PL160363B1 - Method of obtaining a microelements containing liquid fertilizer - Google Patents
Method of obtaining a microelements containing liquid fertilizerInfo
- Publication number
- PL160363B1 PL160363B1 PL1989280618A PL28061889A PL160363B1 PL 160363 B1 PL160363 B1 PL 160363B1 PL 1989280618 A PL1989280618 A PL 1989280618A PL 28061889 A PL28061889 A PL 28061889A PL 160363 B1 PL160363 B1 PL 160363B1
- Authority
- PL
- Poland
- Prior art keywords
- microelements
- potassium
- liquid fertilizer
- solution
- acid
- Prior art date
Links
- 239000003337 fertilizer Substances 0.000 title claims abstract description 25
- 238000000034 method Methods 0.000 title claims abstract description 19
- 239000007788 liquid Substances 0.000 title claims abstract description 15
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000011777 magnesium Substances 0.000 claims abstract description 7
- 102000011782 Keratins Human genes 0.000 claims abstract description 5
- 108010076876 Keratins Proteins 0.000 claims abstract description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000002253 acid Substances 0.000 claims abstract description 5
- 238000005904 alkaline hydrolysis reaction Methods 0.000 claims abstract description 5
- 238000000354 decomposition reaction Methods 0.000 claims abstract description 5
- 239000001095 magnesium carbonate Substances 0.000 claims abstract description 5
- 235000014380 magnesium carbonate Nutrition 0.000 claims abstract description 5
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims abstract description 5
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims abstract description 5
- 238000004519 manufacturing process Methods 0.000 claims abstract description 5
- 239000011591 potassium Substances 0.000 claims abstract description 5
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 5
- 235000021120 animal protein Nutrition 0.000 claims abstract description 4
- 239000003531 protein hydrolysate Substances 0.000 claims abstract description 4
- 150000003839 salts Chemical class 0.000 claims abstract 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 7
- 239000010949 copper Substances 0.000 claims description 7
- 239000011572 manganese Substances 0.000 claims description 6
- 239000011701 zinc Substances 0.000 claims description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 5
- 229910052750 molybdenum Inorganic materials 0.000 claims description 5
- 239000011733 molybdenum Substances 0.000 claims description 5
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 5
- 229910021538 borax Inorganic materials 0.000 claims description 4
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 4
- 239000011702 manganese sulphate Substances 0.000 claims description 4
- 235000007079 manganese sulphate Nutrition 0.000 claims description 4
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 4
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 4
- 239000002699 waste material Substances 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 2
- 239000004327 boric acid Substances 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000011790 ferrous sulphate Substances 0.000 claims description 2
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 2
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 2
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims description 2
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 claims description 2
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- 229910000365 copper sulfate Inorganic materials 0.000 claims 1
- 230000029087 digestion Effects 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 150000002751 molybdenum Chemical class 0.000 claims 1
- 229960001763 zinc sulfate Drugs 0.000 claims 1
- 239000000243 solution Substances 0.000 abstract description 10
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 abstract description 2
- 239000011654 magnesium acetate Substances 0.000 abstract description 2
- 235000011285 magnesium acetate Nutrition 0.000 abstract description 2
- 229940069446 magnesium acetate Drugs 0.000 abstract description 2
- 108010009736 Protein Hydrolysates Proteins 0.000 abstract 1
- 239000003637 basic solution Substances 0.000 abstract 1
- 235000015097 nutrients Nutrition 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000011575 calcium Substances 0.000 description 4
- 230000001681 protective effect Effects 0.000 description 4
- 239000011686 zinc sulphate Substances 0.000 description 4
- 235000009529 zinc sulphate Nutrition 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005530 etching Methods 0.000 description 3
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical class [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 3
- 229920000137 polyphosphoric acid Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 238000003898 horticulture Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229920001184 polypeptide Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 102000004196 processed proteins & peptides Human genes 0.000 description 2
