PL413492A1 - Protonic salts of diphenoconazol with organic anion, method for obtaining them and their application as fungicides - Google Patents
Protonic salts of diphenoconazol with organic anion, method for obtaining them and their application as fungicidesInfo
- Publication number
- PL413492A1 PL413492A1 PL413492A PL41349215A PL413492A1 PL 413492 A1 PL413492 A1 PL 413492A1 PL 413492 A PL413492 A PL 413492A PL 41349215 A PL41349215 A PL 41349215A PL 413492 A1 PL413492 A1 PL 413492A1
- Authority
- PL
- Poland
- Prior art keywords
- organic anion
- fungicides
- salts
- diphenoconazol
- protonic
- Prior art date
Links
- 150000002891 organic anions Chemical class 0.000 title abstract 4
- 239000000417 fungicide Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 150000003839 salts Chemical class 0.000 title abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 abstract 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-M 3-carboxy-2-(carboxymethyl)-2-hydroxypropanoate Chemical compound OC(=O)CC(O)(C(O)=O)CC([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-M 0.000 abstract 1
- PXRKCOCTEMYUEG-UHFFFAOYSA-N 5-aminoisoindole-1,3-dione Chemical compound NC1=CC=C2C(=O)NC(=O)C2=C1 PXRKCOCTEMYUEG-UHFFFAOYSA-N 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000005760 Difenoconazole Substances 0.000 abstract 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-M L-tartrate(1-) Chemical compound OC(=O)[C@H](O)[C@@H](O)C([O-])=O FEWJPZIEWOKRBE-JCYAYHJZSA-M 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Natural products OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract 1
- 229940120124 dichloroacetate Drugs 0.000 abstract 1
- JXTHNDFMNIQAHM-UHFFFAOYSA-N dichloroacetic acid Chemical compound OC(=O)C(Cl)Cl JXTHNDFMNIQAHM-UHFFFAOYSA-N 0.000 abstract 1
- BQYJATMQXGBDHF-UHFFFAOYSA-N difenoconazole Chemical compound O1C(C)COC1(C=1C(=CC(OC=2C=CC(Cl)=CC=2)=CC=1)Cl)CN1N=CN=C1 BQYJATMQXGBDHF-UHFFFAOYSA-N 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-M oxalate(1-) Chemical compound OC(=O)C([O-])=O MUBZPKHOEPUJKR-UHFFFAOYSA-M 0.000 abstract 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 abstract 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 abstract 1
- 229960001860 salicylate Drugs 0.000 abstract 1
- 229960004889 salicylic acid Drugs 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Przedmiotem wynalazku są protonowe sole difenokonazolu z anionem organicznym, o wzorze ogólnym 1, w którym A- oznacza: anion organiczny: diwodorocytrynianowy lub salicylanowy, lub wodorowinianowy, lub wodoroszczawianowy, lub dichlorooctanowy, sposób ich otrzymywania oraz zastosowania jako fungicydów. Sposób ich otrzymywania polega na tym, że difenokonazol rozpuszcza się w alkoholu alifatycznym o długości łańcucha węglowego od jednego do czterech atomów węgla, lub ich mieszaninie, korzystnie w metanolu, dalej miesza się z metanolowym roztworem kwasu cytrynowego lub salicylowego, lub winowego, lub szczawiowego, lub dichlorooctowego, o stężeniu co najmniej 1%, w stosunku molowym od 1:1 do 1:1,05, korzystnie 1:1, w temperaturze poniżej 100°C, korzystnie w 20°C, w czasie co 4 najmniej 40 minut, po czym usuwa się rozpuszczalnik. Ujawniono także zastosowanie nowych protonowych soli difenokonazolu z anionem organicznym jako fungicydów.The subject of the invention are proton salts of diphenoconazole with an organic anion, of general formula 1, wherein A- is: an organic anion: dihydrogen citrate or salicylate, or hydrogen tartrate, or hydrogen oxalate, or dichloroacetate, the method of their preparation and their use as fungicides. The method of their preparation consists in the fact that difenoconazole dissolves in an aliphatic alcohol with a carbon chain length of one to four carbon atoms, or a mixture thereof, preferably in methanol, is further mixed with a methanolic solution of citric or salicylic acid, or tartaric or oxalic, or dichloroacetic, at a concentration of at least 1%, in a molar ratio of 1: 1 to 1: 1.05, preferably 1: 1, at a temperature below 100 ° C, preferably at 20 ° C, for at least every 40 minutes, after which the solvent is removed. The use of new proton salts of diphenoconazole with an organic anion as fungicides has also been disclosed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL413492A PL229317B1 (en) | 2015-08-10 | 2015-08-10 | Protonic salts of diphenoconazol with organic anion, method for obtaining them and their application as fungicides |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL413492A PL229317B1 (en) | 2015-08-10 | 2015-08-10 | Protonic salts of diphenoconazol with organic anion, method for obtaining them and their application as fungicides |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL413492A1 true PL413492A1 (en) | 2017-02-13 |
| PL229317B1 PL229317B1 (en) | 2018-07-31 |
Family
ID=57965468
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL413492A PL229317B1 (en) | 2015-08-10 | 2015-08-10 | Protonic salts of diphenoconazol with organic anion, method for obtaining them and their application as fungicides |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL229317B1 (en) |
-
2015
- 2015-08-10 PL PL413492A patent/PL229317B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL229317B1 (en) | 2018-07-31 |
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