NZ240571A - Liquid detergents containing an enzyme system of lipase and modified protease - Google Patents

Liquid detergents containing an enzyme system of lipase and modified protease

Info

Publication number: NZ240571A
Authority: NZ; New Zealand
Prior art keywords: detergent composition; composition according; protease; lipase; amino acid
Prior art date: 1990-11-14

Application number

NZ24057191A

Other languages

English (en)

Inventor

James Pyott Johnston

Pierre Marie Alain Lenoir

Christiaan Arthur J K Thoen

Original Assignee

Procter & Gamble

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-11-14

Filing date

1991-11-13

Publication date

1994-11-25

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=26128002&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=NZ240571(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1991-11-13 Application filed by Procter & Gamble filed Critical Procter & Gamble

1994-11-25 Publication of NZ240571A publication Critical patent/NZ240571A/en

Links

239000003599 detergent Substances 0.000 title claims description 43
102000004882 Lipase Human genes 0.000 title claims description 35
108090001060 Lipase Proteins 0.000 title claims description 35
239000004367 Lipase Substances 0.000 title claims description 34
235000019421 lipase Nutrition 0.000 title claims description 34
108091005804 Peptidases Proteins 0.000 title claims description 30
239000004365 Protease Substances 0.000 title claims description 30
102000004190 Enzymes Human genes 0.000 title claims description 25
108090000790 Enzymes Proteins 0.000 title claims description 25
239000007788 liquid Substances 0.000 title claims description 17
102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 title claims 5
239000000203 mixture Substances 0.000 claims description 75
230000001580 bacterial effect Effects 0.000 claims description 23
108010022999 Serine Proteases Proteins 0.000 claims description 19
102000012479 Serine Proteases Human genes 0.000 claims description 19
229930182817 methionine Natural products 0.000 claims description 16
150000001413 amino acids Chemical group 0.000 claims description 14
MTCFGRXMJLQNBG-UHFFFAOYSA-N Serine Natural products OCC(N)C(O)=O MTCFGRXMJLQNBG-UHFFFAOYSA-N 0.000 claims description 12
FFEARJCKVFRZRR-BYPYZUCNSA-N L-methionine Chemical compound CSCC[C@H](N)C(O)=O FFEARJCKVFRZRR-BYPYZUCNSA-N 0.000 claims description 10
235000001014 amino acid Nutrition 0.000 claims description 10
102000013142 Amylases Human genes 0.000 claims description 8
108010065511 Amylases Proteins 0.000 claims description 8
235000019418 amylase Nutrition 0.000 claims description 8
239000004094 surface-active agent Substances 0.000 claims description 8
125000000129 anionic group Chemical group 0.000 claims description 7
239000004382 Amylase Substances 0.000 claims description 5
230000002366 lipolytic effect Effects 0.000 claims description 5
125000001360 methionine group Chemical group N[C@@H](CCSC)C(=O)* 0.000 claims description 5
DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 5
235000013772 propylene glycol Nutrition 0.000 claims description 5
244000063299 Bacillus subtilis Species 0.000 claims description 4
235000014469 Bacillus subtilis Nutrition 0.000 claims description 4
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 3
241000223258 Thermomyces lanuginosus Species 0.000 claims description 3
239000004327 boric acid Substances 0.000 claims description 2
125000005619 boric acid group Chemical group 0.000 claims description 2
125000002091 cationic group Chemical group 0.000 claims description 2
235000018417 cysteine Nutrition 0.000 claims description 2
XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Natural products SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 claims description 2
230000006641 stabilisation Effects 0.000 claims 3
