PL105135B1 - STAINING AGENT FOR COLORING PRODUCTS MIXED WITH POLYESTER FLEANS AND Wool - Google Patents
STAINING AGENT FOR COLORING PRODUCTS MIXED WITH POLYESTER FLEANS AND Wool Download PDFInfo
- Publication number
- PL105135B1 PL105135B1 PL19548977A PL19548977A PL105135B1 PL 105135 B1 PL105135 B1 PL 105135B1 PL 19548977 A PL19548977 A PL 19548977A PL 19548977 A PL19548977 A PL 19548977A PL 105135 B1 PL105135 B1 PL 105135B1
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- PL
- Poland
- Prior art keywords
- group
- atom
- dye
- hydrogen atom
- nitroaniline
- Prior art date
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- 229920000728 polyester Polymers 0.000 title claims description 18
- 238000010186 staining Methods 0.000 title description 4
- 238000004040 coloring Methods 0.000 title description 2
- 239000000975 dye Substances 0.000 claims description 51
- 239000000835 fiber Substances 0.000 claims description 26
- 210000002268 wool Anatomy 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 17
- 238000004043 dyeing Methods 0.000 claims description 12
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- -1 hydroxyethyl group Chemical group 0.000 claims description 10
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 9
- 229910052801 chlorine Inorganic materials 0.000 claims description 8
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 8
- 125000003277 amino group Chemical group 0.000 claims description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 6
- 125000004422 alkyl sulphonamide group Chemical group 0.000 claims description 5
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 5
- 125000001424 substituent group Chemical group 0.000 claims description 5
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 4
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 4
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 4
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 4
- 125000000565 sulfonamide group Chemical group 0.000 claims description 4
- QPQKUYVSJWQSDY-CCEZHUSRSA-N 4-(phenylazo)aniline Chemical compound C1=CC(N)=CC=C1\N=N\C1=CC=CC=C1 QPQKUYVSJWQSDY-CCEZHUSRSA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 3
- LXQOQPGNCGEELI-UHFFFAOYSA-N 2,4-dinitroaniline Chemical compound NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O LXQOQPGNCGEELI-UHFFFAOYSA-N 0.000 claims description 2
- NUOZYXSTSXKJNQ-UHFFFAOYSA-N 2-amino-N-(4-phenyldiazenylphenyl)acetamide Chemical compound C1=CC=C(C=C1)N=NC2=CC=C(C=C2)NC(=O)CN NUOZYXSTSXKJNQ-UHFFFAOYSA-N 0.000 claims description 2
- 125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 claims description 2
- XTTIQGSLJBWVIV-UHFFFAOYSA-N 2-methyl-4-nitroaniline Chemical compound CC1=CC([N+]([O-])=O)=CC=C1N XTTIQGSLJBWVIV-UHFFFAOYSA-N 0.000 claims description 2
- DPJCXCZTLWNFOH-UHFFFAOYSA-N 2-nitroaniline Chemical compound NC1=CC=CC=C1[N+]([O-])=O DPJCXCZTLWNFOH-UHFFFAOYSA-N 0.000 claims description 2
- XJCVRTZCHMZPBD-UHFFFAOYSA-N 3-nitroaniline Chemical compound NC1=CC=CC([N+]([O-])=O)=C1 XJCVRTZCHMZPBD-UHFFFAOYSA-N 0.000 claims description 2
- QSNSCYSYFYORTR-UHFFFAOYSA-N 4-chloroaniline Chemical compound NC1=CC=C(Cl)C=C1 QSNSCYSYFYORTR-UHFFFAOYSA-N 0.000 claims description 2
- TYMLOMAKGOJONV-UHFFFAOYSA-N 4-nitroaniline Chemical compound NC1=CC=C([N+]([O-])=O)C=C1 TYMLOMAKGOJONV-UHFFFAOYSA-N 0.000 claims description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 claims description 2
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 239000011651 chromium Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical group [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims description 2
- 125000004464 hydroxyphenyl group Chemical group 0.000 claims description 2
- 125000001841 imino group Chemical group [H]N=* 0.000 claims description 2
- 125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 claims description 2
- CHMBIJAOCISYEW-UHFFFAOYSA-N n-(4-aminophenyl)acetamide Chemical compound CC(=O)NC1=CC=C(N)C=C1 CHMBIJAOCISYEW-UHFFFAOYSA-N 0.000 claims description 2
- BHAAPTBBJKJZER-UHFFFAOYSA-N p-anisidine Chemical compound COC1=CC=C(N)C=C1 BHAAPTBBJKJZER-UHFFFAOYSA-N 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 229940124530 sulfonamide Drugs 0.000 claims description 2
