description 7
239000000243 solution Substances 0.000 description 7
239000000126 substance Substances 0.000 description 7
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 6
230000003213 activating effect Effects 0.000 description 6
238000001212 derivatisation Methods 0.000 description 6
239000002270 dispersing agent Substances 0.000 description 6
238000001035 drying Methods 0.000 description 6
239000003112 inhibitor Substances 0.000 description 6
239000003999 initiator Substances 0.000 description 6
229920005989 resin Polymers 0.000 description 6
239000011347 resin Substances 0.000 description 6
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 5
RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 5
229920000945 Amylopectin Polymers 0.000 description 5
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 5
229910000831 Steel Inorganic materials 0.000 description 5
150000003926 acrylamides Chemical class 0.000 description 5
125000000129 anionic group Chemical group 0.000 description 5
239000011230 binding agent Substances 0.000 description 5
239000007795 chemical reaction product Substances 0.000 description 5
239000006185 dispersion Substances 0.000 description 5
239000012153 distilled water Substances 0.000 description 5
239000003995 emulsifying agent Substances 0.000 description 5
239000001257 hydrogen Substances 0.000 description 5
229910052739 hydrogen Inorganic materials 0.000 description 5
239000003960 organic solvent Substances 0.000 description 5
239000010959 steel Substances 0.000 description 5
125000001424 substituent group Chemical group 0.000 description 5
KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 5
150000003672 ureas Chemical class 0.000 description 5
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 4
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
OROQEEMZZJQQSA-UHFFFAOYSA-N [N].NC(=O)C=C Chemical group [N].NC(=O)C=C OROQEEMZZJQQSA-UHFFFAOYSA-N 0.000 description 4
239000000853 adhesive Substances 0.000 description 4
230000001070 adhesive effect Effects 0.000 description 4
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 4
239000003153 chemical reaction reagent Substances 0.000 description 4
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
238000001125 extrusion Methods 0.000 description 4
230000006870 function Effects 0.000 description 4
238000001879 gelation Methods 0.000 description 4
125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
239000000463 material Substances 0.000 description 4
239000004014 plasticizer Substances 0.000 description 4
239000002904 solvent Substances 0.000 description 4
239000004094 surface-active agent Substances 0.000 description 4
230000008961 swelling Effects 0.000 description 4
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 3
240000008042 Zea mays Species 0.000 description 3
235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 3
235000002017 Zea mays subsp mays Nutrition 0.000 description 3
150000007513 acids Chemical class 0.000 description 3
150000001252 acrylic acid derivatives Chemical class 0.000 description 3
230000002411 adverse Effects 0.000 description 3
150000008064 anhydrides Chemical class 0.000 description 3
239000008346 aqueous phase Substances 0.000 description 3
125000003118 aryl group Chemical group 0.000 description 3
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
150000001735 carboxylic acids Chemical class 0.000 description 3
238000005266 casting Methods 0.000 description 3
125000002091 cationic group Chemical group 0.000 description 3
239000001913 cellulose Substances 0.000 description 3
229920002678 cellulose Polymers 0.000 description 3
230000008859 change Effects 0.000 description 3
235000005822 corn Nutrition 0.000 description 3
239000002706 dry binder Substances 0.000 description 3
238000006266 etherification reaction Methods 0.000 description 3
238000006460 hydrolysis reaction Methods 0.000 description 3
238000007654 immersion Methods 0.000 description 3
230000006872 improvement Effects 0.000 description 3
230000006698 induction Effects 0.000 description 3
239000002198 insoluble material Substances 0.000 description 3
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
LVHBHZANLOWSRM-UHFFFAOYSA-N itaconic acid Chemical compound OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 3
239000007788 liquid Substances 0.000 description 3
150000002734 metacrylic acid derivatives Chemical class 0.000 description 3
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
229910052708 sodium Inorganic materials 0.000 description 3
239000011734 sodium Substances 0.000 description 3
239000002195 soluble material Substances 0.000 description 3
238000005406 washing Methods 0.000 description 3
239000001993 wax Substances 0.000 description 3
IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 description 2
STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
INQDDHNZXOAFFD-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOC(=O)C=C INQDDHNZXOAFFD-UHFFFAOYSA-N 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
229920001685 Amylomaize Polymers 0.000 description 2
239000004859 Copal Substances 0.000 description 2
229920002261 Corn starch Polymers 0.000 description 2
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241000782205 Guibourtia conjugata Species 0.000 description 2
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
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240000003183 Manihot esculenta Species 0.000 description 2
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229920000881 Modified starch Polymers 0.000 description 2
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
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240000007594 Oryza sativa Species 0.000 description 2
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240000004713 Pisum sativum Species 0.000 description 2
235000010582 Pisum sativum Nutrition 0.000 description 2
DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical class [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 2
240000006394 Sorghum bicolor Species 0.000 description 2
235000011684 Sorghum saccharatum Nutrition 0.000 description 2
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
239000003377 acid catalyst Substances 0.000 description 2
238000007605 air drying Methods 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
150000001447 alkali salts Chemical class 0.000 description 2
125000003545 alkoxy group Chemical group 0.000 description 2
102000004139 alpha-Amylases Human genes 0.000 description 2
108090000637 alpha-Amylases Proteins 0.000 description 2
229940024171 alpha-amylase Drugs 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
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MZJSINIFJJRPLQ-ARJAWSKDSA-N 2-[(z)-4-ethoxy-4-oxobut-2-enoyl]oxyethanesulfonic acid Chemical compound CCOC(=O)\C=C/C(=O)OCCS(O)(=O)=O MZJSINIFJJRPLQ-ARJAWSKDSA-N 0.000 description 1
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239000004645 polyester resin Substances 0.000 description 1
229920000139 polyethylene terephthalate Polymers 0.000 description 1
239000005020 polyethylene terephthalate Substances 0.000 description 1
229920005862 polyol Polymers 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
229920002689 polyvinyl acetate Polymers 0.000 description 1
239000011118 polyvinyl acetate Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
239000002243 precursor Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
150000003141 primary amines Chemical class 0.000 description 1
125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
238000012545 processing Methods 0.000 description 1
AZIQALWHRUQPHV-UHFFFAOYSA-N prop-2-eneperoxoic acid Chemical compound OOC(=O)C=C AZIQALWHRUQPHV-UHFFFAOYSA-N 0.000 description 1
239000011253 protective coating Substances 0.000 description 1
239000002994 raw material Substances 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
230000009467 reduction Effects 0.000 description 1
230000008929 regeneration Effects 0.000 description 1
238000011069 regeneration method Methods 0.000 description 1
230000008439 repair process Effects 0.000 description 1
230000033458 reproduction Effects 0.000 description 1
239000003340 retarding agent Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
238000009991 scouring Methods 0.000 description 1
238000007650 screen-printing Methods 0.000 description 1
238000005201 scrubbing Methods 0.000 description 1
150000003335 secondary amines Chemical class 0.000 description 1
238000007493 shaping process Methods 0.000 description 1
239000004208 shellac Substances 0.000 description 1
ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
235000013874 shellac Nutrition 0.000 description 1
229940113147 shellac Drugs 0.000 description 1
238000004513 sizing Methods 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000003351 stiffener Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
150000005846 sugar alcohols Polymers 0.000 description 1
125000000475 sulfinyl group Chemical group [*:2]S([*:1])=O 0.000 description 1
125000004434 sulfur atom Chemical group 0.000 description 1
229920001059 synthetic polymer Polymers 0.000 description 1
229920003002 synthetic resin Polymers 0.000 description 1
239000000057 synthetic resin Substances 0.000 description 1
ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
230000008719 thickening Effects 0.000 description 1
239000002562 thickening agent Substances 0.000 description 1
150000003568 thioethers Chemical class 0.000 description 1
125000003396 thiol group Chemical class [H]S* 0.000 description 1
150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 1
125000003944 tolyl group Chemical group 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
238000012546 transfer Methods 0.000 description 1
125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
238000005200 wet scrubbing Methods 0.000 description 1
239000000080 wetting agent Substances 0.000 description 1
229940100445 wheat starch Drugs 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1
239000011592 zinc chloride Substances 0.000 description 1
235000005074 zinc chloride Nutrition 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/08—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated side groups
- C08F290/10—Polymers provided for in subclass C08B

