NO975007L - Katalysatorsystem for polymerisering - Google Patents

Katalysatorsystem for polymerisering

Info

Publication number: NO975007L
Authority: NO; Norway
Prior art keywords: sup; sub; group; whose value; polymerization
Prior art date: 1996-10-30

Application number

NO975007A

Other languages

English (en)

Other versions

NO319295B1 (no

NO975007D0 (no

Inventor

Jose Sancho Royo

Antonio Munoz-Escalon Lafuente

Begona Pena Garcia

Carlos Martin Marcos

Original Assignee

Repsol Quimica Sa

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-10-30

Filing date

1997-10-30

Publication date

1998-05-04

1997-10-30 Application filed by Repsol Quimica Sa filed Critical Repsol Quimica Sa

1997-10-30 Publication of NO975007D0 publication Critical patent/NO975007D0/no

1998-05-04 Publication of NO975007L publication Critical patent/NO975007L/no

2005-07-11 Publication of NO319295B1 publication Critical patent/NO319295B1/no

Links

239000003054 catalyst Substances 0.000 title abstract 2
238000006116 polymerization reaction Methods 0.000 title 1
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
239000002879 Lewis base Substances 0.000 abstract 1
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
229910052768 actinide Inorganic materials 0.000 abstract 1
150000001255 actinides Chemical class 0.000 abstract 1
125000003342 alkenyl group Chemical group 0.000 abstract 1
125000002877 alkyl aryl group Chemical group 0.000 abstract 1
125000000217 alkyl group Chemical group 0.000 abstract 1
125000005018 aryl alkenyl group Chemical group 0.000 abstract 1
125000003710 aryl alkyl group Chemical group 0.000 abstract 1
125000003118 aryl group Chemical group 0.000 abstract 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
229910052794 bromium Inorganic materials 0.000 abstract 1
125000004432 carbon atom Chemical group C* 0.000 abstract 1
229910052801 chlorine Inorganic materials 0.000 abstract 1
239000000460 chlorine Substances 0.000 abstract 1
150000001875 compounds Chemical class 0.000 abstract 1
125000000753 cycloalkyl group Chemical group 0.000 abstract 1
150000004820 halides Chemical class 0.000 abstract 1
229910052739 hydrogen Inorganic materials 0.000 abstract 1
239000001257 hydrogen Substances 0.000 abstract 1
125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 abstract 1
229910052747 lanthanoid Inorganic materials 0.000 abstract 1
150000002602 lanthanoids Chemical class 0.000 abstract 1
150000007527 lewis bases Chemical class 0.000 abstract 1
229910052751 metal Inorganic materials 0.000 abstract 1
239000002184 metal Substances 0.000 abstract 1
230000007935 neutral effect Effects 0.000 abstract 1
229910052760 oxygen Inorganic materials 0.000 abstract 1
230000000737 periodic effect Effects 0.000 abstract 1
229910052710 silicon Inorganic materials 0.000 abstract 1
229910052717 sulfur Inorganic materials 0.000 abstract 1
229910052723 transition metal Inorganic materials 0.000 abstract 1
150000003624 transition metals Chemical class 0.000 abstract 1
239000004711 α-olefin Substances 0.000 abstract 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/146—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of boron
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1608—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes the ligands containing silicon
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/46—Titanium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/48—Zirconium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/49—Hafnium
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Inorganic Chemistry (AREA)
Health & Medical Sciences (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

NO19975007A 1996-10-30 1997-10-30 Katalysatorsystem for polymerisering NO319295B1 (no)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
ES9602302		1996-10-30

Publications (3)

Publication Number	Publication Date
NO975007D0 NO975007D0 (no)	1997-10-30
NO975007L true NO975007L (no)	1998-05-04
NO319295B1 NO319295B1 (no)	2005-07-11

Family

ID=8296545

Family Applications (3)

Application Number	Title	Priority Date	Filing Date
NO19975008A NO316699B1 (no)	1996-10-30	1997-10-30	Katalysatorsystem for polymerisering
NO19975007A NO319295B1 (no)	1996-10-30	1997-10-30	Katalysatorsystem for polymerisering
NO19974998A NO317950B1 (no)	1996-10-30	1997-10-30	Katalysatorsystem for polymerisering

