PL409652A1 - Method for epoxidation of limonene - Google Patents
Method for epoxidation of limoneneInfo
- Publication number
- PL409652A1 PL409652A1 PL409652A PL40965214A PL409652A1 PL 409652 A1 PL409652 A1 PL 409652A1 PL 409652 A PL409652 A PL 409652A PL 40965214 A PL40965214 A PL 40965214A PL 409652 A1 PL409652 A1 PL 409652A1
- Authority
- PL
- Poland
- Prior art keywords
- limonene
- epoxidation
- catalyst
- hydrogen peroxide
- titanium
- Prior art date
Links
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 title abstract 6
- 229940087305 limonene Drugs 0.000 title abstract 3
- 235000001510 limonene Nutrition 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 238000006735 epoxidation reaction Methods 0.000 title abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
Landscapes
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Sposób epoksydacji limonenu za pomocą wodnego roztworu nadtlenku wodoru, w obecności katalizatora tytanowo - silikalitowego oraz rozpuszczalnika, charakteryzuje się tym, że jako katalizator tytanowo - silikalitowy stosuje się katalizator TS - 1 w ilości 3% wagowych w mieszaninie reakcyjnej, przy czym proces prowadzi się 60% roztworem wodnym nadtlenku wodoru, w temperaturach 0 - 120°C, przy stosunku molowym limonen/utleniacz = 1 : 2, w czasie od 0,5 h do 24 h.The method of epoxidation of limonene by means of an aqueous hydrogen peroxide solution in the presence of a titanium silicalite catalyst and a solvent is characterized by the fact that a TS-1 catalyst in the amount of 3% by weight in the reaction mixture is used as a titanium-silicalite catalyst, the process being carried out 60 % aqueous solution of hydrogen peroxide, at temperatures from 0 - 120 ° C, with a limonene / oxidant molar ratio = 1: 2, for 0.5 h to 24 h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL409652A PL226640B1 (en) | 2014-09-30 | 2014-09-30 | Method for epoxidation of limonene |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL409652A PL226640B1 (en) | 2014-09-30 | 2014-09-30 | Method for epoxidation of limonene |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL409652A1 true PL409652A1 (en) | 2016-04-11 |
| PL226640B1 PL226640B1 (en) | 2017-08-31 |
Family
ID=55646090
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL409652A PL226640B1 (en) | 2014-09-30 | 2014-09-30 | Method for epoxidation of limonene |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL226640B1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL422186A1 (en) * | 2017-07-11 | 2019-01-14 | Zachodniopomorski Uniwersytet Technologiczny W Szczecinie | Method for oxidation of limonene to 1,2-epoxylimonene |
-
2014
- 2014-09-30 PL PL409652A patent/PL226640B1/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL422186A1 (en) * | 2017-07-11 | 2019-01-14 | Zachodniopomorski Uniwersytet Technologiczny W Szczecinie | Method for oxidation of limonene to 1,2-epoxylimonene |
Also Published As
| Publication number | Publication date |
|---|---|
| PL226640B1 (en) | 2017-08-31 |
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