PL419421A1 - Zastosowanie kompleksów rutenu w reakcji metatezy olefin - Google Patents

Zastosowanie kompleksów rutenu w reakcji metatezy olefin

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Publication number
PL419421A1
PL419421A1 PL419421A PL41942116A PL419421A1 PL 419421 A1 PL419421 A1 PL 419421A1 PL 419421 A PL419421 A PL 419421A PL 41942116 A PL41942116 A PL 41942116A PL 419421 A1 PL419421 A1 PL 419421A1
Authority
PL
Poland
Prior art keywords
application
ruthenium complexes
metathesis reaction
olefins metathesis
olefins
Prior art date
Application number
PL419421A
Other languages
English (en)
Other versions
PL241085B1 (pl
Inventor
Krzysztof Skowerski
Rafał GAWIN
Michał Paweł CHWALBA
Original Assignee
Apeiron Synthesis Spółka Akcyjna
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Apeiron Synthesis Spółka Akcyjna filed Critical Apeiron Synthesis Spółka Akcyjna
Priority to PL419421A priority Critical patent/PL241085B1/pl
Priority to PL17823208.8T priority patent/PL3538537T3/pl
Priority to US16/348,721 priority patent/US10974236B2/en
Priority to EP17823208.8A priority patent/EP3538537B1/en
Priority to KR1020197016041A priority patent/KR20190086479A/ko
Priority to PCT/IB2017/056992 priority patent/WO2018087678A1/en
Priority to JP2019524231A priority patent/JP7210443B2/ja
Publication of PL419421A1 publication Critical patent/PL419421A1/pl
Priority to IL266559A priority patent/IL266559B2/en
Publication of PL241085B1 publication Critical patent/PL241085B1/pl

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B01J31/2278—Complexes comprising two carbene ligands differing from each other, e.g. Grubbs second generation catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B01J31/2269—Heterocyclic carbenes
    • B01J31/2273—Heterocyclic carbenes with only nitrogen as heteroatomic ring members, e.g. 1,3-diarylimidazoline-2-ylidenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C67/347—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by addition to unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/475—Preparation of carboxylic acid esters by splitting of carbon-to-carbon bonds and redistribution, e.g. disproportionation or migration of groups between different molecules
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/40—Non-coordinating groups comprising nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/60—Groups characterized by their function
    • B01J2540/62—Activating groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/10—Systems containing only non-condensed rings with a five-membered ring the ring being unsaturated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Przedmiotem zgłoszenia jest zastosowanie kompleksów rutenu, będących homogenicznymi katalizatorami i/lub prekatalizatorami reakcji metatezy olefin, które prowadzą do wytworzenia alkenów, zawierających wewnętrzne (nieterminalne) wiązanie podwójne C=C.
PL419421A 2016-11-10 2016-11-10 Zastosowanie kompleksów rutenu w reakcji metatezy olefin PL241085B1 (pl)

Priority Applications (8)

Application Number Priority Date Filing Date Title
PL419421A PL241085B1 (pl) 2016-11-10 2016-11-10 Zastosowanie kompleksów rutenu w reakcji metatezy olefin
PL17823208.8T PL3538537T3 (pl) 2016-11-10 2017-11-09 Zastosowanie kompleksów rutenu w reakcji metatezy olefin
US16/348,721 US10974236B2 (en) 2016-11-10 2017-11-09 Use of ruthenium complexes in olefin metathesis reaction
EP17823208.8A EP3538537B1 (en) 2016-11-10 2017-11-09 Use of ruthenium complexes in olefin metathesis reaction
KR1020197016041A KR20190086479A (ko) 2016-11-10 2017-11-09 올레핀 복분해 반응에서 루테늄 착물의 용도
PCT/IB2017/056992 WO2018087678A1 (en) 2016-11-10 2017-11-09 Use of ruthenium complexes in olefin metathesis reaction
JP2019524231A JP7210443B2 (ja) 2016-11-10 2017-11-09 オレフィンメタセシス反応におけるルテニウム錯体の使用
IL266559A IL266559B2 (en) 2016-11-10 2019-05-12 Use of ruthenium complexes in olefin metathesis reaction

