PL417100A1 - Bicyclic imidazolium chlorides with the nature of ionic liquids, method for producing them and application - Google Patents

Bicyclic imidazolium chlorides with the nature of ionic liquids, method for producing them and application

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Publication number
PL417100A1
PL417100A1 PL417100A PL41710016A PL417100A1 PL 417100 A1 PL417100 A1 PL 417100A1 PL 417100 A PL417100 A PL 417100A PL 41710016 A PL41710016 A PL 41710016A PL 417100 A1 PL417100 A1 PL 417100A1
Authority
PL
Poland
Prior art keywords
application
imidazolium chlorides
bicyclic
bicyclic imidazolium
chlorides
Prior art date
Application number
PL417100A
Other languages
Polish (pl)
Other versions
PL231375B1 (en
Inventor
Joanna Feder-Kubis
Original Assignee
Politechnika Wrocławska
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Politechnika Wrocławska filed Critical Politechnika Wrocławska
Priority to PL417100A priority Critical patent/PL231375B1/en
Publication of PL417100A1 publication Critical patent/PL417100A1/en
Publication of PL231375B1 publication Critical patent/PL231375B1/en

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  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

Przedmiotem zgłoszenia są bicykliczne chlorki imidazoliowe o charakterze cieczy jonowych, o wzorze ogólnym 1, zawierające w części kationowej grupę (1S)-endo-(-)- borneolu połączoną mostkiem metylenowym z atomem azotu typu pirolowego imidazolu w pozycji N-1 oraz grupę funkcyjną R połączoną z atomem azotu typu pirydyniowego imidazolu w pozycji N-3, stanowiącą łańcuch alkilowy zawierający od jednego do czternastu atomów węgla, natomiast w części anionowej nieorganiczny jon chlorkowy oraz ich zastosowanie jako środków o działaniu antyelektrostatycznym. Zgłoszenie dotyczy również sposobu wytwarzania bicyklicznych chlorków imidazoliowych, o wzorze ogólnym 1, który polega na tym, że odpowiedni 1-alkiloimidazol, wybrany z grupy od 1-metyloimidazolu do 1-tetradecyloimidazolu, poddaje się reakcji z eterem chlorometylowo[(1S)-endo-(-)-borneolowym], określonym wzorem 2, w stosunku molowym 0,89 - 1,5 w temperaturze od 273,15 do 373,15 K, w obecności rozpuszczalnika organicznego. Zgłoszenie obejmuje również zastosowanie bicyklicznych chlorków imidazoliowych.The subject of the application are bicyclic imidazolium chlorides of ionic liquid character, of general formula 1, containing in the cationic part the (1S) -endo - (-) - borneol group connected by a methylene bridge with the nitrogen atom of the imidazole pyrrole type in the N-1 position and the functional group R combined with the nitrogen atom of the pyridinium imidazole in the N-3 position, which is an alkyl chain containing from one to fourteen carbon atoms, while in the anionic part an inorganic chloride ion and their use as antistatic agents. The application also relates to a process for the production of bicyclic imidazolium chlorides of general formula 1, which consists in reacting the corresponding 1-alkylimidazole selected from the group from 1-methylimidazole to 1-tetradecylimidazole with chloromethyl ether [(1S) -endo- (-) - borneol], defined by the formula 2, in a molar ratio of 0.89 - 1.5 at a temperature from 273.15 to 373.15 K, in the presence of an organic solvent. The application also includes the use of bicyclic imidazolium chlorides.

PL417100A 2016-05-04 2016-05-04 Bicyclic imidazolium chlorides with the nature of ionic liquids, method for producing them and application PL231375B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL417100A PL231375B1 (en) 2016-05-04 2016-05-04 Bicyclic imidazolium chlorides with the nature of ionic liquids, method for producing them and application

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL417100A PL231375B1 (en) 2016-05-04 2016-05-04 Bicyclic imidazolium chlorides with the nature of ionic liquids, method for producing them and application

Publications (2)

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PL417100A1 true PL417100A1 (en) 2017-09-25
PL231375B1 PL231375B1 (en) 2019-02-28

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Family Applications (1)

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PL417100A PL231375B1 (en) 2016-05-04 2016-05-04 Bicyclic imidazolium chlorides with the nature of ionic liquids, method for producing them and application

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PL (1) PL231375B1 (en)

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Publication number Publication date
PL231375B1 (en) 2019-02-28

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