238000011105 stabilization Methods 0.000 claims 3
150000001732 carboxylic acid derivatives Chemical class 0.000 claims 1
125000000151 cysteine group Chemical group N[C@@H](CS)C(=O)* 0.000 claims 1
229960004063 propylene glycol Drugs 0.000 claims 1
102000035195 Peptidases Human genes 0.000 description 25
-1 alkyl radical Chemical class 0.000 description 23
229940088598 enzyme Drugs 0.000 description 20
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 19
KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical class OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 16
239000011734 sodium Substances 0.000 description 13
125000000217 alkyl group Chemical group 0.000 description 12
125000004432 carbon atom Chemical group C* 0.000 description 10
150000003839 salts Chemical class 0.000 description 10
229910052708 sodium Inorganic materials 0.000 description 10
239000004615 ingredient Substances 0.000 description 9
MTCFGRXMJLQNBG-REOHCLBHSA-N (2S)-2-Amino-3-hydroxypropansäure Chemical compound OC[C@H](N)C(O)=O MTCFGRXMJLQNBG-REOHCLBHSA-N 0.000 description 8
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 7
229960004106 citric acid Drugs 0.000 description 7
150000002191 fatty alcohols Chemical class 0.000 description 7
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
125000003342 alkenyl group Chemical group 0.000 description 6
235000014113 dietary fatty acids Nutrition 0.000 description 6
229930195729 fatty acid Natural products 0.000 description 6
239000000194 fatty acid Substances 0.000 description 6
239000000047 product Substances 0.000 description 6
239000001384 succinic acid Substances 0.000 description 6
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
239000000654 additive Substances 0.000 description 5
239000007859 condensation product Substances 0.000 description 5
WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 4
LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 4
QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 4
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 4
ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 4
239000004435 Oxo alcohol Substances 0.000 description 4
239000002253 acid Substances 0.000 description 4
150000004996 alkyl benzenes Chemical class 0.000 description 4
201000011243 gastrointestinal stromal tumor Diseases 0.000 description 4
239000008103 glucose Substances 0.000 description 4
QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 4
238000000034 method Methods 0.000 description 4
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
230000000087 stabilizing effect Effects 0.000 description 4
150000003871 sulfonates Chemical class 0.000 description 4
150000003467 sulfuric acid derivatives Chemical class 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
108010083608 Durazym Proteins 0.000 description 3
239000005642 Oleic acid Substances 0.000 description 3
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
239000004280 Sodium formate Substances 0.000 description 3
108090000787 Subtilisin Proteins 0.000 description 3
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
150000008051 alkyl sulfates Chemical class 0.000 description 3
229940025131 amylases Drugs 0.000 description 3
239000003945 anionic surfactant Substances 0.000 description 3
229940077388 benzenesulfonate Drugs 0.000 description 3
229910052700 potassium Inorganic materials 0.000 description 3
239000011591 potassium Substances 0.000 description 3
235000019254 sodium formate Nutrition 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
244000060011 Cocos nucifera Species 0.000 description 2
235000013162 Cocos nucifera Nutrition 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
150000008064 anhydrides Chemical group 0.000 description 2
150000001768 cations Chemical class 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
