PL103600B1 - STAINING AGENT FOR COLORING PRODUCTS MIXED WITH POLYESTER FLEANS AND Wool - Google Patents
STAINING AGENT FOR COLORING PRODUCTS MIXED WITH POLYESTER FLEANS AND Wool Download PDFInfo
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- PL103600B1 PL103600B1 PL19227776A PL19227776A PL103600B1 PL 103600 B1 PL103600 B1 PL 103600B1 PL 19227776 A PL19227776 A PL 19227776A PL 19227776 A PL19227776 A PL 19227776A PL 103600 B1 PL103600 B1 PL 103600B1
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- Poland
- Prior art keywords
- group
- dye
- formula
- atom
- polyester
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- 229920000728 polyester Polymers 0.000 title claims description 14
- 238000004040 coloring Methods 0.000 title description 6
- 238000010186 staining Methods 0.000 title description 6
- 239000000975 dye Substances 0.000 claims description 37
- 239000000835 fiber Substances 0.000 claims description 22
- 238000004043 dyeing Methods 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- 210000002268 wool Anatomy 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- -1 hydroxyethyl group Chemical group 0.000 claims description 9
- 229910052801 chlorine Chemical group 0.000 claims description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 8
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 8
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000000460 chlorine Chemical group 0.000 claims description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 4
- 125000004422 alkyl sulphonamide group Chemical group 0.000 claims description 4
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 125000000565 sulfonamide group Chemical group 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 125000001424 substituent group Chemical group 0.000 claims description 3
- 125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 claims description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical group [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical class C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 claims description 2
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical group [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 229940124530 sulfonamide Drugs 0.000 claims description 2
- 150000003456 sulfonamides Chemical group 0.000 claims description 2
- HHVIBTZHLRERCL-UHFFFAOYSA-N sulfonyldimethane Chemical group CS(C)(=O)=O HHVIBTZHLRERCL-UHFFFAOYSA-N 0.000 claims description 2
- 229910052721 tungsten Inorganic materials 0.000 claims description 2
- 238000009736 wetting Methods 0.000 claims description 2
- 229910052727 yttrium Inorganic materials 0.000 claims description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 3
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims 2
- 239000011651 chromium Substances 0.000 claims 1
- 125000001841 imino group Chemical group [H]N=* 0.000 claims 1
- 239000003086 colorant Substances 0.000 description 15
- 238000000034 method Methods 0.000 description 9
- 239000004753 textile Substances 0.000 description 7
- 210000004243 sweat Anatomy 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 2
- 239000000980 acid dye Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000000986 disperse dye Substances 0.000 description 2
- 239000000434 metal complex dye Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- 101100008049 Caenorhabditis elegans cut-5 gene Proteins 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000257303 Hymenoptera Species 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 241001415849 Strigiformes Species 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 1
- YXVFYQXJAXKLAK-UHFFFAOYSA-N biphenyl-4-ol Chemical compound C1=CC(O)=CC=C1C1=CC=CC=C1 YXVFYQXJAXKLAK-UHFFFAOYSA-N 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 description 1
- 150000002466 imines Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000010409 ironing Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Landscapes
- Coloring (AREA)
Description
Przedmiotem wynalazku sar; srodek, barwiacy do barwienia wyrobów z mieszaniny wlókien polie¬ strowych i welnianych na kolor czerwony.The subject of the invention is sar; agent, coloring to dyeing articles made of a mixture of polyester fibers linen and woolen in red.
Dotychczas wyroby wlókiennicze z mieszaniny wlókien poliestrowych i welnianych barwiono na kolor czerwony metoda dwukapielowa przy uzy¬ ciu barwników zawiesinowych i barwników kwa¬ sowych lub barwników metalokompleksowych.So far, mixed textiles polyester and wool fibers were dyed on red color two-pot method with three disperse dyes and acid dyes owls or metal complex dyes.
Stosowane dotychczas barwniki zawiesinowe barwia skladnik poliestrowy wyrobu, natomiast nie zabarwiaja skladnika welnianego.Disperse dyes used so far dyes the polyester component of the product, while they do not stain the wool component.
