NO910471L - Bionedbrytbare laktidholdige termoplastmaterialer. - Google Patents
Bionedbrytbare laktidholdige termoplastmaterialer.Info
- Publication number
- NO910471L NO910471L NO91910471A NO910471A NO910471L NO 910471 L NO910471 L NO 910471L NO 91910471 A NO91910471 A NO 91910471A NO 910471 A NO910471 A NO 910471A NO 910471 L NO910471 L NO 910471L
- Authority
- NO
- Norway
- Prior art keywords
- lactide
- polymer
- mixture
- mixtures
- biodegradable
- Prior art date
Links
Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/53—Polyethers; Polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/22—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing macromolecular materials
- A61L15/26—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/62—Compostable, hydrosoluble or hydrodegradable materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
- C08G63/08—Lactones or lactides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
- C09J167/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/19—Details relating to the geometry of the reactor
- B01J2219/194—Details relating to the geometry of the reactor round
- B01J2219/1941—Details relating to the geometry of the reactor round circular or disk-shaped
- B01J2219/1942—Details relating to the geometry of the reactor round circular or disk-shaped spherical
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/04—Polyesters derived from hydroxy carboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/28—Non-macromolecular organic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
- C08L67/025—Polyesters derived from dicarboxylic acids and dihydroxy compounds containing polyether sequences
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Epidemiology (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- Manufacturing & Machinery (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Hematology (AREA)
- Wood Science & Technology (AREA)
- Biological Depolymerization Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
ionedbrytbare blandinger av L-laktid, D-laktid, meso D,L-laktid og rasemisk D,L-laktid egnet for bøyelige filmer og andre emballasjeformål fremstilles ved polymerisering av L-laktid, D-laktid, D,L-laktid eller blandinger derav under anvendelse av en katalysator ved kontrollerte betingelser slik at polymeren i blandingen kan bli plastisert ved hjelp, av ureagert laktidmonomer. Miljømessig bionedbrytbar polymer, blandinger og fremgangsmåte for en polymer og en blanding. Den bionedbrytbare polymer omfatter polymeriserte melkesyre-enheter med struktur (I), hvori n er et helt tall mellom 75 og 10.000 og alfakarbonatomet er en blanding av L- og D-konfigurasjoner, hvor den uorienterte polymer har en strekk-styrke på minst 350 kg/cmog en tangentmodul på minst 14.000 kg/cm. En ytterligere utførelsesform tilveiebringer en miljømessig nedbrytbar blanding omfattende blandinger av en fysikalsk blanding av polymelkesyre og en polymer valgt fra gruppen bestående av polymerer av etylentereftalat, en polymer eller kopolymer av styren, etylen, propylen, vinylklorid, vinylacetat, alkylmetakrylat, alkylakrylat og fysikalske blandinger derav.
Applications Claiming Priority (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US22989488A | 1988-08-08 | 1988-08-08 | |
| US22993988A | 1988-08-08 | 1988-08-08 | |
| US22989688A | 1988-08-08 | 1988-08-08 | |
| US31739189A | 1989-03-01 | 1989-03-01 | |
| US38767689A | 1989-07-31 | 1989-07-31 | |
| US38767889A | 1989-07-31 | 1989-07-31 | |
| US38684489A | 1989-07-31 | 1989-07-31 | |
| US38767089A | 1989-07-31 | 1989-07-31 | |
| PCT/US1989/003380 WO1990001521A1 (en) | 1988-08-08 | 1989-08-04 | Degradable thermoplastic from lactides |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| NO910471D0 NO910471D0 (no) | 1991-02-07 |
| NO910471L true NO910471L (no) | 1991-04-08 |
Family
ID=27575232
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO91910471A NO910471L (no) | 1988-08-08 | 1991-02-07 | Bionedbrytbare laktidholdige termoplastmaterialer. |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0428620B1 (no) |
| KR (1) | KR900701934A (no) |
| AT (1) | ATE177134T1 (no) |
| BR (1) | BR8907604A (no) |