- 108090000765 processed proteins & peptides Proteins 0.000 description 2
- 239000004328 sodium tetraborate Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910017234 MnSO4 H2O Inorganic materials 0.000 description 1
- 229910004619 Na2MoO4 Inorganic materials 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000004720 fertilization Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 229940099596 manganese sulfate Drugs 0.000 description 1
- ISPYRSDWRDQNSW-UHFFFAOYSA-L manganese(II) sulfate monohydrate Chemical compound O.[Mn+2].[O-]S([O-])(=O)=O ISPYRSDWRDQNSW-UHFFFAOYSA-L 0.000 description 1
- 239000011785 micronutrient Substances 0.000 description 1
- 235000013369 micronutrients Nutrition 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 231100000255 pathogenic effect Toxicity 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011684 sodium molybdate Substances 0.000 description 1
- 235000015393 sodium molybdate Nutrition 0.000 description 1
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
Landscapes
- Fertilizers (AREA)
Abstract
Description
Przedmiotem wynalazku jest sposób wytwarzania nawozu ciekłego, przydatnego do wykorzystania zarówno w rolnictwie jak i w warzywnictwie i ogrodnictwie, charakteryzującego się zawartością składników nawozowych w formie organicznej jak i nieorganicznej a ponadto wykazujący własności ochroniarskie.The subject of the invention is a method of producing a liquid fertilizer, useful both in agriculture and in horticulture and horticulture, characterized by the content of fertilizing components in organic and inorganic form, and also showing protective properties.
Stosowanie nawozów w formie płynnej wykazuje szereg zalet w stosunku do nawozów konwencjonalnych. Przede wszystkim nawozy w tej postaci charakteryzują się wyższym stopniem wykorzystania składników nawozowych a ponadto można je w sposób bardzo równomierny rozprowadzić na powierzchni gleby lub pod jej powierzchnią przy użyciu urządzeń mechanicznych. W operacji tej można praktycznie wyeliminować udział pracy fizycznej, co jest głównym utrudnieniem w stosowaniu nawozów konwencjonalnych.The use of liquid fertilizers has a number of advantages over conventional fertilizers. First of all, fertilizers in this form are characterized by a higher degree of utilization of nutrients and, moreover, they can be very evenly distributed over the soil surface or under its surface using mechanical devices. In this operation, manual labor can be virtually eliminated, which is the main difficulty in using conventional fertilizers.
Znany jest z publikacji J. Machej i współpracowników /Przemysł Chemiczny 1980,2,102 102/ sposób wytwarzania nawozu ciekłego na bazie ekstrakcyjnego kwasu polifosforowego uzyskanego przez zatężenie ekstrakcyjnego kwasu fosforowego w wyparce z palnikiem tunelowym. Zatężony do zawartości 72-76% mas. P2O5 / w tym ok. 50% w formie nie orto/kwas polifosforowy w sposób ciągły jest neutralizowany wodą amoniakalną i po rozcieńczeniu wodą uzyskuje się ciekły nawóz typu 10:34:0 lub 11:34:0. Znany jest z raportu pt. Fluid Fertilizers, wydanego przez Tennessee Valley Authority National Fertilizer Development Center, Alabama 1984, sposób wytwarzania i stosowania nawozów wapniowych w postaci płynnej, uzyskanych przez rozprowadzenie w wodzie węglanu wapniowego z dodatkiem czynnika stabilizującego zawiesinę. Znany jest również z tego samego środka wpływ substancji organicznych typu ligninowego i podobnych na wzrost wykorzystania i zwiększenia czasu oddziaływania składników nawozowych przez rośliny. Związki te w glebie tworzą trwałe połączenia z azotem i innymi składnikami nawozowymi, co przedłuża ich działanie, a ponadto wpływa na zmniejszenie ogólnych strat składników nawozowych na skutek wymywania.It is known from the publication of J. Machej et al. / Przemysł Chemiczny 1980, 2, 102, 102 / a method of producing a liquid fertilizer based on extractive polyphosphoric acid obtained by concentration of extractive phosphoric acid in an evaporator with a tunnel burner. Concentrated to 72-76 wt%. P2O5 / of which approx. 50% in the form of non-ortho / polyphosphoric acid is continuously neutralized with ammonia water and, after dilution with water, a liquid fertilizer of the 10: 34: 0 or 11: 34: 0 type is obtained. He is known from the report entitled Fluid Fertilizers, issued by the Tennessee Valley Authority National Fertilizer Development Center, Alabama 1984, a method of producing and using liquid calcium fertilizers, obtained by dispersing calcium carbonate in water with the addition of a suspension stabilizing agent. It is also known from the same agent the influence of organic substances of the lignin type and the like on the increase in the use and time of the impact of fertilizing components by plants. These compounds in the soil form permanent connections with nitrogen and other nutrients, which prolongs their action, and also reduces the overall loss of nutrients due to leaching.
