OA10672A - Improved method for the thermo-chemical dewaxing of large dimension lines - Google Patents
Improved method for the thermo-chemical dewaxing of large dimension lines Download PDFInfo
- Publication number
- OA10672A OA10672A OA9800030A OA9800030A OA10672A OA 10672 A OA10672 A OA 10672A OA 9800030 A OA9800030 A OA 9800030A OA 9800030 A OA9800030 A OA 9800030A OA 10672 A OA10672 A OA 10672A
- Authority
- OA
- OAPI
- Prior art keywords
- nitrogen
- improved method
- reaction
- aliphatic
- copolyanhydride
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 44
- 239000000126 substance Substances 0.000 title claims abstract description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 95
- 238000006243 chemical reaction Methods 0.000 claims abstract description 63
- 239000012190 activator Substances 0.000 claims abstract description 60
- 239000003495 polar organic solvent Substances 0.000 claims abstract description 41
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 30
- 230000009471 action Effects 0.000 claims abstract description 23
- 230000003111 delayed effect Effects 0.000 claims abstract description 23
- 150000002829 nitrogen Chemical class 0.000 claims abstract description 20
- 239000012188 paraffin wax Substances 0.000 claims abstract description 17
- 239000008346 aqueous phase Substances 0.000 claims abstract description 10
- 230000005540 biological transmission Effects 0.000 claims abstract description 9
- 239000012074 organic phase Substances 0.000 claims abstract description 9
- 230000001590 oxidative effect Effects 0.000 claims abstract description 9
- 239000000839 emulsion Substances 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910001873 dinitrogen Inorganic materials 0.000 claims abstract description 5
- 230000001939 inductive effect Effects 0.000 claims abstract description 3
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 claims description 48
- 229910052757 nitrogen Inorganic materials 0.000 claims description 45
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 40
- 239000000243 solution Substances 0.000 claims description 36
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 33
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical group ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 30
- 230000007062 hydrolysis Effects 0.000 claims description 24
- 238000006460 hydrolysis reaction Methods 0.000 claims description 24
- 238000007334 copolymerization reaction Methods 0.000 claims description 11
- 229920000642 polymer Polymers 0.000 claims description 11
- 239000002904 solvent Substances 0.000 claims description 11
- 239000007864 aqueous solution Substances 0.000 claims description 9
- 230000000694 effects Effects 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 6
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 4
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 claims description 4
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 claims description 4
- 239000007795 chemical reaction product Substances 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 238000010992 reflux Methods 0.000 claims description 2
- SGPGESCZOCHFCL-UHFFFAOYSA-N Tilisolol hydrochloride Chemical compound [Cl-].C1=CC=C2C(=O)N(C)C=C(OCC(O)C[NH2+]C(C)(C)C)C2=C1 SGPGESCZOCHFCL-UHFFFAOYSA-N 0.000 claims 3
- GYSCBCSGKXNZRH-UHFFFAOYSA-N 1-benzothiophene-2-carboxamide Chemical compound C1=CC=C2SC(C(=O)N)=CC2=C1 GYSCBCSGKXNZRH-UHFFFAOYSA-N 0.000 claims 1
- GHVNFZFCNZKVNT-UHFFFAOYSA-N Decanoic acid Natural products CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 claims 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract description 11
- 229930195733 hydrocarbon Natural products 0.000 abstract description 10
- 150000002430 hydrocarbons Chemical class 0.000 abstract description 10
- 239000007788 liquid Substances 0.000 abstract description 3
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 24
- 239000012530 fluid Substances 0.000 description 22
- 239000003960 organic solvent Substances 0.000 description 19
- 229940116353 sebacic acid Drugs 0.000 description 19
- 239000000203 mixture Substances 0.000 description 18
- 239000000047 product Substances 0.000 description 15
- 230000008569 process Effects 0.000 description 14
- 238000005086 pumping Methods 0.000 description 14
- 238000004519 manufacturing process Methods 0.000 description 13
- 239000001361 adipic acid Substances 0.000 description 12
- 235000011037 adipic acid Nutrition 0.000 description 12
- 229920002732 Polyanhydride Polymers 0.000 description 10
- 150000008064 anhydrides Chemical class 0.000 description 10
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 10
- 239000000725 suspension Substances 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 230000004913 activation Effects 0.000 description 7
- 229920001577 copolymer Polymers 0.000 description 7
- 150000002500 ions Chemical class 0.000 description 7
- 239000003350 kerosene Substances 0.000 description 7
- 238000002844 melting Methods 0.000 description 7
- 230000008018 melting Effects 0.000 description 7
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 6
- 229920001730 Moisture cure polyurethane Polymers 0.000 description 6
- -1 aliphatic anhydrides Chemical class 0.000 description 6
- 230000001965 increasing effect Effects 0.000 description 6
- 235000010288 sodium nitrite Nutrition 0.000 description 5
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- 230000035484 reaction time Effects 0.000 description 4
- 235000019270 ammonium chloride Nutrition 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 230000007928 solubilization Effects 0.000 description 3
- 238000005063 solubilization Methods 0.000 description 3
- 238000011144 upstream manufacturing Methods 0.000 description 3
- 238000013019 agitation Methods 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 238000005243 fluidization Methods 0.000 description 2
