PL2703380T3 - Sposób obróbki produktu wyjściowego z hydroformylowania - Google Patents
Sposób obróbki produktu wyjściowego z hydroformylowaniaInfo
- Publication number
- PL2703380T3 PL2703380T3 PL13184322T PL13184322T PL2703380T3 PL 2703380 T3 PL2703380 T3 PL 2703380T3 PL 13184322 T PL13184322 T PL 13184322T PL 13184322 T PL13184322 T PL 13184322T PL 2703380 T3 PL2703380 T3 PL 2703380T3
- Authority
- PL
- Poland
- Prior art keywords
- working
- hydroformylation output
- hydroformylation
- output
- Prior art date
Links
- 238000007037 hydroformylation reaction Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D1/00—Evaporating
- B01D1/22—Evaporating by bringing a thin layer of the liquid into contact with a heated surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US7804608P | 2008-07-03 | 2008-07-03 | |
| EP13184322.9A EP2703380B1 (en) | 2008-07-03 | 2009-07-02 | Process for working up a hydroformylation output |
| EP09774522.8A EP2297077B1 (en) | 2008-07-03 | 2009-07-02 | Process of controlling heavies in a recycle catalyst stream |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL2703380T3 true PL2703380T3 (pl) | 2016-05-31 |
Family
ID=41128560
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL09774522T PL2297077T3 (pl) | 2008-07-03 | 2009-07-02 | Sposób regulowania ilości substancji ciężkich w strumieniu powrotnym katalizatora |
| PL13184322T PL2703380T3 (pl) | 2008-07-03 | 2009-07-02 | Sposób obróbki produktu wyjściowego z hydroformylowania |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL09774522T PL2297077T3 (pl) | 2008-07-03 | 2009-07-02 | Sposób regulowania ilości substancji ciężkich w strumieniu powrotnym katalizatora |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US8404903B2 (pl) |
| EP (2) | EP2297077B1 (pl) |
| JP (1) | JP5587877B2 (pl) |
| KR (1) | KR101629043B1 (pl) |
| CN (1) | CN102143933B (pl) |
| CA (1) | CA2729643C (pl) |
| ES (2) | ES2495748T3 (pl) |
| MX (1) | MX2010014570A (pl) |
| MY (1) | MY155290A (pl) |
| PL (2) | PL2297077T3 (pl) |
| WO (1) | WO2010003073A1 (pl) |
| ZA (1) | ZA201100027B (pl) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101310552B1 (ko) | 2010-04-20 | 2013-09-23 | 주식회사 엘지화학 | 올레핀의 하이드로포르밀화에 의한 알데히드 제조 방법 |
| SG11201502824VA (en) * | 2012-10-12 | 2015-05-28 | Evonik Degussa Gmbh | Mixture of different asymmetrical bisophosphites and use thereof as a catalyst mixture for hydroformylation |
| EP2740535A1 (en) | 2012-12-04 | 2014-06-11 | Dow Technology Investments LLC | Bidentate ligands for hydroformylation of ethylene |
| CN104837800B (zh) * | 2012-12-06 | 2017-08-29 | 陶氏技术投资有限责任公司 | 氢甲酰化方法 |
| DE102012223572A1 (de) | 2012-12-18 | 2014-06-18 | Evonik Industries Ag | Steuerung der Viskosität von Reaktionslösungen in Hydroformylierungverfahren |
| CN104725170B (zh) * | 2013-12-19 | 2019-08-23 | 陶氏技术投资有限责任公司 | 加氢甲酰化方法 |
| WO2015094781A1 (en) | 2013-12-19 | 2015-06-25 | Dow Technology Investments Llc | Hydroformylation process |