Przedstawiony sposób wytwarzania ciekłego nawozu wysokoskoncentrowanego jest jednak niedogodny z uwagi na energochłonny sposób wytwarzania kwasu polifosforowego. Przedstawiony sposób uzyskiwania i stosowania płynnego nawozu wapniowego lub stosowanie substancji organicznych cechuje się ograniczonym działaniem nawozowym i nie jest możliwe bez utraty własności nawozowych tych produktów, wprowadzanie dodatkowych składników nawozowych lub preparatów likwidujących oddziaływanie patogenne.However, the presented method of producing a highly concentrated liquid fertilizer is inconvenient due to the energy-consuming method of producing polyphosphoric acid. The presented method of obtaining and using liquid calcium fertilizer or the use of organic substances is characterized by a limited fertilizing effect and it is not possible without losing the fertilizing properties of these products, adding additional fertilizing ingredients or preparations eliminating the pathogenic effect.
Ograniczeń i niedogodności wymienionych sposobów można uniknąć stosując sposób według wynalazku, w którym uzyskuje się ciekły nawóz wieloskładnikowy zawierający poza makro- i mikroelementami nawozowymi również wapń oraz substancję organiczną. Uzyskany według sposobu nawóz wykazuje ponadto własności ochroniarskie. Istotą wynalazku jest sposób wytwarzania nawozu ciekłego o wielostronnym oddziaływaniu nawozowym zawartych składników zarówno w formie organicznej jak i nieorganicznej oraz ochroniarskim na patogeny. Stosowanie nawozu w formie płynnej wykazuje szereg zalet w stosunku do nawozów konwencjonalnych. Przede wszystkim nawóz w tej postaci charakteryzuje się wyższym stopniem wykorzystania składników nawozowych przez rośliny.The limitations and disadvantages of the mentioned methods can be avoided by using the method according to the invention, in which a liquid multi-component fertilizer is obtained, containing, in addition to the fertilizing macro- and microelements, also calcium and an organic substance. Moreover, the fertilizer obtained according to the method shows protective properties. The essence of the invention is a method of producing a liquid fertilizer with a multilateral fertilization effect of the contained ingredients, both in an organic and inorganic form, and a protective effect on pathogens. The use of liquid fertilizer has a number of advantages over conventional fertilizers. First of all, the fertilizer in this form is characterized by a higher degree of utilization of nutrients by plants.
Przedstawiony według wynalazku produkt posiada więc korzystne wszechstronne działanie agrotechniczne w stosunku do wzrostu i ochrony roślin, a niektóre z tych cech wykazują działanie synergetyczne.The product presented according to the invention therefore has an advantageous all-round agrotechnical effect with respect to plant growth and protection, some of these features having a synergistic effect.
