NZ280498A - Attrition resistant, controlled release fertiliser comprising particulate fertiliser containing at least one water-soluble nutrient surrounded by a plurality of coatings, one being an amine cured epoxy resin - Google Patents

Attrition resistant, controlled release fertiliser comprising particulate fertiliser containing at least one water-soluble nutrient surrounded by a plurality of coatings, one being an amine cured epoxy resin

Info

Publication number: NZ280498A
Authority: NZ; New Zealand
Prior art keywords: fertilizer; coating; epoxide; polymer; wax
Prior art date: 1994-11-21

Application number

NZ280498A

Other languages

English (en)

Inventor

Alice Peterson Hudson

Original Assignee

Lesco Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1994-11-21

Filing date

1995-11-20

Publication date

1998-01-26

1995-11-20 Application filed by Lesco Inc filed Critical Lesco Inc

1998-01-26 Publication of NZ280498A publication Critical patent/NZ280498A/en

Links

239000003337 fertilizer Substances 0.000 title claims abstract description 114
238000000576 coating method Methods 0.000 title claims abstract description 56
150000001412 amines Chemical class 0.000 title claims abstract description 19
229920000647 polyepoxide Polymers 0.000 title claims abstract description 17
239000003822 epoxy resin Substances 0.000 title claims abstract description 16
238000013270 controlled release Methods 0.000 title claims abstract description 9
235000015097 nutrients Nutrition 0.000 title claims description 13
150000002118 epoxides Chemical class 0.000 claims abstract description 32
239000011248 coating agent Substances 0.000 claims abstract description 29
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
239000007795 chemical reaction product Substances 0.000 claims abstract description 15
239000003795 chemical substances by application Substances 0.000 claims abstract description 12
239000002245 particle Substances 0.000 claims description 77
229920000642 polymer Polymers 0.000 claims description 72
239000004202 carbamide Substances 0.000 claims description 46
XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 46
239000000203 mixture Substances 0.000 claims description 45
239000004593 Epoxy Substances 0.000 claims description 36
239000004711 α-olefin Substances 0.000 claims description 21
125000004432 carbon atom Chemical group C* 0.000 claims description 11
239000000539 dimer Substances 0.000 claims description 9
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
239000002253 acid Substances 0.000 claims description 8
239000000463 material Substances 0.000 claims description 8
229920001169 thermoplastic Polymers 0.000 claims description 8
239000012530 fluid Substances 0.000 claims description 7
238000011065 in-situ storage Methods 0.000 claims description 7
229920000768 polyamine Polymers 0.000 claims description 7
239000002904 solvent Substances 0.000 claims description 7
GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical group C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 claims description 6
239000004816 latex Substances 0.000 claims description 5
229920000126 latex Polymers 0.000 claims description 5
229920001281 polyalkylene Polymers 0.000 claims description 5
LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 claims description 4
150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 4
229910052757 nitrogen Inorganic materials 0.000 claims description 4
229920001328 Polyvinylidene chloride Polymers 0.000 claims description 3
125000000217 alkyl group Chemical group 0.000 claims description 3
150000001875 compounds Chemical class 0.000 claims description 3
239000005033 polyvinylidene chloride Substances 0.000 claims description 3
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
239000011247 coating layer Substances 0.000 claims description 2
239000011574 phosphorus Substances 0.000 claims description 2
229910052698 phosphorus Inorganic materials 0.000 claims description 2
239000011591 potassium Substances 0.000 claims description 2
229910052700 potassium Inorganic materials 0.000 claims description 2
125000001931 aliphatic group Chemical group 0.000 claims 2
239000007787 solid Substances 0.000 claims 2
239000007921 spray Substances 0.000 claims 1
238000000034 method Methods 0.000 abstract description 28
239000000047 product Substances 0.000 abstract description 22
238000005299 abrasion Methods 0.000 abstract description 14
238000004519 manufacturing process Methods 0.000 abstract description 12
239000008199 coating composition Substances 0.000 abstract description 3
239000001993 wax Substances 0.000 description 51
239000008187 granular material Substances 0.000 description 26
239000002987 primer (paints) Substances 0.000 description 23
239000000565 sealant Substances 0.000 description 23
KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 17
229920002635 polyurethane Polymers 0.000 description 15
239000004814 polyurethane Substances 0.000 description 15
239000000126 substance Substances 0.000 description 14
238000007792 addition Methods 0.000 description 13
KYBYPDUGGWLXNO-GRVYQHKQSA-N ethane-1,2-diamine;(9z,12z)-octadeca-9,12-dienoic acid Chemical compound NCCN.CCCCC\C=C/C\C=C/CCCCCCCC(O)=O.CCCCC\C=C/C\C=C/CCCCCCCC(O)=O KYBYPDUGGWLXNO-GRVYQHKQSA-N 0.000 description 11