239000003240 coconut oil Substances 0.000 description 2
235000019864 coconut oil Nutrition 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
150000004665 fatty acids Chemical class 0.000 description 2
125000001183 hydrocarbyl group Chemical group 0.000 description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
125000002768 hydroxyalkyl group Chemical group 0.000 description 2
238000011065 in-situ storage Methods 0.000 description 2
239000002736 nonionic surfactant Substances 0.000 description 2
SECPZKHBENQXJG-FPLPWBNLSA-N palmitoleic acid Chemical compound CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 description 2
235000018102 proteins Nutrition 0.000 description 2
102000004169 proteins and genes Human genes 0.000 description 2
108090000623 proteins and genes Proteins 0.000 description 2
230000017854 proteolysis Effects 0.000 description 2
239000002994 raw material Substances 0.000 description 2
125000003607 serino group Chemical group [H]N([H])[C@]([H])(C(=O)[*])C(O[H])([H])[H] 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
239000003760 tallow Substances 0.000 description 2
JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical class OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 2
OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
QDCPNGVVOWVKJG-UHFFFAOYSA-N 2-dodec-1-enylbutanedioic acid Chemical compound CCCCCCCCCCC=CC(C(O)=O)CC(O)=O QDCPNGVVOWVKJG-UHFFFAOYSA-N 0.000 description 1
YLAXZGYLWOGCBF-UHFFFAOYSA-N 2-dodecylbutanedioic acid Chemical compound CCCCCCCCCCCCC(C(O)=O)CC(O)=O YLAXZGYLWOGCBF-UHFFFAOYSA-N 0.000 description 1
GCVQVCAAUXFNGJ-UHFFFAOYSA-N 2-hexadecylbutanedioic acid Chemical compound CCCCCCCCCCCCCCCCC(C(O)=O)CC(O)=O GCVQVCAAUXFNGJ-UHFFFAOYSA-N 0.000 description 1
125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
PFBBCIYIKJWDIN-UHFFFAOYSA-N 2-tetradec-1-enylbutanedioic acid Chemical compound CCCCCCCCCCCCC=CC(C(O)=O)CC(O)=O PFBBCIYIKJWDIN-UHFFFAOYSA-N 0.000 description 1
MWTDCUHMQIAYDT-UHFFFAOYSA-N 2-tetradecylbutanedioic acid Chemical compound CCCCCCCCCCCCCCC(C(O)=O)CC(O)=O MWTDCUHMQIAYDT-UHFFFAOYSA-N 0.000 description 1
GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
108010059892 Cellulase Proteins 0.000 description 1
108010084185 Cellulases Proteins 0.000 description 1
102000005575 Cellulases Human genes 0.000 description 1
YASYEJJMZJALEJ-UHFFFAOYSA-N Citric acid monohydrate Chemical compound O.OC(=O)CC(O)(C(O)=O)CC(O)=O YASYEJJMZJALEJ-UHFFFAOYSA-N 0.000 description 1
RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
229930091371 Fructose Natural products 0.000 description 1
RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
239000005715 Fructose Substances 0.000 description 1
CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 1
HNDVDQJCIGZPNO-YFKPBYRVSA-N L-histidine Chemical compound OC(=O)[C@@H](N)CC1=CN=CN1 HNDVDQJCIGZPNO-YFKPBYRVSA-N 0.000 description 1
GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
235000019482 Palm oil Nutrition 0.000 description 1
235000021319 Palmitoleic acid Nutrition 0.000 description 1
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
101710194948 Protein phosphatase PhpP Proteins 0.000 description 1
239000004902 Softening Agent Substances 0.000 description 1
229910021536 Zeolite Inorganic materials 0.000 description 1
YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
125000003368 amide group Chemical group 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
230000000844 anti-bacterial effect Effects 0.000 description 1
235000003704 aspartic acid Nutrition 0.000 description 1
239000003899 bactericide agent Substances 0.000 description 1
WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 1
GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical class O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
