OA10396A - Agents zéolitiques de désulfuration et leur application au traitement des gaz contenant du co2 - Google Patents
Agents zéolitiques de désulfuration et leur application au traitement des gaz contenant du co2 Download PDFInfo
- Publication number
- OA10396A OA10396A OA60954A OA60954A OA10396A OA 10396 A OA10396 A OA 10396A OA 60954 A OA60954 A OA 60954A OA 60954 A OA60954 A OA 60954A OA 10396 A OA10396 A OA 10396A
- Authority
- OA
- OAPI
- Prior art keywords
- adsorbent according
- weight
- expressed
- pct
- mmol
- Prior art date
Links
- 239000007789 gas Substances 0.000 title claims abstract description 16
- 239000003463 adsorbent Substances 0.000 claims abstract description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052742 iron Inorganic materials 0.000 claims abstract description 5
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 4
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229960000892 attapulgite Drugs 0.000 claims abstract 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052901 montmorillonite Inorganic materials 0.000 claims abstract 2
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 16
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 8
- 239000004927 clay Substances 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 229910021529 ammonia Inorganic materials 0.000 claims description 4
- 239000013081 microcrystal Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000008187 granular material Substances 0.000 claims description 3
- 150000002500 ions Chemical class 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000003345 natural gas Substances 0.000 claims description 3
- 238000000746 purification Methods 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims 1
- JYIMWRSJCRRYNK-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4] JYIMWRSJCRRYNK-UHFFFAOYSA-N 0.000 claims 1
- -1 labentonite Inorganic materials 0.000 claims 1
- JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 abstract description 22
- 239000013078 crystal Substances 0.000 abstract description 15
- 229910021536 Zeolite Inorganic materials 0.000 abstract description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract description 3
- 239000010457 zeolite Substances 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 2
- 239000000440 bentonite Substances 0.000 abstract 1
- 229910000278 bentonite Inorganic materials 0.000 abstract 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 abstract 1
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 description 13
- 238000005755 formation reaction Methods 0.000 description 10
- 238000001179 sorption measurement Methods 0.000 description 10
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 8
- 239000011148 porous material Substances 0.000 description 5
- 244000052616 bacterial pathogen Species 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 4
- 239000002156 adsorbate Substances 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 230000005070 ripening Effects 0.000 description 3
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000274 adsorptive effect Effects 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000010411 cooking Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 235000013379 molasses Nutrition 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- RBTBFTRPCNLSDE-UHFFFAOYSA-N 3,7-bis(dimethylamino)phenothiazin-5-ium Chemical compound C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 RBTBFTRPCNLSDE-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 241000545760 Unio Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 229960000907 methylthioninium chloride Drugs 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
- B01J20/183—Physical conditioning without chemical treatment, e.g. drying, granulating, coating, irradiation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S95/00—Gas separation: processes
- Y10S95/90—Solid sorbent
- Y10S95/902—Molecular sieve
Landscapes
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Treating Waste Gases (AREA)
- Separation Of Gases By Adsorption (AREA)
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/FR1994/000932 WO1996003199A1 (fr) | 1994-07-26 | 1994-07-26 | Agents zeolitiques de desulfuration et leur application au traitement des gaz contenant du co¿2? |
| US08/290,957 US5609842A (en) | 1994-07-26 | 1994-07-26 | Zeolitic desulfuring agents and their application in the processing of gasses containing notable CO2 proportions |
| AU73472/94A AU7347294A (en) | 1994-07-26 | 1994-07-26 | Zeolitic desulfurazation agents and their application to co2-containing gas treatment |
| DE69428375T DE69428375D1 (de) | 1994-07-26 | 1994-07-26 | Zeolitische entschwefelungsmittel und ihre verwendung zur behandlung von c02 enthaltenden gasen |
| JP8505505A JPH10505536A (ja) | 1994-07-26 | 1994-07-26 | ゼオライト系脱硫剤とco▲下2▼含有ガス処理へのその利用 |
| EP94922304A EP0783362B1 (de) | 1994-07-26 | 1994-07-26 | Zeolitische entschwefelungsmittel und ihre verwendung zur behandlung von c02 enthaltenden gasen |
| AT94922304T ATE205742T1 (de) | 1994-07-26 | 1994-07-26 | Zeolitische entschwefelungsmittel und ihre verwendung zur behandlung von c02 enthaltenden gasen |
| RU97102730A RU2127631C1 (ru) | 1994-07-26 | 1994-07-26 | Цеолитовый адсорбент для обессеривания газов и его применение для обработки газов, содержащих co2 |
