PL110001B1 - Method of producing polyvinyl chloride by suspension polymerization - Google Patents

Method of producing polyvinyl chloride by suspension polymerization Download PDF

Info

Publication number: PL110001B1
Authority: PL; Poland
Prior art keywords: initiator; polymerization; tank; vinyl chloride; water
Prior art date: 1977-03-09

Application number

PL1978205165A

Other languages

English (en)

Polish (pl)

Other versions

PL205165A1 (pl

Original Assignee

Hoechst Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-03-09

Filing date

1978-03-08

Publication date

1980-06-30

1978-03-08 Application filed by Hoechst Ag filed Critical Hoechst Ag

1979-02-12 Publication of PL205165A1 publication Critical patent/PL205165A1/xx

1980-06-30 Publication of PL110001B1 publication Critical patent/PL110001B1/pl

Links

238000000034 method Methods 0.000 title claims description 42
229920000915 polyvinyl chloride Polymers 0.000 title claims description 9
239000004800 polyvinyl chloride Substances 0.000 title claims description 9
238000010557 suspension polymerization reaction Methods 0.000 title description 2
239000003999 initiator Substances 0.000 claims description 59
238000006116 polymerization reaction Methods 0.000 claims description 55
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 44
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 33
229920000642 polymer Polymers 0.000 claims description 14
239000000725 suspension Substances 0.000 claims description 14
239000003381 stabilizer Substances 0.000 claims description 11
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
239000001301 oxygen Substances 0.000 claims description 9
229910052760 oxygen Inorganic materials 0.000 claims description 9
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 7
238000006243 chemical reaction Methods 0.000 claims description 6
BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 claims description 6
239000007900 aqueous suspension Substances 0.000 claims description 5
238000002156 mixing Methods 0.000 claims description 4
239000002904 solvent Substances 0.000 claims description 4
150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 3
150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 3
BSVQJWUUZCXSOL-UHFFFAOYSA-N cyclohexylsulfonyl ethaneperoxoate Chemical group CC(=O)OOS(=O)(=O)C1CCCCC1 BSVQJWUUZCXSOL-UHFFFAOYSA-N 0.000 claims description 3
238000010438 heat treatment Methods 0.000 claims description 3
239000003960 organic solvent Substances 0.000 claims description 3
125000005498 phthalate group Chemical class 0.000 claims description 3
150000001350 alkyl halides Chemical class 0.000 claims description 2
239000007789 gas Substances 0.000 claims description 2
230000000379 polymerizing effect Effects 0.000 claims description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 6
230000015572 biosynthetic process Effects 0.000 description 5
230000008569 process Effects 0.000 description 5
239000003054 catalyst Substances 0.000 description 4
238000011049 filling Methods 0.000 description 4
238000011068 loading method Methods 0.000 description 4
239000000178 monomer Substances 0.000 description 4
230000002028 premature Effects 0.000 description 4
238000005096 rolling process Methods 0.000 description 4
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 4
230000000052 comparative effect Effects 0.000 description 3
229960002380 dibutyl phthalate Drugs 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
GTJOHISYCKPIMT-UHFFFAOYSA-N 2-methylundecane Chemical compound CCCCCCCCCC(C)C GTJOHISYCKPIMT-UHFFFAOYSA-N 0.000 description 2
SGVYKUFIHHTIFL-UHFFFAOYSA-N Isobutylhexyl Natural products CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 description 2
YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 2
230000002776 aggregation Effects 0.000 description 2
238000004132 cross linking Methods 0.000 description 2
239000002270 dispersing agent Substances 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
VKPSKYDESGTTFR-UHFFFAOYSA-N isododecane Natural products CC(C)(C)CC(C)CC(C)(C)C VKPSKYDESGTTFR-UHFFFAOYSA-N 0.000 description 2
239000000203 mixture Substances 0.000 description 2
229920002689 polyvinyl acetate Polymers 0.000 description 2
239000011118 polyvinyl acetate Substances 0.000 description 2
238000000926 separation method Methods 0.000 description 2
229920002554 vinyl polymer Polymers 0.000 description 2
JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
ZACVGCNKGYYQHA-UHFFFAOYSA-N 2-ethylhexoxycarbonyloxy 2-ethylhexyl carbonate Chemical compound CCCCC(CC)COC(=O)OOC(=O)OCC(CC)CCCC ZACVGCNKGYYQHA-UHFFFAOYSA-N 0.000 description 1
NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
239000004372 Polyvinyl alcohol Substances 0.000 description 1
239000012190 activator Substances 0.000 description 1
238000005054 agglomeration Methods 0.000 description 1
238000004220 aggregation Methods 0.000 description 1
239000008346 aqueous phase Substances 0.000 description 1
230000008901 benefit Effects 0.000 description 1
LQKBKHFGCGFBAF-UHFFFAOYSA-N butyl carboxyoxy carbonate Chemical group CCCCOC(=O)OOC(O)=O LQKBKHFGCGFBAF-UHFFFAOYSA-N 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
229920003086 cellulose ether Polymers 0.000 description 1
239000000084 colloidal system Substances 0.000 description 1
230000009849 deactivation Effects 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
239000011888 foil Substances 0.000 description 1
BUXJGUZPQJRBAY-UHFFFAOYSA-N hexylsulfonyl ethaneperoxoate Chemical compound C(CCCCC)S(=O)(=O)OOC(C)=O BUXJGUZPQJRBAY-UHFFFAOYSA-N 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
239000007788 liquid Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
238000005259 measurement Methods 0.000 description 1
239000003921 oil Substances 0.000 description 1
210000000056 organ Anatomy 0.000 description 1
239000002245 particle Substances 0.000 description 1
230000002093 peripheral effect Effects 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
239000012071 phase Substances 0.000 description 1
229920000151 polyglycol Polymers 0.000 description 1
239000010695 polyglycol Substances 0.000 description 1
229920002451 polyvinyl alcohol Polymers 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
238000007789 sealing Methods 0.000 description 1
239000010802 sludge Substances 0.000 description 1
230000002269 spontaneous effect Effects 0.000 description 1
238000005507 spraying Methods 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
230000007704 transition Effects 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J4/00—Feed or outlet devices; Feed or outlet control devices
- B01J4/02—Feed or outlet devices; Feed or outlet control devices for feeding measured, i.e. prescribed quantities of reagents
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Health & Medical Sciences (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Polymerisation Methods In General (AREA)

