PL3842411T3 - Ester trimetylowy kwasu 3,3',3''-(cykloheksano-1,2,4-triylo)tripropionowego - Google Patents
Ester trimetylowy kwasu 3,3',3''-(cykloheksano-1,2,4-triylo)tripropionowegoInfo
- Publication number
- PL3842411T3 PL3842411T3 PL20193080.7T PL20193080T PL3842411T3 PL 3842411 T3 PL3842411 T3 PL 3842411T3 PL 20193080 T PL20193080 T PL 20193080T PL 3842411 T3 PL3842411 T3 PL 3842411T3
- Authority
- PL
- Poland
- Prior art keywords
- triyl
- cyclohexane
- acid trimethyl
- trimethyl ester
- tripropionic acid
- Prior art date
Links
- BAPSRHABEMVGMM-UHFFFAOYSA-N C1(C(CC(CC1)CCC(=O)OC)CCC(=O)OC)CCC(=O)OC Chemical compound C1(C(CC(CC1)CCC(=O)OC)CCC(=O)OC)CCC(=O)OC BAPSRHABEMVGMM-UHFFFAOYSA-N 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/608—Esters of carboxylic acids having a carboxyl group bound to an acyclic carbon atom and having a ring other than a six-membered aromatic ring in the acid moiety
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/62—Use of additives, e.g. for stabilisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/462—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
- C07C67/40—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester by oxidation of primary alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C09D127/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
- B01J2231/49—Esterification or transesterification
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
- B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/824—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/842—Iron
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/003—Esters of saturated alcohols having the esterified hydroxy group bound to an acyclic carbon atom
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP19216884.7A EP3838886B1 (de) | 2019-12-17 | 2019-12-17 | Alkoxycarbonylierung von trivinylcyclohexan |
| EP20193080.7A EP3842411B1 (de) | 2019-12-17 | 2019-12-17 | 3,3',3''-(cyclohexan-1,2,4-triyl)tripropionsäuretrimethylester |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL3842411T3 true PL3842411T3 (pl) | 2023-10-02 |
Family
ID=68944161
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL20193080.7T PL3842411T3 (pl) | 2019-12-17 | 2019-12-17 | Ester trimetylowy kwasu 3,3',3''-(cykloheksano-1,2,4-triylo)tripropionowego |
| PL19216884.7T PL3838886T3 (pl) | 2019-12-17 | 2019-12-17 | Alkoksykarbonylowanie triwinylocykloheksanu |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL19216884.7T PL3838886T3 (pl) | 2019-12-17 | 2019-12-17 | Alkoksykarbonylowanie triwinylocykloheksanu |
Country Status (12)
| Country | Link |
|---|---|
| US (2) | US11629115B2 (pl) |
| EP (2) | EP3838886B1 (pl) |
| JP (2) | JP7532224B2 (pl) |
| KR (1) | KR102848607B1 (pl) |
| CN (1) | CN112979468B (pl) |
| CA (1) | CA3102638C (pl) |
| ES (2) | ES2953133T3 (pl) |
| MY (1) | MY194660A (pl) |
| PL (2) | PL3842411T3 (pl) |
| SG (1) | SG10202012353QA (pl) |
| TW (1) | TWI787686B (pl) |
| ZA (1) | ZA202007803B (pl) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP4703422A1 (de) | 2024-09-03 | 2026-03-04 | Evonik Oxeno GmbH & Co. KG | Weichmacherzusammensetzung enthaltend trimethylester der 1,2,4-cyclohexantripropionsäure und einen 1,4-dialkylcyclohexandicarbonsäureester |
