NO793588L - Fremgangsmaate for syntetisering av blandede alkoksy-hydrid-derivater av al og jordalkalimetaller - Google Patents

Fremgangsmaate for syntetisering av blandede alkoksy-hydrid-derivater av al og jordalkalimetaller

Info

Publication number: NO793588L
Authority: NO; Norway
Prior art keywords: mmol; alkaline earth; solution; toluene; aliphatic
Prior art date: 1978-11-10

Application number

NO793588A

Other languages

English (en)

Norwegian (no)

Inventor

Giovanni Dozzi

Salvatore Cucinella

Original Assignee

Anic Spa

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-11-10

Filing date

1979-11-07

Publication date

1980-05-13

1978-11-10 Priority claimed from IT29699/78A external-priority patent/IT1100219B/it

1979-04-04 Priority claimed from IT2156479A external-priority patent/IT1166727B/it

1979-11-07 Application filed by Anic Spa filed Critical Anic Spa

1980-05-13 Publication of NO793588L publication Critical patent/NO793588L/no

Links

238000000034 method Methods 0.000 title claims description 30
-1 POTASSIUM METALS Chemical class 0.000 title claims description 7
229910052751 metal Inorganic materials 0.000 title claims 2
239000002184 metal Substances 0.000 title claims 2
229910052700 potassium Inorganic materials 0.000 title 1
239000011591 potassium Substances 0.000 title 1
230000003407 synthetizing effect Effects 0.000 title 1
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 141
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 70
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical group CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 28
239000000203 mixture Substances 0.000 claims description 26
238000006243 chemical reaction Methods 0.000 claims description 24
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 19
150000001342 alkaline earth metals Chemical class 0.000 claims description 19
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 18
239000002904 solvent Substances 0.000 claims description 16
238000005984 hydrogenation reaction Methods 0.000 claims description 13
229910052783 alkali metal Inorganic materials 0.000 claims description 7
150000001340 alkali metals Chemical class 0.000 claims description 7
239000002879 Lewis base Substances 0.000 claims description 6
150000002576 ketones Chemical class 0.000 claims description 6
150000007527 lewis bases Chemical group 0.000 claims description 6
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 6
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
125000001931 aliphatic group Chemical group 0.000 claims description 5
150000001875 compounds Chemical class 0.000 claims description 5
150000001298 alcohols Chemical class 0.000 claims description 4
229910052782 aluminium Inorganic materials 0.000 claims description 4
125000000524 functional group Chemical group 0.000 claims description 4
150000004820 halides Chemical class 0.000 claims description 4
125000000075 primary alcohol group Chemical group 0.000 claims description 4
150000003333 secondary alcohols Chemical class 0.000 claims description 4
239000000758 substrate Substances 0.000 claims description 4
230000002194 synthesizing effect Effects 0.000 claims description 4
BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 claims description 3
150000001299 aldehydes Chemical class 0.000 claims description 3
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
229910052736 halogen Inorganic materials 0.000 claims description 3
239000003960 organic solvent Substances 0.000 claims description 3
150000003509 tertiary alcohols Chemical class 0.000 claims description 3
150000001412 amines Chemical class 0.000 claims description 2
150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 2
125000004122 cyclic group Chemical group 0.000 claims description 2
238000000354 decomposition reaction Methods 0.000 claims description 2
125000005270 trialkylamine group Chemical group 0.000 claims description 2
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims 3
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims 2
150000001338 aliphatic hydrocarbons Chemical class 0.000 claims 1