Sposób wytwarzania środka według wynalazku polega na tym, że w organicznym hydrolizacie białkowym otrzymanym przez hydrolizę alkaliczną białka zwierzęcego keratyny rozpuszcza się roztwór uzyskany przez rozkład prażonego magnezytu kwasem octowym, stosując dla rozkładu do 10% nadmiar kwasu w stosunku do normy stechiometrycznej otrzymywania octanu magnezowe^ wprowadzając w tej formie do bazowego roztworu od 0,1 do 25g Mg/dm3, a następnie wprowadza się mikroelementy w formie soh do stężeń od 0,1 do 5g FeMm3 od 0,1 do 5g Cu/dm3, od 0,1 do 5g Zn/dm3 od 0,1 do 2g Mo/dm3, od 0,1 do 2g Mn/dm3 i 0,01 do 15 g K/dm3, przy czym uzyskany klarowny roztwór nawozowy zawiera ponadto składniki hydrolizatu białkowego w formie polipeptydowych połączeń w ilości od 50 do lOOg N/dm3 od 4 do lOg PzOs/dm oraz od 30 do 40g CaO/dm3.A process for preparing the composition according to the invention consists in that in an organic hydrolyzate of protein obtained by alkaline hydrolysis of animal protein keratin dissolved solution obtained by the decomposition of the calcined magnesite acetic acid, using for distribution to 10% excess of acid relative to the normal stoichiometric preparation of ethyl ma g nezowe ^ p in the ditch d addressed in the d-form of a solution of the azo b d d of 0.1 Mg 25 g / dm 3, and then in seq ę ditch p d t o for trace elements in the form of soh d st E with ñ 0 , 1 to 5g FeMm 3 from 0.1 to 5g Cu / dm 3, o d 0.1 d o 5g Zn / dm 3 o d 0, 1 d o 2g M o / d m 3, o d 0.1 d o 2 g M n / d m 3 and 0.01 to 15 g K / dm3, the obtained clear fertilizing solution also contains protein hydrolyzate components in the form of polypeptide combinations in the amount of 50 to 100 g N / dm 3 4 to 10 g PzOs / dm and from 30 to 40g CaO / dm 3 .
Okazało się że środek posiada korzystne własności jeżeli mikroelementy wprowadza się w następującej postaci: żelazo w postaci siarczanu miedzi, cynk w postaci siarczanu cynku, bor w postaci boranu sodu lub kwasu borowego, molibden w postaci soli molibdenianowej lub odpadowego roztworu molibdenu z procesu trawienia tego pierwiastka, mangan w postaci siarczanu manganu oraz potas w postaci wodorotlenku potasu lub chlorku potasu.It turned out that the agent has favorable properties if the microelements are introduced in the following form: iron in the form of copper sulphate, zinc in the form of zinc sulphate, boron in the form of sodium borate or boric acid, molybdenum in the form of a molybdate salt or molybdenum waste solution from the etching process of this element , manganese in the form of manganese sulfate and potassium in the form of potassium hydroxide or potassium chloride.
Nieoczekiwanie okazało się, że środek posiada własności synergetyczne i ochroniarskie zawartego octanu magnezowego i połączeń polipeptydowych, a także optymalną przyswajalność składników nawozowych przy zawartoścc: 60-80 g/drn3N, 4.5 g/dm3 P2O5, 8 g/dm3 K2O, l,2g/dm3 Mg 35g/dm3 Ca° 2g/dm3Fe 2 g/dm3 Cu 2g/dm3 Zn,lg/dm3B, lg/dm3 Mo, lg/dm3 Mn.Unexpectedly, it turned out that the agent has synergistic and protective properties of the contained magnesium acetate and polypeptide combinations, as well as optimal bioavailability of nutrients at the content of: 60-80 g / dm 3 N, 4.5 g / dm 3 P2O5, 8 g / dm3 K2O, l , 2g / dm 3 Mg 35g / d m 3 Ca ° 2g / dm 3F e 2 g / dm 3 Cu 2g / d m 3 Z n, l g / dm 3 B , lg / d m 3 M o, lg / dm 3 Mn.