- 150000003456 sulfonamides Chemical group 0.000 claims description 2
- HHVIBTZHLRERCL-UHFFFAOYSA-N sulfonyldimethane Chemical group CS(C)(=O)=O HHVIBTZHLRERCL-UHFFFAOYSA-N 0.000 claims description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims 2
- KRTJTTYITKHQEU-UHFFFAOYSA-N 2-[(4-aminophenyl)diazenyl]phenol Chemical compound OC1=C(C=CC=C1)N=NC1=CC=C(C=C1)N KRTJTTYITKHQEU-UHFFFAOYSA-N 0.000 claims 1
- WCDSVWRUXWCYFN-UHFFFAOYSA-N 4-aminobenzenethiol Chemical compound NC1=CC=C(S)C=C1 WCDSVWRUXWCYFN-UHFFFAOYSA-N 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 1
- 150000003217 pyrazoles Chemical class 0.000 claims 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 claims 1
- 238000009736 wetting Methods 0.000 claims 1
- 239000003086 colorant Substances 0.000 description 13
- 210000004243 sweat Anatomy 0.000 description 8
- 239000004753 textile Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 2
- 239000000980 acid dye Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 239000000986 disperse dye Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- LOCWBQIWHWIRGN-UHFFFAOYSA-N 2-chloro-4-nitroaniline Chemical compound NC1=CC=C([N+]([O-])=O)C=C1Cl LOCWBQIWHWIRGN-UHFFFAOYSA-N 0.000 description 1
- MOMKYJPSVWEWPM-UHFFFAOYSA-N 4-(chloromethyl)-2-(4-methylphenyl)-1,3-thiazole Chemical compound C1=CC(C)=CC=C1C1=NC(CCl)=CS1 MOMKYJPSVWEWPM-UHFFFAOYSA-N 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 description 1
- 241000872198 Serjania polyphylla Species 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- DMLAVOWQYNRWNQ-UHFFFAOYSA-N azobenzene Chemical compound C1=CC=CC=C1N=NC1=CC=CC=C1 DMLAVOWQYNRWNQ-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 1
- YXVFYQXJAXKLAK-UHFFFAOYSA-N biphenyl-4-ol Chemical compound C1=CC(O)=CC=C1C1=CC=CC=C1 YXVFYQXJAXKLAK-UHFFFAOYSA-N 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 229960004279 formaldehyde Drugs 0.000 description 1
- 235000019256 formaldehyde Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- ORTFAQDWJHRMNX-UHFFFAOYSA-N hydroxidooxidocarbon(.) Chemical group O[C]=O ORTFAQDWJHRMNX-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000010409 ironing Methods 0.000 description 1
- 239000000434 metal complex dye Substances 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000019983 sodium metaphosphate Nutrition 0.000 description 1
- 238000007447 staining method Methods 0.000 description 1
- FDDDEECHVMSUSB-UHFFFAOYSA-N sulfanilamide Chemical compound NC1=CC=C(S(N)(=O)=O)C=C1 FDDDEECHVMSUSB-UHFFFAOYSA-N 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Coloring (AREA)
Description
Przedmiotem wynalazku jest srodek barwiacy do bar¬ wienia wyrobów z mieszaniny wlókien poliestrowych i welnianych na kolor szary lub na kolor czarny.The subject of the invention is a colorant making products made of a mixture of polyester fibers and woolen gray or black.
Dotychczas wyroby wlókiennicze z mieszaniny wló¬ kien poliestrowych i welnianych barwiono na kolor szary lub na kolor czarny metoda dwukapielowa przy uzyciu barwników zawiesinowych i barwników kwasowych lub barwników metalokompleksowych.Until now, textiles made of a mixture of fibers The polyester and woolen fabrics were dyed gray or for black, two-pot method when used disperse dyes and acid dyes or metal complex dyes.
Stosowane dotychczas barwniki zawiesinowe barwia skladnik poliestrowy wyrobu, natomiast nie zabarwiaja skladnika welnianego.Disperse dyes used so far dyes The polyester component of the product, but they do not stain the wool component.
Stosowane do barwienia skladnika welnianego mie¬ szanki wlókienniczej barwniki kwasowe lub barwniki me- talokompleksowe musza charakteryzowac sie wysokimi wskaznikami odpornosci wybarwien, a mianowicie: swia¬ tlo 5 °, woda 4—5 °, pranie 4 °, pot 4 °, tarcie 4 °, przy czym 8° dla swiatla, a 5° dla pozostalych trwalosci oznacza od¬ pornosc najwyzsza.Used for dyeing the wool component of the property textile materials, acid dyes or textile dyes talocomplex must be high indicators of color fastness, namely: back 5 °, water 4-5 °, wash 4 °, sweat 4 °, rub 4 °, the 8 ° for light and 5 ° for other durability is od the highest porn.
