NO861233L - Fremgangsmaate og katalysator for fremstilling av formaldehyd fra metan. - Google Patents

Fremgangsmaate og katalysator for fremstilling av formaldehyd fra metan.

Info

Publication number: NO861233L
Authority: NO; Norway
Prior art keywords: catalyst; silicon oxide; ppm; weight; less
Prior art date: 1985-04-16

Application number

NO861233A

Other languages

English (en)

Norwegian (no)

Inventor

Nicholas David Spencer

Original Assignee

Grace W R & Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1985-04-16

Filing date

1986-03-26

Publication date

1986-10-17

1985-04-16 Priority claimed from US06/723,680 external-priority patent/US4607127A/en

1986-03-26 Application filed by Grace W R & Co filed Critical Grace W R & Co

1986-10-17 Publication of NO861233L publication Critical patent/NO861233L/no

Links

239000003054 catalyst Substances 0.000 title claims description 95
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims description 86
238000000034 method Methods 0.000 title claims description 24
238000002360 preparation method Methods 0.000 title description 6
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 119
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 96
239000011734 sodium Substances 0.000 claims description 61
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 55
229910052708 sodium Inorganic materials 0.000 claims description 55
229910052814 silicon oxide Inorganic materials 0.000 claims description 50
238000007254 oxidation reaction Methods 0.000 claims description 17
230000003647 oxidation Effects 0.000 claims description 16
229910002027 silica gel Inorganic materials 0.000 claims description 14
239000000741 silica gel Substances 0.000 claims description 14
239000007789 gas Substances 0.000 claims description 9
239000000203 mixture Substances 0.000 claims description 8
238000004519 manufacturing process Methods 0.000 claims description 7
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
229910052710 silicon Inorganic materials 0.000 claims description 6
239000010703 silicon Substances 0.000 claims description 6
230000007062 hydrolysis Effects 0.000 claims description 5
238000006460 hydrolysis reaction Methods 0.000 claims description 5
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 2
229910001882 dioxygen Inorganic materials 0.000 claims description 2
239000012535 impurity Substances 0.000 claims 1
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 27
239000000377 silicon dioxide Substances 0.000 description 26
229910052750 molybdenum Inorganic materials 0.000 description 20
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 14
239000011733 molybdenum Substances 0.000 description 14
238000006243 chemical reaction Methods 0.000 description 12
230000000694 effects Effects 0.000 description 9
239000000243 solution Substances 0.000 description 9
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 6
GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 6
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
230000000052 comparative effect Effects 0.000 description 6
239000001301 oxygen Substances 0.000 description 6
229910052760 oxygen Inorganic materials 0.000 description 6
230000036284 oxygen consumption Effects 0.000 description 6
239000000047 product Substances 0.000 description 6
235000012239 silicon dioxide Nutrition 0.000 description 6
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
239000002253 acid Substances 0.000 description 5
238000001354 calcination Methods 0.000 description 5
229930195733 hydrocarbon Natural products 0.000 description 5
150000002430 hydrocarbons Chemical class 0.000 description 5
229910044991 metal oxide Inorganic materials 0.000 description 5
150000004706 metal oxides Chemical class 0.000 description 5
229910000476 molybdenum oxide Inorganic materials 0.000 description 5
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 5
PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 5
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 4
239000000499 gel Substances 0.000 description 4
JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 4
239000002245 particle Substances 0.000 description 4
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 4
230000007306 turnover Effects 0.000 description 4
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
239000004215 Carbon black (E152) Substances 0.000 description 3
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 3
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
239000000969 carrier Substances 0.000 description 3
QXYJCZRRLLQGCR-UHFFFAOYSA-N dioxomolybdenum Chemical compound O=[Mo]=O QXYJCZRRLLQGCR-UHFFFAOYSA-N 0.000 description 3
238000001704 evaporation Methods 0.000 description 3
230000008020 evaporation Effects 0.000 description 3
239000000463 material Substances 0.000 description 3
WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 3
-1 molybdenum oxide-silicon oxide Chemical compound 0.000 description 3
239000010453 quartz Substances 0.000 description 3
238000000859 sublimation Methods 0.000 description 3
230000008022 sublimation Effects 0.000 description 3
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 2
IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 2
239000001273 butane Substances 0.000 description 2
ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 2
229910052791 calcium Inorganic materials 0.000 description 2
239000011575 calcium Substances 0.000 description 2
229910002092 carbon dioxide Inorganic materials 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
229910052681 coesite Inorganic materials 0.000 description 2
229910052906 cristobalite Inorganic materials 0.000 description 2
230000000881 depressing effect Effects 0.000 description 2
239000000543 intermediate Substances 0.000 description 2
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
239000007800 oxidant agent Substances 0.000 description 2
239000001294 propane Substances 0.000 description 2
LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 2
229910052682 stishovite Inorganic materials 0.000 description 2
238000003786 synthesis reaction Methods 0.000 description 2
229910052905 tridymite Inorganic materials 0.000 description 2
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
229910052721 tungsten Inorganic materials 0.000 description 2
239000010937 tungsten Substances 0.000 description 2
229910052720 vanadium Inorganic materials 0.000 description 2
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
238000005406 washing Methods 0.000 description 2
SBMYBOVJMOVVQW-UHFFFAOYSA-N 2-[3-[[4-(2,2-difluoroethyl)piperazin-1-yl]methyl]-4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]pyrazol-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound FC(CN1CCN(CC1)CC1=NN(C=C1C=1C=NC(=NC=1)NC1CC2=CC=CC=C2C1)CC(=O)N1CC2=C(CC1)NN=N2)F SBMYBOVJMOVVQW-UHFFFAOYSA-N 0.000 description 1
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
239000004809 Teflon Substances 0.000 description 1
229920006362 Teflon® Polymers 0.000 description 1
229910052770 Uranium Inorganic materials 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
230000002411 adverse Effects 0.000 description 1
230000001476 alcoholic effect Effects 0.000 description 1
239000004411 aluminium Substances 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
235000011114 ammonium hydroxide Nutrition 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
239000000292 calcium oxide Substances 0.000 description 1
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
229910002090 carbon oxide Inorganic materials 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
238000010960 commercial process Methods 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
239000004020 conductor Substances 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
239000012045 crude solution Substances 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
238000001514 detection method Methods 0.000 description 1
238000011143 downstream manufacturing Methods 0.000 description 1
238000001035 drying Methods 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
238000004880 explosion Methods 0.000 description 1
229910021485 fumed silica Inorganic materials 0.000 description 1
238000007654 immersion Methods 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
238000009616 inductively coupled plasma Methods 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
239000007788 liquid Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
150000002751 molybdenum Chemical class 0.000 description 1
YJEJUIVHAMABCA-UHFFFAOYSA-J molybdenum(4+);oxalate Chemical compound [Mo+4].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O YJEJUIVHAMABCA-UHFFFAOYSA-J 0.000 description 1
229910052758 niobium Inorganic materials 0.000 description 1
239000010955 niobium Substances 0.000 description 1
GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
239000001272 nitrous oxide Substances 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
DHRLEVQXOMLTIM-UHFFFAOYSA-N phosphoric acid;trioxomolybdenum Chemical compound O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.OP(O)(O)=O DHRLEVQXOMLTIM-UHFFFAOYSA-N 0.000 description 1
239000011148 porous material Substances 0.000 description 1
CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 1
229910001950 potassium oxide Inorganic materials 0.000 description 1
239000000843 powder Substances 0.000 description 1
239000002994 raw material Substances 0.000 description 1
230000001603 reducing effect Effects 0.000 description 1
229910052702 rhenium Inorganic materials 0.000 description 1
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000002002 slurry Substances 0.000 description 1
KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
229910001948 sodium oxide Inorganic materials 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000007858 starting material Substances 0.000 description 1
238000000629 steam reforming Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000006228 supernatant Substances 0.000 description 1
238000001308 synthesis method Methods 0.000 description 1
229910052715 tantalum Inorganic materials 0.000 description 1
GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
229910052713 technetium Inorganic materials 0.000 description 1
GKLVYJBZJHMRIY-UHFFFAOYSA-N technetium atom Chemical compound [Tc] GKLVYJBZJHMRIY-UHFFFAOYSA-N 0.000 description 1
JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 1
239000002912 waste gas Substances 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