| MY184826A (en) | 2014-12-04 | 2021-04-24 | Dow Technology Investments Llc | Hydroformylation process |
| EP3374340B1 (en) | 2015-11-10 | 2021-12-29 | Dow Technology Investments LLC | Process for producing aldehydes |
| EP3414220B1 (en) | 2016-02-11 | 2021-10-13 | Dow Technology Investments LLC | Processes for converting olefins to alcohols, ethers, or combinations thereof |
| CN107141204B (zh) * | 2016-03-01 | 2022-03-15 | 陶氏技术投资有限责任公司 | 氢甲酰化工艺 |
| CN109071394B (zh) * | 2016-03-18 | 2022-02-08 | 陶氏技术投资有限责任公司 | 加氢甲酰化工艺 |
| TW201840362A (zh) | 2016-11-08 | 2018-11-16 | 美商陶氏科技投資有限公司 | 使去活化的氫甲醯化催化劑溶液再生的方法 |
| TWI758353B (zh) | 2016-11-08 | 2022-03-21 | 美商陶氏科技投資有限公司 | 使去活化的氫甲醯化催化劑溶液再生的方法 |
| TW201840363A (zh) | 2016-11-08 | 2018-11-16 | 美商陶氏科技投資有限公司 | 處理氫甲醯化催化劑溶液之方法 |
| TWI788364B (zh) | 2017-06-23 | 2023-01-01 | 美商陶氏科技投資有限公司 | 氫甲醯化反應製程 |
| CN110809623B (zh) | 2017-06-28 | 2022-09-06 | 陶氏环球技术有限责任公司 | 易于生物降解的烷氧基化物混合物 |
| CN107469860B (zh) * | 2017-08-22 | 2020-05-19 | 中国海洋石油集团有限公司 | 一种提高铑/双亚膦酸酯催化剂稳定性的方法 |
| TWI793216B (zh) | 2017-12-07 | 2023-02-21 | 美商陶氏科技投資公司 | 氫甲醯化方法 |
| JP2021525165A (ja) | 2018-05-30 | 2021-09-24 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | ヒドロホルミル化プロセスにおける触媒失活を遅らせるための方法、および／またはテトラホスフィン配位子の使用を遅らせるための方法 |
| EP3801898A1 (en) | 2018-05-30 | 2021-04-14 | Dow Technology Investments LLC | Catalyst composition comprising the combination of a monophopsphine, a tetraphosphine ligand and a hydroformylation process using it |
| MY201587A (en) | 2018-05-30 | 2024-03-02 | Dow Technology Investments Llc | Methods of controlling hydroformylation processes |
| MY203235A (en) | 2018-11-29 | 2024-06-19 | Dow Technology Investments Llc | Hydroformylation process |
| GB201907659D0 (en) * | 2019-05-30 | 2019-07-17 | Johnson Matthey Davy Technologies Ltd | Process |
| KR102489172B1 (ko) | 2019-07-04 | 2023-01-18 | 주식회사 엘지화학 | 디에스터계 물질의 제조 유닛 및 이를 포함하는 디에스터계 물질의 제조 시스템 |
| KR102489171B1 (ko) | 2019-07-04 | 2023-01-18 | 주식회사 엘지화학 | 디에스터계 물질의 제조 유닛 및 이를 포함하는 디에스터계 물질의 제조 시스템 |
| CN112441892B (zh) * | 2019-08-30 | 2023-03-14 | 中国石油化工股份有限公司 | 来自混合丁烯烃氢甲酰化反应装置的液相物流的分离方法和装置 |
| US11976017B2 (en) | 2019-12-19 | 2024-05-07 | Dow Technology Investments Llc | Processes for preparing isoprene and mono-olefins comprising at least six carbon atoms |
| GB202012930D0 (en) | 2020-08-19 | 2020-09-30 | Johnson Matthey Davy Technologies Ltd | Process for hydroformylation with removal of dissolved hydrogen |
| KR20220037341A (ko) * | 2020-09-17 | 2022-03-24 | 주식회사 엘지화학 | 알데히드의 제조방법 및 알데히드의 제조장치 |
| CN112403401B (zh) * | 2020-11-06 | 2022-06-21 | 中国海洋石油集团有限公司 | 一种烯烃氢甲酰化制醛中醛和催化剂分离的装置和方法 |
| CA3201268A1 (en) | 2020-12-14 | 2022-06-23 | Michael A. Brammer | Processes to improve catalytic metal accountability in hydroformylation processes |
| GB202102673D0 (en) * | 2021-02-25 | 2021-04-14 | Johnson Matthey Davy Technologies Ltd | Process |
| EP4430218A1 (en) | 2021-11-11 | 2024-09-18 | Dow Technology Investments LLC | Processes for recovering rhodium from hydroformylation processes |