| CA002195683A CA2195683C (fr) | 1994-07-26 | 1994-07-26 | Agents zeolitiques de desulfuration et leur application au traitement des gaz contenant du co2 |
| SG1995000944A SG28472A1 (en) | 1994-07-26 | 1995-07-25 | Zeolitic desulfuring agents and their application in the processing of gases containing notable CO2 proportions |
| OA60954A OA10396A (fr) | 1994-07-26 | 1997-01-24 | Agents zéolitiques de désulfuration et leur application au traitement des gaz contenant du co2 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/FR1994/000932 WO1996003199A1 (fr) | 1994-07-26 | 1994-07-26 | Agents zeolitiques de desulfuration et leur application au traitement des gaz contenant du co¿2? |
| OA60954A OA10396A (fr) | 1994-07-26 | 1997-01-24 | Agents zéolitiques de désulfuration et leur application au traitement des gaz contenant du co2 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| OA10396A true OA10396A (fr) | 2001-12-04 |
Family
ID=33436244
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| OA60954A OA10396A (fr) | 1994-07-26 | 1997-01-24 | Agents zéolitiques de désulfuration et leur application au traitement des gaz contenant du co2 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US5609842A (de) |
| EP (1) | EP0783362B1 (de) |
| JP (1) | JPH10505536A (de) |
| AT (1) | ATE205742T1 (de) |
| AU (1) | AU7347294A (de) |
| CA (1) | CA2195683C (de) |
| DE (1) | DE69428375D1 (de) |
| OA (1) | OA10396A (de) |
| RU (1) | RU2127631C1 (de) |
| WO (1) | WO1996003199A1 (de) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5858068A (en) * | 1997-10-09 | 1999-01-12 | Uop Llc | Purification of carbon dioxide |
| US6579347B1 (en) * | 1998-04-28 | 2003-06-17 | Matsushita Electric Industrial Co., Ltd. | Method for removing sulfur compound present in city gas |
| US6511528B1 (en) | 1999-03-26 | 2003-01-28 | Uop Llc | Purification of carbon dioxide |
| US6143057A (en) * | 1999-04-23 | 2000-11-07 | The Boc Group, Inc. | Adsorbents and adsorptive separation process |
| FR2850963B1 (fr) * | 2003-02-11 | 2005-03-25 | Ceca Sa | Adsorbants agglomeres, leur procede de preparation et leur utilisation pour le sechage de composes organiques |
| US6908497B1 (en) * | 2003-04-23 | 2005-06-21 | The United States Of America As Represented By The Department Of Energy | Solid sorbents for removal of carbon dioxide from gas streams at low temperatures |
| CA2527443C (en) * | 2003-06-06 | 2011-03-15 | Peter Hawes | Method for sulfur compounds removal from contaminated gas and liquid streams |
| JP4529647B2 (ja) * | 2004-11-09 | 2010-08-25 | セイコーエプソン株式会社 | プラズマ処理装置 |
| JP4792013B2 (ja) * | 2007-07-19 | 2011-10-12 | 大陽日酸株式会社 | 硫化水素除去方法およびガス精製装置 |
| JP5424543B2 (ja) * | 2007-07-19 | 2014-02-26 | 大陽日酸株式会社 | バイオガス生成システム |
| RU2565697C1 (ru) * | 2014-03-26 | 2015-10-20 | Закрытое акционерное общество "Молекулярные технологии и новые материалы" | Цеолитный адсорбент |
| FR3040636B1 (fr) * | 2015-09-08 | 2019-11-01 | Arkema France | Utilisation de tamis moleculaires pour la decarbonatation de gaz naturel |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU1013403A1 (ru) * | 1981-05-28 | 1983-04-23 | Предприятие П/Я А-3843 | Адсорбент дл выделени @ -парофинов из углеводородов |
| DD294874A5 (de) * | 1986-07-17 | 1991-10-17 | Chemie Ag Bitterfeld-Wolfen,De | Verwendung eines zeolithischen adsorptionsmittels mit hoher co tief 2 - adsorptionskapazitaet |
| FR2618085A1 (fr) * | 1987-07-17 | 1989-01-20 | Rhone Poulenc Chimie | Adsorbant pour la purification des gaz et procede de purification |
| SU1648547A1 (ru) * | 1989-05-24 | 1991-05-15 | Грозненский Филиал Всесоюзного Научно-Исследовательского И Проектно-Конструкторского Института Биологической Техники | Адсорбент дл очистки фурфурола |
| FR2675712B1 (fr) * | 1991-04-29 | 1994-08-26 | Ceca Sa | Perfectionnement aux procedes d'epuration des gaz par adsorption sur adsorbants zeolitiques. |
| FR2678525B3 (fr) * | 1992-07-06 | 1994-10-07 | Bitterfeld Wolfen Chemie | Agent d'adsorption a base de tamis moleculaire pour la purification du gaz naturel, des composes sulfures. |
-
1994
- 1994-07-26 AT AT94922304T patent/ATE205742T1/de not_active IP Right Cessation
- 1994-07-26 EP EP94922304A patent/EP0783362B1/de not_active Expired - Lifetime
- 1994-07-26 US US08/290,957 patent/US5609842A/en not_active Expired - Lifetime
- 1994-07-26 CA CA002195683A patent/CA2195683C/fr not_active Expired - Fee Related
- 1994-07-26 AU AU73472/94A patent/AU7347294A/en not_active Abandoned
- 1994-07-26 DE DE69428375T patent/DE69428375D1/de not_active Expired - Lifetime
- 1994-07-26 RU RU97102730A patent/RU2127631C1/ru not_active IP Right Cessation
- 1994-07-26 JP JP8505505A patent/JPH10505536A/ja active Pending
- 1994-07-26 WO PCT/FR1994/000932 patent/WO1996003199A1/fr not_active Ceased
-
1997
- 1997-01-24 OA OA60954A patent/OA10396A/fr unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CA2195683A1 (fr) | 1996-02-08 |
| JPH10505536A (ja) | 1998-06-02 |
| RU2127631C1 (ru) | 1999-03-20 |
| DE69428375D1 (de) | 2001-10-25 |
| WO1996003199A1 (fr) | 1996-02-08 |
| CA2195683C (fr) | 2000-12-12 |
| AU7347294A (en) | 1996-02-22 |
| ATE205742T1 (de) | 2001-10-15 |
| EP0783362A1 (de) | 1997-07-16 |
| EP0783362B1 (de) | 2001-09-19 |
| US5609842A (en) | 1997-03-11 |
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