Ze wzgledu na ograniczona ilosc barwników z grupy zawiesinowych i barwników do welny spelniajacych sta¬ wiane powyzej wymagania, praktycznie uniemozliwione jest stosowanie metody jednokapielowej. Dodatkowymi mankamentami sa: trudnosc uzyskania jednolicie i rów¬ nomiernie zabarwionych obydwu rodzajów wlókien w wyrobie" wlókienniczym badecym mieszanka wlókien o róznych wlasciwosciach fizyko-chemicznych, jak równiez osadzanie sie barwnika na powierzchni przedzy miesza¬ nej poliester-welna podczas barwienia przedzy w nawo¬ jach, w aparatach farbiarskich z cyrkulujaca kapiela bar¬ wiaca, co powoduje nastepnie niska odpornosc wybarwienia na tarcie, zwlaszcza przy kolorach intensywnych.Due to the limited amount of dyes from the group suspensions and dyes for wool that meet solids the above requirements, practically impossible is to use the single-bath method. Additional the shortcomings are: the difficulty of obtaining uniformly and evenly of consistently dyed both types of fibers a textile research product of a mixture of fibers of o different physico-chemical properties as well deposition of the dye on the surface of the mix of polyester-wool during the dyeing of the yarn in the fertilizer yachts, in dyeing machines with a circulating bar-drip faint, which causes a subsequent low color fastness friction, especially with intense colors.
Celem wynalazku jest równoczesne, jednolite zabar¬ wienie Wyrobów z mieszaniny wlókien poliestrowych i welny metoda jednokapielowa-jednostopniowa, na ko¬ lor szary lub na kolor czarny o wysokich wartosciach u- zytfcowych wybarwien i niezmienionych wlasnosciach fizyko-chemicznych wlókien.The object of the invention is a simultaneous, uniform color making of Products made of a mixture of polyester fibers and wool, one-bath-one-step method, on the horse lor gray or black with high u- unchanged colors and unchanged properties physico-chemical fibers.
Cel ten osiagnieto barwiac wyroby z wlókien miesza¬ nych poliestrowo-welnianych srodkiem barwiacym we¬ dlug wynalazku zawierajacym 12—25 czesci wagowych technicznego barwnika o wzorze ogólnym 1, w którym R± oznacza niskoczasteczkowy rodnik alkilowy, R2 oznacza zdwuazowana aniline lub zdwuazowana p-chloroaniline lub zdwuazowana p-nitroaniline lub zdwuazowana m- -nitroaniline lub zdwuazowana o-nitroaniline lub zdwu¬ azowana p-anizydyne lub zdwuazowana p-acetyloamino- aniline lub zdwuazowana p-sulfamyloaniline lub zdwua- zowana 2,4-dwunitroaniline lub zdwuazowana 2-metylo- -4-nitroaniline lub zdwuazowana 2-chloro-4-nitroaniline lub zdwuazowany p-aminoazobenzen lub zdwuazowany p-aminoacetyloaminoazobenzen lub zdwuazowany p-ami- . nohydroksyazobenzen lub zdwuazowany p-aminocyjano- alkoksyazobenzen lub zdwuazowany p-aminoalkoksyalki- lokrabonyloazobenzen lub zdwuazowany p-aminosulfamy- loalkiloazobenzen lub zdwuazowany p-aminoazobenzen zawierajacy w czasteczce zestryfikowane grupy sulfo¬ nowe lub zdwuazowany p-aminoarylosulfonyloazobenzen lub ich wzajemne mieszaniny, 3—10 czesci wagowych. 105 1353? technicznego barwnika o wzorze ogólnym 2, w którym V oznacza atom wodoru lub atom chloru lub atom bromu lub grupe cyjanowa lub grupe metylosulfonowa, Z ozna¬ cza grupe nitrowa, U oznacza atom wodoru .lub grupe metylowa, X oznacza grupe alkilowa CnHan+i dla^ n oznaczajacego liczbe calkowita od 1 do 4 lub grupe hydro- ksyetylowa lub grupe acetylowa lub grupe acetyloetylowa, Y oznacza grupe hydroksyetylowa lub grupe cyjanoety- lowa lub grupe acetyloetylowa, 40—60 czesci wagowych technicznych barwników o wzorze ogólnym 3, w którym X1 oznacza grupe aminowa lub grupe metyloaminowa lub grupe fenyloaminowa, X2 oznacza grupe wodorotle¬ nowa lub grupe aminowa lub grupe fenyloaminowa, X3 oznacza atom wodoru l,ub grupe aminowa lub grupe wo¬ dorotlenowa, X4 oznacza atom wodoru lub grupe aminowa lub grupe wodorotlenowa, Y1 jest równe lub rózne od Y2 i oznacza atom wodoru lub atom bromu lub grupe hydro- ksyfenylowa lub grupe metoksyfenylowa lub ich wzajemne mieszaniny, oraz 20—35 czesci wagowych technicznego barwnika o wzorze ogólnym 4, w którym Me oznacza atom chromu lub atom kobaltu, A oznacza metal alka¬ liczny, X1 oznacza atom tlenu lub rodnik grupy karboksy¬ lowej, X2 oznacza atom tlenu lub grupe iminowa, Y1 jest równe lub rózne od Y2 i oznacza atom wodoru lub atom chloru