OA11237A - Homogeneous oxidation catalysis using metal complexes - Google Patents

Homogeneous oxidation catalysis using metal complexes Download PDF

Info

Publication number: OA11237A
Authority: OA; OAPI
Prior art keywords: oxidizable; sites; site; catalyst; cation
Prior art date: 1997-06-20

Application number

OA9900283A

Other languages

English (en)

Inventor

Terrence J Collins

Scott W Gordon-Wylie

Colin P Horwitz

Erich S Uffelman

Christine G Woomer

Original Assignee

Univ Carnegie Mellon

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1997-06-20

Filing date

1999-12-15

Publication date

2003-05-27

1999-12-15 Application filed by Univ Carnegie Mellon filed Critical Univ Carnegie Mellon

2003-05-27 Publication of OA11237A publication Critical patent/OA11237A/en

Links

238000007254 oxidation reaction Methods 0.000 title claims description 60
230000003647 oxidation Effects 0.000 title claims description 57
229910052751 metal Inorganic materials 0.000 title description 6
239000002184 metal Substances 0.000 title description 6
238000006555 catalytic reaction Methods 0.000 title description 2
239000003054 catalyst Substances 0.000 claims abstract description 69
238000000034 method Methods 0.000 claims abstract description 59
150000001875 compounds Chemical class 0.000 claims abstract description 51
-1 such as a proton Substances 0.000 claims abstract description 33
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229910052760 oxygen Inorganic materials 0.000 claims abstract description 19
125000004430 oxygen atom Chemical group O* 0.000 claims abstract description 19
239000002841 Lewis acid Substances 0.000 claims abstract description 16
150000007517 lewis acids Chemical class 0.000 claims abstract description 16
125000001424 substituent group Chemical group 0.000 claims abstract description 15
230000001590 oxidative effect Effects 0.000 claims abstract description 13
239000001301 oxygen Substances 0.000 claims abstract description 11
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 10
239000003513 alkali Substances 0.000 claims abstract description 6
229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 4
150000002910 rare earth metals Chemical class 0.000 claims abstract description 4
239000011968 lewis acid catalyst Substances 0.000 claims abstract 3
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Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
- B01J31/182—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine comprising aliphatic or saturated rings
- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B53/00—Asymmetric syntheses
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
- B01J2531/0258—Flexible ligands, e.g. mainly sp3-carbon framework as exemplified by the "tedicyp" ligand, i.e. cis-cis-cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
- B01J2531/38—Lanthanides other than lanthanum
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
- B01J2531/39—Actinides
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
- B01J2531/72—Manganese
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/842—Iron

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Organic Chemistry (AREA)
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Inorganic Chemistry (AREA)
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Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

OA9900283A 1997-06-20 1999-12-15 Homogeneous oxidation catalysis using metal complexes OA11237A (en)

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US87975297A	1997-06-20	1997-06-20

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EP (1)	EP0991468A1 (no)
JP (1)	JP2002505688A (no)
KR (1)	KR20010013986A (no)
CN (1)	CN1267238A (no)
AP (1)	AP9901723A0 (no)
AU (1)	AU8152998A (no)
BR (1)	BR9810754A (no)
CA (1)	CA2295006A1 (no)
IL (1)	IL133484A0 (no)
NO (1)	NO996282L (no)
OA (1)	OA11237A (no)
PL (1)	PL337523A1 (no)
WO (1)	WO1998058735A1 (no)

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US6797196B2 (en)	2001-01-10	2004-09-28	Kao Corporation	Bleaching formulation
JP4104966B2 (ja) *	2002-03-06	2008-06-18	花王株式会社	漂白触媒
KR100561058B1 (ko) *	2004-09-23	2006-03-17	삼성토탈 주식회사	페녹시계 리간드가 포함된 올레핀 중합용 촉매 및 이를사용한 올레핀 (공)중합방법
JP5002761B2 (ja) *	2007-03-09	2012-08-15	国立大学法人大阪大学	オキソポルフィリン系電極触媒材料
CN104785296B (zh) *	2015-04-17	2017-03-08	中国石油大学(华东)	一种用于液化石油气脱硫醇的液体钴磺化酞菁催化剂
CN106082419B (zh) *	2016-05-10	2019-05-31	北京服装学院	大环酰胺金属配合物降解含有机污染物废水的方法及应用
CN106111199B (zh) *	2016-06-21	2018-10-12	中南民族大学	多含硫氮杂卟啉阵列纳米晶的制备与应用
CN112675908A (zh) *	2020-12-23	2021-04-20	清华大学	一种醇类的有氧氧化方法
CN119977974A (zh) *	2024-12-23	2025-05-13	河北工业大学	一种苯并咪唑改性酞菁镍催化剂及其制备方法和应用

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US4758682A (en) *	1983-03-17	1988-07-19	California Institute Of Technology	Homogeneous coordination compounds as oxidation catalysts
US5665890A (en) *	1995-03-14	1997-09-09	President And Fellows Of Harvard College	Stereoselective ring opening reactions
US5847120A (en) *	1996-07-22	1998-12-08	Carnegie Mellon University	Long-lived homogenous oxidation catalysts

1998
- 1998-06-18 PL PL98337523A patent/PL337523A1/xx unknown
- 1998-06-18 CN CN98808220A patent/CN1267238A/zh active Pending
- 1998-06-18 AU AU81529/98A patent/AU8152998A/en not_active Abandoned
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1999
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BR9810754A (pt)	2000-08-15
NO996282D0 (no)	1999-12-17
AP9901723A0 (en)	1999-12-31
KR20010013986A (ko)	2001-02-26
AU8152998A (en)	1999-01-04
NO996282L (no)	2000-02-21
WO1998058735A1 (en)	1998-12-30
JP2002505688A (ja)	2002-02-19
PL337523A1 (en)	2000-08-28
CA2295006A1 (en)	1998-12-30
IL133484A0 (en)	2001-04-30
CN1267238A (zh)	2000-09-20
EP0991468A1 (en)	2000-04-12

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Papanikolaou et al.	2022	A combined experimental and theoretical investigation of oxidation catalysis by cis-[VIV (O)(Cl/F)(N4)]+ species mimicking the active center of metal-enzymes
A. Brito et al.	2011	cis-Dioxomolybdenum (VI) complexes containing chiral ligands: Synthesis and catalytic application in olefin epoxidation