NO874052L - Fremgangsmaate ved gruppeoverfoeringspolymerisering og initiatorer for anvendelse ved denne. - Google Patents

Fremgangsmaate ved gruppeoverfoeringspolymerisering og initiatorer for anvendelse ved denne.

Info

Publication number: NO874052L
Authority: NO; Norway
Prior art keywords: radical; aliphatic; carbon atoms; aromatic; independently
Prior art date: 1986-09-29

Application number

NO874052A

Other languages

English (en)

Norwegian (no)

Other versions

NO874052D0 (no

Inventor

Walter Raymond Hertler

Original Assignee

Du Pont

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-09-29

Filing date

1987-09-28

Publication date

1988-03-30

1987-09-28 Application filed by Du Pont filed Critical Du Pont

1987-09-28 Publication of NO874052D0 publication Critical patent/NO874052D0/no

1988-03-30 Publication of NO874052L publication Critical patent/NO874052L/no

Links

239000003999 initiator Substances 0.000 title claims description 37
238000000034 method Methods 0.000 title claims description 37
238000006116 polymerization reaction Methods 0.000 title claims description 31
229920000642 polymer Polymers 0.000 claims description 59
239000000178 monomer Substances 0.000 claims description 48
125000004432 carbon atom Chemical group C* 0.000 claims description 32
125000001931 aliphatic group Chemical group 0.000 claims description 26
-1 bifluoride Chemical compound 0.000 claims description 24
125000001424 substituent group Chemical group 0.000 claims description 20
125000004069 aziridinyl group Chemical group 0.000 claims description 19
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 18
125000003118 aryl group Chemical group 0.000 claims description 16
239000000203 mixture Substances 0.000 claims description 16
125000002723 alicyclic group Chemical group 0.000 claims description 15
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 13
150000001875 compounds Chemical class 0.000 claims description 13
230000000977 initiatory effect Effects 0.000 claims description 13
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
229910052732 germanium Inorganic materials 0.000 claims description 10
229910052718 tin Inorganic materials 0.000 claims description 10
229910052710 silicon Inorganic materials 0.000 claims description 9
PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 claims description 7
125000000217 alkyl group Chemical group 0.000 claims description 7
239000002879 Lewis base Substances 0.000 claims description 5
239000003426 co-catalyst Substances 0.000 claims description 5
150000007527 lewis bases Chemical class 0.000 claims description 5
238000004519 manufacturing process Methods 0.000 claims description 5
XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims description 4
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 4
239000002841 Lewis acid Substances 0.000 claims description 4
150000007517 lewis acids Chemical class 0.000 claims description 4
239000003505 polymerization initiator Substances 0.000 claims description 4
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 3
SNVLJLYUUXKWOJ-UHFFFAOYSA-N methylidenecarbene Chemical compound C=[C] SNVLJLYUUXKWOJ-UHFFFAOYSA-N 0.000 claims description 3
125000000082 organogermanium group Chemical group 0.000 claims description 3
239000010703 silicon Substances 0.000 claims description 3
125000005439 maleimidyl group Chemical group C1(C=CC(N1*)=O)=O 0.000 claims description 2
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 30
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 30
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 28
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 28
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 23
229920003229 poly(methyl methacrylate) Polymers 0.000 description 18
239000004926 polymethyl methacrylate Substances 0.000 description 18
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 15
239000002904 solvent Substances 0.000 description 14
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 14
XEZCCHVCBAZAQD-UHFFFAOYSA-N 2-(aziridin-1-yl)ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCN1CC1 XEZCCHVCBAZAQD-UHFFFAOYSA-N 0.000 description 10
238000006243 chemical reaction Methods 0.000 description 10
238000002360 preparation method Methods 0.000 description 10
229920001577 copolymer Polymers 0.000 description 9