lub grupe sulfonamidowa lub grupe alkilosulfo- namidowa lub grupe nitrowa lub grupe metoksylowa lub grupe etoksylowa lub grupe metylowa, Z1 jest równe lub rózne od Z2 i oznacza atom wodoru lub atom chloru lub grupe sulfonamidowa lub grupe alkilosulfonowa lub gru- ge alkilosulfonamidowa lub grupe nitrowa lub grupe metoksylowa lub grupe etoksylowa lub grupe metylowa lub grupe fenylowa, n oznacza liczbe calkowita 1 lub 2, W1 jest równe lub rózne od W2 i oznacza atom wodoru lub atom chloru lub grupe, nitrowa lub grupe metylowa, B1 jest równe lub rózne od B2 i oznacza reszte skladnika biernego posiadajaca zdolnosc sprzegania w pozycji orto do grupy X dla zwiazków szeregu benzenu, naftalenu lub pirazolu, lub reszte skladnika biernego posiadajaca zdolnosc sprzegania dzieki obecnosci w czasteczce reak¬ tywnego ukladu alifatycznego, przy czym dobór podstaw¬ ników: W, Y i Z winien byc taki, zeby w czasteczce barw¬ nika wystepowaly co najmniej dwie grupy ulatwiajace rozpuszczalnosc barwnika w wodzie, najkorzystniej grupy sulfonamidowe lub alkilosulfonamidowe.This aim has been achieved by dyeing fiber products with mixtures polyester-woolen dyes with a wool dye the length of the invention containing 12-25 parts by weight technical dye of general formula I, where R ± represents a low molecular weight alkyl radical, R2 is diazotized aniline or diazotized p-chloroaniline or diazotized p-nitroaniline or diazotized m- -nitroaniline or diazotized o-nitroaniline or doublet azated p-anisidine or diazotized p-acetylamino- aniline or diazotized p-sulfamylaniline or doubled 2-methylated 2,4-dinitroaniline or diazotized 2-methyl -4-nitroaniline or diazotized 2-chloro-4-nitroaniline or diazotized p-aminoazobenzene or diazotized p-aminoacetylaminoazobenzene or diazotized p-am- . nohydroxyazobenzene or diazotized p-aminocyano- alkoxyazobenzene or diazotized p-aminoalkoxyalky- locrabonylazobenzene or diazotized p-aminosulfamy- loalkylazobenzene or diazotized p-aminoazobenzene containing esterified sulfo groups in the molecule new or diazotized p-aminoarylsulfonyl azobenzene or mixtures thereof, 3-10 parts by weight. 105 1353? technical dye of general formula 2, in which V. is hydrogen or chlorine or bromine or a cyano group or a methylsulfone group, a nitro group, U is a hydrogen atom. or a group methyl, X is CnHan + alkyl and for Rn denoting an integer from 1 to 4 or a hydro- xyethyl or acetyl group or acetylethyl group, Y is a hydroxyethyl group or a cyanoethyl group acyl or acetyl ethyl group, 40-60 parts by weight technical dyes of general formula 3, in which X1 is an amino group or a methylamino group or a phenylamino group, X2 is a hydroxyl group new or amino group or phenylamino group, X3 represents a hydrogen atom, or an amino group or a water group hydroxyl, X4 is hydrogen or amino or a hydroxyl group, Y1 is equal to or different from Y2 and is a hydrogen atom or a bromine atom or a hydro xyphenyl or methoxyphenyl or reciprocal thereof mixtures, and 20-35 parts by weight of technical of a dye of general formula 4 in which Me is a chromium atom or a cobalt atom, A is an alkali metal X1 is an oxygen atom or a carboxy radical X2 is oxygen or imino, Y1 is equal to or different from Y2 and is hydrogen or an atom chlorine or sulfonamide group or alkylsulfo- namide or nitro or methoxy group or an ethoxy group or a methyl group, Z1 is equal to or other than Z2 and is hydrogen or chlorine or sulfonamide group or alkylsulfone group or group ge alkylsulfonamide or nitro group or group methoxy or ethoxy group or methyl group or phenyl group, n is an integer of 1 or 2, W1 is equal to or different from W2 and is hydrogen or a chlorine atom or a nitro or a methyl group, B1 is equal to or different from B2 and represents the remainder of the component passive having the ability to couple in the ortho position to group X for compounds of the benzene, naphthalene series or pyrazole, or the rest of the passive component having the ability to couple due to the presence of a reaction in the molecule the active aliphatic system, the selection being based on for: W, Y and Z should be such that there is a color in the molecule there were at least two facilitating groups the solubility of the dye in water, most preferably the group sulfonamides or alkylsulfonamides.