CMFFZBGFNICZIS-UHFFFAOYSA-N butanedioic acid;2,3-dihydroxybutanedioic acid Chemical compound OC(=O)CCC(O)=O.OC(=O)CCC(O)=O.OC(=O)C(O)C(O)C(O)=O CMFFZBGFNICZIS-UHFFFAOYSA-N 0.000 description 1
BMWZKJJCLPAELA-UHFFFAOYSA-N butanedioic acid;ethanol Chemical compound CCO.OC(=O)CCC(O)=O BMWZKJJCLPAELA-UHFFFAOYSA-N 0.000 description 1
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
239000003093 cationic surfactant Substances 0.000 description 1
229940106157 cellulase Drugs 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
SECPZKHBENQXJG-UHFFFAOYSA-N cis-palmitoleic acid Natural products CCCCCCC=CCCCCCCCC(O)=O SECPZKHBENQXJG-UHFFFAOYSA-N 0.000 description 1
229960002303 citric acid monohydrate Drugs 0.000 description 1
238000003776 cleavage reaction Methods 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
210000003298 dental enamel Anatomy 0.000 description 1
239000003814 drug Substances 0.000 description 1
239000000975 dye Substances 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
230000002255 enzymatic effect Effects 0.000 description 1
238000007046 ethoxylation reaction Methods 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
230000002068 genetic effect Effects 0.000 description 1
HNDVDQJCIGZPNO-UHFFFAOYSA-N histidine Natural products OC(=O)C(N)CC1=CN=CN1 HNDVDQJCIGZPNO-UHFFFAOYSA-N 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
230000002209 hydrophobic effect Effects 0.000 description 1
239000008101 lactose Substances 0.000 description 1
239000000463 material Substances 0.000 description 1
150000002742 methionines Chemical class 0.000 description 1
108010020132 microbial serine proteinases Proteins 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
150000002889 oleic acids Chemical class 0.000 description 1
239000003605 opacifier Substances 0.000 description 1
239000003346 palm kernel oil Substances 0.000 description 1
235000019865 palm kernel oil Nutrition 0.000 description 1
239000002540 palm oil Substances 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
239000002304 perfume Substances 0.000 description 1
XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
235000019419 proteases Nutrition 0.000 description 1
150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
238000006268 reductive amination reaction Methods 0.000 description 1
230000002829 reductive effect Effects 0.000 description 1
230000007017 scission Effects 0.000 description 1
238000002741 site-directed mutagenesis Methods 0.000 description 1
239000002002 slurry Substances 0.000 description 1
HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 1
235000019832 sodium triphosphate Nutrition 0.000 description 1
HJHVQCXHVMGZNC-JCJNLNMISA-M sodium;(2z)-2-[(3r,4s,5s,8s,9s,10s,11r,13r,14s,16s)-16-acetyloxy-3,11-dihydroxy-4,8,10,14-tetramethyl-2,3,4,5,6,7,9,11,12,13,15,16-dodecahydro-1h-cyclopenta[a]phenanthren-17-ylidene]-6-methylhept-5-enoate Chemical compound [Na+].O[C@@H]([C@@H]12)C[C@H]3\C(=C(/CCC=C(C)C)C([O-])=O)[C@@H](OC(C)=O)C[C@]3(C)[C@@]2(C)CC[C@@H]2[C@]1(C)CC[C@@H](O)[C@H]2C HJHVQCXHVMGZNC-JCJNLNMISA-M 0.000 description 1
MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
239000002689 soil Substances 0.000 description 1
241000894007 species Species 0.000 description 1
239000007858 starting material Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
239000000758 substrate Substances 0.000 description 1
150000003443 succinic acid derivatives Chemical class 0.000 description 1
230000001180 sulfating effect Effects 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
239000010457 zeolite Substances 0.000 description 1
239000002888 zwitterionic surfactant Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38663—Stabilised liquid enzyme compositions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)
Apparatus Associated With Microorganisms And Enzymes (AREA)
Preparation Of Compounds By Using Micro-Organisms (AREA)

