PL413629A1 - Method for obtaining allyl glycidol ether - Google Patents
Method for obtaining allyl glycidol etherInfo
- Publication number
- PL413629A1 PL413629A1 PL413629A PL41362915A PL413629A1 PL 413629 A1 PL413629 A1 PL 413629A1 PL 413629 A PL413629 A PL 413629A PL 41362915 A PL41362915 A PL 41362915A PL 413629 A1 PL413629 A1 PL 413629A1
- Authority
- PL
- Poland
- Prior art keywords
- hydrogen peroxide
- titanium
- glycidol ether
- catalyst
- diallyl ether
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 title 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 title 1
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 title 1
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 abstract 6
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 6
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- 239000010936 titanium Substances 0.000 abstract 2
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 abstract 1
- 238000006735 epoxidation reaction Methods 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
Landscapes
- Epoxy Compounds (AREA)
- Catalysts (AREA)
Abstract
Sposób otrzymywania eteru allilowo - glicydolowego, polegający na epoksydacji eteru diallilowego za pomocą 30% nadtlenku wodoru w obecności katalizatora tytanowo - silikalitowego TS - 1, w środowisku acetonitrylu jako rozpuszczalnika, charakteryzuje się tym, że do reaktora szklanego wprowadza się substraty w kolejności: katalizator tytanowo - silikalitowy TS - 1, eter diallilowy, acetonitryl, a na końcu 30% nadtlenek wodoru, przy czym ilość katalizatora tytanowo - silikalitowego TS - 1 w mieszaninie reakcyjnej wynosi od 1 do 9%, stosunek molowy eteru diallilowego do nadtlenku wodoru wynosi od 0,7 : 1 do 5 : 1, a stężenie metanolu wynosi od 10 do 90% wagowych.The method of obtaining allyl glycidyl ether, consisting of epoxidation of diallyl ether with 30% hydrogen peroxide in the presence of a TS - 1 titanium silicalite catalyst in an acetonitrile as solvent, is characterized by the introduction of substrates in the order of the titanium catalyst: - TS-1 silicalite, diallyl ether, acetonitrile, and finally 30% hydrogen peroxide, whereby the amount of TS-1 titanium-silica catalyst in the reaction mixture is from 1 to 9%, the molar ratio of diallyl ether to hydrogen peroxide is from 0, 7: 1 to 5: 1, and the methanol concentration is from 10 to 90% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL413629A PL228409B1 (en) | 2015-08-24 | 2015-08-24 | Method for obtaining allyl glycidol ether |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL413629A PL228409B1 (en) | 2015-08-24 | 2015-08-24 | Method for obtaining allyl glycidol ether |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL413629A1 true PL413629A1 (en) | 2017-02-27 |
| PL228409B1 PL228409B1 (en) | 2018-03-30 |
Family
ID=58092031
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL413629A PL228409B1 (en) | 2015-08-24 | 2015-08-24 | Method for obtaining allyl glycidol ether |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL228409B1 (en) |
-
2015
- 2015-08-24 PL PL413629A patent/PL228409B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL228409B1 (en) | 2018-03-30 |
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