PL408565A1 - Sieci metalo-organiczne typu MOF o wzorze [M2(dcx)2L2], zawierające dikarboksylany (dcx) oraz hydrazony (L), sposób ich otrzymywania i zastosowanie - Google Patents

Sieci metalo-organiczne typu MOF o wzorze [M2(dcx)2L2], zawierające dikarboksylany (dcx) oraz hydrazony (L), sposób ich otrzymywania i zastosowanie

Info

Publication number
PL408565A1
PL408565A1 PL408565A PL40856514A PL408565A1 PL 408565 A1 PL408565 A1 PL 408565A1 PL 408565 A PL408565 A PL 408565A PL 40856514 A PL40856514 A PL 40856514A PL 408565 A1 PL408565 A1 PL 408565A1
Authority
PL
Poland
Prior art keywords
dcx
mof
dicarboxylates
hydrazones
obtaining
Prior art date
Application number
PL408565A
Other languages
English (en)
Other versions
PL232317B1 (pl
Inventor
Dariusz Matoga
Kornel Roztocki
Original Assignee
Univ Jagielloński
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Jagielloński filed Critical Univ Jagielloński
Priority to PL408565A priority Critical patent/PL232317B1/pl
Priority to PCT/IB2015/054558 priority patent/WO2015193820A1/en
Priority to EP15750111.5A priority patent/EP3154987B1/en
Priority to US15/318,678 priority patent/US10307730B2/en
Publication of PL408565A1 publication Critical patent/PL408565A1/pl
Publication of PL232317B1 publication Critical patent/PL232317B1/pl

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/223Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
    • B01J20/226Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/3085Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235Nitrogen containing compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1691Coordination polymers, e.g. metal-organic frameworks [MOF]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2204Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208Oxygen, e.g. acetylacetonates
    • B01J31/2226Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2239Bridging ligands, e.g. OAc in Cr2(OAc)4, Pt4(OAc)8 or dicarboxylate ligands
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C07F1/005Compounds containing elements of Groups 1 or 11 of the Periodic Table without C-Metal linkages
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/04Nickel compounds
    • C07F15/045Nickel compounds without a metal-carbon linkage
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/06Cobalt compounds
    • C07F15/065Cobalt compounds without a metal-carbon linkage
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00Compounds containing elements of Groups 2 or 12 of the Periodic Table
    • C07F3/003Compounds containing elements of Groups 2 or 12 of the Periodic Table without C-Metal linkages
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/003Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/056Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/16Copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/26Zinc
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/27Cadmium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72Manganese
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84Metals of the iron group
    • B01J2531/845Cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84Metals of the iron group
    • B01J2531/847Nickel
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/054Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/002Inorganic electrolyte
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0025Organic electrolyte
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pyridine Compounds (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

Przedmiotem rozwiązania są polimery koordynacyjne typu MOF, zawierają powtarzalną jednostkę o wzorze ogólnym [M2(dcx)2(L)2], przy czym M oznacza kation metalu (M2+), dcx oznacza anion kwasu dikarboksylowego i L oznacza obojętną cząsteczkę hydrazonu oraz sposób wytwarzania polimerów koordynacyjnych typu MOF, w którym w pierwszym etapie związek z grupy aldehydów lub ketonów poddaje się reakcji kondensacji z hydrazydem, a w drugim etapie produkt kondensacji poddaje się reakcji z użyciem związku metalu oraz kwasu dikarboksylowego. Ujawniono też zastosowanie polimerów koordynacyjnych typu MOF do wykrywania, wyłapywania, separacji lub magazynowania cząsteczek, do wytwarzania przewodników jonowych, do budowy baterii i ogniw paliwowych oraz jako nośniki leków.
PL408565A 2014-06-16 2014-06-16 Polimer koordynacyjny typu MOF PL232317B1 (pl)

Priority Applications (4)