NZ24057191A 1990-11-14 1991-11-13 Liquid detergents containing an enzyme system of lipase and modified protease NZ240571A (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
EP90870212		1990-11-14
EP19910200149 EP0486073B1 (fr)	1990-11-14	1991-01-25	Composition détergente liquide contenant une lipase et une protéase

Publications (1)

Publication Number	Publication Date
NZ240571A true NZ240571A (en)	1994-11-25

Family

ID=26128002

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NZ24057191A NZ240571A (en)	1990-11-14	1991-11-13	Liquid detergents containing an enzyme system of lipase and modified protease

Country Status (14)

Country	Link
EP (1)	EP0486073B1 (fr)
JP (1)	JPH06504555A (fr)
CN (1)	CN1062374A (fr)
AU (1)	AU9041691A (fr)
CA (1)	CA2096256C (fr)
DE (1)	DE69121059T2 (fr)
DK (1)	DK0486073T3 (fr)
ES (1)	ES2091280T3 (fr)
IE (1)	IE913951A1 (fr)
MX (1)	MX9102022A (fr)
NZ (1)	NZ240571A (fr)
TR (1)	TR27423A (fr)
TW (1)	TW215108B (fr)
WO (1)	WO1992008779A1 (fr)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE69206795T2 (de) *	1991-04-30	1996-09-05	Procter & Gamble	ARYLBORONSäURE ENTHALTENDE FLüSSIGWASCHMITTEL
CZ91194A3 (en) *	1991-10-16	1994-12-15	Unilever Nv	Stable aqueous enzymatic detergent and process for preparing thereof
US5442100A (en) *	1992-08-14	1995-08-15	The Procter & Gamble Company	β-aminoalkyl and β-N-peptidylaminoalkyl boronic acids
JP2859520B2 (ja) *	1993-08-30	1999-02-17	ノボノルディスクアクティーゼルスカブ	リパーゼ及びそれを生産する微生物及びリパーゼ製造方法及びリパーゼ含有洗剤組成物
DE69434635D1 (en)	1993-10-08	2006-04-27	Novo Nordisk As	Amylasevarianten
DE4344154A1 (de) *	1993-12-23	1995-06-29	Henkel Kgaa	Enzymhaltiges Flüssigwaschmittel
US7491362B1 (en) *	2008-01-28	2009-02-17	Ecolab Inc.	Multiple enzyme cleaner for surgical instruments and endoscopes
US20120258507A1 (en) *	2009-12-21	2012-10-11	Danisco Us Inc.	Detergent compositions containing thermobifida fusca lipase and methods of use thereof
CN102444018B (zh) *	2011-10-26	2013-07-31	芜湖南翔羽绒有限公司	一种羽绒的生化联合精洗工艺
CN102604754B (zh) *	2012-02-03	2013-07-03	深圳市绿微康生物工程有限公司	生物酶清洗剂及其制备方法
DE102013224250A1 (de)	2013-11-27	2015-05-28	Henkel Ag & Co. Kgaa	Lipasestabilisierung in Geschirrspülmitteln
EP3313966B1 (fr) *	2015-06-26	2020-07-29	Unilever PLC	Composition de détergent pour lessive
BR112018003766A2 (pt) *	2015-08-28	2018-09-25	Unilever Nv	composição detergente líquida compreendendo enzima protease e não protease

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4760025A (en) *	1984-05-29	1988-07-26	Genencor, Inc.	Modified enzymes and methods for making same
US4980288A (en) *	1986-02-12	1990-12-25	Genex Corporation	Subtilisin with increased thermal stability
DE3750450T2 (de) *	1986-08-29	1995-01-05	Novo Industri As	Enzymhaltiger Reinigungsmittelzusatz.
DK571587D0 (da) *	1987-11-02	1987-11-02	Novo Industri As	Enzymatisk detergentsammensaetning
CN1056187C (zh) *	1988-02-11	2000-09-06	金克克国际有限公司	新的蛋白水解酶及其在洗涤剂中的应用
CA2006527A1 (fr) *	1988-12-30	1990-06-30	Martin S. Cardinali	Compositions detergentes liquides aux enzymes
US4959179A (en) *	1989-01-30	1990-09-25	Lever Brothers Company	Stabilized enzymes liquid detergent composition containing lipase and protease
US5030378A (en) *	1990-01-02	1991-07-09	The Procter & Gamble Company	Liquid detergents containing anionic surfactant, builder and proteolytic enzyme

1991
- 1991-01-25 EP EP19910200149 patent/EP0486073B1/fr not_active Expired - Lifetime
- 1991-01-25 DK DK91200149T patent/DK0486073T3/da active
- 1991-01-25 ES ES91200149T patent/ES2091280T3/es not_active Expired - Lifetime
- 1991-01-25 DE DE1991621059 patent/DE69121059T2/de not_active Expired - Lifetime
- 1991-11-04 JP JP4500878A patent/JPH06504555A/ja active Pending
- 1991-11-04 WO PCT/US1991/008041 patent/WO1992008779A1/fr not_active Ceased
- 1991-11-04 AU AU90416/91A patent/AU9041691A/en not_active Abandoned
- 1991-11-04 CA CA002096256A patent/CA2096256C/fr not_active Expired - Fee Related
- 1991-11-12 MX MX9102022A patent/MX9102022A/es not_active IP Right Cessation
- 1991-11-13 NZ NZ24057191A patent/NZ240571A/en unknown
- 1991-11-13 IE IE395191A patent/IE913951A1/en unknown
- 1991-11-14 CN CN 91111550 patent/CN1062374A/zh active Pending
- 1991-12-04 TR TR106991A patent/TR27423A/xx unknown
1992
- 1992-01-25 TW TW81100525A patent/TW215108B/zh active