Oprócz substancji barwiacych, srodek barwiacy wedlug wynalazku ewentualnie zawiera niewielkie ilosci zna¬ nych srodków dyspergujacych, zwilzajacych oraz nasta¬ wiajacych, takich jak: dekstryna, sól kuchenna, szescio- metafosforan sodowy, soda, które to srodki nie maja zad¬ nego wplywu na sposób barwienia i wlasciwosci uzytkowe wybarwien.In addition to coloring substances, the coloring agent according to the invention may contain minor amounts of symbols various dispersants, wetting agents and the following binders, such as: dextrin, table salt, six sodium metaphosphate, soda, both of which have no problems different influence on the method of dyeing and performance discoloration.
Barwnik o wzorze ogólnym 1, którego podstawniki zostaly omówione powyzej zabarwia wlókno poliestrowe, natomiast wlókno welniane zabarwia na kolor zólty W sposób nietrwaly (brudzi), dajac na tym wlóknie odpor¬ nosci wybarwien: swiatlo 2—3°, woda 3°, pranie 2—3°, pot 2 °, tarcie 2—3 °.Dye of general formula I whose substituents have been discussed above dyes polyester fiber, while the wool fiber turns yellow In a non-permanent (stains) manner, making the fibers resistant to it dyes: light 2-3 °, water 3 °, washing 2-3 °, sweat 2 °, friction 2-3 °.
Barwnik o wzorze ogólnym 2, którego podstawniki zostaly omówione powyzej zabarwia wlókno poliestrowe, natomiast wlókno welniane zabarwia na kolor czerwony w sposób nietrwaly (brudzi), dajac na tym wlóknie od- * pornosci wybarwien: swiatlo 3 °, woda 2—3 °, pranie 2 °, pot 2 °, tarcie 2 °.A dye of general formula 2 whose substituents have been discussed above dyes polyester fiber, while the woolen color turns red in an unstable (stains) manner, making the fibers * color porn: light 3 °, water 2-3 °, washing 2 °, sweat 2 °, friction 2 °.
Barwniki o wzorze ogólnym 3, którego podstawniki zostaly omówione powyzej zabarwiaja wlókno poliestro- 135 4 we, natomiast wlókno welniane zabarwiaja na kolor nie¬ bieski w sposób nietrwaly (brudza), dajac na tym wlók¬ nie odpornosci wybarwien: swiatlo 3°, woda 2°, pranie 2°, pot 2°, tarcie 2-3°.Dyes of general formula 3 whose substituents have been discussed above color the polyester fiber 135 4 wool, while the wool stains it a color blue in a non-permanent (stains) way, resulting in fiber no color fastness: light 3 °, water 2 °, wash 2 °, sweat 2 °, friction 2-3 °.
Barwniki o wzorze ogólnym 4, którego podstawniki zostaly omówione powyzej barwia welne, ale dotychczas nie byly stosowane do barwienia wyrobów z wlókien mie¬ szanych poliester—welna z uwagi na zbyt niskie trwalos¬ ci uzytkowe zabarwionych wlókien mieszanych: swiat¬ lo 3—4°, woda 3—4°, pranie 3°, pot 3°, tarcie 2—3°.Dyes of general formula 4 whose substituents have been discussed above wool dyes, but so far they were not used to dye textile products sewn polyester-wool due to insufficient durability utensils of colored mixed fibers: light lo 3-4 °, water 3-4 °, wash 3 °, sweat 3 °, rubbing 2-3 °.