| DE (1) | DE68928938T2 (no) |
| DK (1) | DK50391A (no) |
| HU (1) | HUT64576A (no) |
| NO (1) | NO910471L (no) |
| WO (1) | WO1990001521A1 (no) |
Families Citing this family (109)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5180765A (en) * | 1988-08-08 | 1993-01-19 | Biopak Technology, Ltd. | Biodegradable packaging thermoplastics from lactides |
| US5502158A (en) * | 1988-08-08 | 1996-03-26 | Ecopol, Llc | Degradable polymer composition |
| US5424346A (en) * | 1988-08-08 | 1995-06-13 | Ecopol, Llc | Biodegradable replacement of crystal polystyrene |
| US5444113A (en) * | 1988-08-08 | 1995-08-22 | Ecopol, Llc | End use applications of biodegradable polymers |
| US6027677A (en) * | 1988-08-08 | 2000-02-22 | Chronopol, Inc. | Films containing poly(hydroxy acid)s |
| US5216050A (en) * | 1988-08-08 | 1993-06-01 | Biopak Technology, Ltd. | Blends of polyactic acid |
| US5252642A (en) * | 1989-03-01 | 1993-10-12 | Biopak Technology, Ltd. | Degradable impact modified polyactic acid |
| US6323307B1 (en) | 1988-08-08 | 2001-11-27 | Cargill Dow Polymers, Llc | Degradation control of environmentally degradable disposable materials |
| JP2986509B2 (ja) * | 1989-05-26 | 1999-12-06 | 三井化学株式会社 | 変性ポリエステル樹脂組成物、その製造方法、およびその用途 |
| US5227415A (en) * | 1990-04-06 | 1993-07-13 | Director-General Of Agency Of Industrial Science And Technology | Biodegradable plastic composition |
| US5091544A (en) * | 1990-05-08 | 1992-02-25 | E. I. Du Pont De Nemours And Company | Process for rapid conversion of oligomers to cyclic esters |
| EP0463194A1 (de) * | 1990-06-23 | 1992-01-02 | Boehringer Ingelheim Kg | Verfahren zur Herstellung von Poly-(D,L-lactid) und seine Verwendung als Wirkstoffträger |
| JPH04226125A (ja) * | 1990-06-23 | 1992-08-14 | Boehringer Ingelheim Kg | ポリ−d,l−ラクチドの製造方法及び活性物質の担体としてのそれらの使用 |
| JP2744696B2 (ja) * | 1990-07-13 | 1998-04-28 | イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー | ラクチドの高収率再生方法 |
| US5076983A (en) * | 1990-07-16 | 1991-12-31 | E. I. Du Pont De Nemours And Company | Polyhydroxy acid films |
| BR9106821A (pt) * | 1990-09-06 | 1993-07-13 | Battelle Memorial Institute | Termoplasticos para embalagem provenientes de acido latico |
| CA2090977A1 (en) * | 1990-09-11 | 1992-03-12 | George J. Ostapchenko | Films containing polyhydroxy acids |
| US5117008A (en) * | 1990-10-23 | 1992-05-26 | E. I. Du Pont De Nemours And Company | Solvent scrubbing recovery of lactide and other dimeric cyclic esters |
| US5089632A (en) * | 1991-01-30 | 1992-02-18 | E. I. Du Pont De Nemours And Company | Process for preparing cyclic esters using a fluorocarbon |
| SE9100610D0 (sv) * | 1991-03-04 | 1991-03-04 | Procordia Ortech Ab | Bioresorbable material for medical use |
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| CA2067451A1 (en) * | 1991-05-24 | 1993-10-29 | Gregory B. Kharas | Polylactide blends |
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| US5264617A (en) * | 1991-11-22 | 1993-11-23 | E. I. Du Pont De Nemours And Company | Preparation of alkyl esters by depolymerization |
| US5264614A (en) * | 1991-11-22 | 1993-11-23 | E. I. Du Pont De Nemours And Company | Recovery of polyhydroxy acids |
| US5264626A (en) * | 1991-11-22 | 1993-11-23 | E. I. Du Pont De Nemours And Company | Rapid depolymerization of polyhydroxy acids |
| US5229528A (en) * | 1991-11-22 | 1993-07-20 | E. I. Du Pont De Nemours And Company | Rapid depolymerization of polyhydroxy acids |
| US5268507A (en) * | 1991-11-22 | 1993-12-07 | E. I. Du Pont De Nemours And Company | Preparation of amide derivatives of hydroxy acids |
| US5270400A (en) * | 1991-12-31 | 1993-12-14 | Maria Spinu | L-Dpolylactide copolymers with controlled morphology |
| US5346966A (en) * | 1991-12-31 | 1994-09-13 | E. I. Du Pont De Nemours And Company | L,d-polylactide copolymers with controlled morphology |
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| US5258488A (en) * | 1992-01-24 | 1993-11-02 | Cargill, Incorporated | Continuous process for manufacture of lactide polymers with controlled optical purity |
| JP3150426B2 (ja) * | 1992-06-29 | 2001-03-26 | 三井化学株式会社 | 分解性複合材料 |
