PL2285930T3 - Azeotropowe i azeotropo-podobne kompozycje Z-1,1,1,4,4,4-heksafluoro-2-butenu - Google Patents

Azeotropowe i azeotropo-podobne kompozycje Z-1,1,1,4,4,4-heksafluoro-2-butenu

Info

Publication number
PL2285930T3
PL2285930T3 PL09767799T PL09767799T PL2285930T3 PL 2285930 T3 PL2285930 T3 PL 2285930T3 PL 09767799 T PL09767799 T PL 09767799T PL 09767799 T PL09767799 T PL 09767799T PL 2285930 T3 PL2285930 T3 PL 2285930T3
Authority
PL
Poland
Prior art keywords
azeotrope
hexafluoro
azeotropic
butene
compositions
Prior art date
Application number
PL09767799T
Other languages
English (en)
Inventor
Mark L Robin
Original Assignee
Du Pont
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=40929514&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=PL2285930(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Du Pont filed Critical Du Pont
Publication of PL2285930T3 publication Critical patent/PL2285930T3/pl

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02—Materials undergoing a change of physical state when used
    • C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
    • C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
    • C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
    • C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02—Materials undergoing a change of physical state when used
    • C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
    • A—HUMAN NECESSITIES
    • A62—LIFE-SAVING; FIRE-FIGHTING
    • A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A—HUMAN NECESSITIES
    • A62—LIFE-SAVING; FIRE-FIGHTING
    • A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/0028—Liquid extinguishing substances
    • A62D1/0057—Polyhaloalkanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/142—Compounds containing oxygen but no halogen atom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
    • C08J9/145—Halogen containing compounds containing carbon, halogen and hydrogen only only chlorine as halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
    • C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/149—Mixtures of blowing agents covered by more than one of the groups C08J9/141 - C08J9/143
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/30—Materials not provided for elsewhere for aerosols
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/10—Components
    • C09K2205/108—Aldehydes or ketones
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/10—Components
    • C09K2205/11—Ethers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/10—Components
    • C09K2205/12—Hydrocarbons
    • C09K2205/126—Unsaturated fluorinated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/32—The mixture being azeotropic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Physics & Mathematics (AREA)
  • Combustion & Propulsion (AREA)
  • Thermal Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • Dispersion Chemistry (AREA)
  • Fire-Extinguishing Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Detergent Compositions (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
PL09767799T 2008-06-20 2009-06-19 Azeotropowe i azeotropo-podobne kompozycje Z-1,1,1,4,4,4-heksafluoro-2-butenu PL2285930T3 (pl)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US7417808P 2008-06-20 2008-06-20
US7417908P 2008-06-20 2008-06-20
US7418108P 2008-06-20 2008-06-20
PCT/US2009/047912 WO2009155490A1 (en) 2008-06-20 2009-06-19 Azeotropic and azeotrope-like compositions of z-1,1,1,4,4,4-hexafluoro-2-butene
EP09767799.1A EP2285930B1 (en) 2008-06-20 2009-06-19 Azeotropic and azeotrope-like compositions of z-1,1,1,4,4,4-hexafluoro-2-butene

Publications (1)

Publication Number Publication Date
PL2285930T3 true PL2285930T3 (pl) 2016-07-29

Family

ID=40929514

Family Applications (1)

Application Number Title Priority Date Filing Date
PL09767799T PL2285930T3 (pl) 2008-06-20 2009-06-19 Azeotropowe i azeotropo-podobne kompozycje Z-1,1,1,4,4,4-heksafluoro-2-butenu

Country Status (12)