Nieoczekiwanie okazalo sie, ze srodek barwiacy, zawie¬ rajacy jako komponenty odpowiednio dobrane ilosciowo barwniki o wzorach ogólnych 1, 2, 3 i 4 zabarwia trwale wyroby wlókiennicze z mieszanek poliester—welna, na jednolity kolor szary lub na jednolity kolor czarny, a war- tosci uzytkowe wybarwien srodkami barwiacymi znacznie przewyzszaja wartosci uzyskane skladnikami srodków barwiacych gdyz wynosza: swiatlo 5—6° lub 6—7°, wo¬ da 5 °, pranie 4—5 °, pot 5 °, tarcie 4—5 °. Powyzsze nieo¬ czekiwane efekty techniczne (trwalosci uzytkowe wy- barwien srodkami barwiacymi) nie wynikaja z wlasci¬ wosci technicznych poszczególnych komponentów i wska¬ zuja na synergizm dzialania skladników srodka barwia¬ cego.It turned out unexpectedly that the coloring agent failed Rajacy as components appropriately selected quantitatively dyes of general formulas 1, 2, 3 and 4 stain permanently textiles made of polyester-wool blends, na solid gray or solid black, and the Usable staining with tinting agents significantly exceed the values obtained with the components of the funds of dyes, because they are: light 5-6 ° or 6-7 °, oxygen will give 5 °, wash 4-5 °, sweat 5 °, rub 4-5 °. The above no awaited technical effects (service life of dyed with coloring agents) are not due to properties technical qualities of individual components and indications they affect the synergism of the action of the ingredients of the dye what.
Srodkiem barwiacym wedlug wynalazku barwi sie wy- roby z mieszaniny wlókien poliestrowych i welny metoda jednokapielowa jednostopniowa w wodnej kapieli far- biarskiej o krotnosci 40:1 w stosunku do ciezaru wlókna w temperaturze wrzenia z dodatkiem orto lub parafenylo- fenolu lub innego zwiazku jako przenosnika w ciagu oko- lo 1,5 godziny ,lub w kapieli wodnej o krotnosci 10:1 w temperaturze 105—115°C z dodatkiem aldehydu mrów¬ kowego w ciagu okolo 1 godziny. Nastepnie zabarwione wyroby na kolor szary lub na kolor czarny pierze sie i plucze wedlug znanych metod. Zabarwione wyroby na kolor czarny poddaje sie dodatkowo obróbce redukcyjno- -alkalicznej znanymi sposobami, w temperaturze nie przekraczajacej 45 °C, w ciagu 20 minut.The dyeing agent according to the invention is colored made of a mixture of polyester fibers and wool single-bath single-stage water bath biarska with a ratio of 40: 1 in relation to the weight of the fiber at boiling point with the addition of ortho or para-phenyl phenol or other compound as a carrier within an 1.5 hours, or in a 10: 1 water bath temperature 105-115 ° C with the addition of form aldehyde within approximately 1 hour. Then tinted gray or black products are washed and washed rinses according to known methods. Colored products on the black color is additionally subjected to reduction treatment -alkaline by known methods, at no temperature 45 ° C or higher within 20 minutes.
Barwiac srodkiem barwiacym wedlug wynalazku otrzy¬ muje sie równomierne-zabarwione na kolor szary lub na kolor czarny wyroby wlókiennicze z wlókien mieszanych poliester—welna, odznaczajace sie wysokimi odpornos- ciami uzytkowymi zwlaszcza na swiatlo 5—6° lub 6—7°> tarcie 4—5 °, czynniki mokre 4—5 ° i obróbke termiczna jak prasowanie, plisowanie 5° oraz charakteryzujace sie 45 . niezmienionymi wlasnosciami fizyko-chemicznymi wló¬ kien.Dyeing with the coloring agent according to the invention is obtained it is even - colored gray or on black color textiles made of mixed fibers polyester - wool, distinguished by high resistance Usable fabrics, especially for light from 5 to 6 ° or 6 to 7 °> friction 4-5 °, wet media 4-5 ° and heat treatment like ironing, 5 ° pleating and the characteristic 45. unchanged physico-chemical properties of the hob kien.