238000010992 reflux Methods 0.000 description 9
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 8
239000007787 solid Substances 0.000 description 8
229920001400 block copolymer Polymers 0.000 description 7
238000001704 evaporation Methods 0.000 description 7
230000008020 evaporation Effects 0.000 description 7
238000005227 gel permeation chromatography Methods 0.000 description 7
239000000047 product Substances 0.000 description 7
HZLCGUXUOFWCCN-UHFFFAOYSA-N 2-hydroxynonadecane-1,2,3-tricarboxylic acid Chemical compound CCCCCCCCCCCCCCCCC(C(O)=O)C(O)(C(O)=O)CC(O)=O HZLCGUXUOFWCCN-UHFFFAOYSA-N 0.000 description 6
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
238000007792 addition Methods 0.000 description 6
229910052744 lithium Inorganic materials 0.000 description 6
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 5
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 5
238000004458 analytical method Methods 0.000 description 5
229920000578 graft copolymer Polymers 0.000 description 5
NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 4
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
239000005977 Ethylene Substances 0.000 description 4
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 4
238000005481 NMR spectroscopy Methods 0.000 description 4
150000001336 alkenes Chemical class 0.000 description 4
239000003054 catalyst Substances 0.000 description 4
230000008878 coupling Effects 0.000 description 4
238000010168 coupling process Methods 0.000 description 4
238000005859 coupling reaction Methods 0.000 description 4
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
238000003756 stirring Methods 0.000 description 4
FPGGTKZVZWFYPV-UHFFFAOYSA-M tetrabutylammonium fluoride Chemical compound [F-].CCCC[N+](CCCC)(CCCC)CCCC FPGGTKZVZWFYPV-UHFFFAOYSA-M 0.000 description 4
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 3
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 3
239000012300 argon atmosphere Substances 0.000 description 3
125000003710 aryl alkyl group Chemical group 0.000 description 3
238000009833 condensation Methods 0.000 description 3
230000005494 condensation Effects 0.000 description 3
238000004132 cross linking Methods 0.000 description 3
125000000753 cycloalkyl group Chemical group 0.000 description 3
239000000706 filtrate Substances 0.000 description 3
239000011541 reaction mixture Substances 0.000 description 3
125000004178 (C1-C4) alkyl group Chemical group 0.000 description 2
ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 2
229940093475 2-ethoxyethanol Drugs 0.000 description 2
LTVRSJBNXLZFGT-UHFFFAOYSA-N 2-silylethenone Chemical compound [SiH3]C=C=O LTVRSJBNXLZFGT-UHFFFAOYSA-N 0.000 description 2
CSDQQAQKBAQLLE-UHFFFAOYSA-N 4-(4-chlorophenyl)-4,5,6,7-tetrahydrothieno[3,2-c]pyridine Chemical compound C1=CC(Cl)=CC=C1C1C(C=CS2)=C2CCN1 CSDQQAQKBAQLLE-UHFFFAOYSA-N 0.000 description 2
XLYMOEINVGRTEX-ARJAWSKDSA-N Ethyl hydrogen fumarate Chemical compound CCOC(=O)\C=C/C(O)=O XLYMOEINVGRTEX-ARJAWSKDSA-N 0.000 description 2
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
239000004698 Polyethylene Substances 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 2
230000003213 activating effect Effects 0.000 description 2
125000005234 alkyl aluminium group Chemical group 0.000 description 2
150000001450 anions Chemical class 0.000 description 2
238000009835 boiling Methods 0.000 description 2
WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
IJOOHPMOJXWVHK-UHFFFAOYSA-N chlorotrimethylsilane Chemical compound C[Si](C)(C)Cl IJOOHPMOJXWVHK-UHFFFAOYSA-N 0.000 description 2
239000011248 coating agent Substances 0.000 description 2
238000000576 coating method Methods 0.000 description 2
238000001816 cooling Methods 0.000 description 2
GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
239000000835 fiber Substances 0.000 description 2
XLYMOEINVGRTEX-UHFFFAOYSA-N fumaric acid monoethyl ester Natural products CCOC(=O)C=CC(O)=O XLYMOEINVGRTEX-UHFFFAOYSA-N 0.000 description 2
229920001002 functional polymer Polymers 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
239000007788 liquid Substances 0.000 description 2
150000002642 lithium compounds Chemical class 0.000 description 2
239000000463 material Substances 0.000 description 2
229920003145 methacrylic acid copolymer Polymers 0.000 description 2
