PL2547638T3 - Jednoczesne odwadnianie i izomeryzacja szkieletu izobutanolu na katalizatorach kwasowych - Google Patents
Jednoczesne odwadnianie i izomeryzacja szkieletu izobutanolu na katalizatorach kwasowychInfo
- Publication number
- PL2547638T3 PL2547638T3 PL11708283T PL11708283T PL2547638T3 PL 2547638 T3 PL2547638 T3 PL 2547638T3 PL 11708283 T PL11708283 T PL 11708283T PL 11708283 T PL11708283 T PL 11708283T PL 2547638 T3 PL2547638 T3 PL 2547638T3
- Authority
- PL
- Poland
- Prior art keywords
- isobutanol
- acid catalysts
- simultaneous dehydration
- skeletal isomerisation
- isomerisation
- Prior art date
Links
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 title 2
- 239000003377 acid catalyst Substances 0.000 title 1
- 230000018044 dehydration Effects 0.000 title 1
- 238000006297 dehydration reaction Methods 0.000 title 1
- 238000006317 isomerization reaction Methods 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
- B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
- B01J29/85—Silicoaluminophosphates [SAPO compounds]
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/08—Alkenes with four carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/08—Alkenes with four carbon atoms
- C07C11/09—Isobutene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/23—Rearrangement of carbon-to-carbon unsaturated bonds
- C07C5/25—Migration of carbon-to-carbon double bonds
- C07C5/2506—Catalytic processes
- C07C5/2518—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2767—Changing the number of side-chains
- C07C5/277—Catalytic processes
- C07C5/2775—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP10156537A EP2366682A1 (en) | 2010-03-15 | 2010-03-15 | Simultaneous dehydration and skeletal isomerisation of isobutanol on acid catalysts |
| EP10159463A EP2374781A1 (en) | 2010-04-09 | 2010-04-09 | Simultaneous dehydration and skeletal isomerisation of isobutanol on acid catalysts |
| EP10161125 | 2010-04-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL2547638T3 true PL2547638T3 (pl) | 2017-02-28 |
Family
ID=44242479
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL11708283T PL2547638T3 (pl) | 2010-03-15 | 2011-03-15 | Jednoczesne odwadnianie i izomeryzacja szkieletu izobutanolu na katalizatorach kwasowych |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US9233886B2 (pl) |
| EP (1) | EP2547638B1 (pl) |
| JP (1) | JP5784646B2 (pl) |
| KR (1) | KR101544257B1 (pl) |
| CN (1) | CN102892729B (pl) |
| AR (1) | AR080756A1 (pl) |
| BR (1) | BR112012023262B1 (pl) |
| CA (1) | CA2791218C (pl) |
| CO (1) | CO6602154A2 (pl) |
| DK (1) | DK2547638T3 (pl) |
| EA (1) | EA025806B1 (pl) |
| ES (1) | ES2603029T3 (pl) |
| MY (1) | MY158968A (pl) |
| PE (1) | PE20130759A1 (pl) |
| PL (1) | PL2547638T3 (pl) |
| WO (1) | WO2011113834A1 (pl) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2583957A1 (de) * | 2011-10-18 | 2013-04-24 | LANXESS Deutschland GmbH | Lineare Butene aus Isobutanol |
| JP5797545B2 (ja) * | 2011-12-26 | 2015-10-21 | 旭化成ケミカルズ株式会社 | 触媒前駆体の熱処理方法、触媒の製造方法、並びにプロピレンの製造方法 |
| FR2988718B1 (fr) * | 2012-03-29 | 2014-04-11 | Ifp Energies Now | Procede de deshydratation et d'isomerisation d'alcools utilisant un solide de type aluminosilicate non zeolithique |
| SG11201607927WA (en) * | 2014-05-07 | 2016-11-29 | Mitsubishi Rayon Co | Method for producing isobutylene from isobutanol |
| EP2949635A1 (de) * | 2014-05-28 | 2015-12-02 | Linde Aktiengesellschaft | Verfahren zur Herstellung von Produktolefinen durch katalytische Dehydratisierung geeigneter Reaktanden |
| US10512903B2 (en) | 2014-09-26 | 2019-12-24 | Total Research & Technology Feluy | Modified crystalline aluminosilicate for dehydration of alcohols |