Ponadto okazalo sie, ze stosujac srodek barwiacy we¬ dlug wynalazku uzyskuje sie dobre krycie nierównomier- nosci materialowych oraz wyeliminowanie niekorzyst¬ nego efektu polysku wlasciwego wlóknom poliestrowym* Okazalo sie równiez, ze barwiac srodkami barwiacymi wedlug wynalazku przedze mieszana poliester—welna w nawojach, w aparatach farbiarskich z cyrkulujaca ka¬ piela barwiaca, nie powoduje sie osadzania sie barwnika na powierzchni przedzy, dzieki czemu wybarwienia cha¬ rakteryzuja sie wysoka odpornoscia na tarcie, równiez przy kolorach intensywnych.Moreover, it turned out that when using a dye of wool the debt of the invention, good coverage of unevenly materials and the elimination of disadvantages shine effect characteristic of polyester fibers * It also turned out to stain with tinting agents According to the invention, polyester-wool blends are used in coils, in dyeing machines with circulating canals the dye does not deposit the dye on the surface of the yarn, thanks to which the discoloration may occur are characterized by high friction resistance, also with intense colors.
Srodek barwiacy wedlug wynalazku zabarwia w sposób 60 równomierny i trwaly równiez takie mieszanki welny i po¬ liestru, w których zawartosc skladnika póliestrowego siega 70%, a zatem jest znacznie wyzsza niz spotyka sie to w konwencjonalnych mieszankach wlókienniczych a 65 skladzie 55% wlókna poliestrowego i 45% wlókna wel-105 135 nianego. Barwienie srodkiem barwiacym wedlug wyna¬ lazku skraca czas barwienia wyrobów z wlókien miesza¬ nych poliester—welna i nie naraza wlókien welnianych na dlugotrwale operacje we wrzacej kapieli farbiarskiej.The coloring agent according to the invention will color in a manner 60 even and durable, also such mixtures of wool and pans polyester, in which the content of the polyester component reaches 70% and is therefore much higher than meets then in conventional textile blends a 65 consists of 55% polyester fiber and 45% wel-105 135 fiber the new one. Staining with a coloring agent according to the invention The dyeing time of the mixed fiber products is reduced Polyester - wool and will not expose wool fibers for prolonged operations in the boiling dyeing bath.
Przyklady sporzadzenia srodka barwiacego wedlug wy- 5 nalazku.Examples of the preparation of a coloring agent according to ex 5 invention.
Przyklad I. 16 czesci wagowych technicznego produktu w koncentracji 100/100 zawierajacego barwnik o wzorze 5, miesza sie z 6 czesciami wagowymi technicz¬ nego produktu w koncentracji 100/100 zawierajacego 10 barwnik o wzorze 6, z 24 czesciami wagowymi technicz¬ nego produktu w koncentracji 100/100 zawierajacego barwnik o wzorze 7, z 24 czesciami wagowymi technicz¬ nego produktu w koncentracji 100/100 zawierajacego barwnik o wzorze 8, oraz z 30 czesciami wagowymi tech- 15 nicznego produktu w koncentracji 100/100 zawieraja¬ cego barwnik o wzorze 9. Calosc uciera sie i homogeni¬ zuje w przystosowanych do tego celu urzadzeniach. O- trzymany srodek barwiacy stosuje sie do barwienia metoda jednokapielowa jednoetapowa na kolor szary wyrobów z 20 mieszaniny wlókien poliestrowych i welny. Uzyskane wybarwienia odznaczaja sie dobra równomiernoscia wy- barwienia i wysokimi wskaznikami odpornosci uzytkowych, szczególnie na swiatlo 5—6°, wode 5°, pranie 5°, pot 5°, tarcie 4—5°. 25 Przyklad II. 20 czesci wagowych technicznego produktu w koncentracji 100/100 zawierajacego barwnik . o wzorze 5, miesza sie z 5 czesciami wagowymi technicz¬ nego produktu w koncentracji 100/100 zawierajacego barwnik o wzorze 6, z 25 czesciami wagowymi technicz- 30 nego produktu w koncentracji 100/100 zawierajacego barwnik o wzorze 7 z 25 czesciami wagowymi technicz¬ nego produktu w koncentracji 100/100 zawierajacego barwnik o wzorze 8 z 2,6 czesciami wagowymi technicz¬ nego produktu w koncentracji 100/100 zawierajacego 35 barwnik o wzorze 10, z 4 czesciami wagowymi technicz¬ nego produktu w koncentracji 100/100 zawierajacego barwnik o wzorze 11, z 1,5 czesciami wagowymi technicz¬ nego produktu w koncentracji 100/100 zawierajacego barwnik o wzorze 12, z 5,8 czesciami wagowymi technicz- 40 nego produktu w koncentracji 100/100 zawierajacego barwnik o wzorze 13 oraz z 11,1 czesciami wagowymi technicznego produktu w koncentracji 100/100 zawiera¬ jacego barwnik o wzorze 14. Calosc uciera sie i homoge¬ nizuje na przystosowanych do tego urzadzeniach. 