PL3113879T3 - Katalizatory rutenowo-fenolowe do reakcji przeniesienia wodoru - Google Patents

Katalizatory rutenowo-fenolowe do reakcji przeniesienia wodoru

Info

Publication number
PL3113879T3
PL3113879T3 PL15707938T PL15707938T PL3113879T3 PL 3113879 T3 PL3113879 T3 PL 3113879T3 PL 15707938 T PL15707938 T PL 15707938T PL 15707938 T PL15707938 T PL 15707938T PL 3113879 T3 PL3113879 T3 PL 3113879T3
Authority
PL
Poland
Prior art keywords
ruthenium
hydrogen transfer
transfer reactions
catalysts
phenol
Prior art date
Application number
PL15707938T
Other languages
English (en)
Inventor
Carolin Limburg
Rocco Paciello
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of PL3113879T3 publication Critical patent/PL3113879T3/pl

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/511—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of singly bound oxygen functional groups to >C = O groups
    • C07C45/512—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of singly bound oxygen functional groups to >C = O groups the singly bound functional group being a free hydroxyl group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0202—Alcohols or phenols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/44—Allylic alkylation, amination, alkoxylation or analogues
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/643—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
PL15707938T 2014-03-05 2015-03-04 Katalizatory rutenowo-fenolowe do reakcji przeniesienia wodoru PL3113879T3 (pl)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP14157826.0A EP2915584A1 (en) 2014-03-05 2014-03-05 Ruthenium-phenol catalysts for transfer hydrogenation reactions
EP15707938.5A EP3113879B1 (en) 2014-03-05 2015-03-04 Ruthenium-phenol catalysts for transfer hydrogenation reactions
PCT/EP2015/054453 WO2015132275A1 (en) 2014-03-05 2015-03-04 Ruthenium-phenol catalysts for transfer hydrogenation reactions

Publications (1)

Publication Number Publication Date
PL3113879T3 true PL3113879T3 (pl) 2018-10-31

Family

ID=50230956

Family Applications (1)

Application Number Title Priority Date Filing Date
PL15707938T PL3113879T3 (pl) 2014-03-05 2015-03-04 Katalizatory rutenowo-fenolowe do reakcji przeniesienia wodoru

Country Status (8)

Country Link
US (2) US9790157B2 (pl)
EP (2) EP2915584A1 (pl)
JP (1) JP6529509B2 (pl)
CN (1) CN106068160B (pl)
ES (1) ES2676580T3 (pl)
MX (1) MX373623B (pl)
PL (1) PL3113879T3 (pl)
WO (1) WO2015132275A1 (pl)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3362426B1 (en) 2015-10-12 2020-09-02 Basf Se Hydroformylation process for producing 1,6-disubstituted hexane derivatives
US11028033B2 (en) * 2017-08-26 2021-06-08 Symrise Ag Method for producing terpene aldehydes and terpene ketones
CN107602357B (zh) * 2017-09-28 2020-06-02 万华化学集团股份有限公司 一种制备薄荷酮的方法
CN107721833B (zh) * 2017-10-18 2020-11-20 万华化学集团股份有限公司 一种制备薄荷酮的方法
CN109593029B (zh) * 2018-11-26 2022-01-07 万华化学集团股份有限公司 一种制备高纯度l-薄荷酮的方法及用于该方法的催化剂体系
CN109651115B (zh) * 2018-12-25 2022-02-18 万华化学集团股份有限公司 一种制备l-薄荷酮的方法
CN110357927A (zh) * 2019-07-11 2019-10-22 聊城大学 一种双核钯催化剂的制备方法及用途
CN110922316B (zh) * 2019-12-04 2022-11-08 万华化学集团股份有限公司 一种由r-香茅醛制备l-薄荷酮的方法

Family Cites Families (27)