Stosowane do barwienia skladnika welnianego mieszanki wlókienniczej barwniki kwasowe lub barwniki metalokompleksowe musza charaktery¬ zowac sie wysokimi wskaznikami odpornosci wy- barwien, a mianowicie: swiatlo 5.°, woda 4—5°, pranie 4°, pot 4°, tarcie 4°, przy czym 8° dla swiatla, a 5° dla pozostalych trwalosci oznacza odpornosc najwyzsza. Ze wzgledu na ograniczona ilosc barwników z grupy zawiesinowych i barwni¬ ków do welny spelniajacych stawiane powyzej wymagania, praktycznie uniemozliwione jest sto¬ sowanie metody jednokapielowej.Used for dyeing the wool component textile blend acid dyes or metal complex dyes have to be characterized be concerned with high indices of resistance to colored, namely: light 5 °, water 4-5 °, wash 4 °, sweat 4 °, rub 4 °, with 8 ° for light, and 5 ° durability for other means the highest resistance. Due to the limited the amount of dyes from the group of disperse and dyes wool loops conforming to the above requirements, a hundred is practically impossible using the single-bath method.
Dodatkowe mankamenty stanowi trudnosc uzy¬ skania jednolicie i równomiernie zabarwionych obydwu rodzajów wlókien w wyrobie wlókienni¬ czym bedacym mieszanka wlókien o róznych wla¬ sciwosciach fizyko-chemicznych, jak równiez osa¬ dzanie sie barwnika na powierzchni przedzy mie¬ szanej poliester-welna podczas barwienia przedzy > w iwrogachs: w- aparata(^^4^illi^^i<^^oc3^rkula* jaca kapiela barwiaca, co powoduje nastepnie ni¬ ska odpornosc wybarwienia na tarcie, zwlaszcza przy kolorach intensywnych.Another drawback is the difficulty of using spikes uniformly and evenly colored of both types of fibers in a textile product which is a mixture of different fibers physico-chemical properties as well as wasp dye on the surface of the copper of polyester-wool fabric when dying yarns > w iwrogachs: w- aparata (^^ 4 ^ illi ^^ i <^^ oc3 ^ rkula * the dye drip, which then causes nothing color fastness to rubbing, especially with intense colors.
Celem wynalazku jest równoczesne, jednolite zabarwienie wyrobów z mieszaniny wlókien po¬ liestrowych i welny metoda jednokapielowa — jednostopniowa, na kolor czerwony o wysokich wartosciach uzytkowych wybarwien i niezmienio¬ nych wlasnosciach fizyko-chemicznych wlókien.The object of the invention is simultaneous, uniform the coloring of the products made of a mixture of polymers for polyester and wool, the single bath method - single-stage, red and high the utility values of the colors and unchanged physical and chemical properties of fibers.