45 Otrzymany srodek barwiacy stosuje sie do barwienia metoda jednokapielowa jednoetapowa na kolor czarny wy¬ robów z mieszaniny wlókien poliestrowych i welny. U- zyskane wybarwienia odznaczaja sie dobra równomier¬ noscia wybarwienia i wysokimi wskaznikami odpornosci 50 uzytkowych szczególnie na swiatlo 6—7°, wode 5°, pra¬ nie 4—5°, pot 5°, tarcie 4—5°. %r -i-C^-r1 V\| z er k i CH3 n=n7^)-n=k-M WLÓr 5 chi ^Oksn<> CLH5 Wz.or 6 ?H u 0H OH ° OH 8r ii Wzór ft105 135 Cr rr- \lwls\J "W et W NaVK+ Wzór 15 T \ N 0\l /N^^-sOtNttj. m°^-0? l^i NO, Wzór 1>t Na LZG Z-d 3 w Pab., zam. 940^79, nakl, 1«0+M eglz.Example I. 16 parts by weight technical a product in a concentration of 100/100 containing the dye of formula 5, is mixed with 6 technical weight parts product in a concentration of 100/100 containing 10 dye formula 6 with 24 technical parts by weight product in a concentration of 100/100 containing dye formula 7 with 24 technical parts by weight product in a concentration of 100/100 containing dye of formula 8, and with 30 parts by weight of tech of any product in a concentration of 100/100 contain containing the dye of formula 9. The whole is ground and homogenized in devices adapted for this purpose. ABOUT- the held coloring agent is used for staining method single-bath single-step gray-colored products from 20 mixtures of polyester fibers and wool. Obtained dyes are characterized by good uniformity of dyeing and high indexes of wear resistance, especially for light 5-6 °, water 5 °, wash 5 °, sweat 5 °, friction 4-5 °. 25 Example II. 20 parts by weight of technical a product in a concentration of 100/100 containing the dye . of formula 5, is mixed with 5 technical parts by weight product in a concentration of 100/100 containing dye of formula 6, with 25 technical parts by weight product in a concentration of 100/100 containing dye of formula 7 with 25 technical parts by weight product in a concentration of 100/100 containing dye of formula 8 with 2.6 parts by weight technical of a product in a concentration of 100/100 containing 35 dye of formula 10 with 4 technical parts by weight product in a concentration of 100/100 containing dye of formula 11, with 1.5 parts by weight technical product in a concentration of 100/100 containing dye of formula 12, with 5.8 parts by technical weight - 40 product in a concentration of 100/100 containing dye of formula 13 and with 11.1 parts by weight technical product in 100/100 concentration contains his dye of formula 14. The whole is ground and homogeneous on devices adapted to this. 45 The resulting coloring agent is used for staining one-bath method one-step black off robes made of a mixture of polyester fibers and wool. AT- the dyeing obtained is characterized by a good uniformity wearing color and high resistance indexes 50 especially for use under light 6-7 °, water 5 °, work no 4-5 °, sweat 5 °, friction 4-5 °. % r -i-C ^ -r1 V \ | with er k and CH3 n = n7 ^) - n = k-M WLÓr 5 chi ^ Oksn <> CLH5 Model 6 ? H u OH OH ° OH 8r ii Formula ft105 135 Cr yy- \ lwls \ J "W et W. NaVK + Formula 15 Y \ N 0 \ l / N ^^ - sOtNttj. m ° ^ -0? l ^ and NO, Formula 1> t On LZG Z-d 3 in Pab., Residing in 940 ^ 79, Nakl, 1 < 0 + M ex.
Cena 45 zlPrice PLN 45
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL19548977A PL105135B1 (en) | 1977-01-21 | 1977-01-21 | STAINING AGENT FOR COLORING PRODUCTS MIXED WITH POLYESTER FLEANS AND Wool |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL19548977A PL105135B1 (en) | 1977-01-21 | 1977-01-21 | STAINING AGENT FOR COLORING PRODUCTS MIXED WITH POLYESTER FLEANS AND Wool |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL195489A1 PL195489A1 (en) | 1978-08-14 |
| PL105135B1 true PL105135B1 (en) | 1979-09-29 |
Family
ID=19980598
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL19548977A PL105135B1 (en) | 1977-01-21 | 1977-01-21 | STAINING AGENT FOR COLORING PRODUCTS MIXED WITH POLYESTER FLEANS AND Wool |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL105135B1 (en) |
-
1977
- 1977-01-21 PL PL19548977A patent/PL105135B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL195489A1 (en) | 1978-08-14 |
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