PL162043B2 - Softening agent - Google Patents

Abstract

Softening agent containing emulsifiers, oils, and products obtained by attaching ethylene oxide to alcohols and acids, characterized in that it contains from 35.0 to 55.0 parts by weight of hydrogenated derivative of a distillation fraction of crude oil containing 71.2 to 75.8 parts by weight of paraffin-naphthalene hydrocarbons, 23.7 to 28.0 by weight of aromatic hydrocarbons and 0.4 to 0.5 by weight of resins and other products, and also contains from 7.5 to 10.0 parts by weight of nonylphenol oxyethylenated with approximately 7 moles of ethylene oxide, 7.5 to 10.0 parts by weight of oleinic alcohol oxyethylenated with approximately 3 moles of ethylene oxide, 15.0 to 20.0 parts by weight of a product which is a mixture of 60.0 parts by weight of stearinic amine quaternized with dimethyl sulphate and oxyethylenated with approximately 8 moles of ethylene oxide, 30 parts by weight of the product of oxyethylating 1 mole of a mixture of plant-derived unsaturated and saturated fatty acids with carbon chain length C14-C22 with approximately 7 moles of ethylene oxide, and 10 parts by weight of lauryl alcohol oxyethylenated with approximately 4 moles of ethylene oxide, and also 15.0 to 20.0 parts by weight of stearinic acid amide oxyethylenated with approximately 7 moles of ethylene oxide and cationized with acetic acid and/or 15.0 to 20.0 parts by weight of stearinic acid oxyethylenated with approximately 7 moles of ethylene oxide with the addition of 3.0 to 5.0 parts by weight of emulsion stabilizer in the form of nonylphenol oxyethylenated with approximately 3 moles of ethylene oxide and water in a quantity of 0.5-1.0 dm<3> per 100 kg of finished product.

Description

The present invention relates to a humus-like softening agent intended to be used in textile applications for finishing flat articles such as woven and knitted fabrics. Many softeners are known for use in the textile industry. As softeners, anionic, cathoneic, nuphotorinic, non-ionic agents are used. 1 emuUsyJnl For the softening of nuous substances, polerylate dispersions, dispersions of natural and synthetic waxes, as well as stilon nuouss are included.

As emollients, mainly Jlaranowznl vegetable oils, sulfonates of fatty alcohols, sulfosuccinates, fatty acids and their amino derivatives, as well as their oxyethylated vegetable oils, are used. Some of the known and used softeners in the textile industry are unstable, easily decompose, especially at elevated temperatures, cannot be used in a wide range of environmental pH, especially problems arise when training wool fibers. Some of the known agents are sparingly soluble in water and require warming. Ponaato used agents always give a satisfactory softening effect to the product. After the termoo saablzacc! Process, most domestic softeners lower the abrasion resistance of the above-mentioned dyes.

During trials and tests, it turned out that the use of a new oil base in a wetting agent, which has not been used for the purpose so far, gives an unexpectedly good tamping effect on various types of fibers, eliminating many drawbacks of known agents.

The essence of the invention is the use of a hydrated derivative of a certain distillation fraction - crude oil, which has not been used so far for this purpose, and the appropriate proportion of pine used in the subsides.

The agent according to the invention presses from 35.0 to 55.0 parts by weight of the hydrogenated distillation fraction of crude oil having in its composition from 71.2 to 75.0 parts by weight

162,043 paraffin-naphthalene hydrocarbons, from 23.7 to 28.0 parts by weight of aromatic hydrocarbons, and from 0.4 to 0.7 parts by weight of resins and other products obtained from the processing of crude oil fractions, furthermore contains 7.5-10 0 parts by weight of ethylene oxide of about 7 y) o.ayi nonylphenol ethylene oxide, 7.5 to 10.0 parts by weight of ethylene oxide ethylene of about 3 moles of Howe alcohol, 15.0-20.0 parts by weight of the product, which is a mixture of 60 parts by weight of quaternary sulfate oxyethylene about 8% ethylene oxide with stearic 30 parts by weight of oxyethylene oxide about 7 pieces, ethylene oxide 1 mole of a mixture of saturated and unsaturated fatty acids of vegetable origin with a carbon chain length - C22, 10 parts by weight of oxylethylene oxide about 4 moles % of ethylene oxide of low alcohol, as well as 15.0 to 20.0 parts by weight of oxyethylated acid, about 7 parts, ethylene oxide, amide of stearic acid, ca'tlnτylated g with acetic acid and / or 15.0 to 20.0 parts by weight of oxyethylene glycol with about 7 moles of ethylene oxide steayic acid with the addition of 3.0 to 5.0 parts by weight of an ethoxylated ernusion stabilizer of about 3 milam. 3 nonylpholyl ethylene oxide and water in the amount of 0.5-1.0 dm3 per 100 kg of the finished product,