| ES2992663T3 (en) * | 2021-11-19 | 2024-12-16 | Evonik Oxeno Gmbh & Co Kg | Process for producing aldehydes and cooling a mass flow |
| US20240399349A1 (en) | 2021-12-16 | 2024-12-05 | Dow Technology Investments Llc | Transition metal complex hydroformylation catalyst precuror compositions comprising such compounds, and hydroformylation processes |
| WO2023114579A1 (en) | 2021-12-16 | 2023-06-22 | Dow Technology Investments Llc | Compounds, transition metal complex hydroformylation catalyst precuror compositions comprising such compounds, and hydroformylation processes |
| CN114773172B (zh) * | 2022-06-20 | 2022-10-18 | 中海油天津化工研究设计院有限公司 | 一种烯烃氢甲酰化制醛工艺优化方法 |
| WO2024123510A1 (en) | 2022-12-06 | 2024-06-13 | Dow Technology Investments Llc | Process of controlling heavies in a recycle catalyst stream |
| CN120282943A (zh) | 2022-12-13 | 2025-07-08 | 陶氏技术投资有限责任公司 | 通过利用降解产物使多膦使用最小化的方法 |
| WO2025006020A1 (en) | 2023-06-26 | 2025-01-02 | Dow Technology Investments Llc | Methods of controlling hydroformylation processes |
| WO2025029349A1 (en) | 2023-08-03 | 2025-02-06 | Dow Technology Investments Llc | Hydroformylation process |
| WO2025029369A1 (en) | 2023-08-03 | 2025-02-06 | Dow Technology Investments Llc | Process for improving rhodium/phosphite- based homogenous hydroformylation catalyst activity |
| CN121490411A (zh) * | 2023-11-03 | 2026-02-10 | 中国石油化工股份有限公司 | 一种羰基合成催化剂与羰基合成产物的分离系统、分离方法及应用 |
| CN119925960B (zh) * | 2023-11-03 | 2025-10-31 | 中国石油化工股份有限公司 | 一种羰基合成催化剂的回收系统、回收方法及应用 |
Family Cites Families (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3415906A (en) | 1964-05-29 | 1968-12-10 | Hooker Chemical Corp | Phosphite phospholane and phosphorinane compounds |
| US3527809A (en) | 1967-08-03 | 1970-09-08 | Union Carbide Corp | Hydroformylation process |
| US4148830A (en) | 1975-03-07 | 1979-04-10 | Union Carbide Corporation | Hydroformylation of olefins |
| US4166773A (en) * | 1977-12-22 | 1979-09-04 | Union Carbide Corporation | Continuous process for separating high boiling, heat sensitive materials |
| DE16286T1 (de) | 1979-03-21 | 1983-05-11 | Davy Mckee (London) Ltd., London | Hydroformylierungsverfahren. |
| NO156742C (no) | 1979-03-28 | 1987-11-18 | Union Carbide Corp | Fremgangsmaate for fremstilling av et hydroformyleringsmedium, og fremgangsmaate for fremstilling av aldehyder. |
| GB8334359D0 (en) | 1983-12-23 | 1984-02-01 | Davy Mckee Ltd | Process |
| US4599206A (en) | 1984-02-17 | 1986-07-08 | Union Carbide Corporation | Transition metal complex catalyzed reactions |
| US4789753A (en) | 1984-02-17 | 1988-12-06 | Union Carbide Corporation | Phosphite ligands |
| US4567302A (en) | 1984-07-20 | 1986-01-28 | Angus Chemical | Polymeric quaternary ammonium salts possessing antimicrobial activity and methods for preparation and use thereof |
| US4737588A (en) | 1984-12-28 | 1988-04-12 | Union Carbide Corporation | Transition metal complex catalyzed reactions |
| US4748261A (en) | 1985-09-05 | 1988-05-31 | Union Carbide Corporation | Bis-phosphite compounds |
