PL408698A1 - Method for obtaining methoxy derivatives of dibenz[b,f] oxepin - Google Patents
Method for obtaining methoxy derivatives of dibenz[b,f] oxepinInfo
- Publication number
- PL408698A1 PL408698A1 PL408698A PL40869814A PL408698A1 PL 408698 A1 PL408698 A1 PL 408698A1 PL 408698 A PL408698 A PL 408698A PL 40869814 A PL40869814 A PL 40869814A PL 408698 A1 PL408698 A1 PL 408698A1
- Authority
- PL
- Poland
- Prior art keywords
- oxepin
- dibenz
- methoxy derivatives
- obtaining
- dissolves
- Prior art date
Links
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 title abstract 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 abstract 3
- PXIPVTKHYLBLMZ-UHFFFAOYSA-N Sodium azide Chemical compound [Na+].[N-]=[N+]=[N-] PXIPVTKHYLBLMZ-UHFFFAOYSA-N 0.000 abstract 2
- LIBPVNZICNFUQK-AATRIKPKSA-N 2-[(e)-2-(2,4-dinitrophenyl)ethenyl]phenol Chemical compound OC1=CC=CC=C1\C=C\C1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O LIBPVNZICNFUQK-AATRIKPKSA-N 0.000 abstract 1
- UKZDBVIEPQUMTA-UHFFFAOYSA-N 2-nitrobenzo[b][1]benzoxepine Chemical class C1=CC2=CC=CC=C2OC2=CC([N+](=O)[O-])=CC=C21 UKZDBVIEPQUMTA-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
Landscapes
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
Sposób otrzymywania nowych pochodnych 7-nitrodibenzo[b,f]oksepin o wzorze ogólnym 1, gdzie R1, R2, R3, R4 oznaczają niezależnie wodór lub grupę metoksylową, przy czym co najmniej jedna z grup R1, R2, R3, R4 oznacza grupę metoksylową, polega na tym, że (E)-2'-hydroksy-2,4-dinitrostilben o wzorze ogólnym 2, gdzie R1, R2, R3, R4 mają podane powyżej znaczenie, rozpuszcza się w rozpuszcza się w dimetyloformamidzie w temperaturze 90 - 130°C z dodatkiem azydku sodu.The method of obtaining new 7-nitrodibenzo [b, f] oxepine derivatives of general formula 1, where R1, R2, R3, R4 are independently hydrogen or methoxy, where at least one of R1, R2, R3, R4 is methoxy , consists in the fact that (E) -2'-hydroxy-2,4-dinitrostilbene of general formula 2, where R1, R2, R3, R4 have the meanings given above, dissolves in dissolves in dimethylformamide at a temperature of 90 - 130 ° C with addition of sodium azide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL408698A PL228768B1 (en) | 2014-06-30 | 2014-06-30 | Method for obtaining methoxy derivatives of dibenz[b,f] oxepin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL408698A PL228768B1 (en) | 2014-06-30 | 2014-06-30 | Method for obtaining methoxy derivatives of dibenz[b,f] oxepin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL408698A1 true PL408698A1 (en) | 2016-01-04 |
| PL228768B1 PL228768B1 (en) | 2018-05-30 |
Family
ID=54978721
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL408698A PL228768B1 (en) | 2014-06-30 | 2014-06-30 | Method for obtaining methoxy derivatives of dibenz[b,f] oxepin |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL228768B1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL424768A1 (en) * | 2018-03-05 | 2019-09-09 | Politechnika Warszawska | Method for obtaining dibenzo[b,f]oxepine derivatives substituted in aromatic ring |
| PL443656A1 (en) * | 2023-02-01 | 2024-08-05 | Politechnika Warszawska | Amine derivatives of dihydrodibenzo[b,f]oxepins and a method of their production |
-
2014
- 2014-06-30 PL PL408698A patent/PL228768B1/en unknown
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL424768A1 (en) * | 2018-03-05 | 2019-09-09 | Politechnika Warszawska | Method for obtaining dibenzo[b,f]oxepine derivatives substituted in aromatic ring |
| PL443656A1 (en) * | 2023-02-01 | 2024-08-05 | Politechnika Warszawska | Amine derivatives of dihydrodibenzo[b,f]oxepins and a method of their production |
| PL247188B1 (en) * | 2023-02-01 | 2025-05-26 | Politechnika Warszawska | Amine derivatives of dihydrodibenzo[b,f]oxepins and the method of obtaining them |
Also Published As
| Publication number | Publication date |
|---|---|
| PL228768B1 (en) | 2018-05-30 |
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