Proces technologiczny przeprowadza się w ten sposób, że prowadzi się alkaliczną hydrolizę keratyny mlekiem wapiennym. Uzyskuje się hydrolizat zawierający między innymi 60%120g N/dm , 5-7 gp2O5/dm3 oraz 25-50g CaO/dm3. HydroHzat ten jest podstawowym składnikiem nawozu ciekłego, w którym rozpuszcza się ponadto: produkt reakcji rozkładu prazonego magnezytu kwasem octowym dodawanym w dości od 0,1 do 25g Mg/dm3 w przeliczeniu na ten pierwiastek, od 0^1 do 5g Fe/dm3, miedzi i cynku dodawanych w postaci soli siarczanowych, od 0,1 do 2g Mo/dm3 dodawanego w postaci soli molibdenianowej lub odpadowego kwaśnego roztworu molibdenu z procesu trawienia tego metalu oraz od 0,1 do 2g Mn/dm3 dodawanego w postaci siarczanu manganu. Następnie wprowadza się potas w ilości od 0,1 do 15g K2O/dm3 w postaci soń potasowej lub wodorottenku.The technological process is carried out in such a way that the alkaline hydrolysis of keratin with lime milk is carried out. Obtained hydrolyzate having, inter alia, 120g of 60% N / m, 5 P 2 O 5 -7 g / dm 3, and 25 - 50g Ca O / d m 3. Hy roHzat d is the d joints y m of the liquid fertilizer components, which are dissolved are: a reaction product of the decomposition is injured by p nez g of acetic acid there s d d y m avant The quantities of d of d of 0.1 Mg 25 g / l 3 in terms of this element, from 0 ^ 1 to 5g Fe / dm3, copper and zinc added in the form of sulphate salts, from 0.1 to 2g Mo / dm3 added as a molybdate salt or waste acid molybdenum solution from the etching process of this metal and from 0.1 to 2 g Mn / dm 3 added in the form of manganese sulphate. Potassium is then introduced in an amount of from 0.1 to 15 g K2 O / m 3 d p stand to Son l of potassium wodorotten b k u.
Wytworzony według wynalazku roztwór jest gotowym produktem o gęstości od 1 do 1,22 kg/dm3, pH 6,5 do 8,5 tepko&i od 10 do 50 cp. Wylewalność gotowego produktu wynosi od 98 do 100 %. Produkt ten konfekcjonuje się do opakowań jednostkowych. Sposób wytworzenia objaśniono na następujących przykładach:The resulting solution of the invention is a finished product having a density of from 1 to 1.22 kg / dm 3, pH 6.5 to 8.5 and tepko & d of 10 to 50 cp. In ylew al wear Æ g Otow g of product away and d of 98 to 100%. This product is packed into unit packages. The production method is explained in the following examples:
Przykład 1. Do reaktora wprowadzono roztwór uzyskany przez rozkład 20,64 kg prażonego magnezytu bezwodnym kwasem octowym w ilości 67,65 kg i rozpuszczono go w hydrolizacie białkowym w ilości 223 dm3 otrzymanym przez hydrolizę alkaliczną białka zwierzęcego - keratyny. Następnie do reaktora wprowadzono 18,6 dm3 odpadowego kwaśnego roztworu molibdenianu z trawienia tego metalu oraz 10 kg siarczanu żelazawego /FeSO4 7H2O/, 8kg siarczanu miedzi /CuSCM 5H2O/, 9kg siarczanu cynku /ZnSO-ł 7H2O/. 9kg boraksu /NajB.łCb IOH2O/ i 3 kg siarczanu magnezu /MnSC4 H2O/. Po dokładnym wymieszaniu do rozpuszczenia wprowadzonych składników, wprowadzono lOkg KOH i poddano homogenizacji przez intensywne mieszame do petaego rozpuszczema. W wyn&u uzyskano 1 m3 klarownego nawozuExample 1. The solution obtained by decomposing 20.64 kg of calcined magnesite with anhydrous acetic acid in the amount of 67.65 kg was introduced into the reactor, and it was dissolved in the protein hydrolyzate in the amount of 223 dm3 obtained by the alkaline hydrolysis of the animal protein - keratin. Then 18.6 dm3 of the waste acid molybdate solution from etching this metal and 10 kg of ferrous sulphate (FeSO4 7H2O), 8 kg of copper sulphate (CuSCM 5H2O), 9 kg of zinc sulphate (ZnSO-7H2O) were introduced into the reactor. 9 kg of borax / EXCLUSIVE Cb IOH2O / and 3 kg of magnesium sulphate / MnSC4 H2O /. After thorough mixing to dissolve the components listed introduced lOkg KOH and were homogenised for intens mieszame s Century D p etaego rozpuszczema. In y N & obtained in 1 m3 of fertilizer clear
160 363 ciekłego z mikroelementami o gęstości 1,17 kg/dm , pH=8, lepkości 33 cP, wylewności 99,5 %. W 1 dm3 nawozu zawarte jest 54g N, 4g P2O5, 8kg K2O, 12,5g Mg, 35g CaO, 2g Fe, 2g Cu, 2g Zn, lg B, lg Mo, lg Mn.160 363 liquid with micronutrients, density 1.17 kg / dm, pH = 8, viscosity 33 cP, flow rate 99.5%. 1 dm 3 of fertilizer contains 54g N, 4g P2O5, 8kg K2O, 12.5g Mg, 35g CaO, 2g Fe, 2g Cu, 2g Zn, lg B, lg Mo, lg Mn.