238000013019 agitation Methods 0.000 description 10
239000010410 layer Substances 0.000 description 10
239000000758 substrate Substances 0.000 description 9
229930195733 hydrocarbon Natural products 0.000 description 7
150000002430 hydrocarbons Chemical class 0.000 description 7
-1 polypropylene Polymers 0.000 description 7
238000006243 chemical reaction Methods 0.000 description 6
238000002156 mixing Methods 0.000 description 6
VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 5
REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 5
238000002844 melting Methods 0.000 description 5
230000008018 melting Effects 0.000 description 5
229960001124 trientine Drugs 0.000 description 5
230000000052 comparative effect Effects 0.000 description 4
229920001577 copolymer Polymers 0.000 description 4
229920005989 resin Polymers 0.000 description 4
239000011347 resin Substances 0.000 description 4
229920006395 saturated elastomer Polymers 0.000 description 4
RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 3
150000007513 acids Chemical class 0.000 description 3
150000001336 alkenes Chemical class 0.000 description 3
IMUDHTPIFIBORV-UHFFFAOYSA-N aminoethylpiperazine Chemical compound NCCN1CCNCC1 IMUDHTPIFIBORV-UHFFFAOYSA-N 0.000 description 3
238000001816 cooling Methods 0.000 description 3
150000004985 diamines Chemical class 0.000 description 3
235000013305 food Nutrition 0.000 description 3
LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 3
230000033001 locomotion Effects 0.000 description 3
238000003756 stirring Methods 0.000 description 3
238000003860 storage Methods 0.000 description 3
FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 3
RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 2
239000004215 Carbon black (E152) Substances 0.000 description 2
229920000089 Cyclic olefin copolymer Polymers 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical group NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
239000004698 Polyethylene Substances 0.000 description 2
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
239000002671 adjuvant Substances 0.000 description 2
125000002947 alkylene group Chemical group 0.000 description 2
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
229910052921 ammonium sulfate Inorganic materials 0.000 description 2
235000011130 ammonium sulphate Nutrition 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
239000004359 castor oil Substances 0.000 description 2
235000019438 castor oil Nutrition 0.000 description 2
239000003153 chemical reaction reagent Substances 0.000 description 2
230000003247 decreasing effect Effects 0.000 description 2
239000000975 dye Substances 0.000 description 2
239000005038 ethylene vinyl acetate Substances 0.000 description 2
238000001704 evaporation Methods 0.000 description 2
230000008020 evaporation Effects 0.000 description 2
ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
239000007788 liquid Substances 0.000 description 2
239000000178 monomer Substances 0.000 description 2
229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
229920000573 polyethylene Polymers 0.000 description 2
229920000098 polyolefin Polymers 0.000 description 2
229920001451 polypropylene glycol Polymers 0.000 description 2
239000004800 polyvinyl chloride Substances 0.000 description 2
229920000915 polyvinyl chloride Polymers 0.000 description 2
230000008569 process Effects 0.000 description 2
GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
239000002689 soil Substances 0.000 description 2
229910001220 stainless steel Inorganic materials 0.000 description 2
239000010935 stainless steel Substances 0.000 description 2
229920003048 styrene butadiene rubber Polymers 0.000 description 2
239000011593 sulfur Substances 0.000 description 2
229910052717 sulfur Inorganic materials 0.000 description 2
FJLUATLTXUNBOT-UHFFFAOYSA-N 1-Hexadecylamine Chemical compound CCCCCCCCCCCCCCCCN FJLUATLTXUNBOT-UHFFFAOYSA-N 0.000 description 1
MQCPOLNSJCWPGT-UHFFFAOYSA-N 2,2'-Bisphenol F Chemical compound OC1=CC=CC=C1CC1=CC=CC=C1O MQCPOLNSJCWPGT-UHFFFAOYSA-N 0.000 description 1
PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
229920003319 Araldite® Polymers 0.000 description 1
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
239000009261 D 400 Substances 0.000 description 1
BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
231100000674 Phytotoxicity Toxicity 0.000 description 1
239000002202 Polyethylene glycol Substances 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
239000002174 Styrene-butadiene Substances 0.000 description 1
PLZVEHJLHYMBBY-UHFFFAOYSA-N Tetradecylamine Chemical compound CCCCCCCCCCCCCCN PLZVEHJLHYMBBY-UHFFFAOYSA-N 0.000 description 1
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 1
239000007875 V-40 Substances 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 1
150000001252 acrylic acid derivatives Chemical class 0.000 description 1
239000000654 additive Substances 0.000 description 1
238000005054 agglomeration Methods 0.000 description 1
230000002776 aggregation Effects 0.000 description 1