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL419421A PL241085B1 (pl) 2016-11-10 2016-11-10 Zastosowanie kompleksów rutenu w reakcji metatezy olefin

Publications (2)

Publication Number Publication Date
PL419421A1 true PL419421A1 (pl) 2018-05-21
PL241085B1 PL241085B1 (pl) 2022-08-01

Family

ID=62110452

Family Applications (2)

Application Number Title Priority Date Filing Date
PL419421A PL241085B1 (pl) 2016-11-10 2016-11-10 Zastosowanie kompleksów rutenu w reakcji metatezy olefin
PL17823208.8T PL3538537T3 (pl) 2016-11-10 2017-11-09 Zastosowanie kompleksów rutenu w reakcji metatezy olefin

Family Applications After (1)

Application Number Title Priority Date Filing Date
PL17823208.8T PL3538537T3 (pl) 2016-11-10 2017-11-09 Zastosowanie kompleksów rutenu w reakcji metatezy olefin

Country Status (7)

Country Link
US (1) US10974236B2 (pl)
EP (1) EP3538537B1 (pl)
JP (1) JP7210443B2 (pl)
KR (1) KR20190086479A (pl)
IL (1) IL266559B2 (pl)
PL (2) PL241085B1 (pl)
WO (1) WO2018087678A1 (pl)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102321960B1 (ko) * 2017-06-23 2021-11-08 광주과학기술원 루테늄 착물 형성을 위한 리간드, 루테늄 착물 촉매 및 이의 제조방법과 용도
PL426318A1 (pl) * 2018-07-12 2020-01-13 Apeiron Synthesis Spółka Akcyjna Zastosowanie N-chelatujących kompleksów rutenu w reakcji metatezy
CN111068789B (zh) * 2019-12-31 2021-10-08 中国科学院过程工程研究所 一种用于co2参与的烯烃羰基酯化反应的催化剂
US20230095887A1 (en) * 2020-03-05 2023-03-30 Firmenich Sa Process for preparing perfuming intermediate
PL441535A1 (pl) * 2022-06-23 2023-12-27 Uniwersytet Warszawski Nowe kompleksy rutenu, sposób ich otrzymywania, związki pośrednie stosowane w tym sposobie, sposób ich wytwarzania oraz zastosowanie nowych kompleksów rutenu w reakcjach metatezy olefin
EP4588926A1 (en) * 2024-01-18 2025-07-23 Umicore AG & Co. KG Organometallic compounds

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2947189B1 (fr) * 2009-06-29 2011-07-29 Rhodia Operations Procede de peparation d'une composition catalytique pour la metathese de corps gras insatures
FR2959742B1 (fr) 2010-05-07 2012-08-24 Arkema France Procede de preparation d'amino-acides ou esters satures comprenant une etape de metathese
WO2014047356A1 (en) * 2012-09-24 2014-03-27 Exxonmobil Chemical Patents Inc. Functionalized resins obtained via olefin metathesis
US9249170B2 (en) * 2013-04-11 2016-02-02 California Institute Of Technology Cyclic alkyl amino carbene (CAAC) ruthenium complexes as improved catalysts for ethenolysis reactions
PL238806B1 (pl) * 2015-09-30 2021-10-04 Apeiron Synthesis Spolka Akcyjna Kompleks rutenu i sposób jego wytwarzania, związek pośredni stosowany w tym sposobie oraz zastosowanie kompleksu rutenu i związku pośredniego w metatezie olefin

Also Published As

Publication number Publication date
US20190291089A1 (en) 2019-09-26
IL266559B (en) 2022-10-01
IL266559A (en) 2019-07-31
KR20190086479A (ko) 2019-07-22
JP7210443B2 (ja) 2023-01-23
EP3538537A1 (en) 2019-09-18
PL3538537T3 (pl) 2025-04-28
IL266559B2 (en) 2023-02-01
EP3538537B1 (en) 2025-02-26
WO2018087678A1 (en) 2018-05-17
JP2019535701A (ja) 2019-12-12
PL241085B1 (pl) 2022-08-01
US10974236B2 (en) 2021-04-13

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