Cel ten osiagnieto barwiac wyroby z wlókien mieszanych poliestrowo-welnianych srodkiem bar¬ wiacym wedlug wynalazku zawierajacym 50—70 czesci wagowych technicznych barwników o wzo¬ rze ogólnym 1, w którym V oznacza atom wodo¬ ru lub atom chloru lub atom bromu lub grupe cyjanowa lub grupe metylosulfonowa, Z oznacza grupe nitrowa, U oznacza atom wodoru lub gru¬ pke metylowa, X oznacza grupe alkilowa CnH2n+i dla n oznaczajacego liczbe calkowita od 1 do 4 lub grupe hydroksyetylowa lub grupe acety- lowa lub grupe acetyloetylowa, Y oznacza gru¬ pe hydroksyetylowa lub grupe cyjanoetylowa, lub grupe acetyloetylowa oraz 30—50 czesci wagowych technicznych barwinków o wzorze ogólnym 2, w którym Me oznacza atom chro¬ mu lub atom kobaltu, A oznacza metal alka¬ liczny, X1 oznacza atom tlenu lub rodnik grupy karboksylowej, X2 oznacza atom tlenu lub grupe iminowa, Y1 jest równe lub rózne od Y* i ozna- 103 600103 < 3 - ¦ cza atom chloru lub grupe sulfonamidowa lub grupe nitrowa lub grupe metoksylowa lub grupe etoksylowa lub grupe metylowa, Z1 jest. równe lub rózne od Z2 i oznacza atom wodoru lub atpm chloru lub grupe sulfonamidowa lub grupe alki- 5 losulfonamidowa lub grupe nitrowa lub grupe me¬ toksylowa lub grupe etoksylowa lub grupe mety¬ lowa lub grupe fenylowa, n oznacza liczbe calko¬ wita 1 lub 2, W1 jest równe lub rózne od W2 i oznacza atom wodoru lub atom chloru lub grupe 10 nitrowa lub grupe metylowa, B1 jest równe lub rózne od B2 i oznacza reszte skladnika biernego posiadajaca zdolnosc sprzegania w pozycji orto do grupy X dla zwiazkpw szeregu benzenu, naf¬ talenu lub pirazolu, lub reszte skladnika' bier- 15 nego posiadajaca zdolnosc sprzegania dzieki obec¬ nosci w czasteczce reaktywnego ukladu alifatycz¬ nego, przy czym dobór podstawników: W, Y i Z winien byc taki, zeby w czasteczce barwnika wy¬ stepowaly " co ' najmniej ' dwie ' grupy "ulatwiajace" 2o rozpuszczalnosc barwnika w wodzie, najkorzyst¬ niej grupy sulfonamidowe lub alkilosulfonamido- we.This goal has been achieved by dyeing fiber products mixed polyester-woolen with a dye a binding according to the invention of 50-70 parts by weight of technical dyes with a pattern general structure 1 in which V is hydrogen ru or chlorine or bromine or group cyano or methylsulfone group, Z is a nitro group, U is a hydrogen atom or a group pk methyl, X is CnH2n + i alkyl group for n denoting an integer from 1 to 4 or a hydroxyethyl group or an acetyl group a group or an acetylethyl group, Y is a group pe hydroxyethyl or cyanoethyl group, or an acetylethyl group and 30-50 parts by weight technical dyes of formula general 2 in which Me is a chromium atom mu or cobalt, A is an alkali metal numerous, X1 is an oxygen atom or a group radical carboxyl, X2 is oxygen or a group imine, Y1 is equal to or different from Y * and is 103 600 103 < 3 - linkage of a chlorine atom or a sulfonamide group or a nitro group or a methoxy group or group ethoxy or methyl group, Z1 is. equal or other than Z2 and is hydrogen or atm chlorine or sulfonamide group or alkyl group 5 the losulfonamide group or the nitro group or the meta group a toxic or ethoxy group or a methyl group a low or phenyl group, n is an integer wit 1 or 2, W1 is equal to or different from W2 and is hydrogen or chlorine or group 10 nitro or methyl group, B1 is equal to or different from B2 and represents the remainder of the passive component having the ability to couple in the ortho position to the group X for compounds in the benzene series, naphtha talene or pyrazole, or the rest of the passive component with the ability to connect thanks to the present carries in the molecule of the reactive aliphatic system the choice of substituents: W, Y and Z it should be such that the dye molecule disintegrates stepowaly "at least" two "groups" facilitating "2o the solubility of the dye in water, most preferably there are sulfonamide or alkylsulfonamide groups in.