230000004888 barrier function Effects 0.000 description 1
238000010923 batch production Methods 0.000 description 1
229910052796 boron Inorganic materials 0.000 description 1
150000001639 boron compounds Chemical class 0.000 description 1
MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 description 1
239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
239000007931 coated granule Substances 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
238000010276 construction Methods 0.000 description 1
238000010924 continuous production Methods 0.000 description 1
230000007547 defect Effects 0.000 description 1
125000005442 diisocyanate group Chemical group 0.000 description 1
238000006471 dimerization reaction Methods 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
239000000428 dust Substances 0.000 description 1
238000010410 dusting Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000013265 extended release Methods 0.000 description 1
239000006260 foam Substances 0.000 description 1
238000009472 formulation Methods 0.000 description 1
238000013038 hand mixing Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
239000004009 herbicide Substances 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
239000008172 hydrogenated vegetable oil Substances 0.000 description 1
125000002636 imidazolinyl group Chemical group 0.000 description 1
229910052738 indium Inorganic materials 0.000 description 1
239000002917 insecticide Substances 0.000 description 1
239000002198 insoluble material Substances 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
159000000014 iron salts Chemical class 0.000 description 1
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
239000012948 isocyanate Substances 0.000 description 1
150000002513 isocyanates Chemical class 0.000 description 1
238000002386 leaching Methods 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
239000002480 mineral oil Substances 0.000 description 1
235000010446 mineral oil Nutrition 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
239000012170 montan wax Substances 0.000 description 1
SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
239000000575 pesticide Substances 0.000 description 1
230000008635 plant growth Effects 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
229920001225 polyester resin Polymers 0.000 description 1
239000004645 polyester resin Substances 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
229920013716 polyethylene resin Polymers 0.000 description 1
239000004848 polyfunctional curative Substances 0.000 description 1
239000002861 polymer material Substances 0.000 description 1
239000002952 polymeric resin Substances 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
229920005862 polyol Polymers 0.000 description 1
150000003077 polyols Chemical class 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
239000001103 potassium chloride Substances 0.000 description 1
235000011164 potassium chloride Nutrition 0.000 description 1
230000001737 promoting effect Effects 0.000 description 1
230000009467 reduction Effects 0.000 description 1
239000004576 sand Substances 0.000 description 1
238000000935 solvent evaporation Methods 0.000 description 1
230000007480 spreading Effects 0.000 description 1
238000003892 spreading Methods 0.000 description 1
239000010959 steel Substances 0.000 description 1
239000011115 styrene butadiene Substances 0.000 description 1
229920003002 synthetic resin Polymers 0.000 description 1
239000003760 tallow Substances 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
AGGKEGLBGGJEBZ-UHFFFAOYSA-N tetramethylenedisulfotetramine Chemical compound C1N(S2(=O)=O)CN3S(=O)(=O)N1CN2C3 AGGKEGLBGGJEBZ-UHFFFAOYSA-N 0.000 description 1
239000011573 trace mineral Substances 0.000 description 1
235000013619 trace mineral Nutrition 0.000 description 1
150000003626 triacylglycerols Chemical class 0.000 description 1
239000013638 trimer Substances 0.000 description 1
150000004072 triols Chemical class 0.000 description 1
235000021122 unsaturated fatty acids Nutrition 0.000 description 1
150000004670 unsaturated fatty acids Chemical class 0.000 description 1
239000012178 vegetable wax Substances 0.000 description 1
238000009736 wetting Methods 0.000 description 1
239000011701 zinc Substances 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/36—Hydroxylated esters of higher fatty acids
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
- B01J2/006—Coating of the granules without description of the process or the device by which the granules are obtained
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/30—Layered or coated, e.g. dust-preventing coatings
- C05G5/37—Layered or coated, e.g. dust-preventing coatings layered or coated with a polymer
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/30—Layered or coated, e.g. dust-preventing coatings
- C05G5/38—Layered or coated, e.g. dust-preventing coatings layered or coated with wax or resins
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Health & Medical Sciences (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Life Sciences & Earth Sciences (AREA)
Pest Control & Pesticides (AREA)
Fertilizers (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)