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Graft Or Block Polymers (AREA)
Polysaccharides And Polysaccharide Derivatives (AREA)
Macromonomer-Based Addition Polymer (AREA)
Polymerisation Methods In General (AREA)
Compositions Of Macromolecular Compounds (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

NO771449A 1976-04-27 1977-04-26 Kopolymeriserbar, hydrofil, filmdannende stivelsesblanding NO771449L (no)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US05/680,549 US4079025A (en)	1976-04-27	1976-04-27	Copolymerized starch composition

Publications (1)

Publication Number	Publication Date
NO771449L true NO771449L (no)	1977-10-28

Family

ID=24731562

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO771449A NO771449L (no)	1976-04-27	1977-04-26	Kopolymeriserbar, hydrofil, filmdannende stivelsesblanding

Country Status (15)

Country	Link
US (2)	US4079025A (fr)
JP (1)	JPS6017209B2 (fr)
BE (1)	BE854010A (fr)
BR (1)	BR7702648A (fr)
CA (1)	CA1082829A (fr)
DE (1)	DE2718210A1 (fr)
DK (1)	DK181877A (fr)
ES (1)	ES458239A1 (fr)
FR (1)	FR2349617A1 (fr)
GB (1)	GB1575246A (fr)
IT (1)	IT1081941B (fr)
MX (1)	MX3583E (fr)
NL (1)	NL7704541A (fr)
NO (1)	NO771449L (fr)
SE (1)	SE432429B (fr)