Country Link
EP (1) EP2285930B1 (pl)
JP (3) JP5806111B2 (pl)
KR (2) KR101618900B1 (pl)
CN (1) CN102066521B (pl)
AU (1) AU2009259965B2 (pl)
BR (1) BRPI0909619A2 (pl)
CA (2) CA2944302C (pl)
CO (1) CO6280546A2 (pl)
ES (1) ES2568429T3 (pl)
MX (1) MX2010014094A (pl)
PL (1) PL2285930T3 (pl)
WO (1) WO2009155490A1 (pl)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2826376T3 (es) 2009-06-02 2021-05-18 Chemours Co Fc Llc Composiciones azeotrópicas y similares a azeótropos de Z-1,1,1,4,4,4-hexafluoro-2-buteno
AU2013204160B2 (en) * 2009-12-16 2015-07-02 Honeywell International Inc. Azeotrope-like compositions of cis-1,1,1,4,4,4-hexafluoro-2-butene
US20110144216A1 (en) * 2009-12-16 2011-06-16 Honeywell International Inc. Compositions and uses of cis-1,1,1,4,4,4-hexafluoro-2-butene
US8846754B2 (en) * 2009-12-16 2014-09-30 Honeywell International Inc. Azeotrope-like compositions of cis-1,1,1,4,4,4-hexafluoro-2-butene
AU2015234339B2 (en) * 2009-12-16 2017-03-16 Solstice Advanced Materials Us, Inc. Azeotrope-like compositions of cis-1,1,1,4,4,4-hexafluoro-2-butene
US8821749B2 (en) 2010-04-26 2014-09-02 E I Du Pont De Nemours And Company Azeotrope-like compositions of E-1,1,1,4,4,4-hexafluoro-2-butene and 1-chloro-3,3,3-trifluoropropene
JP6271115B2 (ja) * 2010-06-11 2018-01-31 株式会社ダイゾー エアゾール製品
US8066901B1 (en) 2011-01-19 2011-11-29 Honeywell International Inc. Azeotrope-like compositions of trans-1,1,1,4,4,4-hexafluoro-2-butene and water
TWI573971B (zh) 2011-01-31 2017-03-11 杜邦股份有限公司 使用包含ｚ－１，１，１，４，４，４－六氟－２－丁烯之工作流體製熱
AU2012212084B2 (en) * 2011-02-04 2016-03-10 The Chemours Company Fc, Llc. Azeotropic and azeotrope-like compositions involving certain haloolefins and uses thereof
HK1198590A1 (en) * 2011-08-19 2015-04-30 The Chemours Company Fc, Llc Processes and compositions for organic rankine cycles for generating mechanical energy from heat
EP2794806A4 (en) * 2011-12-22 2015-10-14 Honeywell Int Inc AZEOTROPÄHNLICHE COMPOSITIONS WITH CIS-1-CHLORO-3,3,3-TRIFLUORPROPEN
HK1199854A1 (en) * 2012-02-17 2015-07-24 E. I. Du Pont De Nemours And Company Azeotrope-like compositions of z-1,1,1,4,4,4-hexafluoro-2-butene and e-1,1,1,4,4,4-hexafluoro-2-butene and uses thereof
JP2017534704A (ja) * 2014-09-16 2017-11-24 ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー Ｚ−１，１，１，４，４，４−ヘキサフルオロ−２−ブテンとメチルパーフルオロプロピルエーテルとを含む共沸性又は共沸混合物様組成物
WO2016126792A1 (en) 2015-02-06 2016-08-11 The Chemours Company Fc, Llc Compositions comprising z-1,1,1,4,4,4-hexafluoro-2-butene and uses thereof
JP5805345B1 (ja) * 2015-06-04 2015-11-04 積水化学工業株式会社 フェノール樹脂発泡体
CN104927775B (zh) * 2015-07-01 2016-08-24 西安科技大学 煤矿地热利用中的高温热泵混合工质
US20210261747A1 (en) * 2018-07-16 2021-08-26 The Chemours Company Fc, Llc Blowing agent blends
WO2020150437A1 (en) * 2019-01-17 2020-07-23 The Chemours Company Fc, Llc Azeotrope and azeotrope-like compositions comprising (e)-1,1,1,4,4,4-hexafluorobut-2-ene