NZ280498A 1994-11-21 1995-11-20 Attrition resistant, controlled release fertiliser comprising particulate fertiliser containing at least one water-soluble nutrient surrounded by a plurality of coatings, one being an amine cured epoxy resin NZ280498A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US08/342,808 US5698002A (en)	1994-11-21	1994-11-21	Controlled release fertilizers utilizing an epoxy polymer primer coat and methods of production

Publications (1)

Publication Number	Publication Date
NZ280498A true NZ280498A (en)	1998-01-26

Family

ID=23343358

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NZ280498A NZ280498A (en)	1994-11-21	1995-11-20	Attrition resistant, controlled release fertiliser comprising particulate fertiliser containing at least one water-soluble nutrient surrounded by a plurality of coatings, one being an amine cured epoxy resin

Country Status (11)

Country	Link
US (1)	US5698002A (da)
EP (1)	EP0716057B1 (da)
JP (1)	JP3288210B2 (da)
CN (1)	CN1130612A (da)
AT (1)	ATE165592T1 (da)
AU (1)	AU688151B2 (da)
CA (1)	CA2163275C (da)
DE (1)	DE69502257T2 (da)
DK (1)	DK0716057T3 (da)
ES (1)	ES2116686T3 (da)
NZ (1)	NZ280498A (da)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US7708799B2 (en)	2005-05-23	2010-05-04	Plant Protectants, Llc	Dithiocarbamates and phosphite formulations