| FR3026406B1 (fr) * | 2014-09-26 | 2016-12-09 | Ifp Energies Now | Procede de deshydratation isomerisante d'une charge alcool primaire substitue en position 2 par un groupement alkyl sur un catalyseur comprenant une zeolithe de type fer |
| CN105585396B (zh) | 2014-10-20 | 2018-03-20 | 中国石油化工股份有限公司 | 一种由含氧化合物制取低碳烯烃的方法 |
| KR101871641B1 (ko) | 2015-04-22 | 2018-06-26 | 미쯔비시 케미컬 주식회사 | 이소부틸렌 제조용 촉매 및 이소부틸렌의 제조 방법 |
| KR101966773B1 (ko) | 2015-05-13 | 2019-04-08 | 주식회사 엘지화학 | 이성질화 반응을 이용한 노말부텐의 분리방법 및 노말부텐을 분리하기 위한 공정시스템 |
| WO2017005719A1 (en) | 2015-07-09 | 2017-01-12 | Total Research & Technology Feluy | Modified crystalline aluminosilicate for dehydration of alcohols |
| EP3162763A1 (en) | 2015-10-30 | 2017-05-03 | Total Research & Technology Feluy SA | Simultaneous dehydration and skeletal isomerisation of isobutanol on ti-containing zeolite catalysts |
| WO2018047773A1 (ja) | 2016-09-06 | 2018-03-15 | 三菱ケミカル株式会社 | イソブチレンの分離精製方法およびイソブチレンの製造方法 |
| DK3509745T3 (da) * | 2016-09-09 | 2020-08-10 | Total Res & Technology Feluy | Katalysatorsammensætning omfattende modificeret krystallinsk aluminosilikat til dehydrering af alkoholer |
| FR3056982A1 (fr) * | 2016-09-30 | 2018-04-06 | IFP Energies Nouvelles | Procede de production d'isoprene biosource mettant en œuvre une etape de deshydratation de butanols, une etape de metathese et une etape de deshydrogenation |
| PL3523269T3 (pl) * | 2016-10-06 | 2021-10-25 | Shell Internationale Research Maatschappij B.V. | Katalizator do konwersji związków alkiloaromatycznych |
| FR3058414B1 (fr) | 2016-11-08 | 2019-08-16 | IFP Energies Nouvelles | Procede de deshydratation isomerisante d'un alcool primaire non lineaire sur un catalyseur comprenant une zeolithe de type fer et un liant aluminique |
| FR3058415B1 (fr) * | 2016-11-08 | 2018-12-07 | IFP Energies Nouvelles | Procede de deshydratation isomerisante d'une charge alcool primaire non lineaire en presence d'injection d'eau et d' un catalyseur comprenant une zeolithe de type fer ou mfs |
| FR3058413A1 (fr) | 2016-11-08 | 2018-05-11 | IFP Energies Nouvelles | Procede de deshydratation isomerisante d'une charge d'un monoalcool primaire non lineaire sur un catalyseur comprenant une zeolithe de type fer et un alcalin |
| CA2965062A1 (en) * | 2017-04-25 | 2018-10-25 | Nova Chemicals Corporation | Complex comprising odh unit with integrated oxygen separation module |
| CN107118069A (zh) * | 2017-06-17 | 2017-09-01 | 安徽海德石油化工有限公司 | 一种利用异丁醇脱水制备异丁烯的方法 |
| FR3068692B1 (fr) * | 2017-07-10 | 2019-08-16 | IFP Energies Nouvelles | Procede de deshydratation des alcools en olefines comprenant une etape de selectivation du catalyseur |
| EP3678774A4 (en) * | 2017-09-07 | 2021-05-05 | BASF Corporation | ZEOLITE WITH REDUCED EXTRA FRAME ALUMINUM |
| FR3074803B1 (fr) | 2017-12-13 | 2019-11-29 | IFP Energies Nouvelles | Procede d’elimination simultanee d’isobutanal et d’ethanol de charges olefiniques par adsorption sur un materiau a base d’oxyde refractaire poreux |
| FR3077818B1 (fr) | 2018-02-09 | 2020-02-28 | IFP Energies Nouvelles | Procede de separation d'olefines non lineaires d'une charge olefinique par distillation reactive |
| CN108218654A (zh) * | 2018-02-12 | 2018-06-29 | 安徽海德化工科技有限公司 | 一种利用异丁醇制备异辛烷的方法 |
| FR3080546B1 (fr) | 2018-04-25 | 2022-12-16 | Ifp Energies Now | Procede de deshydratation isomerisante de monoalcool primaire non lineaire sur un catalyseur zeolithique quadrilobe de type fer |
| CA3154623A1 (en) | 2019-09-30 | 2021-04-08 | Gevo, Inc. | Simultaneous dehydration, dimerization, and metathesis of c2-c5 alcohols |
| CN113877624B (zh) * | 2020-07-03 | 2024-01-26 | 中国石油化工股份有限公司 | 一种碳四烯烃骨架正构化方法及其应用 |
| KR20240000547A (ko) | 2021-04-23 | 2024-01-02 | 게보 인코포레이티드 | C1-c5 알코올의 c2-c5 올레핀 혼합물로의 촉매 전환을 위한 시스템 및 방법 |
| FR3157389A1 (fr) | 2023-12-22 | 2025-06-27 | Axens | Procédé de production de bioalkylat ou d’essence biosourcée |