| EP4703420A1 (de) * | 2024-09-03 | 2026-03-04 | Evonik Oxeno GmbH & Co. KG | Weichmacherzusammensetzung enthaltend c4- bis c9-alkylester der 1,2,4-cyclohexantripropionsäure und dibutylterephthalat oder dipentylterephthalat |
| EP4703346A1 (de) | 2024-09-03 | 2026-03-04 | Evonik Oxeno GmbH & Co. KG | Weichmacherzusammensetzung enthaltend trimethylester der 1,2,4-cyclohexantripropionsäure und 1,2-dialkylcyclohexandicarbonsäureester |
| EP4703421A1 (de) | 2024-09-03 | 2026-03-04 | Evonik Oxeno GmbH & Co. KG | Weichmacherzusammensetzung enthaltend trimethylester der 1,2,4-cyclohexantripropionsäure und einen dialkylterephthalsäureester |
| EP4703423A1 (de) | 2024-09-03 | 2026-03-04 | Evonik Oxeno GmbH & Co. KG | Weichmacherzusammensetzung enthaltend trimethylester der 1,2,4-cyclohexantripropionsäure und deren längerkettige derivate |
| EP4703418A1 (de) | 2024-09-03 | 2026-03-04 | Evonik Oxeno GmbH & Co. KG | Weichmacherzusammensetzung enthaltend trimethylester der 1,2,4-cyclohexantripropionsäure und dialkylphthalsäureester |
| EP4703348A1 (de) | 2024-09-03 | 2026-03-04 | Evonik Oxeno GmbH & Co. KG | Mischester der 1,2,4-cyclohexantripropionsäure und eine weichmacherzusammensetzung enthaltend die mischester |
| EP4703419A1 (de) | 2024-09-03 | 2026-03-04 | Evonik Oxeno GmbH & Co. KG | Weichmacherzusammensetzung enthaltend trimethylester der 1,2,4-cyclohexantripropionsäure und ein trialkyltrimellitat |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4101355A1 (de) | 1991-01-18 | 1992-07-23 | Huels Chemische Werke Ag | Carboxylgruppenhaltige cyclohexanderivate |
| WO2006106483A1 (en) * | 2005-04-05 | 2006-10-12 | Firmenich Sa | Hydrogenation of esters with ru/bidentate ligands complexes |
| JP5451209B2 (ja) | 2008-07-08 | 2014-03-26 | 国立大学法人東京工業大学 | エステル類およびラクトン類の実用的な還元方法 |
| WO2011048727A1 (ja) * | 2009-10-23 | 2011-04-28 | 高砂香料工業株式会社 | 3座配位子を有する新規ルテニウムカルボニル錯体、並びにその製造法及び用途 |
| US20170022138A1 (en) * | 2015-07-23 | 2017-01-26 | Evonik Degussa Gmbh | Butyl-bridged diphosphine ligands for alkoxycarbonylation |
| JP6610236B2 (ja) * | 2015-12-21 | 2019-11-27 | 東洋インキScホールディングス株式会社 | カーボンナノファイバー含有架橋性組成物、および、カーボンナノファイバー複合体 |
| EP3272733B1 (de) * | 2016-07-19 | 2019-01-02 | Evonik Degussa GmbH | Verfahren zur alkoxycarbonylierung von olefinen in einem medium mit geringer brønstedsäurenkonzentration |
| ES2807545T3 (es) * | 2017-12-21 | 2021-02-23 | Evonik Operations Gmbh | Procedimiento para la hidroxicarbonilación de diisobuteno catalizada con Pd: proporción ácido acético/diisobuteno |
| EP3838888B1 (de) | 2019-12-17 | 2022-03-30 | Evonik Operations GmbH | Triester der cyclohexantripropionsäure |
-
2019
- 2019-12-17 PL PL20193080.7T patent/PL3842411T3/pl unknown
- 2019-12-17 EP EP19216884.7A patent/EP3838886B1/de active Active
- 2019-12-17 PL PL19216884.7T patent/PL3838886T3/pl unknown
- 2019-12-17 ES ES20193080T patent/ES2953133T3/es active Active
- 2019-12-17 EP EP20193080.7A patent/EP3842411B1/de active Active
- 2019-12-17 ES ES19216884T patent/ES2953067T3/es active Active
-
2020
- 2020-11-24 JP JP2020194198A patent/JP7532224B2/ja active Active