Oprócz substancji barwiacych, srodek barwia¬ cy wedlug wynalazku ewentualnie zawieraja nie- 25 wielkie ilosci znanych srodków dyspergujacych, . zwilzajacych oraz nastawiajacych, takich jak: dek¬ stryna, sól kuchenna"," szesciometafosfóran sodowy," soda, które to srodki nie maja zadnego wply¬ wu na sposób barwienia i wlasciwosci uzytko- 30 we wybarwien. Barwniki o wzorzex ogólnym 1, którego podstawniki zostaly omówione powyzej zabrawiaja wlókno poliestrowe, natomiast wlókno welniane zabarwiaja na kolor czerwony w sposób nietrwaly (brudza), dajac na tym wlóknie odpór- 35 nosci wybarwien: swiatlo 3°, woda 2—3°, pranie 2°, pot 2°, tarcie 2°.In addition to coloring substances, a coloring agent The compounds according to the invention optionally contain no large amounts of known dispersants,. wetting and setting agents, such as: dec¬ strin, table salt "," sodium hexametaphosphate, " soda, both of which have no effect the method of dyeing and usage properties - 30 in staining. Dyes of formula x general 1, whose substituents have been discussed above they dye the polyester fiber, while the fiber woolen colors red in a way unstable (stains), thus resisting the fibers - 35 dyes: light 3 °, water 2-3 °, washing 2 °, sweat 2 °, friction 2 °.
Barwniki o wzorze ogólnym 2, którego podsta¬ wniki zostaly podane powyzej barwia welne, ale dotychczas nie byly stosowane do barwienia wy- 40 robówv z wlókien mteszanych poliester-welna z uwagi na zbyt niskie trwalosci uzytkowe zabar¬ wionych wlókien mieszanych: swiatlo 5°, woda 4°, pranie 3^°, pot 4°, tarcie 3°.Dyes of general formula II, the basis of which the penetrations were given above the wool color, but so far they have not been used for staining dyes robes made of a polyester-wool braid due to the too low durability of the colors blended mixed fibers: 5 ° light, water 4 °, wash 3 °, sweat 4 °, rub 3 °.
Nieoczekiwanie okazalo sie, . ze srodki barwia- 45 ce, zawierajace jako komponenty odpowiednio do¬ brane ilosciowo barwniki o wzorach ogólnych 1 i 2, zabarwiaja trwale wyroby wlókiennicze z mie¬ szanek poliester-welna, na jednolity kolor czerwo¬ ny, a wartosci uzytkowe wybarwien srodkami bar- 50 wiacymi znacznie przewyzszaja wartosci uzyska¬ ne skladnikami srodków barwiacych gdyz wyno¬ sza: swiatlo 6°, woda 5°, pranie 4—5°, pot 5°, tar¬ cie 5°.Unexpectedly it turned out. with dyes - 45 containing as components respectively quantitatively taken dyes of general formulas 1 and 2, permanently color the textiles with the property polyester-wool cover, uniform red color ny, and the utility values of dyeing with bar- 50 therefore they significantly exceed the values obtained They are not used in coloring agents because they are gray: light 6 °, water 5 °, wash 4-5 °, sweat 5 °, rub cut 5 °.
Powyzsze nieoczekiwane efekty techniczne 55 (trwalosci uzytkowe wybarwien srodkami barwia¬ cymi) , nie wynikaja z wlasciwosci technicznych poszczególnych komponentów i wskazuja na sy- nargizm dzialania skladników srodków barwia¬ cych. 60 Srodkami barwiacymi wedlug wynalazku barwi sie wyroby z mieszaniny wlókien poliestrowych i welny metoda jednokapielowa jednostopniqwa w wodnej kapieli farbiarskiej o krotnosci 40:1 w stosunku do ciezaru wlókna w temperaturze wrze- 65 4 nia z dodatkiem orto lub parafenylofenolu lub in¬ nego zwiazku jako przenosnika w ciagu okolo 1,5 godziny, lub w kapieli wodnej o krotnosci 10:1 w temperaturze 105—115°C z dodatkiem aldehydu mrówkowego w ciagu okolo 1 godziny.The above unexpected technical effects 55 (usable durability of staining with staining agents cymi) are not based on technical properties individual components and indicate the sy- nargism of the action of the ingredients of the agents stain people. 60 The coloring agents according to the invention are colored products are made of a mixture of polyester fibers and wool one-step method in a water dyeing bath with a ratio of 40: 1 in based on the weight of fiber at the boiling point of 65 4 with the addition of ortho or para-phenylphenol or the like one compound as a conveyor within about 1.5 hours, or in a 10: 1 water bath temperature 105-115 ° C with the addition of aldehyde form ants within about 1 hour.