229940117841 methacrylic acid copolymer Drugs 0.000 description 2
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
229920000573 polyethylene Polymers 0.000 description 2
229920005604 random copolymer Polymers 0.000 description 2
239000012258 stirred mixture Substances 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
JNOGVQJEBGEKMG-UHFFFAOYSA-N (1-methoxy-2-methylprop-1-enoxy)-trimethylsilane Chemical compound COC(=C(C)C)O[Si](C)(C)C JNOGVQJEBGEKMG-UHFFFAOYSA-N 0.000 description 1
ZMYIIHDQURVDRB-UHFFFAOYSA-N 1-phenylethenylbenzene Chemical group C=1C=CC=CC=1C(=C)C1=CC=CC=C1 ZMYIIHDQURVDRB-UHFFFAOYSA-N 0.000 description 1
WUGOQZFPNUYUOO-UHFFFAOYSA-N 2-trimethylsilyloxyethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCO[Si](C)(C)C WUGOQZFPNUYUOO-UHFFFAOYSA-N 0.000 description 1
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 1
229910015900 BF3 Inorganic materials 0.000 description 1
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
241000897276 Termes Species 0.000 description 1
VNDYJBBGRKZCSX-UHFFFAOYSA-L Zinc bromide Inorganic materials Br[Zn]Br VNDYJBBGRKZCSX-UHFFFAOYSA-L 0.000 description 1
UAYWVJHJZHQCIE-UHFFFAOYSA-L Zinc iodide Inorganic materials I[Zn]I UAYWVJHJZHQCIE-UHFFFAOYSA-L 0.000 description 1
239000002253 acid Substances 0.000 description 1
229920000800 acrylic rubber Polymers 0.000 description 1
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminum chloride Substances Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 1
150000008064 anhydrides Chemical group 0.000 description 1
239000000010 aprotic solvent Substances 0.000 description 1
229910052786 argon Inorganic materials 0.000 description 1
229910052785 arsenic Inorganic materials 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
239000002585 base Substances 0.000 description 1
238000010923 batch production Methods 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
150000001732 carboxylic acid derivatives Chemical group 0.000 description 1
125000002843 carboxylic acid group Chemical group 0.000 description 1
238000005266 casting Methods 0.000 description 1
229910052681 coesite Inorganic materials 0.000 description 1
239000013065 commercial product Substances 0.000 description 1
229910052906 cristobalite Inorganic materials 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000004821 distillation Methods 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
229920005648 ethylene methacrylic acid copolymer Polymers 0.000 description 1
239000011521 glass Substances 0.000 description 1
125000005842 heteroatom Chemical group 0.000 description 1
150000004678 hydrides Chemical class 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
125000005395 methacrylic acid group Chemical group 0.000 description 1
239000003595 mist Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
125000000896 monocarboxylic acid group Chemical group 0.000 description 1
GLHOMAJVILUFPP-UHFFFAOYSA-N n-[dimethylamino(trimethylsilyloxy)phosphanyl]-n-methylmethanamine Chemical compound CN(C)P(N(C)C)O[Si](C)(C)C GLHOMAJVILUFPP-UHFFFAOYSA-N 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
239000012299 nitrogen atmosphere Substances 0.000 description 1
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
229920002338 polyhydroxyethylmethacrylate Polymers 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
108090000623 proteins and genes Proteins 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
238000007086 side reaction Methods 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
229910052682 stishovite Inorganic materials 0.000 description 1
239000000758 substrate Substances 0.000 description 1
150000003628 tricarboxylic acids Chemical class 0.000 description 1
229910052905 tridymite Inorganic materials 0.000 description 1
RFPCAOZQZVOGEB-UHFFFAOYSA-N trimethyl-(2-methyl-1-trimethylsilyloxyprop-1-enoxy)silane Chemical group C[Si](C)(C)OC(=C(C)C)O[Si](C)(C)C RFPCAOZQZVOGEB-UHFFFAOYSA-N 0.000 description 1
IARSSOVWSJAVSZ-UHFFFAOYSA-N tris(dimethylamino)sulfanium Chemical compound CN(C)[S+](N(C)C)N(C)C IARSSOVWSJAVSZ-UHFFFAOYSA-N 0.000 description 1
229940102001 zinc bromide Drugs 0.000 description 1
235000005074 zinc chloride Nutrition 0.000 description 1
239000011592 zinc chloride Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44