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1976
- 1976-04-27 US US05/680,549 patent/US4079025A/en not_active Expired - Lifetime
1977
- 1977-03-16 CA CA274,111A patent/CA1082829A/fr not_active Expired
- 1977-04-06 MX MX775613U patent/MX3583E/es unknown
- 1977-04-13 GB GB15265/77A patent/GB1575246A/en not_active Expired
- 1977-04-23 DE DE19772718210 patent/DE2718210A1/de not_active Withdrawn
- 1977-04-25 FR FR7712380A patent/FR2349617A1/fr active Granted
- 1977-04-26 IT IT49105/77A patent/IT1081941B/it active
- 1977-04-26 DK DK181877A patent/DK181877A/da not_active Application Discontinuation
- 1977-04-26 NL NL7704541A patent/NL7704541A/xx not_active Application Discontinuation
- 1977-04-26 NO NO771449A patent/NO771449L/no unknown
- 1977-04-26 SE SE7704794A patent/SE432429B/xx unknown
- 1977-04-27 BE BE177065A patent/BE854010A/fr not_active IP Right Cessation
- 1977-04-27 JP JP52049018A patent/JPS6017209B2/ja not_active Expired
- 1977-04-27 ES ES458239A patent/ES458239A1/es not_active Expired
- 1977-04-27 BR BR7702648A patent/BR7702648A/pt unknown
- 1977-06-20 US US05/808,482 patent/US4115332A/en not_active Expired - Lifetime

Also Published As

Publication number	Publication date
FR2349617B1 (fr)	1981-10-02
JPS52130887A (en)	1977-11-02
IT1081941B (it)	1985-05-21
BR7702648A (pt)	1978-03-21
SE7704794L (sv)	1977-10-28
DE2718210A1 (de)	1977-11-10
FR2349617A1 (fr)	1977-11-25
NL7704541A (nl)	1977-10-31
CA1082829A (fr)	1980-07-29
DK181877A (da)	1977-10-28
JPS6017209B2 (ja)	1985-05-01
BE854010A (fr)	1977-10-27
ES458239A1 (es)	1978-06-01
MX3583E (es)	1981-03-19
US4079025A (en)	1978-03-14
GB1575246A (en)	1980-09-17
SE432429B (sv)	1984-04-02
US4115332A (en)	1978-09-19

Publication	Publication Date	Title
NO771449L (no)	1977-10-28	Kopolymeriserbar, hydrofil, filmdannende stivelsesblanding
US4060506A (en)	1977-11-29	Starch acrylamides and the method for preparing the same
AU621206B2 (en)	1992-03-05	Starch graft polymers
EP0005000B1 (fr)	1981-10-21	Méthode de préparation d'un produit amylacé hydro-absorbant
AU596878B2 (en)	1990-05-17	Printing ink composition
US3891584A (en)	1975-06-24	Water-dispersible hot melt adhesives and products using same
US4474923A (en)	1984-10-02	Self-curable latex compositions
US5536764A (en)	1996-07-16	Cationic starch/vinyl acetate containing board coating binders
US4521565A (en)	1985-06-04	Aqueous dispersion
US6423775B1 (en)	2002-07-23	Starch-based graft polymer, process for its preparation, and use thereof in printing inks and overprint varnishes
JPH0213078B2 (fr)	1990-04-03
US4940741A (en)	1990-07-10	Process for the production of hardboard
EP0000247B1 (fr)	1982-08-04	Copolymères d'amidon absorbant l'eau et leurs méthodes d'obtention
US4395515A (en)	1983-07-26	Resin dispersions having high pigment binding capacity
JP4974428B2 (ja)	2012-07-11	樹脂強化糖ベース化ビニルエマルジョンコポリマー類から構成されるインキおよびその製造法
US4575528A (en)	1986-03-11	Viscosity modifiers for grafted starch polymer solutions
KR840001832B1 (ko)	1984-10-22	공중합체 라텍스의 제조방법
US4963604A (en)	1990-10-16	Polymeric pigments used in paper coating compositions and a process for their preparation
CA1091659A (fr)	1980-12-16	Procede d'obtention d'acrylamides d'amidon
JPH10259590A (ja)	1998-09-29	変成澱粉を用いた表面紙質向上剤
JPS5831195A (ja)	1983-02-23	紙被覆用組成物
JPH05163697A (ja)	1993-06-29	紙の表面強度改良剤
JPS5945370A (ja)	1984-03-14	グラビア印刷紙用塗工液組成物
JPS584952B2 (ja)	1983-01-28	段ボ−ルの製法