| US4668651A (en) | 1985-09-05 | 1987-05-26 | Union Carbide Corporation | Transition metal complex catalyzed processes |
| US4885401A (en) | 1985-09-05 | 1989-12-05 | Union Carbide Corporation | Bis-phosphite compounds |
| US4774361A (en) | 1986-05-20 | 1988-09-27 | Union Carbide Corporation | Transition metal complex catalyzed reactions |
| US4835299A (en) | 1987-03-31 | 1989-05-30 | Union Carbide Corporation | Process for purifying tertiary organophosphites |
| US5113022A (en) | 1988-08-05 | 1992-05-12 | Union Carbide Chemicals & Plastics Technology Corporation | Ionic phosphites used in homogeneous transition metal catalyzed processes |
| US5059710A (en) | 1988-08-05 | 1991-10-22 | Union Carbide Chemicals And Plastics Technology Corporation | Ionic phosphites and their use in homogeneous transition metal catalyzed processes |
| US5114473A (en) | 1988-08-25 | 1992-05-19 | Union Carbide Chemicals And Plastics Technology Corporation | Transition metal recovery |
| US5001274A (en) | 1989-06-23 | 1991-03-19 | Union Carbide Chemicals And Plastics Company Inc. | Hydroformylation process |
| US5277532A (en) | 1989-07-31 | 1994-01-11 | Cefin S.P.A. | Mechanical acceleration device in can welding machines |
| US5210318A (en) | 1990-05-04 | 1993-05-11 | Union Carbide Chemicals & Plastics Technology Corporation | Catalysts and processes useful in producing 1,3-diols and/or 3-hydroxyldehydes |
| DE4026406A1 (de) | 1990-08-21 | 1992-02-27 | Basf Ag | Rhodiumhydroformylierungskatalysatoren mit bis-phosphit-liganden |
| US5179055A (en) | 1990-09-24 | 1993-01-12 | New York University | Cationic rhodium bis(dioxaphosphorus heterocycle) complexes and their use in the branched product regioselective hydroformylation of olefins |
| US5087763A (en) | 1990-11-09 | 1992-02-11 | Union Carbide Chemicals & Plastics Technology Corporation | Hydroformylation process |
| TW213465B (pl) | 1991-06-11 | 1993-09-21 | Mitsubishi Chemicals Co Ltd | |
| DE4204808A1 (de) | 1992-02-18 | 1993-08-19 | Basf Ag | Verfahren zur herstellung von (omega)-formylalkancarbonsaeureestern |
| US5312996A (en) | 1992-06-29 | 1994-05-17 | Union Carbide Chemicals & Plastics Technology Corporation | Hydroformylation process for producing 1,6-hexanedials |
| US5364950A (en) | 1992-09-29 | 1994-11-15 | Union Carbide Chimicals & Plastics Technology Corporation | Process for stabilizing phosphite ligands in hydroformylation reaction mixtures |
| US5463137A (en) * | 1993-09-30 | 1995-10-31 | The Boc Group, Inc. | Process for the production of oxo products |
| DE19530698A1 (de) * | 1995-08-21 | 1997-02-27 | Basf Ag | Verfahren zur Aufarbeitung eines flüssigen Hydroformylierungsaustrags |
| US5874640A (en) | 1996-11-26 | 1999-02-23 | Union Carbide Chemicals & Plastics Technology Corporation | Metal-ligand complex catalyzed processes |
| US5892119A (en) | 1996-11-26 | 1999-04-06 | Union Carbide Chemicals & Plastics Technology Corporation | Metal-ligand complex catalyzed processes |