Application Number Priority Date Filing Date Title
PL408565A PL232317B1 (pl) 2014-06-16 2014-06-16 Polimer koordynacyjny typu MOF
PCT/IB2015/054558 WO2015193820A1 (en) 2014-06-16 2015-06-16 METAL-ORGANIC FRAMEWORKS (MOFs), METHOD FOR THEIR PREPARATION AND THEIR APPLICATION
EP15750111.5A EP3154987B1 (en) 2014-06-16 2015-06-16 Metal-organic frameworks, method for their preparation and their application
US15/318,678 US10307730B2 (en) 2014-06-16 2015-06-16 Metal-organic frameworks (MOFs), method for their preparation and their application

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL408565A PL232317B1 (pl) 2014-06-16 2014-06-16 Polimer koordynacyjny typu MOF

Publications (2)

Publication Number Publication Date
PL408565A1 true PL408565A1 (pl) 2015-12-21
PL232317B1 PL232317B1 (pl) 2019-06-28

Family

ID=53836128

Family Applications (1)

Application Number Title Priority Date Filing Date
PL408565A PL232317B1 (pl) 2014-06-16 2014-06-16 Polimer koordynacyjny typu MOF

Country Status (4)

Country Link
US (1) US10307730B2 (pl)
EP (1) EP3154987B1 (pl)
PL (1) PL232317B1 (pl)
WO (1) WO2015193820A1 (pl)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL443983A1 (pl) * 2023-03-07 2024-09-09 Uniwersytet Im. Adama Mickiewicza W Poznaniu Polimer koordynacyjny typu MOF

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11715864B2 (en) * 2017-02-07 2023-08-01 Ford Cheer International Limited Metal-organic-framework (MOF) coated composite separators for electrochemical devices and applications of same
KR102044806B1 (ko) * 2017-02-15 2019-11-15 기초과학연구원 신규한 화합물 및 이의 용도
CN108623814B (zh) * 2017-03-23 2020-10-16 中国石油化工股份有限公司 一种铜基多孔配位聚合物储氢材料及其制备方法
CN107936263B (zh) * 2017-12-20 2020-06-05 淮北师范大学 一种具有光反应活性的配位聚合物及其制备方法和应用
JP2019163228A (ja) * 2018-03-20 2019-09-26 株式会社東芝 金属有機構造体、蛍光体膜、および分子検出装置
CN109225338B (zh) * 2018-09-14 2020-05-08 中国石油大学(北京) 一种可循环使用的液相乙烯选择性二聚非均相催化剂及其制备方法
CN109593205B (zh) * 2018-10-25 2021-02-05 陕西科技大学 一种钴配位聚合物磁性材料及其制备方法和应用
CN109433159B (zh) * 2018-10-25 2021-05-18 陕西科技大学 一种钴配位聚合物碘蒸气负载材料及其制备方法和应用
CN109553780B (zh) * 2019-01-29 2020-12-04 北京化工大学 一种含铝的金属有机骨架材料的制备方法及其制得的材料
CN110683780A (zh) * 2019-09-03 2020-01-14 浙江大学 一种用于固化封存二氧化碳的改性粉煤灰及其制备方法
CN111763331B (zh) * 2020-08-25 2022-03-01 内蒙古农业大学 一种碱土金属[Mg(lna)2]n单晶吸附材料及其制备方法和应用
CN113817174B (zh) * 2021-09-27 2023-01-17 江苏大学 原位酰肼三维MOFs材料的制备方法及其用途
CN114349972A (zh) * 2022-01-14 2022-04-15 哈尔滨工业大学 一种利用回流搅拌法快速合成hkust-1的方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5648508A (en) 1995-11-22 1997-07-15 Nalco Chemical Company Crystalline metal-organic microporous materials
DE10111230A1 (de) 2001-03-08 2002-09-19 Basf Ag Metallorganische Gerüstmaterialien und Verfahren zu deren Herstellung
DE10355087A1 (de) 2003-11-24 2005-06-09 Basf Ag Verfahren zur elektrochemischen Herstellung eines kristallinen porösen metallorganischen Gerüstmaterials

