PL246548B1 - Systemy fotoinicjujące do procesów fotoinicjowanej polimeryzacji kationowej, rodnikowej, tiol-en i hybrydowej oraz zastosowania pochodnych 4,6-difenylo-2-pirol-1-ylobenzeno-1,3-dikarbonitrylu - Google Patents

Systemy fotoinicjujące do procesów fotoinicjowanej polimeryzacji kationowej, rodnikowej, tiol-en i hybrydowej oraz zastosowania pochodnych 4,6-difenylo-2-pirol-1-ylobenzeno-1,3-dikarbonitrylu

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Publication number
PL246548B1
PL246548B1 PL441158A PL44115822A PL246548B1 PL 246548 B1 PL246548 B1 PL 246548B1 PL 441158 A PL441158 A PL 441158A PL 44115822 A PL44115822 A PL 44115822A PL 246548 B1 PL246548 B1 PL 246548B1
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PL
Poland
Prior art keywords
phenyl
pyrrol
benzene
dicarbonitrile
diphenyl
Prior art date
Application number
PL441158A
Other languages
English (en)
Other versions
PL441158A1 (pl
Inventor
Emilia Hola
Joanna Ortyl
Alicja Gruchała
Mariusz Galek
Original Assignee
Politechnika Krakowska im.Tadeusza Kościuszki
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Politechnika Krakowska im.Tadeusza Kościuszki filed Critical Politechnika Krakowska im.Tadeusza Kościuszki
Priority to PL441158A priority Critical patent/PL246548B1/pl
Publication of PL441158A1 publication Critical patent/PL441158A1/pl
Publication of PL246548B1 publication Critical patent/PL246548B1/pl

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/32—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D207/325—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms with substituted hydrocarbon radicals directly attached to the ring nitrogen atom
    • C07D207/327—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/10—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
    • C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
    • C07D403/10—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a carbon chain containing aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Hydrogenated Pyridines (AREA)
  • Pyrrole Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

Zgłoszenie dotyczy nowych pochodnych 4,6-difenylo-2-pirol-1-ylo-benzeno-1,3-dikabonitrylu o wzorze ogólnym (1), w którym podstawnik R oznacza jedno z poniższych ugrupowań, w których linia przerywana oznacza wiązanie: to jest związek, wybrany z grupy obejmującej: 4-(4-anilinofenylo)-6-fenylo-2-pirol-1-ylo-benzeno-1,3-dikarbonitryl; 4-fenylo-2-pirol-1-ylo-6-[4-[4-(trifluorometylo)anilino]fenylo]benzeno-1,3-dikarbonitryl; 4-fenylo-6-[4-(4-metylosulfanyloanilino)fenylo]-2-pirol-1-ylo-benzeno-1,3-dikarbonitryl; 4-fenylo-6-[4-(4-metyloanilino)fenylo]-2-pirol-1-ylo-benzeno-1,3-dikarbonitryl; 4-[4-(4-cyjanoanilino)fenylo]-6-fenylo-2-pirol-1-ylo-benzeno-1,3-dikarbonitryl; 4-fenylo-6-[4-(4-fluoroanilino)fenylo]-2-pirol-1-ylo-benzeno-1,3-dikarbonitryl; 4-fenylo-6-[4-(N-metyloanilo)fenylo]-2-pirol-1-ylo-benzeno-1,3-dikarbonitryl; 4-fenylo-6-[4-[N-metylo-4-(trifluorometylo)anilino]fenylo]-2-pirol-1-ylo-benzeno-1,3-dikarbonitryl; 4-fenylo-6-[4-(N-metylo-4-metylosulfanylo-anilino)fenylo]-2-pirol-1-ylo-benzeno-1,3-dikarbonitryl; 4-fenylo-6-[4-(N,4-dimetyloanilino)fenylo]-2-pirol-1-ylo-benzeno-1,3-dikarbonitryl; 4-[4-(4-cyjano-N-metylo-anilino)fenylo]-6-fenylo-2-pirol-1-ylo-benzeno-1,3-dikarbonitryl; 4-fenylo-6-[4-(4-fluoro-N-metylo-anilino)fenylo]-2-pirol-1-ylo-benzeno-1,3-dikarbonitryl; 4-fenylo-6-[4-(N-fenyloanilino)fenylo]-2-pirol-1-ylo-benzeno-1,3-dikarbonitryl; 4-fenylo-6-(4-karbazol-9-ylofenylo)-2-pirol-1-ylo-benzeno-1,3-dikarbonitryl; 4-fenylo-6-[4-(1-piperidylo)fenylo]-2-pirol-1-ylo-benzeno-1,3-dikarbonitryl. Przedmiotem zgłoszenia jest także sposób wytwarzania nowych pochodnych 4,6-difenylo-2-pirol-1-ylo-benzeno-1,3-dikabonitrylu o wzorze ogólnym (1), nowe systemy fotoinicjujące z udziałem nowych pochodnych 4,6-difenylo-2-pirol-1-ylo-benzeno-1,3-dikabonitrylu o wzorze ogólnym (1) oraz zastosowania nowych pochodnych 4,6-difenylo-2-pirol-1-ylo-benzeno-1,3-dikabonitrylu o wzorze ogólnym (1).
PL441158A 2022-05-12 2022-05-12 Systemy fotoinicjujące do procesów fotoinicjowanej polimeryzacji kationowej, rodnikowej, tiol-en i hybrydowej oraz zastosowania pochodnych 4,6-difenylo-2-pirol-1-ylobenzeno-1,3-dikarbonitrylu PL246548B1 (pl)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL441158A PL246548B1 (pl) 2022-05-12 2022-05-12 Systemy fotoinicjujące do procesów fotoinicjowanej polimeryzacji kationowej, rodnikowej, tiol-en i hybrydowej oraz zastosowania pochodnych 4,6-difenylo-2-pirol-1-ylobenzeno-1,3-dikarbonitrylu

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL441158A PL246548B1 (pl) 2022-05-12 2022-05-12 Systemy fotoinicjujące do procesów fotoinicjowanej polimeryzacji kationowej, rodnikowej, tiol-en i hybrydowej oraz zastosowania pochodnych 4,6-difenylo-2-pirol-1-ylobenzeno-1,3-dikarbonitrylu

Publications (2)

Publication Number Publication Date
PL441158A1 PL441158A1 (pl) 2023-11-13
PL246548B1 true PL246548B1 (pl) 2025-02-10

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Family Applications (1)

Application Number Title Priority Date Filing Date
PL441158A PL246548B1 (pl) 2022-05-12 2022-05-12 Systemy fotoinicjujące do procesów fotoinicjowanej polimeryzacji kationowej, rodnikowej, tiol-en i hybrydowej oraz zastosowania pochodnych 4,6-difenylo-2-pirol-1-ylobenzeno-1,3-dikarbonitrylu

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Country Link
PL (1) PL246548B1 (pl)

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PL441158A1 (pl) 2023-11-13

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