PL3310824T3 - Wychwytywacze aldehydów do pianek poliuretanowych - Google Patents

Wychwytywacze aldehydów do pianek poliuretanowych

Info

Publication number
PL3310824T3
PL3310824T3 PL15895188T PL15895188T PL3310824T3 PL 3310824 T3 PL3310824 T3 PL 3310824T3 PL 15895188 T PL15895188 T PL 15895188T PL 15895188 T PL15895188 T PL 15895188T PL 3310824 T3 PL3310824 T3 PL 3310824T3
Authority
PL
Poland
Prior art keywords
polyurethane foams
aldehyde scavengers
scavengers
aldehyde
foams
Prior art date
Application number
PL15895188T
Other languages
English (en)
Inventor
Sheng SU
Juan Jesus Burdeniuc
Gauri Sankar Lal
Jennifer E. A. AL-RASHID
Torsten Panitzsch
Original Assignee
Evonik Operations Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Evonik Operations Gmbh filed Critical Evonik Operations Gmbh
Publication of PL3310824T3 publication Critical patent/PL3310824T3/pl

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1825—Catalysts containing secondary or tertiary amines or salts thereof having hydroxy or primary amino groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1833—Catalysts containing secondary or tertiary amines or salts thereof having ether, acetal, or orthoester groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4829—Polyethers containing at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6681—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
    • C08G18/6688—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3271
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/28—Nitrogen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/07—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C08K5/138—Phenolates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/20—Carboxylic acid amides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • C08K5/34922—Melamine; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0008—Foam properties flexible
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2290/00—Compositions for creating anti-fogging
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/28—Nitrogen-containing compounds
    • C08K2003/285—Ammonium nitrates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045—Sulfates
    • C08K2003/3054—Ammonium sulfates

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
PL15895188T 2015-06-16 2015-06-16 Wychwytywacze aldehydów do pianek poliuretanowych PL3310824T3 (pl)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
PCT/CN2015/081524 WO2016201615A1 (en) 2015-06-16 2015-06-16 Aldehyde scavengers for polyurethane foams
EP15895188.9A EP3310824B1 (en) 2015-06-16 2015-06-16 Aldehyde scavengers for polyurethane foams

Publications (1)

Publication Number Publication Date
PL3310824T3 true PL3310824T3 (pl) 2021-01-11

Family

ID=57544736

Family Applications (1)

Application Number Title Priority Date Filing Date
PL15895188T PL3310824T3 (pl) 2015-06-16 2015-06-16 Wychwytywacze aldehydów do pianek poliuretanowych

Country Status (10)

Country Link
US (1) US10683385B2 (pl)
EP (1) EP3310824B1 (pl)
JP (1) JP6657267B2 (pl)
KR (1) KR20180018758A (pl)
CN (1) CN107735419A (pl)
CA (1) CA2989370C (pl)
ES (1) ES2819454T3 (pl)
MX (1) MX2017016191A (pl)
PL (1) PL3310824T3 (pl)
WO (1) WO2016201615A1 (pl)