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US2785188A (en) 1952-02-04 1957-03-12 Union Oil Co Method for preparing 3, 3'-5, 5'-tetraalkyl-4, 4'-diphenoquinones
US2885444A (en) 1958-03-05 1959-05-05 Dow Chemical Co Oxidation of 2, 4-di-tertiary-alkyl-phenols with oxygen
US3247262A (en) 1961-11-17 1966-04-19 Dow Chemical Co Process for making polyphenols
US4097461A (en) 1976-12-03 1978-06-27 Ici Americas Inc. Oxidative coupling of alkylphenols or 1-naphthols catalyzed by metal complexes of diketo compounds
US4134919A (en) 1977-06-14 1979-01-16 Takasago Perfumery Co., Ltd. Process for producing menthone
US4380676A (en) 1980-02-29 1983-04-19 Ciba-Geigy Corporation Process for the production of 2,2'-dihydroxy-biphenyls
JPS6153235A (ja) * 1984-08-24 1986-03-17 Agency Of Ind Science & Technol エチレングリコ−ルの製造方法
DE4236111A1 (de) 1992-10-26 1994-04-28 Henkel Kgaa Verfahren zur Herstellung von L-Menthon
JP2001031633A (ja) * 1999-06-25 2001-02-06 Degussa Huels Ag Ｎ−アシルアミノ酸の製造法
GB0229770D0 (en) * 2002-12-20 2003-01-29 Sasol Technology Uk Ltd Olefinic metathesis in the presence of phenolic compounds
JP4996048B2 (ja) * 2004-09-30 2012-08-08 小川香料株式会社 感覚刺激増強剤
US8575086B2 (en) 2005-01-18 2013-11-05 Takasago International Corporation Flavor and fragrance compositions
US20090317461A1 (en) 2006-08-02 2009-12-24 Wm. Wrigley Jr. Company Oral compositions effective for the treatment of oral cavity malodor associated with the consumption of odor-causing compounds
ES2351059T3 (es) * 2007-04-03 2011-01-31 Acrostak Corp. Bvi Aleaciones basadas en magnesio.
JP5476299B2 (ja) * 2007-07-23 2014-04-23 ビーエーエスエフ ソシエタス・ヨーロピア イソプレゴールの水素化によるメントールの製造方法
WO2011013430A1 (ja) * 2009-07-31 2011-02-03 日立化成工業株式会社 エステル化合物の製造方法
JPWO2011121850A1 (ja) * 2010-03-29 2013-07-04 日立化成株式会社 ナジイミド骨格を有するポリアミドイミド及びその製造方法
US20130281696A1 (en) 2012-04-20 2013-10-24 Basf Se Process for preparing branched alcohols
US9061960B2 (en) 2012-05-30 2015-06-23 Basf Se Method for working up mixtures
US20130331607A1 (en) 2012-06-11 2013-12-12 Basf Se Process for preparing formic acid
DE102012212424A1 (de) 2012-07-16 2014-01-16 Basf Se Verfahren zur Herstellung von Acrylsäure durch eine mit wenigstens einer molekularen Wirkverbindung katalysierte Thermolyse von Poly-3-hydroxypropionat
DE102012212437A1 (de) 2012-07-16 2014-01-16 Basf Se Verfahren zur Herstellung von Acrylsäure aus Ethylenoxid und Kohlenmonoxid
US9085526B2 (en) 2012-07-17 2015-07-21 Basf Se Process for preparing carboxylic acid esters
US8853400B2 (en) 2012-07-23 2014-10-07 Basf Se Process for the homogeneously catalyzed amination of alcohols with ammonia in the presence of a complex catalyst which comprises no anionic ligands
EP2706054A1 (de) 2012-09-10 2014-03-12 Basf Se Verfahren zur Herstellung von Menthon aus Isopulegol
US9029605B2 (en) * 2012-09-10 2015-05-12 Basf Se Method for preparing menthone from isopulegol
WO2015086578A1 (de) 2013-12-11 2015-06-18 Basf Se Verfahren zur aufarbeitung eines reaktionsgemischs (rg), das cyclododecatrien und ein aktives katalysatorsystem enthält

Also Published As

Publication number Publication date
MX2016011476A (es) 2016-12-20
US10421703B2 (en) 2019-09-24
CN106068160B (zh) 2019-09-03
WO2015132275A1 (en) 2015-09-11
EP3113879B1 (en) 2018-04-18
ES2676580T3 (es) 2018-07-23
JP6529509B2 (ja) 2019-06-12
US20170066704A1 (en) 2017-03-09
EP2915584A1 (en) 2015-09-09
US9790157B2 (en) 2017-10-17
EP3113879A1 (en) 2017-01-11
MX373623B (es) 2020-05-22
CN106068160A (zh) 2016-11-02
US20180037530A1 (en) 2018-02-08
JP2017508747A (ja) 2017-03-30

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