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL443983A1 (pl) * 2023-03-07 2024-09-09 Uniwersytet Im. Adama Mickiewicza W Poznaniu Polimer koordynacyjny typu MOF

Also Published As

Publication number Publication date
US20180161755A1 (en) 2018-06-14
WO2015193820A1 (en) 2015-12-23
US10307730B2 (en) 2019-06-04
EP3154987B1 (en) 2020-12-02
EP3154987A1 (en) 2017-04-19
PL232317B1 (pl) 2019-06-28

Similar Documents

Publication Publication Date Title
PL408565A1 (pl) Sieci metalo-organiczne typu MOF o wzorze [M2(dcx)2L2], zawierające dikarboksylany (dcx) oraz hydrazony (L), sposób ich otrzymywania i zastosowanie
Kirillov Hexamethylenetetramine: An old new building block for design of coordination polymers
Lefevre et al. Contribution to the mechanism of copper-catalyzed C–N and C–O bond formation
Loiseau et al. Crystal chemistry of aluminium carboxylates: from molecular species towards porous infinite three-dimensional networks
MX377235B (es) Proceso mejorado para preparar bifenilanilidas y bifenilanilinas cloradas.
Pazderski 15N and 31P NMR coordination shifts in transition metal complexes with nitrogen-and phosphorus-containing heterocycles
Chachkov et al. Quantum-chemical calculation of molecular structures of (5656) macrotetracyclic 3 d-metal complexes “self-assembled” in quaternary systems M (II) ion-ethanedithioamide-formaldehyde-ammonia by the density functional theory method
Huang et al. Stepwise Encapsulation of Sulfate Ions by Ferrocenyl‐Functionalized Tripodal Hexaurea Receptors
Modak et al. Self-assembly of a “cationic-cage” via the formation of Ag–carbene bonds followed by imine condensation
Zhang et al. Chloride encapsulation by a tripodal tris (4-pyridylurea) ligand and effects of countercations on the secondary coordination sphere
Khandaker et al. Excitation functions of deuteron-induced nuclear reactions on natural platinum up to 24 MeV
CN105237576A (zh) 三核锰配合物及其制备方法
Sliznev et al. Vibrational Spectra of Cobalt (II), Nickel (II), Copper (II), Zinc (II) Etioporphyrins-II, MN 4 C 32 H 36
Tolkacheva et al. Formation constants and composition of Ga3+ and In3+ complexes with iminodisuccinic acid in aqueous solutions according to potentiometric data
Degtyarenko et al. Self-assembly cavitand precisely recognizing hexafluorosilicate: a concerted action of two coordination and twelve CH⋯ F bonds
Soldatenko et al. Chemical methods for producing copper nanoparticles
Develay et al. Cyclen based bis-macrocyclic ligands as phosphates receptors. A potentiometric and NMR study
Mikhailov et al. On the possibility of template synthesis through “cross-linkage” of chelate rings with trans-arranged donor atoms in M (II)–ethandithioamide–formaldehyde systems
Amendola et al. The interaction of Mozobil™ with carboxylates
Mikhailov et al. Molecular structures and stability of isomeric asymmetric (565) macrotricyclic chelates of 3 d metals in the M (II)-dithiooxamide-thiosemicarbazide-formaldehyde systems according to DFT calculations
Mikhailov et al. Quantum-chemical modeling of template synthesis in the ternary system metal (II) ion-thiosemicarbazide-diacetyl
JP2014214127A5 (pl)
Mutlu Gençkal et al. Synthesis, characterisation, and equilibrium studies of 1-(2-ethyl-1, 2, 3, 4-tetrahydro-quinazolin-2-yl)-ethanone oxime and the copper (II) complex of its open-chain tautomer
Shchepina et al. Nuclear-chemical synthesis of new nucleogenic cations–precursors for unknown biologically active heterocyclic derivatives
Zhao et al. A new PbII (ethylenediaminetetraacetate) coordination polymer with a two-dimensional layer structure