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US10696777B2 (en) 2015-06-16 2020-06-30 Evonik Operations Gmbh Aldehyde scavengers mixtures for polyurethane foams
WO2018145283A1 (en) 2017-02-09 2018-08-16 Dow Global Technologies Llc Polyurethane foams having low levels of aldehyde emissions
BR112019016967A2 (pt) * 2017-02-16 2020-04-07 Dow Global Technologies Llc espumas de poliuretano que têm emissões reduzidas de aldeído
CN106832176A (zh) * 2017-02-17 2017-06-13 苏州高夫高分子材料有限公司 一种环保汽车前围隔音垫用聚氨酯泡沫及其制备方法
BR112019017144A2 (pt) 2017-02-20 2020-04-14 Dow Global Technologies Llc poliuretano que tem emissões de aldeído reduzidas
EP3409704A1 (de) * 2017-06-01 2018-12-05 Covestro Deutschland AG Polyurethanschaumstoffe basierend auf polyethercarbonatpolyolen
JP2019026753A (ja) * 2017-07-31 2019-02-21 株式会社ブリヂストン ポリウレタン用アルデヒド捕捉剤、ポリウレタン、及びポリウレタンの製造方法
JP7241487B2 (ja) 2017-09-25 2023-03-17 エボニック オペレーションズ ゲーエムベーハー ポリウレタン系の製造
CN111936542A (zh) * 2018-03-07 2020-11-13 科思创知识产权两合公司 基于聚醚碳酸酯多元醇的聚氨酯泡沫材料
EP3536727A1 (de) * 2018-03-07 2019-09-11 Covestro Deutschland AG Polyurethanschaumstoffe basierend auf polyethercarbonatpolyolen
KR102084745B1 (ko) * 2018-03-09 2020-03-04 주식회사 에이치엠솔루션 알데하이드 저감제 조성물 및 이를 이용한 연질 폴리우레탄 폼의 제조방법
CN109485820A (zh) * 2018-07-11 2019-03-19 沁欧环保科技(上海)有限公司 一种低气味低voc聚氨酯高回弹泡沫
US11820855B2 (en) * 2018-08-02 2023-11-21 Dow Global Technologies Llc Methods for reducing aldehyde emissions in polyurethane foams
JP7253037B2 (ja) * 2018-08-02 2023-04-05 ダウ グローバル テクノロジーズ エルエルシー ポリウレタン発泡体のアルデヒド排出量を減少させるための方法
MX2021007440A (es) * 2018-12-21 2021-08-11 Huntsman Int Llc Mezcla de reaccion adecuada para la elaboracion de espuma con emision reducida de aldehido.
JP7693556B2 (ja) * 2019-05-02 2025-06-17 ビーエーエスエフ ソシエタス・ヨーロピア 低下したホルムアルデヒド放出を有するメラミンホルムアルデヒドフォーム
CN114080411A (zh) * 2019-07-10 2022-02-22 科思创有限公司 聚醚及其在制备柔性聚氨酯泡沫中的用途
CN114174364A (zh) * 2019-07-29 2022-03-11 亨斯迈石油化学有限责任公司 具有减少的醛排放的聚氨酯组合物
WO2021035662A1 (en) * 2019-08-30 2021-03-04 Dow Global Technologies Llc Methods for reducing aldehyde emissions in polyether polyols and polyurethane foams
CN110964173B (zh) * 2019-12-13 2022-07-12 万华化学（北京）有限公司 用于蜂窝复合材料的聚氨酯组合物及其制备方法、聚氨酯泡沫及其应用
US20230141792A1 (en) * 2020-03-12 2023-05-11 Dow Global Technologies Llc Process for reducing aldehyde emissions in polyether polyols and polyurethane foams
WO2021236385A1 (en) * 2020-05-19 2021-11-25 Huntsman International Llc A process for recycling a polyurethane material
IT202000012334A1 (it) * 2020-05-26 2021-11-26 Repi S R L Formulazione liquida comprendente uno scavenger di aldeidi.
KR102461461B1 (ko) * 2020-08-31 2022-11-02 (주)동성화인텍 친환경 발포제를 포함하는 폴리이소시아누레이트 폼 형성용 폴리올 조성물 및 이를 이용한 파이프 커버용 폴리이소시아누레이트 폼
CN116601196A (zh) * 2020-11-25 2023-08-15 巴斯夫欧洲公司 醛释放减少的聚氨酯
CN112661646A (zh) * 2020-12-11 2021-04-16 江苏长能节能新材料科技有限公司 活泼亚甲基型除醛剂及其应用
KR102517508B1 (ko) * 2021-04-23 2023-04-04 현대트랜시스 주식회사 휘발성 유기화합물 방출량을 저감시킨 폴리우레탄 수지 조성물, 이를 이용하여 폴리우레탄 폼 성형체를 제조하는 방법 및 상기 방법에 의해 제조된 폴리우레탄 폼 성형체
US20240279382A1 (en) 2021-06-14 2024-08-22 Basf Se Polyamines as aldehyde scavengers
CN115746387A (zh) * 2021-09-03 2023-03-07 欧拓管理股份有限公司 用于车辆的模制内部装饰部件的voc处理
CN114031739B (zh) * 2021-11-24 2023-03-28 杨骏 醛化合物发泡的环保聚氨酯泡沫塑料及其制造方法和应用

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ES2819454T8 (es) 2021-04-27
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US20180171064A1 (en) 2018-06-21
EP3310824B1 (en) 2020-08-12
EP3310824A1 (en) 2018-04-25
CN107735419A (zh) 2018-02-23
EP3310824A4 (en) 2019-03-13
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