Nastepnie zabarwione wyroby na kolor czerwo¬ ny pierze sie i plucze wedlug znanych metod.Then the products dyed red They are washed and rinsed according to known methods.
Barwiac srodkiem barwiacym wedlug wynalaz¬ ku otrzymuje sie równomiernie zabarwione na ko¬ lor czerwony wyroby wlókiennicze z wlókien mie¬ szanych poliester-welna, odznaczajace sie wysoki¬ mi odpornosciami uzytkowymi zwlaszcza na swiat¬ lo 6°, tarcie 5°, czynniki mokre 4—5° i obróbke termiczna jak prasowanie, plisowanie 5° oraz cha¬ rakteryzujace sie niezmienionymi wlasnosciami fi¬ zyko-chemicznymi wlókien. - ' Ponadto okazalo sie, ze stosujac srodek barwia¬ cy wedlug wynalazku uzyskuje sie dobre krycie nierównomiernosci materialowych oraz wyelimino¬ wanie niekorzystnego efektu polysku wlasciwego wlóknom poliestrowym. Okazalo sie równiez, ze barwiac srodkiem barwiacym wedlug wynalazku przedze mieszana poliester-welna. w nawojach, w aparatach farbiarskich z cyrkulujaca kapiela bar¬ wiaca, nie powoduje sie Osadzania sie barwnika na powierzchni przedzy, dzieki czemu wybarwie¬ nia charakteryzuja sie wysoka odpornoscia na tarcie, równiez przy kolorach intensywnych.Dye with the coloring agent according to the invention the color is evenly colored on the horse red lorry textiles made of textile fibers sewn polyester-wool, distinguished by a tall ¬ I have functional resistances, especially to light lo 6 °, friction 5 °, wet media 4-5 ° and machining thermal, such as ironing, pleating 5 ° and cha ¬ characterized by unchanged properties of fi chemical and chemical fibers. - ' In addition, it turned out that when using a dye According to the invention, good coverage is obtained material unevenness and elimination the unfavorable effect of the internal gloss polyester fibers. It also turned out that dyeing with the coloring agent according to the invention Polyester-wool blend front. in coils, in dyeing machines with circulating drip bar it does not cause dye deposition on the surface of the yarn, thanks to which it stains They are characterized by high resistance to friction, also with intense colors.
Srodek barwiacy wedlug wynalazku zabarwia w sposób równomierny i trwaly równiez takie mieszanki welny i poliestru, w których zawar¬ tosc skladnika poliestrowego siega 70%, a zatem jest znacznie wyzsza niz spotyka sie to w kon¬ wencjonalnych mieszankach wlókienniczych o skladzie 55% wlókna poliestrowego i 45% wlókna welnianego.The coloring agent according to the invention colors evenly and permanently also such mixtures of wool and polyester, in which they contain the content of the polyester component reaches 70%, therefore is much higher than it meets in the end conventional textile blends o composed of 55% polyester fiber and 45% fiber woolen.
Barwienie srodkiem barwiacym wedlug wyna¬ lazku skraca czas barwienia wyrobów z wlókien mieszanych' poliester-welna i nie naraza wlókien welnianych na dlugotrwale operacje we wrzacej kapieli farbiarskiej.Staining with a coloring agent according to the invention the dye shortens the dyeing time of fiber products mixed 'polyester-wool and does not expose the fibers for long-term operations in boiling dyeing bath.
Ponizej podano przyklady sporzadzenia srodków barwiacych wedlug wynalazku.Examples of the preparation of measures are given below dyes according to the invention.