CMQZRJBJDCVIEY-JEOLMMCMSA-N alpha-L-Fucp-(1->3)-[beta-D-Galp-(1->4)]-beta-D-GlcpNAc-(1->3)-beta-D-Galp-(1->4)-D-Glcp Chemical group O[C@H]1[C@H](O)[C@H](O)[C@H](C)O[C@H]1O[C@H]1[C@H](O[C@H]2[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO)O2)O)[C@@H](CO)O[C@@H](O[C@@H]2[C@H]([C@H](O[C@@H]3[C@H](OC(O)[C@H](O)[C@H]3O)CO)O[C@H](CO)[C@@H]2O)O)[C@@H]1NC(C)=O CMQZRJBJDCVIEY-JEOLMMCMSA-N 0.000 claims 1
125000004432 carbon atom Chemical group C* 0.000 claims 1
150000004292 cyclic ethers Chemical class 0.000 claims 1
XYFCBTPGUUZFHI-UHFFFAOYSA-N phosphine group Chemical group P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims 1
239000000243 solution Substances 0.000 description 78
238000002360 preparation method Methods 0.000 description 25
238000010992 reflux Methods 0.000 description 24
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 23
239000000725 suspension Substances 0.000 description 23
238000003756 stirring Methods 0.000 description 19
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 15
125000002481 alumanyl group Chemical group [H][Al]([H])[*] 0.000 description 15
239000001110 calcium chloride Substances 0.000 description 15
235000011148 calcium chloride Nutrition 0.000 description 15
229910001628 calcium chloride Inorganic materials 0.000 description 15
JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 14
238000004817 gas chromatography Methods 0.000 description 14
229910052739 hydrogen Inorganic materials 0.000 description 14
239000012299 nitrogen atmosphere Substances 0.000 description 14
WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 12
239000011780 sodium chloride Substances 0.000 description 12
238000005903 acid hydrolysis reaction Methods 0.000 description 11
ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 10
239000011541 reaction mixture Substances 0.000 description 10
239000012265 solid product Substances 0.000 description 10
239000000047 product Substances 0.000 description 9
239000007787 solid Substances 0.000 description 9
SHZIWNPUGXLXDT-UHFFFAOYSA-N ethyl hexanoate Chemical compound CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 description 8
ZKQFHRVKCYFVCN-UHFFFAOYSA-N ethoxyethane;hexane Chemical compound CCOCC.CCCCCC ZKQFHRVKCYFVCN-UHFFFAOYSA-N 0.000 description 7
239000000706 filtrate Substances 0.000 description 7
238000005406 washing Methods 0.000 description 7
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 6
230000015572 biosynthetic process Effects 0.000 description 5
238000011049 filling Methods 0.000 description 5
ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 4
229910020828 NaAlH4 Inorganic materials 0.000 description 4
HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 4
PASDCCFISLVPSO-UHFFFAOYSA-N benzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1 PASDCCFISLVPSO-UHFFFAOYSA-N 0.000 description 4
235000019445 benzyl alcohol Nutrition 0.000 description 4
MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 4
FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 4
239000007791 liquid phase Substances 0.000 description 4
239000012452 mother liquor Substances 0.000 description 4
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 3
UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 3
DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical group CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 3
239000003638 chemical reducing agent Substances 0.000 description 3
230000000694 effects Effects 0.000 description 3
238000001914 filtration Methods 0.000 description 3
239000010413 mother solution Substances 0.000 description 3
238000003786 synthesis reaction Methods 0.000 description 3
PGZVFRAEAAXREB-UHFFFAOYSA-N 2,2-dimethylpropanoyl 2,2-dimethylpropanoate Chemical compound CC(C)(C)C(=O)OC(=O)C(C)(C)C PGZVFRAEAAXREB-UHFFFAOYSA-N 0.000 description 2
XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 2
YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
AMIMRNSIRUDHCM-UHFFFAOYSA-N Isopropylaldehyde Chemical compound CC(C)C=O AMIMRNSIRUDHCM-UHFFFAOYSA-N 0.000 description 2
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 2