Przykład Π. Do reaktora wprowadzono roztwór uzyskany przez rozkład 16,5kg prażonego magnezytu bezwodnym kwasem octowym w ilości 54,12kg i rozpuszczono go w 180 dm3 h^rohzatu białkowego. Następnie do reaktora wprowadzono 2 kg moliMenianu sodu /Na2MoO4 2H2O/, 6,4kg siarczanu miedzi /CuSOą 5H2O/, 7,2 kg siarczanu cynku /ZnSOą 7H2O/, 29kg boraksu /Na2B4Ch IOH2O/, oraz 2,4kg siarczanu manganu /MnSO4 H2O/. Po wymieszaniu do rozpuszczenia składników stałych wprowadzono lOkg soli potasowej /KCk. Mieszaninę poddano ponownie intensywnemu mieszaniu aż do uzyskania klarownego roztworu ciekłego o gęstości M4 k^m3, pH = 8,b kpkość 9 cP wytewno^ ,5% . W 1 dm3 nawozu zawarte jest 56g N, 6,5g K2O, lOg Mg, 36g CaO, l,6g Fe, l,6g Cu, l,6g Zn, 0,8g B, 0,8g Mo, oraz 0,8g Mn.Example Π. To the reactor was added a solution obtained by decomposition of 16,5kg of calcined magnesite anhydrous acetic acid in an amount of 54,12kg and dissolved in 180 d m 3 h ^ rohzatu b Lk and a detailed g o. P N ASTE is not of the reactor d p d trench bride, 2 kg moles of sodium / Na2MoO4 2H2O /, 6.4 kg of copper sulphate / CuSO4 5H2O /, 7.2 kg of zinc sulphate / ZnSO4 7H2O /, 29 kg of borax / Na2B4Ch IOH2O /, and 2.4 kg of manganese sulphate / MnSO4 H2O /. After mixing, 10 kg of potassium salt / KCk was introduced until the solids were dissolved. The mixture was again vigorously stirred to obtain a clear liquid solution of the Estonian COG g of 4 M k ^ m 3, pH = 8, bk p th wheel 9 cP wytewno R, 5%. 1 d m 3 of fertilizer contains 56g N, 6.5g K2O, 10g Mg, 36g CaO, 1.6g Fe, 1.6g Cu, 1.6g Zn, 0.8g B, 0.8g Mo, and 0, 8g Mn.
Zakład Wydawnictw UPRP. Nakład 90egz. Cena 10 000 złThe Publishing House of the Polish Patent Office. Mintage 90 copies. Price: PLN 10,000
Claims (2)
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL1989280618A PL160363B1 (en) | 1989-07-14 | 1989-07-14 | Method of obtaining a microelements containing liquid fertilizer |
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| PL1989280618A PL160363B1 (en) | 1989-07-14 | 1989-07-14 | Method of obtaining a microelements containing liquid fertilizer |
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| PL280618A1 PL280618A1 (en) | 1991-01-28 |
| PL160363B1 true PL160363B1 (en) | 1993-03-31 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016195518A1 (en) | 2015-05-29 | 2016-12-08 | HARCIAREK, Tomasz | A process for producing an organic-mineral fertilizers having a biostimulating activity and fertilizers produced by this process |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016195518A1 (en) | 2015-05-29 | 2016-12-08 | HARCIAREK, Tomasz | A process for producing an organic-mineral fertilizers having a biostimulating activity and fertilizers produced by this process |
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| PL280618A1 (en) | 1991-01-28 |
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