PL1978205165A 1977-03-09 1978-03-08 Method of producing polyvinyl chloride by suspension polymerization PL110001B1 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE19772710121 DE2710121A1 (de)	1977-03-09	1977-03-09	Verfahren zur herstellung von polyvinylchlorid durch suspensionspolymerisation

Publications (2)

Publication Number	Publication Date
PL205165A1 PL205165A1 (pl)	1979-02-12
PL110001B1 true PL110001B1 (en)	1980-06-30

Family

ID=6003095

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
PL1978205165A PL110001B1 (en)	1977-03-09	1978-03-08	Method of producing polyvinyl chloride by suspension polymerization

Country Status (9)

Country	Link
AR (1)	AR224860A1 (de)
BE (1)	BE864680A (de)
DD (1)	DD134535A5 (de)
DE (1)	DE2710121A1 (de)
FR (1)	FR2383203A1 (de)
GB (1)	GB1574572A (de)
IT (1)	IT1101981B (de)
PL (1)	PL110001B1 (de)
YU (1)	YU54478A (de)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP4395478B2 (ja) *	2003-12-26	2010-01-06	信越化学工業株式会社	塩化ビニル系重合体の製造方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR1439957A (fr) *	1964-03-26	1966-05-27	Monsanto Co	Perfectionnements apportés à la polymérisation de monomères vinyliques
US3451985A (en) *	1964-03-26	1969-06-24	Monsanto Co	Method of polymerizing vinyl monomers
DE2442574A1 (de) *	1974-09-05	1976-03-25	Huels Chemische Werke Ag	Verfahren zur herstellung von polyvinylchlorid unter vermeiden von vinylchlorid-emissionen durch diskontinuierliche polymerisation in suspension

1977
- 1977-03-09 DE DE19772710121 patent/DE2710121A1/de not_active Withdrawn
1978
- 1978-03-03 GB GB8544/78A patent/GB1574572A/en not_active Expired
- 1978-03-07 AR AR271342A patent/AR224860A1/es active
- 1978-03-07 IT IT48319/78A patent/IT1101981B/it active
- 1978-03-07 DD DD78204015A patent/DD134535A5/de not_active IP Right Cessation
- 1978-03-08 PL PL1978205165A patent/PL110001B1/pl unknown
- 1978-03-08 BE BE185759A patent/BE864680A/xx not_active IP Right Cessation
- 1978-03-08 YU YU00544/78A patent/YU54478A/xx unknown
- 1978-03-09 FR FR7806859A patent/FR2383203A1/fr active Granted

Also Published As

Publication number	Publication date
IT1101981B (it)	1985-10-07
FR2383203A1 (fr)	1978-10-06
DD134535A5 (de)	1979-03-07
DE2710121A1 (de)	1978-09-14
PL205165A1 (pl)	1979-02-12
GB1574572A (en)	1980-09-10
IT7848319A0 (it)	1978-03-07
FR2383203B1 (de)	1981-06-12
AR224860A1 (es)	1982-01-29
YU54478A (en)	1982-06-30
BE864680A (fr)	1978-09-08

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NO156166B (no)	1987-04-27	Vandig peroksydemulsjon og bruk ved suspensjon(ko)-polymerisering.
US4732784A (en)	1988-03-22	Process for treating a polymerization reactor
IL33738A (en)	1974-11-29	Process for the preparation of vinyl chloride polymers and copolymers insoluble in their monomeric compositions
MX2008012262A (es)	2008-10-07	Procedimiento continuo para la produccion de (co)polimeros de cloruro de vinilo.
CA1064648A (en)	1979-10-16	Aqueous emulsion of vinyl chloride
US6046286A (en)	2000-04-04	Process for the free radical polymerization of ethylenically unsaturated monomers in an aqueous medium
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JPS63218702A (ja)	1988-09-12	高吸水性ポリマ−の製造方法
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JP3005034B2 (ja)	2000-01-31	塩化ビニル系重合体の製造方法
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