229940073608 benzyl chloride Drugs 0.000 description 2
WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
238000001704 evaporation Methods 0.000 description 2
125000005843 halogen group Chemical group 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
150000004678 hydrides Chemical class 0.000 description 2
238000006460 hydrolysis reaction Methods 0.000 description 2
PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 description 2
239000002808 molecular sieve Substances 0.000 description 2
KPSSIOMAKSHJJG-UHFFFAOYSA-N neopentyl alcohol Chemical compound CC(C)(C)CO KPSSIOMAKSHJJG-UHFFFAOYSA-N 0.000 description 2
239000012074 organic phase Substances 0.000 description 2
QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 2
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
WYVAMUWZEOHJOQ-UHFFFAOYSA-N propionic anhydride Chemical compound CCC(=O)OC(=O)CC WYVAMUWZEOHJOQ-UHFFFAOYSA-N 0.000 description 2
238000000746 purification Methods 0.000 description 2
150000003254 radicals Chemical class 0.000 description 2
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
HBAQYPYDRFILMT-UHFFFAOYSA-N 8-[3-(1-cyclopropylpyrazol-4-yl)-1H-pyrazolo[4,3-d]pyrimidin-5-yl]-3-methyl-3,8-diazabicyclo[3.2.1]octan-2-one Chemical class C1(CC1)N1N=CC(=C1)C1=NNC2=C1N=C(N=C2)N1C2C(N(CC1CC2)C)=O HBAQYPYDRFILMT-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
101100448208 Human herpesvirus 6B (strain Z29) U69 gene Proteins 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
125000003158 alcohol group Chemical group 0.000 description 1
150000001335 aliphatic alkanes Chemical class 0.000 description 1
229910000102 alkali metal hydride Inorganic materials 0.000 description 1
150000008046 alkali metal hydrides Chemical class 0.000 description 1
150000001350 alkyl halides Chemical class 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
150000008064 anhydrides Chemical class 0.000 description 1
239000002585 base Substances 0.000 description 1
238000009835 boiling Methods 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000007810 chemical reaction solvent Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
238000003776 cleavage reaction Methods 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
239000002274 desiccant Substances 0.000 description 1
150000002009 diols Chemical class 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000000605 extraction Methods 0.000 description 1
239000012467 final product Substances 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
230000003301 hydrolyzing effect Effects 0.000 description 1
238000007689 inspection Methods 0.000 description 1
239000000543 intermediate Substances 0.000 description 1
239000013067 intermediate product Substances 0.000 description 1
238000002955 isolation Methods 0.000 description 1
150000002596 lactones Chemical class 0.000 description 1
229910001507 metal halide Inorganic materials 0.000 description 1
150000005309 metal halides Chemical class 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
150000002828 nitro derivatives Chemical class 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
150000003003 phosphines Chemical class 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
230000007017 scission Effects 0.000 description 1
239000007858 starting material Substances 0.000 description 1
150000003462 sulfoxides Chemical class 0.000 description 1
150000003568 thioethers Chemical class 0.000 description 1
HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/069—Aluminium compounds without C-aluminium linkages
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/26—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only halogen atoms as hetero-atoms
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/68—Preparation of metal alcoholates
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/68—Preparation of metal alcoholates
- C07C29/70—Preparation of metal alcoholates by converting hydroxy groups to O-metal groups
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/28—Metal alcoholates
- C07C31/32—Aluminium alcoholates
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)