Also Published As

Publication number	Publication date
ES2091280T3 (es)	1996-11-01
EP0486073A3 (en)	1993-06-23
AU9041691A (en)	1992-06-11
EP0486073B1 (fr)	1996-07-24
CA2096256C (fr)	1999-05-11
DK0486073T3 (da)	1996-12-09
TW215108B (fr)	1993-10-21
WO1992008779A1 (fr)	1992-05-29
EP0486073A2 (fr)	1992-05-20
CA2096256A1 (fr)	1992-05-15
MX9102022A (es)	1992-07-08
DE69121059D1 (de)	1996-08-29
CN1062374A (zh)	1992-07-01
DE69121059T2 (de)	1997-03-06
IE913951A1 (en)	1992-05-20
JPH06504555A (ja)	1994-05-26
TR27423A (tr)	1995-04-21

Publication	Publication Date	Title
US5916862A (en)	1999-06-29	Detergent compositions containing amines and anionic surfactants
US5039446A (en)	1991-08-13	Liquid detergent with stabilized enzyme
AU666660B2 (en)	1996-02-22	Built liquid detergents with boric-polyol complex to inhibit proteolytic enzyme
CA2124788C (fr)	1998-02-10	Detergents liquides pour lessive, renfermant de l'acide citrique et un complexe diol-borique pour inhiber l'enzyme proteolytique
PT100446A (pt)	1993-08-31	Detergentes liquidos possuindo um acido arilboronico para inibicao de enzima proteolitica
HUT78084A (hu)	1999-08-30	Lipolitikus enzimet és aminokat tartalmazó mosodai detergens készítmények
IE57605B1 (en)	1993-01-27	Stable liquid detergent compositions
CN1238005A (zh)	1999-12-08	含有蛋白酶和蛋白酶抑制剂的液体洗涤剂
EP0785981B1 (fr)	2002-04-10	Compositions detergentes pour lessive comprenant une enzyme lipolytique et des amines
NZ202423A (en)	1985-11-08	Enzymatic liquid cleaning composition containing alkali metal pentaborate
EP0348183A2 (fr)	1989-12-27	Produit détergents liquides contenant un enzyme
CA2096256C (fr)	1999-05-11	Detersif liquide contenant des lipases et des proteases
CA1302924C (fr)	1992-06-09	Detergents liquides renfermant un surfactif anionique, un adjuvant et une enzyme proteolytique
US5935271A (en)	1999-08-10	Laundry detergent compositions containing lipolytic enzyme and amines
US5733473A (en)	1998-03-31	Liquid detergent composition containing lipase and protease
JPH11512770A (ja)	1999-11-02	アミンとアルキルサルフェートと他の陰イオン界面活性剤とを含有する洗剤組成物
JPH11512761A (ja)	1999-11-02	選ばれた第四級アンモニウム化合物を含有する液体洗濯洗剤
CA2290373A1 (fr)	1998-11-19	Compositions de detergents a vaisselle delicats en liquide ou en gel, ayant un ph regule et des caracteristiques desirables de moussage et d'elimination des taches d'aliments
CZ136098A3 (cs)	1998-10-14	Detergentní prací prostředek s obsahem lipolytického enzymu a vybraných kvartérních amonných saponátů
JPH11512769A (ja)	1999-11-02	選ばれたアルキルアミドアルコイル第四級アンモニウム化合物を含有する液体洗濯洗剤
US6017874A (en)	2000-01-25	Liquid laundry detergents containing selected quaternary ammonium compounds
CA2364229C (fr)	2008-08-12	Composition detergente liquide pour laver la vaisselle renfermant des particules polymeres
EP0713525A4 (fr)	1996-06-05
KR100317948B1 (ko)	2001-12-22	알킬벤젠설폰산마그네슘염을 함유하는 알카리성 액체세제 조성물
JPH11508293A (ja)	1999-07-21	アミンおよびアニオン界面活性剤を含有する洗剤組成物