Landscapes

Chemical & Material Sciences (AREA)
Polymers & Plastics (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Organic Chemistry (AREA)
Materials Engineering (AREA)
Engineering & Computer Science (AREA)
Polymerization Catalysts (AREA)
Graft Or Block Polymers (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Polymerisation Methods In General (AREA)
Dental Preparations (AREA)

NO874052A 1986-09-29 1987-09-28 Fremgangsmaate ved gruppeoverfoeringspolymerisering og initiatorer for anvendelse ved denne. NO874052L (no)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US91211786A	1986-09-29	1986-09-29

Publications (2)

Publication Number	Publication Date
NO874052D0 NO874052D0 (no)	1987-09-28
NO874052L true NO874052L (no)	1988-03-30

Family

ID=25431411

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO874052A NO874052L (no)	1986-09-29	1987-09-28	Fremgangsmaate ved gruppeoverfoeringspolymerisering og initiatorer for anvendelse ved denne.

Country Status (8)

Country	Link
EP (1)	EP0265091A1 (da)
JP (1)	JPS6397609A (da)
KR (1)	KR880004000A (da)
AU (1)	AU7895387A (da)
BR (1)	BR8705003A (da)
DK (1)	DK509187A (da)
NO (1)	NO874052L (da)
ZA (1)	ZA877314B (da)

Families Citing this family (36)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS64500198A (da) *	1986-05-29	1989-01-26
US4822859A (en) *	1986-06-10	1989-04-18	E. I. Du Pont De Nemours And Company	Group transfer polymerization and initiators therefor
JP2750525B2 (ja) *	1988-05-31	1998-05-13	三菱レイヨン株式会社	帯電防止剤の製造方法及びメタクリル樹脂組成物
GB8914577D0 (en) *	1989-06-24	1989-08-16	Ici Plc	Catalysts
GB8914574D0 (en) *	1989-06-24	1989-08-16	Ici Plc	Catalysts
GB8914575D0 (en) *	1989-06-24	1989-08-16	Ici Plc	Catalysts
US5763548A (en)	1995-03-31	1998-06-09	Carnegie-Mellon University	(Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization
US6541580B1 (en)	1995-03-31	2003-04-01	Carnegie Mellon University	Atom or group transfer radical polymerization
US5807937A (en)	1995-11-15	1998-09-15	Carnegie Mellon University	Processes based on atom (or group) transfer radical polymerization and novel (co) polymers having useful structures and properties
US5789487A (en) *	1996-07-10	1998-08-04	Carnegie-Mellon University	Preparation of novel homo- and copolymers using atom transfer radical polymerization
FR2752238B1 (fr) *	1996-08-12	1998-09-18	Atochem Elf Sa	Procede de polymerisation ou copolymerisation radicalaire controlee de monomeres (meth)acryliques et vinyliques et (co)polymeres obtenus
FR2752237B1 (fr) *	1996-08-12	1998-09-18	Atochem Elf Sa	Procede de polymerisation ou copolymerisation radicalaire controlee de monomeres (meth)acryliques et vinyliques et (co)polymeres obtenus
US5910549A (en) *	1996-08-22	1999-06-08	Carnegie-Mellon University	Method for preparation of alkoxyamines from nitroxyl radicals
FR2752845B1 (fr) *	1996-08-30	1998-10-30	Atochem Elf Sa	Procede de (co)polymerisation radicalaire controlee de monomeres (meth)acryliques et vinyliques en presence d'un complexe de fe, ru ou os et (co)polymeres obtenus
FR2755441B1 (fr) *	1996-11-07	1998-12-24	Atochem Elf Sa	Procede de (co)polymerisation radicalaire controlee de monomeres (meth)acryliques, vinyliques, vinylideniques et dieniques en presence d'un complexe de rh, co ou ir
US7125938B2 (en)	1997-03-11	2006-10-24	Carnegie Mellon University	Atom or group transfer radical polymerization
US6121371A (en) *	1998-07-31	2000-09-19	Carnegie Mellon University	Application of atom transfer radical polymerization to water-borne polymerization systems
JP4814422B2 (ja) *	2000-11-09	2011-11-16	株式会社カネカ	重合体の製造法及び重合体
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1987
- 1987-09-25 AU AU78953/87A patent/AU7895387A/en not_active Abandoned
- 1987-09-28 NO NO874052A patent/NO874052L/no unknown
- 1987-09-28 EP EP87308546A patent/EP0265091A1/en not_active Withdrawn
- 1987-09-28 DK DK509187A patent/DK509187A/da not_active Application Discontinuation
- 1987-09-28 BR BR8705003A patent/BR8705003A/pt unknown
- 1987-09-28 JP JP62241020A patent/JPS6397609A/ja active Pending
- 1987-09-29 KR KR870010866A patent/KR880004000A/ko not_active Withdrawn
- 1987-09-29 ZA ZA877314A patent/ZA877314B/xx unknown

Also Published As

Publication number	Publication date
ZA877314B (en)	1989-05-30
JPS6397609A (ja)	1988-04-28
EP0265091A1 (en)	1988-04-27
AU7895387A (en)	1988-03-31
DK509187D0 (da)	1987-09-28
NO874052D0 (no)	1987-09-28
DK509187A (da)	1988-03-30
KR880004000A (ko)	1988-06-01
BR8705003A (pt)	1988-05-24

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