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| DE4234620A1 (de) * | 1992-10-14 | 1994-04-21 | Basf Ag | Verfahren zur Herstellung von geschäumten Polylactid Spritzgießteilen hoher Festigkeit und Steifigkeit |
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| NL9201949A (nl) * | 1992-11-06 | 1994-06-01 | Univ Groningen | Met rubber gemodificeerde polylactide-samenstelling. |
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| US5342969A (en) * | 1993-03-03 | 1994-08-30 | E. I. Du Pont De Nemours And Company | Recovery of hydroxycarboxylic acid values from poly(hydroxycarboxylic acids) |
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| JP4640765B2 (ja) | 2004-09-03 | 2011-03-02 | 株式会社Adeka | ポリ乳酸系樹脂組成物、成形品及びその製造方法 |
| WO2008013316A1 (en) * | 2006-07-28 | 2008-01-31 | Teijin Limited | Resin composition, method for producing the same and molded article |
| US8268913B2 (en) * | 2008-06-30 | 2012-09-18 | Fina Technology, Inc. | Polymeric blends and methods of using same |
| NZ592715A (en) * | 2008-11-07 | 2013-04-26 | Colgate Palmolive Co | Blends of polylactic acid and thermoplastic polymers for packaging applications |
| EP2471856A1 (en) | 2010-12-30 | 2012-07-04 | Dow Global Technologies LLC | Polyolefin compositions |
| WO2013131649A1 (en) * | 2012-03-07 | 2013-09-12 | Huhtamäki Oyj | An essentially biobased, thermoformable composition and containers formed thereof |
| EP4389843A3 (en) | 2014-12-22 | 2024-07-31 | 3M Innovative Properties Company | Compositions and films comprising polylactic acid polymer, polyvinyl acetate polymer and plasticizer |
| CN105676765A (zh) * | 2016-03-11 | 2016-06-15 | 上海应用技术学院 | 一种化工过程安全监控系统 |
| CN109153799B (zh) | 2016-05-20 | 2022-03-08 | 3M创新有限公司 | 取向聚乳酸聚合物基膜 |
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| US10072121B1 (en) | 2017-03-08 | 2018-09-11 | International Business Machines Corporation | Bottlebrush polymers derived from poly(methylidenelactide) |
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| US10570252B2 (en) | 2017-03-08 | 2020-02-25 | International Business Machines Corporation | Flame retardant lactide monomors for polylactide synthesis |
| CA3142475A1 (en) * | 2019-06-13 | 2020-12-17 | Natureworks Llc | Fast-hydrolyzing polylactide resin compositions |
| CN112898752B (zh) * | 2021-02-03 | 2022-12-02 | 湖南工业大学 | 一种高结晶度的聚乳酸材料及其制备方法 |
| CN113026419A (zh) * | 2021-02-26 | 2021-06-25 | 上海紫江喷铝环保材料有限公司 | 连线印刷的环保全息镭射定位包装材料及其制作方法 |
| CN113402867B (zh) * | 2021-07-09 | 2022-10-11 | 大连理工大学 | 一类接枝共聚-共混高抗冲聚乳酸及其制备方法 |
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| CN116789970B (zh) * | 2023-07-17 | 2024-03-26 | 南京大学 | 一种pbat-pla基生物可降解热熔胶粘剂及其制备方法与应用 |
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Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2703316A (en) * | 1951-06-05 | 1955-03-01 | Du Pont | Polymers of high melting lactide |
| CA1256638A (en) * | 1984-07-06 | 1989-06-27 | Motoaki Tanaka | Polymer and its production |
| JP2551756B2 (ja) * | 1985-05-07 | 1996-11-06 | 武田薬品工業株式会社 | ポリオキシカルボン酸エステルおよびその製造法 |
-
1989
- 1989-08-04 WO PCT/US1989/003380 patent/WO1990001521A1/en not_active Ceased
- 1989-08-04 EP EP89910376A patent/EP0428620B1/en not_active Expired - Lifetime
- 1989-08-04 BR BR898907604A patent/BR8907604A/pt not_active IP Right Cessation
- 1989-08-04 DE DE68928938T patent/DE68928938T2/de not_active Expired - Fee Related
- 1989-08-04 AT AT89910376T patent/ATE177134T1/de not_active IP Right Cessation
- 1989-08-04 KR KR1019900700727A patent/KR900701934A/ko not_active Ceased
- 1989-08-04 HU HU895791A patent/HUT64576A/hu unknown
-
1991
- 1991-02-07 NO NO91910471A patent/NO910471L/no unknown
- 1991-03-20 DK DK050391A patent/DK50391A/da not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| KR900701934A (ko) | 1990-12-05 |
| NO910471D0 (no) | 1991-02-07 |
| DE68928938D1 (de) | 1999-04-08 |
| HU895791D0 (en) | 1992-07-28 |
| EP0428620A1 (en) | 1991-05-29 |
| DE68928938T2 (de) | 1999-09-30 |
| BR8907604A (pt) | 1991-07-30 |
| WO1990001521A1 (en) | 1990-02-22 |
| ATE177134T1 (de) | 1999-03-15 |
| DK50391D0 (da) | 1991-03-20 |
| EP0428620B1 (en) | 1999-03-03 |
| HUT64576A (en) | 1994-01-28 |
| DK50391A (da) | 1991-03-20 |
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