PL413493A1 - Quaternary salts of diphenoconazol with inorganic anion, method for obtaining them and application as fungicides - Google Patents
Quaternary salts of diphenoconazol with inorganic anion, method for obtaining them and application as fungicidesInfo
- Publication number
- PL413493A1 PL413493A1 PL413493A PL41349315A PL413493A1 PL 413493 A1 PL413493 A1 PL 413493A1 PL 413493 A PL413493 A PL 413493A PL 41349315 A PL41349315 A PL 41349315A PL 413493 A1 PL413493 A1 PL 413493A1
- Authority
- PL
- Poland
- Prior art keywords
- diphenoconazole
- fungicides
- quaternary salts
- inorganic anion
- anion
- Prior art date
Links
- 150000003839 salts Chemical group 0.000 title abstract 4
- 150000001449 anionic compounds Chemical class 0.000 title abstract 3
- 239000000417 fungicide Substances 0.000 title abstract 3
- 229910001412 inorganic anion Inorganic materials 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 abstract 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 abstract 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical group [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 150000001805 chlorine compounds Chemical group 0.000 abstract 1
- 229910001959 inorganic nitrate Inorganic materials 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Przedmiotem wynalazku są czwartorzędowe sole difenokonazolu z anionem nieorganicznym o wzorze ogólnym 1, którym A- oznacza: anion nieorganiczny azotanowy(V) lub chlorkowy lub wodorosiarczanowy(VI) lub tetrafluoroborowy, sposób ich otrzymywania oraz zastosowania jako fungicydów. Sposób ich otrzymywania polega na tym, że czwartorzędowy chlorek, lub bromek difenokonazolu rozpuszcza się w alkoholu alifatycznym o długości łańcucha węglowego od jednego do czterech atomów węgla, lub ich mieszaninie, miesza się z metanolowym roztworem soli sodowej, lub potasowej, lub amonowej kwasu chlorowodorowego, azotowego(V), lub siarkowego(VI) lub tetrafluoroborowego, o stężeniu co najmniej 1%, w stosunku molowym chlorowodorku difenokonazolu do soli od 1:1 do 1:1,05, korzystnie 1:1, w temperaturze poniżej 100°C, korzystnie w 20°C, w czasie co najmniej 40 minut, następnie produkt izoluje się, po czym rozpuszczalnik usuwa się. Ujawniono także zastosowanie nowych czwartorzędowych soli difenokonazolu z anionem nieorganicznym jako fungicydów.The present invention relates to the quaternary salts of diphenoconazole with an inorganic anion of general formula 1, wherein A- means: an inorganic nitrate (V) or chloride or hydrogen sulfate (VI) or tetrafluoroboron anion, the method of their preparation and their use as fungicides. The method of their preparation is that the diphenoconazole quaternary chloride or bromide dissolves in an aliphatic alcohol with a carbon chain length of one to four carbon atoms, or a mixture thereof, mixed with a methanolic solution of sodium, potassium or ammonium hydrochloric acid. nitric (V) or sulfur (VI) or tetrafluoroboric, at a concentration of at least 1%, in a molar ratio of diphenoconazole hydrochloride to salt from 1: 1 to 1: 1.05, preferably 1: 1, at a temperature below 100 ° C, preferably at 20 ° C for at least 40 minutes, then the product is isolated and the solvent removed. The use of new quaternary salts of diphenoconazole with an inorganic anion as fungicides has also been disclosed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL413493A PL229316B1 (en) | 2015-08-10 | 2015-08-10 | Quaternary salts of diphenoconazol with inorganic anion, method for obtaining them and application as fungicides |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL413493A PL229316B1 (en) | 2015-08-10 | 2015-08-10 | Quaternary salts of diphenoconazol with inorganic anion, method for obtaining them and application as fungicides |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL413493A1 true PL413493A1 (en) | 2017-02-13 |
| PL229316B1 PL229316B1 (en) | 2018-07-31 |
Family
ID=57965335
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL413493A PL229316B1 (en) | 2015-08-10 | 2015-08-10 | Quaternary salts of diphenoconazol with inorganic anion, method for obtaining them and application as fungicides |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL229316B1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109593083B (en) * | 2018-12-28 | 2022-03-01 | 利民化学有限责任公司 | Preparation method of difenoconazole nitrate |
-
2015
- 2015-08-10 PL PL413493A patent/PL229316B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL229316B1 (en) | 2018-07-31 |
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