PL409041A1 - Polyampholites derivatives of dimethylphosphonic acid, polyalkyenepolyamines and imino-bis metylphosphonic acid and method to produce them - Google Patents
Polyampholites derivatives of dimethylphosphonic acid, polyalkyenepolyamines and imino-bis metylphosphonic acid and method to produce themInfo
- Publication number
- PL409041A1 PL409041A1 PL409041A PL40904114A PL409041A1 PL 409041 A1 PL409041 A1 PL 409041A1 PL 409041 A PL409041 A PL 409041A PL 40904114 A PL40904114 A PL 40904114A PL 409041 A1 PL409041 A1 PL 409041A1
- Authority
- PL
- Poland
- Prior art keywords
- acid
- iminobis
- fragment
- fragments
- bis
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- HZCDANOFLILNSA-UHFFFAOYSA-N Dimethyl hydrogen phosphite Chemical class COP(=O)OC HZCDANOFLILNSA-UHFFFAOYSA-N 0.000 title 1
- 239000002253 acid Substances 0.000 title 1
- 239000012634 fragment Substances 0.000 abstract 9
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 6
- 229920001281 polyalkylene Polymers 0.000 abstract 5
- 229920000768 polyamine Polymers 0.000 abstract 5
- ISQSUCKLLKRTBZ-UHFFFAOYSA-N (phosphonomethylamino)methylphosphonic acid Chemical compound OP(O)(=O)CNCP(O)(O)=O ISQSUCKLLKRTBZ-UHFFFAOYSA-N 0.000 abstract 4
- GOJNABIZVJCYFL-UHFFFAOYSA-N dimethylphosphinic acid Chemical compound CP(C)(O)=O GOJNABIZVJCYFL-UHFFFAOYSA-N 0.000 abstract 4
- OTBHHUPVCYLGQO-UHFFFAOYSA-N 1,7-diamino-4-aza-heptane Natural products NCCCNCCCN OTBHHUPVCYLGQO-UHFFFAOYSA-N 0.000 abstract 2
- VHRGRCVQAFMJIZ-UHFFFAOYSA-N cadaverine Chemical compound NCCCCCN VHRGRCVQAFMJIZ-UHFFFAOYSA-N 0.000 abstract 2
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 abstract 2
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 abstract 2
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 abstract 1
- JZUHIOJYCPIVLQ-UHFFFAOYSA-N 2-methylpentane-1,5-diamine Chemical compound NCC(C)CCCN JZUHIOJYCPIVLQ-UHFFFAOYSA-N 0.000 abstract 1
- RXFCIXRFAJRBSG-UHFFFAOYSA-N 3,2,3-tetramine Chemical compound NCCCNCCNCCCN RXFCIXRFAJRBSG-UHFFFAOYSA-N 0.000 abstract 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 abstract 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 abstract 1
- 239000005700 Putrescine Substances 0.000 abstract 1
- MRNZSTMRDWRNNR-UHFFFAOYSA-N bis(hexamethylene)triamine Chemical compound NCCCCCCNCCCCCCN MRNZSTMRDWRNNR-UHFFFAOYSA-N 0.000 abstract 1
- 238000004132 cross linking Methods 0.000 abstract 1
- SSJXIUAHEKJCMH-UHFFFAOYSA-N cyclohexane-1,2-diamine Chemical compound NC1CCCCC1N SSJXIUAHEKJCMH-UHFFFAOYSA-N 0.000 abstract 1
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 abstract 1
- DTSDBGVDESRKKD-UHFFFAOYSA-N n'-(2-aminoethyl)propane-1,3-diamine Chemical compound NCCCNCCN DTSDBGVDESRKKD-UHFFFAOYSA-N 0.000 abstract 1
- LSHROXHEILXKHM-UHFFFAOYSA-N n'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine Chemical compound NCCNCCNCCNCCNCCN LSHROXHEILXKHM-UHFFFAOYSA-N 0.000 abstract 1
- UCJKJXHYIQBION-UHFFFAOYSA-N n-[hydroxy(methoxy)phosphoryl]-methoxyphosphonamidic acid Chemical group COP(O)(=O)NP(O)(=O)OC UCJKJXHYIQBION-UHFFFAOYSA-N 0.000 abstract 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Landscapes
- Phenolic Resins Or Amino Resins (AREA)
Abstract
Wynalazek dotyczy poliamfolitów pochodnych kwasu dimetylofosfinowego, polialkilenopoliamin i kwasu iminobis(metylofosfonowego) o wzorze ogólnym I, w którym A oznacza fragment struktury kwasu dimetylofosfinowego, x oznacza liczbę takich fragmentów w poliamfolicie, natomiast B oznacza fragment struktury polialkilenopoliaminy, w którym n i p mogą być takie same lub różne i oznaczają liczby całkowite od 2 do 12, natomiast q jest liczbą struktur aminopolialkenowych i wynosi od 2 do 6, y oznacza liczbę fragmentów poliaminopolialkenowych w polimerze, natomiast C oznacza fragment struktury kwasu iminobis(metylofosfonowego), a z oznacza liczbę takich fragmentów w poliamfolicie, przy czym wolne miejsca fragmentu A mogą się wiązać tylko z wolnymi miejscami we fragmencie B i C. Wynalazek dotyczy również sposobu wytwarzania poliamfolitów pochodnych kwasu dimetylofosfinowego, polialkilenopoliamin i kwasu iminobis(metylofosfonowego), o wzorze ogólnym I, który polega na tym, że w pierwszym etapie jedną część molową kwasu fosfinowego