Family Applications Before (1)

Application Number	Title	Priority Date	Filing Date
NO19975008A NO316699B1 (no)	1996-10-30	1997-10-30	Katalysatorsystem for polymerisering

Family Applications After (1)

Application Number	Title	Priority Date	Filing Date
NO19974998A NO317950B1 (no)	1996-10-30	1997-10-30	Katalysatorsystem for polymerisering

Country Status (8)

Country	Link
US (1)	US5977392A (no)
EP (2)	EP0839833B1 (no)
JP (3)	JPH10182716A (no)
AT (3)	ATE189822T1 (no)
DE (2)	DE69701306T2 (no)
ES (2)	ES2210479T3 (no)
NO (3)	NO316699B1 (no)
PT (3)	PT839835E (no)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE69703728T2 (de)	1996-10-31	2001-06-28	Repsol Quimica S.A., Madrid	Katalysatorsysteme für die Polymerisation und Copolymerisation von Alpha-Olefinen
EP0856524A1 (en) *	1997-02-01	1998-08-05	Repsol Quimica S.A.	Heterogeneous catalyst components for olefins polymerization, preparation process and use thereof
US6489261B1 (en) *	1997-12-01	2002-12-03	Dsm N.V.	Catalyst composition comprising a reduced transition metal complex and a cocatalyst
PT953581E (pt)	1998-04-27	2004-07-30	Repsol Quimica Sa	Sistemas cataliticos para a polimerizacao e a copolimerizacao de alfa-olefinas
ES2216473T3 (es) *	1998-04-29	2004-10-16	Repsol Quimica S.A.	Preparacion y uso de componentes de catalizador heterogeneos para polimerizacion de olefinas.
EP1392740B1 (en) *	2000-09-25	2008-08-20	Basell Polyolefine GmbH	Process for the preparation of ethylene polymers with a bis-amido titanium compound
GB0102440D0 (en)	2001-01-31	2001-03-14	Borealis Tech Oy	Catalyst
JP2003020416A (ja)	2001-07-06	2003-01-24	Fuji Photo Film Co Ltd	テトラシアノキノジメタン化合物を対アニオンとした特定構造のシアニン色素化合物及び該シアニン色素化合物を含む光情報記録媒体
KR100690345B1 (ko) *	2004-09-03	2007-03-09	주식회사 엘지화학	담지 메탈로센 촉매, 그 제조방법 및 이를 이용한폴리올레핀의 제조방법
KR101959519B1 (ko) *	2016-04-12	2019-03-18	(주)디엔에프	전이금속 화합물, 이의 제조방법 및 이를 포함하는 전이금속함유 박막증착용 조성물
CN116410223B (zh) *	2021-12-31	2025-12-05	中国石油天然气股份有限公司	四芳基乙氧基侧链单茂金属化合物、包含其的催化剂体系及应用进行的聚烯烃合成方法