- 230000014509 gene expression Effects 0.000 description 2
- 231100001261 hazardous Toxicity 0.000 description 2
- 230000003301 hydrolyzing effect Effects 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 2
- 238000011020 pilot scale process Methods 0.000 description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- MGGVALXERJRIRO-UHFFFAOYSA-N 4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-2-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-1H-pyrazol-5-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C=1C(=NN(C=1)CC(=O)N1CC2=C(CC1)NN=N2)O MGGVALXERJRIRO-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229910017917 NH4 Cl Inorganic materials 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 238000010420 art technique Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000013270 controlled release Methods 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 150000002826 nitrites Chemical class 0.000 description 1
- 239000012875 nonionic emulsifier Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000035899 viability Effects 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000004018 waxing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B9/00—Cleaning hollow articles by methods or apparatus specially adapted thereto
- B08B9/02—Cleaning pipes or tubes or systems of pipes or tubes
- B08B9/027—Cleaning the internal surfaces; Removal of blockages
- B08B9/032—Cleaning the internal surfaces; Removal of blockages by the mechanical action of a moving fluid, e.g. by flushing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B9/00—Cleaning hollow articles by methods or apparatus specially adapted thereto
- B08B9/02—Cleaning pipes or tubes or systems of pipes or tubes
- B08B9/027—Cleaning the internal surfaces; Removal of blockages
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/52—Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning
- C09K8/524—Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning organic depositions, e.g. paraffins or asphaltenes
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Organic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polyamides (AREA)
- Polyesters Or Polycarbonates (AREA)
- Fats And Perfumes (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BR9701336A BR9701336A (pt) | 1997-03-19 | 1997-03-19 | Ativadores de ação retardada para sistema gerador de nitrogênio |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| OA10672A true OA10672A (en) | 2002-10-18 |
Family
ID=38326163
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| OA9800030A OA10672A (en) | 1997-03-19 | 1998-03-13 | Improved method for the thermo-chemical dewaxing of large dimension lines |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6003528A (no) |
| EP (1) | EP0865834B1 (no) |
| CN (1) | CN1128862C (no) |
| AR (1) | AR010132A1 (no) |
| BR (1) | BR9701336A (no) |
| CA (1) | CA2227935C (no) |
| ES (1) | ES2256915T3 (no) |
| NO (1) | NO317560B1 (no) |
| OA (1) | OA10672A (no) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7815744B2 (en) * | 2004-11-30 | 2010-10-19 | Halliburton Energy Services, Inc. | Methods for moving a pig through a pipeline using a chemical reaction to generate a high volume of gas |
| US20080069961A1 (en) * | 2006-09-14 | 2008-03-20 | Halliburton Energy Services, Inc. | Methods and compositions for thermally treating a conduit used for hydrocarbon production or transmission to help remove paraffin wax buildup |
| MY165424A (en) * | 2009-07-27 | 2018-03-22 | Petroliam Nasional Berhad Petronas | A method and system for removing organic deposits |
| US8691731B2 (en) * | 2009-11-18 | 2014-04-08 | Baker Hughes Incorporated | Heat generation process for treating oilfield deposits |
| CA2877132A1 (en) | 2012-06-25 | 2014-01-03 | Signa Chemistry, Inc. | Use of metal silicides in hydrocarbon production and transportation |
| GB2505244A (en) * | 2012-08-24 | 2014-02-26 | Green Channel Ltd | Cleaning a waste water vessel using an exothermic reaction |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3669189A (en) * | 1970-10-28 | 1972-06-13 | Union Oil Co | Method for inhibiting the deposition of wax from a wax-containing oil |
| US4755230A (en) * | 1985-01-15 | 1988-07-05 | Baker Oil Tools, Inc. | Method of and composition for removing paraffin deposits from hydrocarbon transmission conduits |
| BR9004200A (pt) * | 1990-08-24 | 1992-03-03 | Petroleo Brasileiro Sa | Processo de desparafinacao de formacoes produtoras |
| BR9301171A (pt) * | 1993-03-15 | 1994-10-18 | Petroleo Brasileiro Sa | Processo termo-químico de desparafinação de dutos condutores de hidrocarbonetos |
-
1997
- 1997-03-19 BR BR9701336A patent/BR9701336A/pt not_active IP Right Cessation
- 1997-12-19 US US08/994,431 patent/US6003528A/en not_active Expired - Lifetime
-
1998
- 1998-01-20 NO NO19980246A patent/NO317560B1/no not_active IP Right Cessation
- 1998-01-22 ES ES98300454T patent/ES2256915T3/es not_active Expired - Lifetime
- 1998-01-22 EP EP98300454A patent/EP0865834B1/en not_active Expired - Lifetime
- 1998-01-27 CA CA002227935A patent/CA2227935C/en not_active Expired - Lifetime
- 1998-02-18 CN CN98104461A patent/CN1128862C/zh not_active Expired - Lifetime
- 1998-03-13 OA OA9800030A patent/OA10672A/en unknown
- 1998-03-19 AR ARP980101247A patent/AR010132A1/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| EP0865834A1 (en) | 1998-09-23 |
| CA2227935C (en) | 2007-07-31 |
| NO980246D0 (no) | 1998-01-20 |
| CN1193656A (zh) | 1998-09-23 |
| BR9701336A (pt) | 1998-11-17 |
| NO317560B1 (no) | 2004-11-15 |
| CA2227935A1 (en) | 1998-09-19 |
| ES2256915T3 (es) | 2006-07-16 |
| NO980246L (no) | 1998-09-21 |
| US6003528A (en) | 1999-12-21 |
| CN1128862C (zh) | 2003-11-26 |
| AR010132A1 (es) | 2000-05-17 |
| EP0865834B1 (en) | 2006-01-04 |
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