| US6090987A (en) | 1998-07-06 | 2000-07-18 | Union Carbide Chemicals & Plastics Technology Corporation | Metal-ligand complex catalyzed processes |
| DE19913352A1 (de) | 1999-03-24 | 2000-09-28 | Basf Ag | Katalysator, umfassend einen Komplex eines Metalls der VIII. Nebengruppe auf Basis eines Phospinamiditliganden |
| DE10006489A1 (de) | 2000-02-14 | 2001-08-16 | Basf Ag | Verfahren zur Aufarbeitung eines flüssigen Hydroformylierungsaustrages |
| US6294700B1 (en) | 2000-03-15 | 2001-09-25 | Union Carbide Chemicals & Plastics Technology Corporation | Separation processes |
| DE10031520A1 (de) * | 2000-06-28 | 2002-01-10 | Basf Ag | Verfahren zur Hydroformylierung von Olefinen mit 2 bis 8 Kohlenstoffatomen |
| DE10031519A1 (de) * | 2000-06-28 | 2002-01-10 | Basf Ag | Verfahren zur Hydroformylierung von Olefinen mit 2 bis 8 Kohlenstoffatomen, I |
| US7351868B2 (en) | 2003-07-03 | 2008-04-01 | Union Carbide Chemicals & Plastics Technology Corporation | Minimization of ligand degradation products, of reversion of same to useful phosphine ligands |
| CN100526279C (zh) * | 2006-04-11 | 2009-08-12 | 中国科学院兰州化学物理研究所 | 连续制备正戊醛的工艺过程 |
-
2009
- 2009-07-02 US US13/002,078 patent/US8404903B2/en active Active
- 2009-07-02 ES ES09774522.8T patent/ES2495748T3/es active Active
- 2009-07-02 JP JP2011516877A patent/JP5587877B2/ja not_active Expired - Fee Related
- 2009-07-02 CN CN200980134089.8A patent/CN102143933B/zh active Active
- 2009-07-02 PL PL09774522T patent/PL2297077T3/pl unknown
- 2009-07-02 PL PL13184322T patent/PL2703380T3/pl unknown
- 2009-07-02 EP EP09774522.8A patent/EP2297077B1/en active Active
- 2009-07-02 KR KR1020117002619A patent/KR101629043B1/ko not_active Expired - Fee Related
- 2009-07-02 ES ES13184322.9T patent/ES2558465T3/es active Active
- 2009-07-02 EP EP13184322.9A patent/EP2703380B1/en active Active
- 2009-07-02 CA CA2729643A patent/CA2729643C/en not_active Expired - Fee Related
- 2009-07-02 WO PCT/US2009/049540 patent/WO2010003073A1/en not_active Ceased
- 2009-07-02 MX MX2010014570A patent/MX2010014570A/es active IP Right Grant
- 2009-07-02 MY MYPI2010006276A patent/MY155290A/en unknown
-
2011
- 2011-01-03 ZA ZA2011/00027A patent/ZA201100027B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP2011527287A (ja) | 2011-10-27 |
| EP2703380A1 (en) | 2014-03-05 |
| EP2703380B1 (en) | 2015-11-04 |
| CA2729643C (en) | 2016-08-16 |
| CN102143933B (zh) | 2014-09-17 |
| KR101629043B1 (ko) | 2016-06-09 |
| US20110269997A1 (en) | 2011-11-03 |
| ES2558465T3 (es) | 2016-02-04 |
| CA2729643A1 (en) | 2010-01-07 |
| MY155290A (en) | 2015-09-30 |
| CN102143933A (zh) | 2011-08-03 |
| EP2297077A1 (en) | 2011-03-23 |
| WO2010003073A1 (en) | 2010-01-07 |
| JP5587877B2 (ja) | 2014-09-10 |
| KR20110047189A (ko) | 2011-05-06 |
| EP2297077B1 (en) | 2014-06-04 |
| ZA201100027B (en) | 2012-08-29 |
| ES2495748T3 (es) | 2014-09-17 |
| PL2297077T3 (pl) | 2014-11-28 |
| US8404903B2 (en) | 2013-03-26 |
| MX2010014570A (es) | 2011-08-15 |
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