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE1022382B (de) *	1956-04-12	1958-01-09	Hoechst Ag	Verfahren zur Polymerisation von niederen Olefinen
US3440237A (en) *	1958-05-22	1969-04-22	Monsanto Co	Production of polyethylene with water-modified ziegler catalyst
US3184416A (en) *	1958-05-22	1965-05-18	Monsanto Co	Production of ziegler polymerization catalysts
US4172945A (en) *	1976-01-14	1979-10-30	E. R. Squibb & Sons, Inc.	Precursors of indanpentol derivatives
DE3127133A1 (de) *	1981-07-09	1983-01-27	Hoechst Ag, 6000 Frankfurt	Verfahren zur herstellung von polyolefinen und deren copolymerisaten
IL85097A (en) *	1987-01-30	1992-02-16	Exxon Chemical Patents Inc	Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5055438A (en) *	1989-09-13	1991-10-08	Exxon Chemical Patents, Inc.	Olefin polymerization catalysts
US4939217A (en) *	1987-04-03	1990-07-03	Phillips Petroleum Company	Process for producing polyolefins and polyolefin catalysts
US5064797A (en) *	1987-04-03	1991-11-12	Phillips Petroleum Company	Process for producing polyolefins and polyolefin catalysts
DE3718888A1 (de) *	1987-06-05	1988-12-22	Hoechst Ag	Verfahren zur herstellung eines 1-olefinpolymers
US4925821A (en) *	1987-12-17	1990-05-15	Exxon Chemical Patents Inc.	Method for utilizing triethyaluminum to prepare an alumoxane support for an active metallocene catalyst
US4937217A (en) *	1987-12-17	1990-06-26	Exxon Chemical Patents Inc.	Method for utilizing triethylaluminum to prepare an alumoxane support for an active metallocene catalyst
US4912075A (en) *	1987-12-17	1990-03-27	Exxon Chemical Patents Inc.	Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization
US5008228A (en) *	1988-03-29	1991-04-16	Exxon Chemical Patents Inc.	Method for preparing a silica gel supported metallocene-alumoxane catalyst
US4935397A (en) *	1988-09-28	1990-06-19	Exxon Chemical Patents Inc.	Supported metallocene-alumoxane catalyst for high pressure polymerization of olefins and a method of preparing and using the same
NZ235032A (en) *	1989-08-31	1993-04-28	Dow Chemical Co	Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5057475A (en) *	1989-09-13	1991-10-15	Exxon Chemical Patents Inc.	Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
DK0426637T4 (da) *	1989-10-30	2002-01-14	Fina Technology	Fremgangsmåde til fremstilling af metallocenkatalysatorer til polymerisation af olefiner
JPH07509752A (ja) *	1992-08-05	1995-10-26	エクソン・ケミカル・パテンツ・インク	オレフィン重合用の担持されたイオン遷移金属触媒
DE69312306T2 (de) *	1992-10-02	1997-11-13	Dow Chemical Co	Aufträger homogener komplexkatalysator für olefinpolymerisation
IT1264680B1 (it) *	1993-07-07	1996-10-04	Spherilene Srl	Catalizzatori supportati per la polimerizzazione delle olefine
EP0668295B1 (en) *	1994-02-17	1998-06-03	Union Carbide Chemicals & Plastics Technology Corporation	Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture
US5486632A (en) *	1994-06-28	1996-01-23	The Dow Chemical Company	Group 4 metal diene complexes and addition polymerization catalysts therefrom
DE69502028T2 (de) *	1994-10-31	1998-12-10	Dsm N.V., Heerlen	Katalytische zusammensetzung und verfahren zur olefinpolymerisation
ES2120868B1 (es) *	1995-08-03	2000-09-16	Repsol Quimica Sa	Sistema de catalizadores hetereogeneos tipo metalogeno, para procesos de obtencion de poliolefinas.
US5688880A (en) *	1995-12-11	1997-11-18	The Dow Chemical Company	Readily supportable metal complexes
WO1998016311A1 (en) *	1996-10-15	1998-04-23	Northwestern University	Phenolate constrained geometry metallocene olefin polymerization catalyst, method of making, and method of using

1997
- 1997-10-30 ES ES97500184T patent/ES2210479T3/es not_active Expired - Lifetime
- 1997-10-30 JP JP9336262A patent/JPH10182716A/ja active Pending
- 1997-10-30 ES ES97500186T patent/ES2142140T3/es not_active Expired - Lifetime
- 1997-10-30 US US08/961,349 patent/US5977392A/en not_active Expired - Fee Related
- 1997-10-30 NO NO19975008A patent/NO316699B1/no unknown
- 1997-10-30 PT PT97500186T patent/PT839835E/pt unknown
- 1997-10-30 EP EP97500184A patent/EP0839833B1/en not_active Expired - Lifetime
- 1997-10-30 DE DE69701306T patent/DE69701306T2/de not_active Expired - Fee Related
- 1997-10-30 DE DE69726821T patent/DE69726821T2/de not_active Expired - Fee Related
- 1997-10-30 JP JP33626397A patent/JP3340064B2/ja not_active Expired - Fee Related
- 1997-10-30 AT AT97500186T patent/ATE189822T1/de not_active IP Right Cessation
- 1997-10-30 PT PT97500184T patent/PT839833E/pt unknown
- 1997-10-30 JP JP33626197A patent/JP3352374B2/ja not_active Expired - Fee Related
- 1997-10-30 AT AT97500184T patent/ATE256706T1/de not_active IP Right Cessation
- 1997-10-30 EP EP97500186A patent/EP0839835B1/en not_active Expired - Lifetime
- 1997-10-30 NO NO19975007A patent/NO319295B1/no unknown
- 1997-10-30 PT PT97500185T patent/PT839834E/pt unknown
- 1997-10-30 NO NO19974998A patent/NO317950B1/no not_active IP Right Cessation
- 1997-10-30 AT AT97500185T patent/ATE202121T1/de not_active IP Right Cessation