NO793588A 1978-11-10 1979-11-07 Fremgangsmaate for syntetisering av blandede alkoksy-hydrid-derivater av al og jordalkalimetaller NO793588L (no)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
IT29699/78A IT1100219B (it)	1978-11-10	1978-11-10	Processo di sintesi di alcossiderivati idraurici misti di alluminio e di metalli alcalino-terrosi
IT2156479A IT1166727B (it)	1979-04-04	1979-04-04	Processo di sintesi di alcossiderivati idrurici misti di alluminio e di metalli alcalino-terrosi

Publications (1)

Publication Number	Publication Date
NO793588L true NO793588L (no)	1980-05-13

Family

ID=26327937

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO793588A NO793588L (no)	1978-11-10	1979-11-07	Fremgangsmaate for syntetisering av blandede alkoksy-hydrid-derivater av al og jordalkalimetaller

Country Status (11)

Country	Link
US (1)	US4313891A (da)
AT (1)	AT376680B (da)
CA (1)	CA1140561A (da)
DE (1)	DE2945348C2 (da)
DK (1)	DK450779A (da)
EG (1)	EG13977A (da)
FR (1)	FR2449094A1 (da)
GB (1)	GB2034309B (da)
NL (1)	NL7908264A (da)
NO (1)	NO793588L (da)
SE (1)	SE7909265L (da)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3823787C1 (da) *	1988-07-14	1989-05-24	Boehringer Ingelheim Kg, 6507 Ingelheim, De
US5597663A (en) *	1995-05-30	1997-01-28	Motorola, Inc.	Low temperature molten lithium salt electrolytes for electrochemical cells
US20080227978A1 (en) *	2005-01-27	2008-09-18	The University Of Nottingham	Method for the Preparation of Enantiomerically Enriched Secondary Alcohols by the Addition of Organoaluminium Reagents to Carbonyl Compounds

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2720506A (en) *	1952-10-03	1955-10-11	Eastman Kodak Co	Organo-metallic aluminum catalysts for the preparation of polyesters
US3147272A (en) *	1959-08-18	1964-09-01	Herbert C Brown	Method of preparing partially reduced organic compounds
US3060216A (en) *	1959-12-08	1962-10-23	Basf Ag	Complex metal aluminum hydrides and their production
US3281443A (en) *	1961-02-24	1966-10-25	Continental Oil Co	Preparation and use of dialkoxyaluminum hydride reducing agents
DE1157622B (de) *	1961-05-12	1963-11-21	Dr Karl Ziegler	Verfahren zur Herstellung sauerstoffhaltiger alkaliorganischer Komplexverbindungen des Aluminiums und/oder des Bors
US3184492A (en) *	1963-02-05	1965-05-18	Hoffmann La Roche	Process for the preparation of sodium aluminum methoxy hydride
GB1064654A (en) *	1963-10-02	1967-04-05	Snam Spa	Process for preparing complex aluminium hydrides partly substituted with alcoholate groups and compounds so obtained
US3761500A (en) *	1970-05-26	1973-09-25	Owens Illinois Inc	Liquid double alkoxides
DE2049400C3 (de) *	1970-10-08	1982-03-11	Dynamit Nobel Ag, 5210 Troisdorf	Verfahren zur Herstellung von Alkalialuminiumalkoxiden
GB1525527A (en) *	1975-12-22	1978-09-20	Asahi Chemical Ind	Method for producing an organomagnesium complex
US4219491A (en) *	1978-11-15	1980-08-26	Anic S.P.A.	Synthesizing mixed hydride alkoxyderivatives of aluminum and alkaline-earth metals, and products obtained thereby

1979
- 1979-10-25 DK DK450779A patent/DK450779A/da not_active Application Discontinuation
- 1979-10-26 US US06/088,581 patent/US4313891A/en not_active Expired - Lifetime
- 1979-10-30 GB GB7937499A patent/GB2034309B/en not_active Expired
- 1979-11-07 NO NO793588A patent/NO793588L/no unknown
- 1979-11-08 SE SE7909265A patent/SE7909265L/xx not_active Application Discontinuation
- 1979-11-09 CA CA000339614A patent/CA1140561A/en not_active Expired
- 1979-11-09 AT AT0720579A patent/AT376680B/de active
- 1979-11-09 FR FR7927749A patent/FR2449094A1/fr active Granted
- 1979-11-09 DE DE2945348A patent/DE2945348C2/de not_active Expired
- 1979-11-10 EG EG677/79A patent/EG13977A/xx active
- 1979-11-12 NL NL7908264A patent/NL7908264A/nl not_active Application Discontinuation

Also Published As

Publication number	Publication date
FR2449094A1 (fr)	1980-09-12
US4313891A (en)	1982-02-02
AT376680B (de)	1984-12-27
GB2034309A (en)	1980-06-04
DE2945348C2 (de)	1983-11-10
GB2034309B (en)	1983-02-16
CA1140561A (en)	1983-02-01
DE2945348A1 (de)	1980-05-14
FR2449094B1 (da)	1982-11-26
NL7908264A (nl)	1980-05-13
ATA720579A (de)	1984-05-15
DK450779A (da)	1980-05-11
EG13977A (en)	1983-12-31
SE7909265L (sv)	1980-05-11

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