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5997599A (en) *	1995-03-03	1999-12-07	Magic Green Corporation	Soil conditioning agglomerates containing cement kiln dust
US6413291B1 (en)	1995-03-03	2002-07-02	Magic Green Corporation	Soil conditioning agglomerates containing calcium
US6287356B1 (en)	1995-03-03	2001-09-11	Magic Green Corporation	Soil conditioning agglomerates containing calcium
JPH09202683A (ja) *	1996-01-23	1997-08-05	Sumitomo Chem Co Ltd	被覆肥料の製造方法
DE19603739A1 (de) *	1996-02-02	1997-08-07	Basf Ag	Granulatmischungen bestehend aus umhüllten und nicht-umhüllten Düngemittelgranulaten
NO305939B1 (no) *	1996-05-24	1999-08-23	Norsk Hydro As	Metode for fremstilling av kalsiumnitratbasert gjoedsel inneholdende svovel, samt slik gjoedsel
US5851261A (en) *	1996-12-30	1998-12-22	Bayer Corporation	Process for the production of polyurea encapsulated fertilizer particles and the encapsulated fertilizer particles produced by this process
NO981350L (no) *	1997-03-26	1998-09-28	Central Glass Co Ltd	Belagt granulær kunstgjödsel og fremgangsmåte for dens fremstilling
US20040016276A1 (en) *	2002-07-26	2004-01-29	Wynnyk Nick P.	Controlled release fertilizer having improved mechanical handling durability and method for production thereof
US8003748B2 (en)	2004-02-17	2011-08-23	Chevron Phillips Chemical Company, Lp	Polythiourethane compositions and processes for making and using same
NZ549073A (en) *	2004-02-17	2010-10-29	Agrium Inc	Thiol ester compositions and processes for making and using same
US7682656B2 (en) *	2004-06-14	2010-03-23	Agruim Inc.	Process and apparatus for producing a coated product
WO2006058422A1 (en) *	2004-11-30	2006-06-08	Agrium Inc.	Process and apparatus for coating a controlled release product in a rotating drum
AU2006279788A1 (en)	2005-08-16	2007-02-22	Chevron Phillips Chemical Company Lp	Polymer compositions and processes for making and using same
CA2619327A1 (en)	2005-08-16	2007-02-22	Chevron Phillips Chemical Company Lp	Mercaptan-hardened epoxy polymer compositions and processes for making and using same
US7862642B2 (en) *	2006-12-14	2011-01-04	Georgia-Pacific Chemicals Llc	Extended-release urea-based granular fertilizer
CA2783244A1 (en)	2009-12-07	2011-06-16	Momentum Technologies, Inc.	Nutrient yielding bio-renewable controlled release fertilizer coatings
SK288066B6 (sk)	2010-05-18	2013-04-03	Duslo, A. S.	Granulated fertilizer with controlled release of nutrients
WO2013173739A2 (en)	2012-05-18	2013-11-21	Basf Se	An encapsulated particle
BR112014028751B1 (pt)	2012-05-18	2020-12-22	Basf Se	partícula encapsulada, e, método para formar uma partícula encapsulada
RU2640885C2 (ru)	2012-11-16	2018-01-12	Басф Се	Инкапсулированная частица удобрения, содержащая пестицид
CN103524238B (zh) *	2013-10-21	2015-07-15	宁夏荣和绿色科技有限公司	一种有机聚合物包衣材料及用其包覆肥料的方法
EP3068527B8 (en)	2013-11-12	2020-11-18	Nous, Llc	System for coating granular materials
US20150376077A1 (en) *	2014-06-27	2015-12-31	Koch Biological Solutions, Llc	Polymer coated fertilizer compositions and methods of making thereof
EP3283494B1 (de) *	2015-04-17	2019-08-07	AlzChem Trostberg GmbH	Härter und härtungsbeschleuniger mit flammschutzwirkung zur härtung von epoxidharzen
US10189752B2 (en)	2016-07-21	2019-01-29	Surface Chemists Of Florida, Inc.	Moisture barrier coatings
US10336662B1 (en)	2016-09-26	2019-07-02	The United States Of America As Represented By The Secretary Of The Navy	Ammonium nitrate prill having a non-hygroscopic shell
US10919816B1 (en)	2020-06-09	2021-02-16	Surface Chemists Of Florida, Inc.	Epoxide moisture barrier coatings containing thermoplastic resins
US11193041B1 (en)	2020-06-09	2021-12-07	Surface Chemists Of Florida, Inc.	Polyurethane moisture barrier coatings containing thermoplastic resins
US11680026B2 (en) *	2020-09-03	2023-06-20	Shell Usa, Inc.	Fertilizer composite and method of reducing dust formation
MX2022002905A (es)	2022-03-09	2023-09-11	Enrique Munoz Morate	Formulacion y metodo para obtencion de acidos nutricionales para vegetales.