In the composition according to the invention, a new oil base was used for the finishing of textiles, which is a product of hydrogenation / hydrotreatment of oils obtained from crude oil. The use of a new base - hydrogenated petroleum derivative and the appropriate selection of the applied subssannc1, which are products of joining ethylene oxide to alcohols and tonic acids, gives the agent in the appropriate form, easily emulating in water, while the functional properties of the substances used improve the softening effect thanks to the synerge ^ ιμιιν action these ingredients. The hydrogenated petroleum fraction used in the center is easily mixed with the remaining components, while the addition of an appropriate amount of water is intended only to dilute the agent, but also to clarify it. The ilacilie agent used lowers the coefficient of friction.

Table 1 shows the results of measurements made in accordance with the specific resistance PN-80 / P-04871, wherein the welding measures were at room temperature when applied ^wet-7 0% and seq ^ę suszmu then at 13 O C for 3 minutes.

Taolica No. 1

Examined

Center

Bath concentration in padding IJ 3

Field fabric! PET fabric

---- γ ---- C -------- 'f ------------ ^h _ ^ ------------ T-- ------------ T-.

khaki color 1 navy blue color black J burgundy color

Raw fabric without preparacc1

f.aZ2

9.5 x 10

9.9 x 10

9.9 x 10 x 10

Zerostat from Ciba-Geigy

The agent according to the invention is called 01mitex H

The agent according to the invention is called 01yltex HR

The agent according to the invention is called 01mitex HR-1

7.7 x 10

3.1 x 10 *

1.7 x 10

7.5 x 10

1.8 x 10

2.5 x 10 *

3.3 x 10

1.0 x 10

2.7 x 10

1.7 x 10

The agent according to the invention easily forms emulsions which can be diluted with warm water.

cold, in any volumetric ratio, it is stable over time, resistant to technological conditions, i.e. hard water, alkaline and acidic environment within the pH limits commonly used in textile finishing, it gives a very good softening effect, one4

162 043 sometimes has antistatic properties and is easily washable from the fiber. The agent of the invention is illustrated by the following embodiments, in which parts are parts by weight and temperature is given in degrees Celsius.

EXAMPLE 1 A mixture of 7.5 parts ethylene oxide ethylene oxide oleyl alcohol is prepared initially and then 15 parts ethylene oxide with approximately 7 mlam is added with continuous stirring. of ethylene oxide, stearic acid amide, catlonylated with acetic acid and 15 parts of the product, which is a mixture of 60% by weight of the dimelyl sulfcaneam, oxyethylene and carbonated with about 8 moles of ethylene oxide, stearic amine, 30 parts of the product of 1-ethylene oxide with about 7 moles of ethylene mole of a mixture of saturated and unsaturated fatty acids of vegetable origin with a carbon chain length of C ^ - Cj ¹ 10 parts lksyetylθoowanθgl about 4 moles of t-Enku et ^y ene ^and able only lauryt-ol ^h ^ owec. The reaction wa zal ^^ ^d to g ^r Zan ^{d e} o ^t I ^ i ^ ^ r rounds ^{s 60} ~ ⁷⁰ ° hydrogenated petroleum hereinafter Hydrorafmae ^ m H-5 in an amount of 54.0 parts. After thorough mixing, it is allowed to cool to room temperature and give the so-called clarifying water - preferably condensate - in the amount of 1000 cm per 100 kg of product. After mixing, the product is a beige paste, which after some time turns into a sticky, cloudy yellow color. The concentration of the active ingredient in the compositions according to the invention is approximately S9%. The agent obtained in this way is used, inter alia, for softening flat products made of synthetic fibers by padding.

Example II. By following the method described in Example 1, the composition of Example 2 additionally comprises a nuush stabilizer.