poddaje się reakcji z co najmniej jedną częścią molową formaldehydu i co najmniej dwiema częściami molowymi grup -NH-, na które składa się suma grup -NH-pochodzących od polialkilenopoliaminy wybranej z grupy zawierającej: 1,2-diaminoetan, 1,3-diaminopropan, 1,4-diaminobutan, 1,5-diaminopentan, 1,6-diaminoheksan, 2-metylo-1,5-diaminopentan, 1,2-diaminocykloheksan, bis(heksametyleno)triaminę, dietylenotriaminę, N-(3-aminopropylo)-1,3-diaminopropan, N-(2-aminoetylo)-1,3-diaminopropan, N,N'-bis(3-aminopropylo)etylenodiaminę, trietylenotetraminę, tetraetylenopentaminę i pentaetylenoheksaminę, i grup -NH- pochodzących od kwasu iminobis(metylofosfonowego), a reakcję prowadzi się w temperaturze 273-373K, w wodzie, aż do przereagowania substratów i utworzenia się poliamfolitu zawierającego fragmenty strukturalne kwasu dimetylofosfinowego, polialkilenopoliaminy i kwasu iminobis(metylofosfonowego), który w trzecim etapie poddaje się dosieciowaniu co najmniej 0,5 części molowej formaldehydu.The invention relates to polyampholytes derived from dimethylphosphinic acid, polyalkylene polyamines and iminobis(methylphosphonic acid) of the general formula I, in which A is a fragment of the dimethylphosphinic acid structure, x is the number of such fragments in the polyampholyte, and B is a fragment of the polyalkylene polyamine structure, in which n and p may be the same or different and mean integers from 2 to 12, while q is the number of aminopolyalkene structures and is from 2 to 6, y means the number of polyaminopolyalkene fragments in the polymer, while C means a fragment of the iminobis(methylphosphonic acid) structure, and z means the number of such fragments in the polyampholyte , whereby the free sites of fragment A can only bind to the free sites in fragment B and C. The invention also relates to a method for preparing polyampholytes derivatives of dimethylphosphinic acid, polyalkylene polyamines and iminobis(methylphosphonic acid), with the general formula I, which consists in in the first step, one mole part of phosphinic acid is reacted with at least one mole part of formaldehyde and at least two mole parts of -NH- groups, which consist of the sum of -NH- groups derived from a polyalkylene polyamine selected from the group containing: 1,2-diaminoethane , 1,3-diaminopropane, 1,4-diaminobutane, 1,5-diaminopentane, 1,6-diaminohexane, 2-methyl-1,5-diaminopentane, 1,2-diaminocyclohexane, bis(hexamethylene)triamine, diethylenetriamine, N -(3-aminopropyl)-1,3-diaminopropane, N-(2-aminoethyl)-1,3-diaminopropane, N,N'-bis(3-aminopropyl)ethylenediamine, triethylenetetramine, tetraethylenepentamine and pentaethylenehexamine, and -NH groups - derived from iminobis(methylphosphonic acid), and the reaction is carried out at a temperature of 273-373K, in water, until the reactants are reacted and polyampholyte is formed containing structural fragments of dimethylphosphinic acid, polyalkylene polyamine and iminobis(methylphosphonic acid), which in the third stage is subjected to cross-linking with at least 0.5 mole of formaldehyde.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL409041A PL223385B1 (en) | 2014-07-31 | 2014-07-31 | Polyampholites derivatives of dimethylphosphonic acid, polyalkyenepolyamines and imino-bis metylphosphonic acid and method to produce them |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL409041A PL223385B1 (en) | 2014-07-31 | 2014-07-31 | Polyampholites derivatives of dimethylphosphonic acid, polyalkyenepolyamines and imino-bis metylphosphonic acid and method to produce them |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL409041A1 true PL409041A1 (en) | 2015-03-02 |
| PL223385B1 PL223385B1 (en) | 2016-10-31 |
Family
ID=52574572
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL409041A PL223385B1 (en) | 2014-07-31 | 2014-07-31 | Polyampholites derivatives of dimethylphosphonic acid, polyalkyenepolyamines and imino-bis metylphosphonic acid and method to produce them |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL223385B1 (en) |
-
2014
- 2014-07-31 PL PL409041A patent/PL223385B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL223385B1 (en) | 2016-10-31 |
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