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3223518A (en) *	1961-08-18	1965-12-14	Archer Daniels Midland	Granular fertilizer having a plurality of coatings and the process of making
US3475154A (en) *	1964-11-30	1969-10-28	Dainippon Toryo Kk	Plural coated pellet form products and process of making
US3259482A (en)	1965-10-14	1966-07-05	Archer Daniels Midland Co	Slow release fertilizer with a plurality of epoxy/polyester resin coatings
DE1620178A1 (de) *	1965-12-03	1970-03-12	Ruhrchemie Ag	Verfahren zur Herstellung von Aminoalkylamino-s-triazinen
US3264088A (en) *	1965-12-08	1966-08-02	Archer Daniels Midland Co	Slow release fertilizer granule having a plurality of epoxy resin coatings
US3264089A (en)	1965-12-10	1966-08-02	Archer Daniels Midland Co	Slow release fertilizer granule having a plurality of urethane resin coatings
US3342577A (en)	1966-12-12	1967-09-19	Tennessee Valley Authority	Sulfur-coated fertilizer pellet having controlled dissolution rate and inhibited against microbial decomposition
BE756433A (fr) *	1969-09-22	1971-03-22	Ruhrchemie Ag	Engrais de bonne conservation ne donnant pas de poussiere et nes'agglomerant pas
JPS6045234B2 (ja) *	1977-02-14	1985-10-08	花王株式会社	水溶性賦形剤
JPS5466260A (en) *	1977-10-25	1979-05-28	Showa Denko Kk	Slowly acting solid fertilizer
JPS5966462A (ja) *	1982-10-07	1984-04-14	Mitsui Petrochem Ind Ltd	被覆用硬化型樹脂組成物
US4891223A (en) *	1987-09-03	1990-01-02	Air Products And Chemicals, Inc.	Controlled release delivery coating formulation for bioactive substances
US5264019A (en) *	1991-03-05	1993-11-23	Eastman Kodak Company	Coating compositions for slow release fertilizer formulations
JPH05295207A (ja) *	1992-04-23	1993-11-09	Achilles Corp	農業用塩化ビニル系樹脂フィルム
JPH05295206A (ja) *	1992-04-23	1993-11-09	Achilles Corp	農業用塩化ビニル系樹脂フィルム

1994
- 1994-11-21 US US08/342,808 patent/US5698002A/en not_active Expired - Lifetime
1995
- 1995-11-20 NZ NZ280498A patent/NZ280498A/en not_active IP Right Cessation
- 1995-11-20 CA CA002163275A patent/CA2163275C/en not_active Expired - Lifetime
- 1995-11-21 JP JP32652195A patent/JP3288210B2/ja not_active Expired - Lifetime
- 1995-11-21 ES ES95308324T patent/ES2116686T3/es not_active Expired - Lifetime
- 1995-11-21 AT AT95308324T patent/ATE165592T1/de active
- 1995-11-21 DK DK95308324T patent/DK0716057T3/da active
- 1995-11-21 AU AU37974/95A patent/AU688151B2/en not_active Expired
- 1995-11-21 DE DE69502257T patent/DE69502257T2/de not_active Expired - Lifetime
- 1995-11-21 CN CN95117522A patent/CN1130612A/zh active Pending
- 1995-11-21 EP EP95308324A patent/EP0716057B1/en not_active Expired - Lifetime

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US7708799B2 (en)	2005-05-23	2010-05-04	Plant Protectants, Llc	Dithiocarbamates and phosphite formulations