Also Published As

Publication number	Publication date
EP0839835B1 (en)	2000-02-16
ES2210479T3 (es)	2004-07-01
NO319295B1 (no)	2005-07-11
PT839834E (pt)	2001-11-30
NO975008D0 (no)	1997-10-30
NO974998L (no)	1998-05-04
DE69701306D1 (de)	2000-03-23
ES2142140T3 (es)	2000-04-01
JPH10226711A (ja)	1998-08-25
EP0839833B1 (en)	2003-12-17
ATE256706T1 (de)	2004-01-15
EP0839833A2 (en)	1998-05-06
JPH10226710A (ja)	1998-08-25
PT839835E (pt)	2000-08-31
JP3340064B2 (ja)	2002-10-28
EP0839833A3 (en)	1998-09-02
NO317950B1 (no)	2005-01-10
NO975007D0 (no)	1997-10-30
JPH10182716A (ja)	1998-07-07
DE69726821T2 (de)	2004-10-21
PT839833E (pt)	2004-05-31
ATE189822T1 (de)	2000-03-15
EP0839835A1 (en)	1998-05-06
NO316699B1 (no)	2004-03-26
NO974998D0 (no)	1997-10-30
DE69726821D1 (de)	2004-01-29
US5977392A (en)	1999-11-02
JP3352374B2 (ja)	2002-12-03
NO975008L (no)	1998-05-04
ATE202121T1 (de)	2001-06-15
DE69701306T2 (de)	2000-09-14

Publication	Publication Date	Title
NO975008D0 (no)	1997-10-30	Katalysatorsystem for polymerisering
KR900011793A (ko)	1990-08-02	올레핀 중합용 촉매
KR960704940A (ko)	1996-10-09	올레핀 중합 방법 및 촉매(catalysts and processes for the polymerization of olefins)
KR900011794A (ko)	1990-08-02	올레핀류의 중합용 촉매
NO983785D0 (no)	1998-08-19	BÕret katalysatorsystem
RU93046499A (ru)	1996-10-10	Способ увеличения относительной плотности полиамидов
ATE258178T1 (de)	2004-02-15	Als cokatalysator geeignete chemische produkte, verfahren zu ihrer herstellung und ihre verwendung in katalysator-systemen zur herstellung von polyolefinen
KR970074795A (ko)	1997-12-10	에틸렌 중합체의 제조방법
NO975049D0 (no)	1997-10-31	Katalysatorsystem for polymerisering
ID24621A (id)	2000-07-27	Katalis polietilena aktivitas tinggi
ZA93548B (en)	1993-08-05	Catalyst and process for the polymerization and copolymerization of olefins.
KR960022548A (ko)	1996-07-18	메탈로센 화합물 및 촉매 성분으로의 이의 용도
NO983787L (no)	1998-10-19	FremgangsmÕte for Õ fremstille alkener ved suspensjonspolymerisasjon
DE69334206D1 (de)	2008-04-03	Substituierte hexahydrobenzo(a) phenanthridine
ATE178609T1 (de)	1999-04-15	Antivirale zusammensetzungen und verfahren zu ihrer verwendung
JP2001510847A5 (no)	2006-01-05
ATE264344T1 (de)	2004-04-15	Verfahren und verwendung von heterogenen katalysatorbestandteilen für die olefinpolymerisation
HUP0101729A1 (hu)	2001-10-28	Polimerizációs katalizátorok és eljárások
KR960041204A (ko)	1996-12-19	올레핀 중합 촉매 및 이를 사용하는 폴리올레핀의 제조방법
IE792067L (en)	1980-04-30	Azatricyclic compounds
KR880701742A (ko)	1988-11-04	α-올레핀의 중합용 촉매 및 중합법
AU2701297A (en)	1997-11-19	Process for preparing low-molecular ethylene polymers under high pressure