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5531916A (en) * 1990-10-03 1996-07-02 E. I. Du Pont De Nemours And Company Hydrofluorocarbon cleaning compositions
JPH05179043A (ja) 1991-11-18 1993-07-20 Daikin Ind Ltd フルオロブテンからなる発泡剤およびプラスチック発泡体の製造方法
US5578137A (en) 1993-08-31 1996-11-26 E. I. Du Pont De Nemours And Company Azeotropic or azeotrope-like compositions including 1,1,1,2,3,4,4,5,5,5-decafluoropentane
US7279451B2 (en) * 2002-10-25 2007-10-09 Honeywell International Inc. Compositions containing fluorine substituted olefins
US9005467B2 (en) 2003-10-27 2015-04-14 Honeywell International Inc. Methods of replacing heat transfer fluids
US9796848B2 (en) * 2002-10-25 2017-10-24 Honeywell International Inc. Foaming agents and compositions containing fluorine substituted olefins and methods of foaming
US8383867B2 (en) 2004-04-29 2013-02-26 Honeywell International Inc. Method for producing fluorinated organic compounds
US20060243944A1 (en) 2005-03-04 2006-11-02 Minor Barbara H Compositions comprising a fluoroolefin
US20060245944A1 (en) * 2005-03-21 2006-11-02 Leck Thomas J Cooling apparatus powered by a ratioed gear drive assembly
TWI626262B (zh) 2005-06-24 2018-06-11 哈尼威爾國際公司 發泡體及其產品
US8420706B2 (en) 2005-06-24 2013-04-16 Honeywell International Inc. Foaming agents, foamable compositions, foams and articles containing halogen substituted olefins, and methods of making same
JP2009518460A (ja) 2005-11-01 2009-05-07 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー フルオロオレフィンを含む組成物およびそれらの使用
KR20150065922A (ko) * 2005-11-01 2015-06-15 이 아이 듀폰 디 네모아 앤드 캄파니 불포화 플루오로카본을 포함하는 발포체 형성을 위한 발포제
US8287752B2 (en) * 2005-11-01 2012-10-16 E I Du Pont De Nemours And Company Fire extinguishing and fire suppression compositions comprising unsaturated fluorocarbons
EP2497821B1 (en) * 2005-11-01 2019-04-03 The Chemours Company FC, LLC Solvent compositions comprising unsaturated fluorinated hydrocarbons
MY160613A (en) 2006-02-28 2017-03-15 Du Pont Azeotropic compositions comprising fluorinated compounds for cleaning applications
FR2899233B1 (fr) 2006-03-31 2010-03-12 Arkema Composition d'agent d'expansion
MY170074A (en) * 2007-04-27 2019-07-03 Du Pont Azeotropic and azeotrope-like compositions of z-1,1,1,4,4,4-hexafluoro-2-butene

Also Published As

Publication number Publication date
JP2014224267A (ja) 2014-12-04
CA2725404A1 (en) 2009-12-23
JP2011525209A (ja) 2011-09-15
CA2944302A1 (en) 2009-12-23
JP5806111B2 (ja) 2015-11-10
AU2009259965A1 (en) 2009-12-23
BRPI0909619A2 (pt) 2015-09-22
ES2568429T3 (es) 2016-04-29
JP6051281B2 (ja) 2016-12-27
MX2010014094A (es) 2011-01-21
CN102066521A (zh) 2011-05-18
KR101618900B1 (ko) 2016-05-09
EP2285930A1 (en) 2011-02-23
WO2009155490A1 (en) 2009-12-23
EP2285930B1 (en) 2016-01-27
CA2944302C (en) 2017-11-21
JP5957493B2 (ja) 2016-07-27
CO6280546A2 (es) 2011-05-20
KR20110038044A (ko) 2011-04-13
AU2009259965B2 (en) 2015-08-27
JP2015227467A (ja) 2015-12-17
CN102066521B (zh) 2013-11-13
KR20160040314A (ko) 2016-04-12

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