Also Published As

Publication number	Publication date
EP0716057A1 (en)	1996-06-12
AU688151B2 (en)	1998-03-05
CN1130612A (zh)	1996-09-11
EP0716057B1 (en)	1998-04-29
ES2116686T3 (es)	1998-07-16
CA2163275A1 (en)	1996-05-22
JPH08245288A (ja)	1996-09-24
ATE165592T1 (de)	1998-05-15
JP3288210B2 (ja)	2002-06-04
DE69502257D1 (de)	1998-06-04
DE69502257T2 (de)	1998-11-12
DK0716057T3 (da)	1998-10-07
CA2163275C (en)	1999-09-28
AU3797495A (en)	1996-05-30
US5698002A (en)	1997-12-16

Legal Events

Date	Code	Title	Description
2001-10-26	ASS	Change of ownership	Owner name: LESCO TECHNOLOGIES, US Free format text: OLD OWNER(S): LESCO, INC.
2002-11-22	RENW	Renewal (renewal fees accepted)
2005-12-23	RENW	Renewal (renewal fees accepted)
2008-11-28	RENW	Renewal (renewal fees accepted)
2013-12-20	ASS	Change of ownership	Owner name: LESCO, INC., US Effective date: 20131219
2014-01-31	ERR	Error or correction	Free format text: THE AGENT HAS BEEN CORRECTED TO 600102, BALDWINS INTELLECTUAL PROPERTY, LEVEL 15, VODAFONE ON THE QUAY, 157 LAMBTON QUAY, WELLINGTON 6011, NZ; THE CONTACT HAS BEEN CORRECTED TO 600102, BALDWINS INTELLECTUAL PROPERTY, LEVEL 15, VODAFONE ON THE QUAY, 157 LAMBTON QUAY, WELLINGTON 6011, NZ Effective date: 20131223
2015-11-27	EXPY	Patent expired

Publication	Publication Date	Title
EP0716057B1 (en)	1998-04-29	Controlled release fertilizers utilizing an epoxy polymer primer coat and methods of production
EP0282513B1 (en)	1991-11-21	Attrition-resistant, controlled release fertilizers
US4711659A (en)	1987-12-08	Attrition resistant controlled release fertilizers
CA1333338C (en)	1994-12-06	One-step method of coating nutrient particles
US5538531A (en)	1996-07-23	Controlled release fertilizers and methods of production
AU768523B2 (en)	2003-12-18	Improved polymer-sulfur-polymer coated fertilizers
JP3006774B2 (ja)	2000-02-07	改善された硫黄被覆尿素遅緩放出性肥料の製造方法
US20150376077A1 (en)	2015-12-31	Polymer coated fertilizer compositions and methods of making thereof
CA2258832C (en)	2003-01-28	Controlled release plant nutrients
US6231633B1 (en)	2001-05-15	Granular coated fertilizer and method for producing the same
US3264089A (en)	1966-08-02	Slow release fertilizer granule having a plurality of urethane resin coatings
US5851261A (en)	1998-12-22	Process for the production of polyurea encapsulated fertilizer particles and the encapsulated fertilizer particles produced by this process
WO2004011395A1 (en)	2004-02-05	Controlled release fertilizer having improved mechanical handling durability and method for production thereof
CA2149075C (en)	2002-05-07	Controlled release fertilizer and methods of production
JP2001328891A (ja)	2001-11-27	粒状被覆肥料の製造方法
MXPA00006838A (en)	2002-07-25	Polymer-sulfur-polymer coated fertilizers

NZ280498A - Attrition resistant, controlled release fertiliser comprising particulate fertiliser containing at least one water-soluble nutrient surrounded by a plurality of coatings, one being an amine cured epoxy resin - Google Patents

Info

Links

Classifications

Landscapes

Applications Claiming Priority (1)

Publications (1)

Family

ID=23343358

Family Applications (1)

Country Status (11)

Cited By (1)

Families Citing this family (31)

Family Cites Families (15)

Cited By (1)

Also Published As

Similar Documents

Legal Events