NO861233A 1985-04-16 1986-03-26 Fremgangsmaate og katalysator for fremstilling av formaldehyd fra metan. NO861233L (no)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US72368185A	1985-04-16	1985-04-16
US06/723,680 US4607127A (en)	1985-04-16	1985-04-16	Process and catalyst for the production of formaldehyde from methane

Publications (1)

Publication Number	Publication Date
NO861233L true NO861233L (no)	1986-10-17

Family

ID=27110845

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO861233A NO861233L (no)	1985-04-16	1986-03-26	Fremgangsmaate og katalysator for fremstilling av formaldehyd fra metan.

Country Status (7)

Country	Link
EP (1)	EP0217855A4 (fr)
CN (1)	CN86102245A (fr)
AU (1)	AU5546786A (fr)
CA (1)	CA1259299A (fr)
ES (1)	ES8706597A1 (fr)
NO (1)	NO861233L (fr)
WO (1)	WO1986006063A1 (fr)

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Publication number	Priority date	Publication date	Assignee	Title
US6028228A (en) *	1997-09-26	2000-02-22	Georgia-Pacific Corporation	Production of formaldehyde from CH4 and H2 S
ITMI981633A1 (it) *	1998-07-16	2000-01-16	Enitecnologie Spa	Catalizzatore a base di molibdeno e suo impiego nell'isomerizzazione di n-paraffine
CA2343836C (fr)	1998-09-14	2007-12-04	Shell Internationale Research Maatschappij B.V.	Support de catalyseur d'epoxydation, sa preparation et son utilisation
US7232786B2 (en)	1998-09-14	2007-06-19	Shell Oil Company	Catalyst composition
US7232918B2 (en)	2001-11-06	2007-06-19	Shell Oil Company	Catalyst composition
US7504525B2 (en)	1998-09-14	2009-03-17	Shell Oil Company	Catalyst composition
WO2000056692A1 (fr) *	1999-03-24	2000-09-28	Lehigh University	Production de formaldehyde a partir de ch4 et de h2s
EP1038578A3 (fr) *	1999-03-26	2002-01-30	President of Shizuoka University, a government agency of Japan	Procédé de production de formaldehyde directement à partir de méthane
AU747541B2 (en) *	2000-03-27	2002-05-16	President Of Shizuoka University	Method of producing formaldehyde directly from methane
RU2283829C1 (ru) *	2005-02-24	2006-09-20	Институт химической физики им. Н.Н. Семенова РАН (ИХФ РАН)	Способ производства формальдегида
EP2125202A2 (fr)	2006-11-20	2009-12-02	Shell Internationale Research Maatschappij B.V.	Procédé de traitement d'un support, procédé de préparation d'un catalyseur, catalyseur et utilisation du catalyseur
CN101723794A (zh) *	2008-10-13	2010-06-09	微宏动力系统（湖州）有限公司	甲烷制备溴甲烷、乙酰溴、醋酸和醋酸酯的方法
US12379376B2 (en)	2018-12-03	2025-08-05	University Of Notre Dame Du Lac	Biosensor and method for detection of analytes

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* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2102160A (en) *	1933-03-15	1937-12-14	Firm Gutehoffnungshutte Oberha	Process for the production of formaldehyde from methane
US2381825A (en) *	1939-04-29	1945-08-07	Universal Oil Prod Co	Catalytic conversion process
US2376668A (en) *	1942-04-16	1945-05-22	Monsanto Chemicals	Process for production of formaldehyde
US2625519A (en) *	1950-03-07	1953-01-13	Du Pont	Oxidation catalysts
GB1244001A (en) *	1968-05-01	1971-08-25	Ici Ltd	Oxygenated hydrocarbons production
DE1940259A1 (de) *	1969-02-13	1970-10-22	Nat Res Dev	Verfahren zur Oxydation von Alkanen
GB1398385A (en) *	1971-09-08	1975-06-18	British Gas Corp	Oxidation of gases which consist principally of hydrocarbons
DE2404738A1 (de) *	1974-02-01	1975-08-21	Bayer Ag	Verfahren zur herstellung von formaldehyd
DE2404737A1 (de) *	1974-02-01	1975-08-21	Bayer Ag	Verfahren zur herstellung von formaldehyd
CH611576A5 (fr) *	1975-06-26	1979-06-15	Buehler Ag Geb
DE2743113C3 (de) *	1977-09-24	1980-09-04	Chemische Werke Huels Ag, 4370 Marl	Verfahren zur Herstellung von Gemischen aus Formaldehyd und Methanol durch partielle Oxidation von Methan
US4280929A (en) *	1979-09-17	1981-07-28	Standard Oil Company	Attrition resistant-higher active component fluid bed catalysts
JPS5892629A (ja) *	1981-11-27	1983-06-02	Masakazu Iwamoto	メタンの部分配化によるメタノールおよびホルムアルデヒドの製速造方法
US4455390A (en) *	1982-08-19	1984-06-19	Union Oil Company Of California	Catalyst and method for impregnating at a pH less than one

1986
- 1986-02-28 CA CA000502970A patent/CA1259299A/fr not_active Expired
- 1986-03-05 AU AU55467/86A patent/AU5546786A/en not_active Abandoned
- 1986-03-05 EP EP19860902131 patent/EP0217855A4/fr not_active Withdrawn
- 1986-03-05 WO PCT/US1986/000474 patent/WO1986006063A1/fr not_active Ceased
- 1986-03-26 NO NO861233A patent/NO861233L/no unknown
- 1986-04-04 CN CN198686102245A patent/CN86102245A/zh active Pending
- 1986-04-15 ES ES554421A patent/ES8706597A1/es not_active Expired

Also Published As

Publication number	Publication date
EP0217855A4 (fr)	1988-11-29
ES8706597A1 (es)	1987-07-01
WO1986006063A1 (fr)	1986-10-23
CA1259299A (fr)	1989-09-12
AU5546786A (en)	1986-11-05
EP0217855A1 (fr)	1987-04-15
CN86102245A (zh)	1986-10-15
ES554421A0 (es)	1987-07-01

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