Przyklad I. 20 czesci wagowych technicz¬ nego produktu, w koncentracji 100/100 zawiera¬ jacego barwnik o wzorze 3, miesza sie z 40 cze¬ sciami wagowymi technicznego produktu w kon¬ centracji 100/100 zawierajacego barwnik o wzorze 4 oraz z 40 czesciami wagowymi technicznego produktu w koncentracji 100/100 zawierajacego barwnik o wzorze 5. Calosc uciera sie i homoge¬ nizuje na przystosowanych do tego urzadzeniach.Example I. 20 parts by weight technical of the product at a concentration of 100/100 his dye of formula 3 is mixed with 40 jun weight of the technical product in the end 100/100 centration containing the dye of formula 4 and with 40 technical parts product in a concentration of 100/100 containing dye of formula 5. The total is ground and homogeneous on devices adapted to this.
Otrzymany srodek barwiacy stosuje sie do bar¬ wienia metoda jednokapielowa jednoetapowa na kolor czerwony wyrobów z mieszaniny wlókien poliestrowych i welny. Uzyskane wybarwienia od¬ znaczaja sie dobra równomiernoscia wybarwienia i wysokimi wskaznikami odpornosci uzytkowych szczególnie . na swiatlo 6°, wode 5°, pranie 4—5°, pot 5°, tarcie 5°.The resulting coloring agent is used for dye one-step method, one-step method on red color of products from a mixture of fibers polyester and wool. The resulting dyes they show good uniformity of coloring and high indexes of functional resistance especially. 6 ° light, 5 ° water, 4-5 ° wash, sweat 5 °, friction 5 °.
Przyklad II. 60 czesci wagowych technicz¬ nego produktu w koncentracji 100/100 zawieraja¬ cego barwnik o wzorze 4, miesza sie z 20 cze¬ sciami wagowymi technicznego produktu w kon¬ centracji 100/100 zawierajacego barwnik o wzo-103 600 6 rze 5 oraz z 20 czesciami wagowymi techniczne¬ go produktu w koncentracji 100/100 zawierajacego barwnik o wzorze 6. Calosc uciera sie i homogeni¬ zuje, na przystosowanych do tego urzadzeniach.Example II. 60 parts by weight technical of the product in a concentration of 100/100 contain containing the dye of formula IV is mixed with 20 June weight of the technical product in the end 100/100 centration containing the dye formula 103 600 6 5 and with 20 technical parts by weight it of the product in a concentration of 100/100 containing dye of formula 6. The total is ground and homogenized zuje, on adapted devices.
Otrzymany srodek barwiacy stosuje sie do barwie¬ nia metoda jednokapielowa jednoetapowa na kolor czerwony wyrobów z mieszaniny wlókien po¬ liestrowych i welny. Uzyskane wybarwienia od¬ znaczaja sie dobra równomiernoscia wybarwienia i .wysokimi wskaznikami odpornosci uzytkowych szczególnie na swiatlo 6°, wode 5°, pranie 4—5°, pot 5°, tarcie 5°. ór S Wrór 6 NaThe resulting coloring agent is used for dyeing one-step method for color red products from a mixture of polycarbonate fibers polyester and wool. The resulting dyes they show good uniformity of coloring and. high resistance indicators in use especially for light 6 °, water 5 °, washing 4-5 °, sweat 5 °, friction 5 °. ór S. Back 6 On
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL19227776A PL103600B1 (en) | 1976-09-08 | 1976-09-08 | STAINING AGENT FOR COLORING PRODUCTS MIXED WITH POLYESTER FLEANS AND Wool |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL19227776A PL103600B1 (en) | 1976-09-08 | 1976-09-08 | STAINING AGENT FOR COLORING PRODUCTS MIXED WITH POLYESTER FLEANS AND Wool |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL192277A1 PL192277A1 (en) | 1978-03-28 |
| PL103600B1 true PL103600B1 (en) | 1979-06-30 |
Family
ID=19978480
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL19227776A PL103600B1 (en) | 1976-09-08 | 1976-09-08 | STAINING AGENT FOR COLORING PRODUCTS MIXED WITH POLYESTER FLEANS AND Wool |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL103600B1 (en) |
-
1976
- 1976-09-08 PL PL19227776A patent/PL103600B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL192277A1 (en) | 1978-03-28 |
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