- 2020-12-10 SG SG10202012353QA patent/SG10202012353QA/en unknown
- 2020-12-14 KR KR1020200174209A patent/KR102848607B1/ko active Active
- 2020-12-14 CA CA3102638A patent/CA3102638C/en active Active
- 2020-12-14 TW TW109144086A patent/TWI787686B/zh active
- 2020-12-15 US US17/122,187 patent/US11629115B2/en active Active
- 2020-12-15 MY MYPI2020006693A patent/MY194660A/en unknown
- 2020-12-15 ZA ZA2020/07803A patent/ZA202007803B/en unknown
- 2020-12-16 CN CN202011488750.XA patent/CN112979468B/zh active Active
-
2023
- 2023-03-07 US US18/179,456 patent/US12077494B2/en active Active
-
2024
- 2024-03-07 JP JP2024034883A patent/JP7610054B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN112979468A (zh) | 2021-06-18 |
| CN112979468B (zh) | 2025-05-13 |
| EP3842411B1 (de) | 2023-05-31 |
| ES2953067T3 (es) | 2023-11-07 |
| KR20210077610A (ko) | 2021-06-25 |
| MY194660A (en) | 2022-12-12 |
| EP3842411A1 (de) | 2021-06-30 |
| CA3102638A1 (en) | 2021-06-17 |
| ES2953133T3 (es) | 2023-11-08 |
| US12077494B2 (en) | 2024-09-03 |
| EP3838886B1 (de) | 2023-05-31 |
| JP7532224B2 (ja) | 2024-08-13 |
| JP2024069345A (ja) | 2024-05-21 |
| TWI787686B (zh) | 2022-12-21 |
| US20210179532A1 (en) | 2021-06-17 |
| JP7610054B2 (ja) | 2025-01-07 |
| CA3102638C (en) | 2025-12-16 |
| US20230219877A1 (en) | 2023-07-13 |
| PL3838886T3 (pl) | 2023-09-18 |
| SG10202012353QA (en) | 2021-07-29 |
| JP2021095390A (ja) | 2021-06-24 |
| TW202136190A (zh) | 2021-10-01 |
| KR102848607B1 (ko) | 2025-08-22 |
| US11629115B2 (en) | 2023-04-18 |
| ZA202007803B (en) | 2021-10-27 |
| EP3838886A1 (de) | 2021-06-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| PL3842411T3 (pl) | Ester trimetylowy kwasu 3,3',3''-(cykloheksano-1,2,4-triylo)tripropionowego | |
| GB2592117B (en) | Oral solution cannabinoid formulations | |
| IL288423A (en) | Cannabinoid formulations | |
| GB201905876D0 (en) | Cannabidiol preparations | |
| EP4516355A3 (en) | Stable cannabinoid formulations | |
| EP4470613A3 (en) | Pth prodrugs | |
| EP4279071A3 (en) | Novel cannabinoid formulations | |
| EP4112611A3 (en) | Modulators of sestrin-gator2 interaction and uses thereof | |
| EP3797815B8 (en) | Respiratory system | |
| HK1246780A1 (zh) | 氮杂-吡啶酮化合物及其用途 | |
| EP4072553A4 (en) | CARIPRAZINE RELEASE COMPOSITIONS | |
| SG11202109102PA (en) | Pharmaceutical formulations | |
| EP3955962A4 (en) | SIALYLATED GLYCOPROTEINS | |
| IL287224A (en) | New formulations containing melphalan | |
| EP3984854A4 (en) | BOGGIE | |
| GB201915516D0 (en) | Cannabidivarin preparations | |
| SI3619199T1 (sl) | Priprava derivatov 2-((1,2,3)triazol-2-il)-benzojske kisline | |
| SG11202104371XA (en) | 1,3,4-oxadiazolone compound and pharmaceutical | |
| CL2016001745A1 (es) | Ácido (s)-3'-metil-abscísico y ésteres del mismo | |
| PH12016502592A1 (en) | 3'-substituted-abscisic acid derivatives | |
| AU2016250265A8 (en) | (S)-2'-vinyl-abscisic acid derivatives | |
| IL283609A (en) | Treatment by oral administration of 6, 8-bis-benzylthio-octanoic acid | |
| EP4062976A4 (en) | CARBALYSOPHOSPHATIDIC ACID | |
| GB201917381D0 (en) | Phagocytosed self-assembling proteins | |
| MX2018010652A (es) | Composiciones farmaceuticas. |