PL418808A1 - Method for obtaining linear polyester biopolyols - Google Patents
Method for obtaining linear polyester biopolyolsInfo
- Publication number
- PL418808A1 PL418808A1 PL418808A PL41880816A PL418808A1 PL 418808 A1 PL418808 A1 PL 418808A1 PL 418808 A PL418808 A PL 418808A PL 41880816 A PL41880816 A PL 41880816A PL 418808 A1 PL418808 A1 PL 418808A1
- Authority
- PL
- Poland
- Prior art keywords
- natural origin
- mixture
- glycols
- carried out
- linear polyester
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 229920000728 polyester Polymers 0.000 title abstract 2
- 239000000203 mixture Substances 0.000 abstract 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 abstract 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 abstract 4
- 150000002334 glycols Chemical class 0.000 abstract 3
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 abstract 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 abstract 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 2
- 238000006068 polycondensation reaction Methods 0.000 abstract 2
- 229920000166 polytrimethylene carbonate Polymers 0.000 abstract 2
- 239000001384 succinic acid Substances 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
Zgłoszenie dotyczy sposobu otrzymywania liniowych biopolioli poliestrowych, który polega na tym, że w pierwszym etapie kwas bursztynowy pochodzenia naturalnego miesza się z 1,3-propanodiolem pochodzenia naturalnego albo 1,4-butanodiolem pochodzenia naturalnego albo mieszaniną 1,3-propanodiolu pochodzenia naturalnego z 1,4-butanodiolem pochodzenia naturalnego zachowując stosunek molowy obu glikoli w zakresie od 1:1 do 1:5, przy czym stosuje się nadmiar glikolu lub mieszaniny glikoli tak aby stosunek molowy kwasu bursztynowego do glikolu lub mieszaniny glikoli we wszystkich przypadkach wynosił od 1:1,05 do 1:1,40, Następnie uzyskaną mieszaninę ogrzewa się w pierwszym etapie przez od 5 do 10 godzin w temperaturze od 140 do 180°C w atmosferze gazu obojętnego do momentu uzyskania co najmniej 60% mas. wody w przeliczeniu na ilość teoretyczną, jako produktu ubocznego. Następnie przeprowadza się drugi etap, czyli polikondensację w ten sposób, że mieszaninę ogrzewa się do temperatury od 160 do 220°C i reakcję prowadzi się pod obniżonym ciśnieniem, zaś proces polikondensacji prowadzi się do momentu osiągnięcia przez produkt liczby kwasowej mniejszej od 3 mg KOH/g.The application relates to a method of obtaining linear polyester biopolies, which consists in the first stage of mixing succinic acid of natural origin with 1,3-propanediol of natural origin or 1,4-butanediol of natural origin or a mixture of 1,3-propanediol of natural origin with 1 , 4-butanediol of natural origin, maintaining a molar ratio of both glycols in the range of 1: 1 to 1: 5, with an excess of glycol or a mixture of glycols being used so that the molar ratio of succinic acid to glycol or a mixture of glycols in all cases is from 1: 1 , 05 to 1: 1.40, The resulting mixture is then heated in a first step for 5 to 10 hours at a temperature of 140 to 180 ° C under an inert gas atmosphere until at least 60% by mass is obtained. water calculated as the theoretical amount as a by-product. Then the second stage is carried out, i.e. polycondensation in such a way that the mixture is heated to a temperature of 160 to 220 ° C and the reaction is carried out under reduced pressure, while the polycondensation process is carried out until the product reaches an acid number less than 3 mg KOH / g.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL418808A PL234556B1 (en) | 2016-09-23 | 2016-09-23 | Method for obtaining linear polyester biopolyols |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL418808A PL234556B1 (en) | 2016-09-23 | 2016-09-23 | Method for obtaining linear polyester biopolyols |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL418808A1 true PL418808A1 (en) | 2017-11-20 |
| PL234556B1 PL234556B1 (en) | 2020-03-31 |
Family
ID=60324404
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL418808A PL234556B1 (en) | 2016-09-23 | 2016-09-23 | Method for obtaining linear polyester biopolyols |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL234556B1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL438914A1 (en) * | 2021-09-10 | 2023-03-13 | Politechnika Gdańska | Linear bio-polyester polyols and method of their preparation |
-
2016
- 2016-09-23 PL PL418808A patent/PL234556B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL234556B1 (en) | 2020-03-31 |
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