| WO2025202393A1 (en) | 2024-03-28 | 2025-10-02 | Basf Se | A process for preparing at least one alkene |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE890953C (de) * | 1938-08-21 | 1953-10-29 | Basf Ag | Verfahren zur Herstellung von Butylen-Isobutylen-Gemischen |
| ZA966107B (en) * | 1995-07-21 | 1997-02-03 | Shell Int Research | Dehydration of primary alcohols. |
| US6768035B2 (en) * | 2002-01-31 | 2004-07-27 | Chevron U.S.A. Inc. | Manufacture of high octane alkylate |
| JP4431408B2 (ja) * | 2004-01-16 | 2010-03-17 | 新日本石油株式会社 | イソブテンの異性化によるｎ−ブテン類の製造方法 |
| US6977318B2 (en) | 2004-05-04 | 2005-12-20 | Equistar Chemicals, Lp | Propylene production |
| DE102005062700A1 (de) * | 2005-12-28 | 2007-07-05 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von 1-Buten aus technischen Mischungen von C4-Kohlenwasserstoffen |
| US20080132741A1 (en) | 2006-06-16 | 2008-06-05 | D Amore Michael B | Process for making butenes from dry isobutanol |
| NZ579780A (en) | 2007-04-18 | 2012-07-27 | Butamax Advanced Biofuels Llc | Fermentive production of isobutanol using highly active ketol-acid reductoisomerase enzymes |
| KR101217957B1 (ko) * | 2008-02-07 | 2013-01-02 | 토탈 리서치 앤드 테크놀로지 펠루이 | 결정질 실리케이트 상에서의 알코올의 탈수 |
| EP2108634A1 (en) * | 2008-04-11 | 2009-10-14 | Total Petrochemicals Research Feluy | Dehydration of alcohols on crystalline silicates |
| EP2090561A1 (en) * | 2008-02-07 | 2009-08-19 | Total Petrochemicals Research Feluy | Dehydration of alcohols on crystalline silicates |
| AU2009211370A1 (en) * | 2008-02-07 | 2009-08-13 | Total Petrochemicals Research Feluy | Dehydration of alcohols in the presence of an inert component |
| US7982086B2 (en) * | 2009-02-03 | 2011-07-19 | Catalytic Distillation Technologies | Deisobutenizer |
-
2011
- 2011-03-15 JP JP2012557529A patent/JP5784646B2/ja not_active Expired - Fee Related
- 2011-03-15 KR KR1020127024104A patent/KR101544257B1/ko not_active Expired - Fee Related
- 2011-03-15 CA CA2791218A patent/CA2791218C/en not_active Expired - Fee Related
- 2011-03-15 EP EP11708283.4A patent/EP2547638B1/en active Active
- 2011-03-15 US US13/582,759 patent/US9233886B2/en not_active Expired - Fee Related
- 2011-03-15 AR ARP110100834A patent/AR080756A1/es not_active Application Discontinuation
- 2011-03-15 CN CN201180024174.6A patent/CN102892729B/zh not_active Expired - Fee Related
- 2011-03-15 MY MYPI2012003837A patent/MY158968A/en unknown
- 2011-03-15 WO PCT/EP2011/053902 patent/WO2011113834A1/en not_active Ceased
- 2011-03-15 EA EA201270737A patent/EA025806B1/ru not_active IP Right Cessation
- 2011-03-15 BR BR112012023262-2A patent/BR112012023262B1/pt not_active IP Right Cessation
- 2011-03-15 ES ES11708283.4T patent/ES2603029T3/es active Active
- 2011-03-15 PE PE2012001548A patent/PE20130759A1/es not_active Application Discontinuation
- 2011-03-15 DK DK11708283.4T patent/DK2547638T3/en active
- 2011-03-15 PL PL11708283T patent/PL2547638T3/pl unknown
-
2012
- 2012-09-14 CO CO12158684A patent/CO6602154A2/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| EP2547638A1 (en) | 2013-01-23 |
| CO6602154A2 (es) | 2013-01-18 |
| JP2013522270A (ja) | 2013-06-13 |
| MY158968A (en) | 2016-11-30 |
| US9233886B2 (en) | 2016-01-12 |
| AR080756A1 (es) | 2012-05-09 |
| PE20130759A1 (es) | 2013-06-21 |
| CA2791218A1 (en) | 2011-09-22 |
| CA2791218C (en) | 2014-11-25 |
| ES2603029T3 (es) | 2017-02-23 |
| KR101544257B1 (ko) | 2015-08-12 |
| CN102892729A (zh) | 2013-01-23 |
| KR20120128685A (ko) | 2012-11-27 |
| EA201270737A1 (ru) | 2013-02-28 |
| EA025806B1 (ru) | 2017-01-30 |
| WO2011113834A1 (en) | 2011-09-22 |
| JP5784646B2 (ja) | 2015-09-24 |
| US20130204057A1 (en) | 2013-08-08 |
| BR112012023262B1 (pt) | 2018-06-19 |
| EP2547638B1 (en) | 2016-08-17 |
| DK2547638T3 (en) | 2016-12-12 |
| CN102892729B (zh) | 2015-08-05 |
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