First, 7.5 parts of ethylene oxide with about 7 moles of nonylphenol ethylene oxide are mixed with 7.5 parts of oxyethylated with about 3 moles. of ethylene oxide of the allyl alcohol, then 5 parts of an emulsion stabilizer in the form of an oxytyloxylated with about 3 moles of nonylphenol ethylene oxide. Then 15 parts of ethylene oxide of about 7 moles of stearic amide catlonated with acetic acid and 15 parts of the product consisting of a mixture of 60 parts of sulfur-quaternized oxyethyl dimylated with about 8 moles of the ethylene oxide of stearyl amine are added, 30 parts of the product of oxyethylene are oxidized. moles of ethylene oxide 1 mole of a mixture of saturated and unsaturated fatty acids of vegetable origin with a carbon chain length of C., - C ?? 1 10 parts of ethylene oxide with about 4 moles of ethylene oxide lauryl alcohol. The whole thing is heated to a temperature of 50-70 HydrorafμβΙθιιι H-5 in the amount of parts. After it is thoroughly allowed to cool down to room temperature, 1000 cm of clarifying water (preferably condensate) is added, 100 kg of product. After mixing, the product becomes a temporary paste and then turns into a sticky, cloudy yellow liquid. The active ingredient content of the product is approximately 99%. The product thus obtained is used in a manner known per se for drenching a flat worm

Example III. 7.5 parts of oxyethylene of about 7 parts of ethylene oxide of nonylphenol are mixed with 7.5 parts of oxyethylene of about 3 parts of ethylene oxide of alcohol. Then 5 parts of emuUsJl stabilizer are added in the form of an oxyitylated with about 3 moles of nonylphenol ethylene ene. Thereafter, 15 parts of ethylene oxide of stearic acid ethylene, 15 parts of stearic acid ethylene oxide and 15 parts of the product, which is 60 parts of doummlyl quaternary sulfate, ethoxylated with about 8 moles of ethylene oxide, stearic amite, 30 parts of the product of oxyethylated with about 7 moles of moles ethylene oxide, saturated and, here, saturated of vegetable origin with a carbon chain length of C 1-22, ¹ part of oxyethylated with about 4 moles of ethylene oxide of laurel alcohol. The reaction treated with ^t o d dgrzanym ^the temperature ^of 0-70 ° ^{6 H} ydrorahnaMm H-5 in an amount of 49 ^{5 c} ye. ^Po (finely ^ i ^, and ^^ conjunction mixture is allowed to cool to room temperature, 1 is added to the so-called. Sparing water / ^her best liondensat / cm at 500 ^J to ^{100 k} g proiiuktu. Owstaje ^P liquid is thick, viscous, almost A clear yellow color, with an active ingredient finish of about 99.5%, and is useful for softening flat products in this manner.

Department of Publishing of the UP RP. Circulation of 90 copies. Price: PLN 10,000

Claims (1)

Patent claim A softening agent containing emulsifiers, oxygenates, ethylene oxide addition products, dt of alcohols and acids, characterized in that it contains from 35.0 to 55.0 parts by weight of the hydrated derivative of the crude oil distillation fraction having in its composition from 71.2 to 75.8 parts by weight of paraffin-naphthalene hydrocarbons, from 23.7 to 28.0 parts by weight of aromatic hydrocarbons and from 0.4 to 0.5 parts by weight of resins and other products, and further contains 7.5 to 10.0 parts by weight of ethoxylated with about 7 moles of oxide nonylphenol ethylene, 7.5 to 10.0 parts by weight ethoxylated with about 3 milli ethyl alcohol ethylene, 15.0 to 20.0 parts by weight of the product being a mixture of 60.0 parts by weight dimethyl quaternary oxide ethoxylated with about 8 moles of ethylene oxide of stearic amine, 30 parts by weight of the product ethoxylate about 7 moles of ethylene oxide with 1 mole of a mixture of saturated and unsaturated fatty acids of vegetable origin Ci carbon chain - C22.10 parts by weight of oxyethylated with about 4 moles of ethylene oxide of a polyurethane alcohol, as well as 15.0 to 20.0 parts by weight of oxyethylene of about 7 moles of ethylene oxide. of stearic acid with acetic acid and / or 15.0 to 20.0 parts by weight of ethylene oxide of stearic acid with about 7 moles of ethylene oxide with the addition of 3.0 to 5.0 parts by weight of an emulation stabilizer in the form of an oxyethylene about about 3 moles of nonylphenol ethylene oxide and water in the amount of 0.5-1.0 dm3 per 100 kg of the finished product. * ♦ *